Search

Dual-comb spectroscopy is a powerful technique to measure optical spectra in a wide spectral range with high-frequency resolution. The development of compact systems operating in the long-wave infrared wavelength range is of high interest for spectroscopic and sensing applications. Amongst the different techniques to obtain optical frequency-combs, electro-optic frequency-comb generation presents major advantages thanks to the tunable repetition rate only limited by the bandwidth of the used electro-optical modulator. However, the development of integrated and efficient electro-optical modulators operating in a wide long-wave infrared spectral band is still at its infancy, and electro-optical frequency-comb has not been demonstrated so far beyond the telecom band. In this work, a Schottky-based modulator embedded in a Ge-rich graded SiGe waveguide is used for electro-optic frequency-comb generation. Considering the limited efficiency of the modulator, harmonically-rich RF signals are used to enhance the generation of comb lines around the optical carrier. Interestingly, this allows us to demonstrate the generation of electro-optical combs spanning over 2.4 GHz around 8 {\mu}m wavelength. This paves the way towards fully integrated and tunable mid-infrared electro-optic frequency-comb generation systems., Comment: 10 pages, 9 figures

Inorganic/inorganic composites are found in multiple applications crucial for the energy transition, from nuclear reactor to energy storage devices. Their microstructures dictate a number of properties, such as mass transport or fracture resistance. There has been a multitude of process developed to control the microstructure of inorganic/inorganic composites, from powder mixing and the use of short or long fibre, to tape casting for laminates up to recently 3D printing. Here, we combined emulsions and slip casting into a simpler, broadly available, inexpensive processing platform that allow for in situ control of a composite's microstructure that also enables complex shaping. Emulsions are used to form droplets of controllable size of one inorganic phase into another, while slip casting enable 3D shaping of the final part. Our study shows that slip casting emulsions trigger a two-steps solvent removal that opens the possibility for conformal coating of porosity. By making magnetically responsive droplets, we form inorganic fibre inside an inorganic matrix during slip casting, demonstrating a simple fabrication for long-fibre reinforced composites. We exemplify the potential of this processing platform by making strong and lightweight alumina scaffolds reinforced by a confirmed zirconia coating and alumina with metallic iron fibres that displays work of fracture an order of magnitude higher than alumina.

Spatial ordering of matter elicits exotic properties sometimes absent from a material's constituents. A few highly mineralised natural materials achieve high toughness through delocalised damage, whereas synthetic particulate composites must trade toughness for mineral content. We test whether ordering the mineral phase in particulate composites through the formation of macroscopic colloidal crystals can trigger the same damage resistance found in natural materials. Our macroscopic silica rod based anisotropic colloidal crystal composites are processed fully at room temperature and pressure, reach volume fraction of mineral higher than 80%, and aided by a ductile interface, unveil plastic strain reaching 10% through the collective movement of rods and damage delocalisation over millimetres. These composites demonstrate key design rules to break free from conventionally accepted structural materials properties trade-off.

The ability to exploit the on-chip nonlinear generation of new frequencies has opened the door to a plethora of applications in fundamental and applied physics. Excitation of dispersive waves is a particularly interesting process that allows efficient nonlinear wavelength conversion by phase-matching of a soliton and waves in the normal dispersion regime. However, controlling the wavelength of dispersive waves in integrated waveguides remains an open challenge, hampering versatile shaping of the nonlinear spectral response. Here, we show that metamaterial silicon waveguides release new degrees of freedom to select the wavelength of dispersive waves. Based on this concept, we experimentally demonstrate excitation of two dispersive waves near 1.55 {\mu}m and 7.5 {\mu}m allowing ultra-wideband supercontinuum generation, covering most of the silicon transparency window. These results stand as an important milestone for versatile nonlinear frequency generation in silicon chips, with a great potential for applications in sensing, metrology and communications.

Porous carbon ablators offer cost-effective thermal protection for aerospace vehicles during re-entry into planetary atmospheres. However, the exploration of more distant planets requires the development of ablators that are able to withstand stronger thermal radiation conditions. Here, we report the development of bio-inspired porous carbon insulators with pore sizes that are deliberately tuned to enhance heat-shielding performance by increasing scattering of high-temperature thermal radiation. Pore size intervals that promote scattering are first estimated using an established model for the radiative contribution to the thermal conductivity of porous insulators. On the basis of this theoretical analysis, we identify a polymer additive that enables the formation of pores in the desired size range through the polymerization-induced phase separation of a mixture of phenolic resin and ethylene glycol. Optical and electron microscopy, porosimetry and mechanical tests are used to characterize the structure and properties of porous insulators prepared with different resin formulations. Insulators with pore sizes in the optimal scattering range reduce laser-induced damage of the porous structures by up to 42%, thus offering a promising and simple route for the fabrication of carbon ablators for enhanced thermal protection at high temperatures., Comment: 34 pages, 9 figures

Waveguide integrated optical modulators in the mid-infrared (mid-IR) wavelength range are of significant interest for molecular spectroscopy in one hand, as on-chip synchronous detection can improve the performance of detection systems, and for free-space communications on the other hand, where optical modulators working in the atmospheric transparency windows are crucially missing. Here we report for the first time the demonstration of optical modulation in mid-IR photonic circuit reaching wavelengths larger than 8 um. Moreover, optical modulation in an unprecedented wavelength range, from 5.5 to 11 um wavelength is shown, relying on a broadband Ge-rich graded-SiGe platform. This first demonstration is used as a proof of concept, to experimentally confirm the free-carrier absorption effect modeling. These results pave the way towards efficient high-performance electrically-driven integrated optical modulators in the mid-IR wavelength range., Comment: 12 pages, 7 figures

In many natural multi-layered composites, such as in the dactyl club of Stomatopods or the shell of bivalve mollusks, the defining functional and structural properties are determined by locally varying orientations of inorganic building blocks within each layer. One approach to artificially produce textured microstructures inspired by such complex composites is magnetically assisted slip-casting (MASC). MASC is a colloidal process in which anisotropic particles are oriented at arbitrarily defined angles using a magnetic field. The orientation of the particles is maintained during growth as particles are collected from the wall of a porous mold. Whereas a number of proof-of-concept studies have established the potential of the technique, the full design space available for MASC-fabricated structures, and the limits of the approach, have so far not been explored in a systematic manner. To fill this gap, we have studied both theoretically and experimentally the various torques that act on the particles at different stage of the assembly process. We define the boundary conditions of the MASC process for magnetically responsive alumina platelets suspended in a low-viscosity aqueous suspension, considering the composition of the colloidal suspension and the dynamics of the particle-alignment process under a rotating magnetic field. Taken together, these findings define a design strategy for the fabrication of designed multi-lamellar microstructures using MASC. Our guidelines are based on a comprehensive understanding of the physical mechanisms governing the orientation and assembly of anisotropic particles during MASC and indicate a route to expanding this technique to building blocks of various chemistries, and thus to broadening the range of bio-inspired composites with customized multi-scale structures that can be produced for specific applications.

The architectures of biological hard materials reveal finely tailored complex assemblies of mineral crystals. Numerous recent studies associate the design of these local assemblies with impressive macroscopic response. Reproducing such exquisite control in technical ceramics conflicts with commonly used processing methods. Here, we circumvent this issue by combining the recently developed Magnetically-Assisted Slip Casting (MASC) technique with the well-established process of Templated Grain Growth (TGG). MASC enables the local control over the orientation of platelets dispersed among smaller isotropic particles. After a high temperature pressure-less treatment, the grains of the final ceramic follow the same orientation of the initial platelets. This combination allows us to produce 95 % dense alumina part with a grain orientation following any deliberate orientation. We successfully fabricated microstructures inspired from biological materials with ceramics that present periodically varying patterns with a programmable pitch of a few tens of microns. We confirmed the capacity of the process to tailor local mechanical properties through local grains orientation using micro-indentation. This micrometer scale control over the local mechanical properties could be applied to adapt ceramic structures to complex loads using this inexpensive and scalable process. In systems where functional properties also depend on anisotropic grain orientation, the principle presented here could enable the creation of new multifunctional ceramics.

New silicon carbide (SiC) and aluminum oxide (Al2O3) of a tailor-made microstructure were produced using the ice-templating technique, which permits controlled pore formation conditions within the material. These prototypes will serve to verify aging of the new advanced target materials under irradiation with proton beams. Before this, the evaluation of their mechanical integrity was made based on the energy deposition spectra produced by FLUKA codes., Comment: 8 pages, 3 figures

The dispersion of nitride and carbide ceramic particles in water is difficult, due to the absence of hydroxyl groups on their surface. Boron nitride is not an exception and despite its numerous applications, no effective dispersant has been identified so far. We demonstrate here the dispersion properties of two cellulose derivatives for hexagonal boron nitride powders, hydroxyl ethyl cellulose and methyl cellulose. The effect of particle sizes and cellulose concentration was investigated. The adsorption of cellulose onto the surface of the BN particles was confirmed by isotherm adsorption. Zeta potential measurements shows a charge screening effect of the cellulose The suspensions obtained were highly loaded and stable versus pH, and thus could lead to homogeneous codispersion of BN particles and sintering additives., Comment: 15 pages, 7 figures

This is a reply to the correspondence of Prof. Robert Ritchie: "On the fracture toughness of bioinspired ceramic materials", submitted to Nature Materials, which discusses the fracture toughness values of the following papers: Bouville, F., Maire, E., Meille, S., Van de Moort\`ele, B., Stevenson, A. J., & Deville, S. (2014). Strong, tough and stiff bioinspired ceramics from brittle constituents. Nature Materials, 13(5), 508-514 and Le Ferrand, H., Bouville, F., Niebel, T. P., & Studart, A. R. (2015). Magnetically assisted slip casting of bioinspired heterogeneous composites. Nature Materials, 14(11), 1172-1172., Comment: 5 pages, 2 figures

Composites are often made heterogeneous in nature to fulfill the functional demands imposed by the environment, but remain difficult to fabricate synthetically due to the lack of adequate and easily accessible processing tools. We report on an additive manufacturing platform to fabricate complex-shaped parts exhibiting bio-inspired heterogeneous microstructures with locally tunable texture, composition and properties and unprecedentedly high volume fractions of inorganic phase (up to 100%). The technology combines an aqueous-based slip casting process with magnetically-directed particle assembly to create programmed microstructural designs using anisotropic stiff platelets in a ceramic, metal or polymer functional matrix. Using quantitative tools to control the casting kinetics and the temporal pattern of the applied magnetic fields, we demonstrate that this robust approach can be exploited to design and fabricate heterogeneous composites with thus far inaccessible microstructures. Proof-of-concept examples include bulk composites with periodic patterns of micro-reinforcement orientation and tooth-like bilayer parts with intricate shapes displaying site-specific composition and texture.

The possibility to align and organize faceted particles in the bulk offers intriguing possibilities for the design and discovery of materials and architectures exhibiting novel functional properties. The growth of ice crystals can be used to trigger the self-assembly of large, anisotropic particles and consequently to obtain three-dimensional porous materials of large dimensions in a limited amount of time. These mechanisms have not been explored so far due to the difficulty to experimentally investigate these systems. Here we elucidate the self-assembly mechanisms of faceted particles driven by ice growth by a combination of X-ray holotomography and discrete element modeling, providing insights into both the dynamics of self-assembly and their final packing. The encapsulation of particles is the result of a delicate balance between the force exerted by the percolating network of concentrated particles and the force exerted by the moving interface. We illustrate the benefits of such self-assembly for thermal management composite materials., Comment: 27 pages, 6 figures, 42 references

We demonstrate a facile method to produce crystallographically textured, macroporous materials using a combination of modified ice templating and templated grain growth (TGG). The process is demonstrated on alumina and the lead-free piezoelectric material sodium potassium niobate. The method provides macroporous materials with aligned, lamellar ceramic walls which are made up of crystallographically aligned grains. Each method showed that the ceramic walls present a long-range order over the entire sample dimensions and have crystallographic texture as a result of the TGG process. We also present a modification of the March-Dollase equation to better characterize the overall texture of materials with textured but slightly misaligned walls. The controlled crystallographic and morphologic orientation at two different length scales demonstrated here can be the basis of multifunctional materials., Comment: 14 pages, 7 figures, 19 references

High strength and high toughness are usually mutually exclusive in engineering materials. Improving the toughness of strong but brittle materials like ceramics thus relies on the introduction of a metallic or polymeric ductile phase to dissipate energy, which conversely decreases the strength, stiffness, and the ability to operate at high temperature. In many natural materials, toughness is achieved through a combination of multiple mechanisms operating at different length scales but such structures have been extremely difficult to replicate. Building upon such biological structures, we demonstrate a simple approach that yields bulk ceramics characterized by a unique combination of high strength (470 MPa), high toughness (22 MPa.m1/2), and high stiffness (290 GPa) without the assistance of a ductile phase. Because only mineral constituents were used, this material retains its mechanical properties at high temperature (600{\deg}C). The bioinspired, material-independent design presented here is a specific but relevant example of a strong, tough, and stiff material, in great need for structural, transportations, and energy-related applications., Comment: 27 pages, 4 figures, supplementary data, 47 references