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HPC systems used for research run a wide variety of software and workflows. This software is often written or modified by users to meet the needs of their research projects, and rarely is built with security in mind. In this paper we explore several of the key techniques that MIT Lincoln Laboratory Supercomputing Center has deployed on its systems to manage the security implications of these workflows by providing enforced separation for processes, filesystem access, network traffic, and accelerators to make every user feel like they are running on a personal HPC.

The key parameter for describing frictional strength at the onset of sliding is the static friction coefficient. Yet, how the static friction coefficient at the macroscale emerges from contacting asperities at the microscale is still an open problem. Here, we present friction experiments in which the normal load was varied over more than three orders of magnitude, so that a transition from a single asperity contact at low loads to multi-asperity contacts at high loads was achieved. We find a remarkable drop in static friction coefficient with increasing normal load. Using a simple stick-slip transition model we identify the presence of pre-sliding and subcritical contact points as the cause of smaller static friction coefficient at increased normal loads. Our measurements and model bridge the gap between friction behavior commonly observed in atomic force microscopy (AFM) experiments at microscopic forces, and industrially relevant multi-asperity contact interfaces loaded with macroscopic forces., Comment: 9 pages, 7 figures

Hyperspectral imaging techniques have a unique ability to probe the inhomogeneity of material properties whether driven by compositional variation or other forms of phase segregation. In the doped cuprates, iridates, and related materials, scanning tunneling microscopy/spectroscopy (STM/STS) measurements have found the emergence of pseudogap 'puddles' from the macroscopically Mott insulating phase with increased doping. However, categorizing this hyperspectral data by electronic order is not trivial, and has often been done with ad hoc methods. In this paper we demonstrate the utility of $k$-means, a simple and easy-to-use unsupervised clustering method, as a tool for classifying heterogeneous scanning tunneling spectroscopy data by electronic order for Rh-doped Sr$_2$IrO$_{4}$, a cuprate-like material. Applied to STM data acquired within the Mott phase, $k$-means successfully identified areas of Mott order and of pseudogap order. The unsupervised nature of $k$-means limits avenues for bias, and provides clustered spectral shapes without a priori knowledge of the physics. Additionally, we demonstrate successful use of $k$-means as a preprocessing tool to constrain phenomenological function fitting. Clustering the data allows us to reduce the fitting parameter space, limiting over-fitting. We suggest $k$-means as a fast, simple model for processing hyperspectral data on materials of mixed electronic order., Comment: 6 pages, 4 figures

Simple yield stress materials are composed of soft particles, bubbles, or droplets with purely repulsive forces. The constituent elements are typically too large to undergo thermal fluctuations, suggesting that the material internal structure, and therefore its rheology, should not change over time. Here, we explore the rheology of Carbopol, a prototypical simple yield stress material, and reveal that gradual, spontaneous relaxation of residual stresses, induced when loading the sample into rheometer, results in a small yet significant reduction in the material dynamic yield stress. This relaxation process can lead to a non-monotonic creep deformation rate under constant stress, culminating in delayed fluidization of the material. These findings highlight that yield stress is not merely a static material property but a function of the material internal stress state.

We show how finiteness properties of a group and a subgroup transfer to finiteness properties of the Schlichting completion relative to this subgroup. Further, we provide a criterion when the dense embedding of a discrete group into the Schlichting completion relative to one of its subgroups induces an isomorphism in (continuous) cohomology. As an application, we show that the continuous cohomology of the Neretin group vanishes in all positive degrees., Comment: corrected formulation of Theorem 1.3

In this experimental and numerical study, we revisit the question of the onset of the elastic regime in viscoelastic pinch-off. This is relevant for all modern filament thinning techniques which aim at measuring the extensional properties of low-viscosity polymer solutions such as the Slow Retraction Method (SRM) in Capillary Breakup Extensional Rheometry (CaBER) as well as the dripping method where a drop detaches from a nozzle. In these techniques, a stable liquid bridge is slowly brought to its stability threshold where capillary-driven thinning starts, slowing down dramatically at a critical radius $h_1$ marking the onset of the elastic regime where the bridge becomes a filament with elasto-capillary thinning dynamics. While a theoretical scaling for this transition radius exists for the classical step-strain CaBER protocol, where polymer chains stretch without relaxing during the fast plate separation, we show that it is not necessarily valid for a slow protocol such as in SRM since polymer chains only start stretching (beyond their equilibrium coiled configuration) when the bridge thinning rate becomes comparable to the inverse of their relaxation time. We derive a universal scaling for $h_1$ valid for both low and high-viscosity polymer solution which is validated by both CaBER (SRM) experiments with different polymer solutions, plate diameters and sample volumes and by numerical simulations using the FENE-P model., Comment: 41 pages, 14 figures

Two-dimensional hybrid organic-inorganic metal halide perovskites offer enhanced stability for perovskite-based applications. Their crystal structure's soft and ionic nature gives rise to strong interactions between charge carriers and ionic rearrangements. Here, we investigate the interaction of photo-generated electrons and ionic polarizations in single-crystal 2D perovskite butylammonium lead iodide, varying the inorganic lammelae thickness in the 2D single crystals. We determined the directionality of the transition dipole moments of the relevant phonon modes (in the 0.3-3 THz range) by angle-and-polarization dependent THz transmission measurements. We find a clear anisotropy of the in-plane photoconductivity, with a 10% reduction along the axis parallel with the transition dipole moment of the most strongly coupled phonon. Detailed calculations, based on Feynman polaron theory, indicate that the anisotropy originates from directional electron-phonon interactions., Comment: 50 pages, 5 figures main text, 13 figures in supplementary information

A major obstacle to understanding high-Tc cuprates is that superconductivity precludes observing normal-state properties at low temperatures. One prime example is the normal-state spin susceptibility: although its decrease upon cooling far above Tc typifies pseudogap behavior, its behavior at low temperatures is generally unknown. Here, our measurements in high magnetic fields expose the spin susceptibility of YBa2Cu3Oy down to low temperatures. Even though superconductivity is suppressed by the field, we uncover two thermally-activated contributions alongside a residual susceptibility at T=0 due to gapless excitations. We relate these two distinct gaps to short-range charge-density waves and to the formation of spin singlets similar to those found in certain quantum spin systems. These phenomena thus collectively contribute to the pseudogap in the spin susceptibility at low temperature, supplementing short-lived antiferromagnetism known to initiate pseudogap behavior at high temperatures. We therefore propose that the pseudogap should be regarded as a composite property.

Despite the large body of research on coalescence, firm agreement between experiment, theory, and computation has not been established for the very earliest times following the initial contact of two liquid volumes. Combining a range of experimental and computational modelling approaches, we have been able to elucidate the influence of the intervening gas, of the van der Waals forces and of thermal fluctuations on coalescence. For simple liquids, the gas influences both pre- and post-contact regimes, with a jump-to-contact the primary mode of merging. Subsequently, wave-like air pockets are observed. For a system with ultralow interfacial tension, that mimics nanodrop behaviour, the very first moments are governed by thermal fluctuations at the interfaces, with a nontrivial opening speed given by stochastic thermally driven motion.

Soft amorphous materials are viscoelastic solids ubiquitously found around us, from clays and cementitious pastes to emulsions and physical gels encountered in food or biomedical engineering. Under an external deformation, these materials undergo a noteworthy transition from a solid to a liquid state that reshapes the material microstructure. This yielding transition was the main theme of a workshop held from January 9 to 13, 2023 at the Lorentz Center in Leiden. The manuscript presented here offers a critical perspective on the subject, synthesizing insights from the various brainstorming sessions and informal discussions that unfolded during this week of vibrant exchange of ideas. The result of these exchanges takes the form of a series of open questions that represent outstanding experimental, numerical, and theoretical challenges to be tackled in the near future., Comment: 21 pages, 7 figures, perspective on the workshop 'Yield stress and fluidization in brittle and ductile amorphous systems' held from January 9 to 13, 2023 at the Lorentz Center in Leiden

Mechanical stresses are increasingly found to be associated with various biological functionalities. At the same time, topological defects are being identified across a diverse range of biological systems and are points of localized mechanical stress. It is therefore important to ask how mechanical stress localization around topological defects is controlled. Here, we use continuum simulations of nonequilibrium, fluctuating and active nematics to explore the patterns of stress localization, as well as their extent and intensity around topological defects. We find that by increasing the orientational elasticity of the material, the isotropic stress pattern around topological defects is changed substantially from a stress dipole characterized by symmetric compression-tension regions around the core of the defect to a localized stress monopole at the defect position. Moreover, we show that elastic anisotropy alters the extent and intensity of the stresses, and can result in the dominance of tension or compression around defects. Finally, including both nonequilibrium fluctuations and active stress generation, we find that the elastic constant tunes the relative effect of each, leading to the flipping of tension and compression regions around topological defects. This flipping of the tension-compression regions only by changing the elastic constant presents an interesting, simple, way of switching the dynamic behavior in active matter by changing a passive material property. We expect these findings to motivate further exploration tuning stresses in active biological materials by varying material properties of the constituent units., Comment: Accepted in Soft Matter

The evolution of the critical superconducting temperature and field, quantum oscillation frequencies and effective mass $m^{*}$ in underdoped YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) crystals ($p$ = 0.11, with $p$ the hole concentration per Cu atom) points to a partial suppression of the charge orders with increasing pressure up to 7 GPa, mimicking doping. Application of pressures up to 25 GPa pushes the sample to the overdoped side of the superconducting dome. Contrary to other cuprates, or to doping studies on YBCO, the frequency of the quantum oscillations measured in that pressure range do not support the picture of a Fermi-surface reconstruction in the overdoped regime, but possibly point to the existence of a new charge order., Comment: 13 pages, 17 figures

We present an exploration of the effect of electron-phonon coupling and broken inversion symmetry on the electronic and thermal properties of the semimetal LaRhGe$_3$. Our transport measurements reveal evidence for electron-hole compensation at low temperatures, resulting in a large magnetoresistance of 3000% at 1.8 K and 14 T. The carrier concentration is on the order of $10^{21}\rm{/cm}^3$ with high carrier mobilities of $2000~\rm{cm}^2/\rm{Vs}$. When coupled to our theoretical demonstration of symmetry-protected $\textit{almost movable}$ Weyl nodal lines, we conclude that LaRhGe$_3$ supports a Weyl semimetallic state. We discover superconductivity in this compound with a $T_{\text c}$ of 0.39(1) K and $B_{\rm{c}}(0)$ of 2.2(1) mT, with evidence from specific heat and transverse-field muon spin relaxation. We find an exponential dependence in the normal state electrical resistivity below $\sim50$ K, while Seebeck coefficient and thermal conductivity measurements each reveal a prominent peak at low temperatures, indicative of strong electron-phonon interactions. To this end, we examine the temperature-dependent Raman spectra of LaRhGe$_3$ and find that the lifetime of the lowest energy $A_1$ phonon is dominated by phonon-electron scattering instead of anharmonic decay. We conclude that LaRhGe$_3$ has strong electron-phonon coupling in the normal state, while the superconductivity emerges from weak electron-phonon coupling. These results open up the investigation of electron-phonon interactions in the normal state of superconducting non-centrosymmetric Weyl semimetals.

In this paper, we introduce CAMRA (Copilot for AMR Annotatations), a cutting-edge web-based tool designed for constructing Abstract Meaning Representation (AMR) from natural language text. CAMRA offers a novel approach to deep lexical semantics annotation such as AMR, treating AMR annotation akin to coding in programming languages. Leveraging the familiarity of programming paradigms, CAMRA encompasses all essential features of existing AMR editors, including example lookup, while going a step further by integrating Propbank roleset lookup as an autocomplete feature within the tool. Notably, CAMRA incorporates AMR parser models as coding co-pilots, greatly enhancing the efficiency and accuracy of AMR annotators. To demonstrate the tool's capabilities, we provide a live demo accessible at: https://camra.colorado.edu, Comment: EMNLP 2023 System Demonstration

The droplet size in emulsions is known to affect the rheological properties and plays a crucial role in the many applications of emulsions. Despite its importance, the underlying mechanisms governing droplet size in emulsification remain poorly understood. We investigate the average drop size and size distribution upon emulsification with a high-shear mixer for model oil-in-water emulsions stabilized by a surfactant. The size distribution is found to be a log-normal distribution, resulting from the repetitive random breakup of drops. High-shear emulsification, the usual way of making emulsions, is therefore found to be very different from turbulent emulsification given by the Kolmogorov-Hinze theory for which power-law distributions of the drop size are expected. In agreement with this, the mean droplet size does not follow a scaling with the Reynolds number of the emulsification flow, but rather a capillary number scaling based on the viscosity of the continuous phase.

We have carried out a search for a pair density wave signature using high-energy X-ray diffraction in fields up to 16 T. We do not see evidence for a signal at the predicted wavevector. This is a report on the details of our experiment, with information on where in reciprocal space we looked., Comment: 5 pages, report on experimental results

Water plays a crucial role in geological, biological, and technological processes. Nanoscale water confinement occurs in many of these settings, including sedimentary rocks, water channel proteins, and applications like desalination and water purification membranes. The structure and properties of water in nanoconfinement can differ significantly from bulk water, exhibiting, for instance, modified hydrogen bonds, dielectric constant, and phase transitions. Despite the importance of strongly nanoconfined water, experimentally elucidating the nanoconfinement effect on water, such as its orientation and hydrogen bond (H-bond) network, has remained challenging. Here, we study two-dimensionally nanoconfined aqueous electrolyte solutions with tunable confinement from nanoscale to angstrom-scale sandwiched between a graphene sheet and CaF2. We employ heterodyne-detection sum-frequency generation (HD-SFG) spectroscopy, a surface-specific vibrational spectroscopy capable of directly and selective probing water orientation and H-bond environment at interfaces and under confinement. Remarkably, the vibrational spectra of the nanoscale confined water can be described quantitatively by the sum of the individual water surface signals from the CaF2/water and water/graphene interfaces until the confinement reduces to angstrom-scale (< ~8 {\AA}). Ab initio molecular dynamics simulations confirm our experimental observation. These results manifest that interfacial, rather than nanoconfinement effects, dominate the water structure until angstrom-level confinement.

A surprising "planar" thermal Hall effect, whereby the field is parallel to the current, has recently been observed in a few magnetic insulators, and this has been attributed to exotic excitations such as Majorana fermions or chiral magnons. Here we investigate the possibility of a planar thermal Hall effect in three different cuprate materials, in which the conventional thermal Hall conductivity $\kappa_{\rm {xy}}$ (with an out-of-plane field perpendicular to the current) is dominated by either electrons or phonons. Our measurements show that the planar $\kappa_{\rm {xy}}$ from electrons in cuprates is zero, as expected from the absence of a Lorentz force in the planar configuration. By contrast, we observe a sizable planar $\kappa_{\rm {xy}}$ in those samples where the thermal Hall response is due to phonons, even though it should in principle be forbidden by the high crystal symmetry. Our findings call for a careful re-examination of the mechanisms responsible for the phonon thermal Hall effect in insulators.

Electron-phonon coupling (EPC) is foundational in condensed matter physics, determining intriguing phenomena and properties in both conventional and quantum materials. In this manuscript, we propose and demonstrate a novel two dimensional (2D) EPC spectroscopy which allows for direct extraction of EPC matrix elements. We find that two pronounced phonon modes of methylammonium lead iodide (MAPI) at room temperature exhibit highly distinctive EPC behaviors, both in strength, geometry, and temperature dependence across the phase transition. This demonstration indicates the potential of our novel 2D spectroscopy for studying the evolution of mode-resolved EPC at various external conditions and phonon-mediated light induced ultrafast control of condensed materials.

CaSb$_2$ is a bulk superconductor and a topological semimetal, making it a great platform for realizing topological superconductivity. In this work, we investigate the superconducting upper and lower critical field anisotropy using magnetic susceptibility, and study the superconducting state using muon spin-relaxation. The temperature dependence of transverse-field relaxation rate can be fitted with a single-gap model or two-gap model. Zero-field relaxation shows little temperature dependence when the muon-spin is parallel to the $c*$-axis, while an increase in relaxation appears below 1 K when the muon-spin is parallel to the $ab$-plane. We conclude an $s+is$ order parameter considering the breaking of time-reversal symmetry (TRS), which originates from competing interband interactions between the three bands of CaSb$_2$. To explain the direction-dependent breaking of TRS we suggest loop currents developing in the plane of distorted square-net of Sb atoms.

The viscoelastic relaxation time of a polymer solution is often measured using Capillary Breakup Extensional Rheometry (CaBER) where a droplet is placed between two plates which are pulled apart to form a thinning filament. For a slow plate retraction protocol, required to avoid inertio-capillary oscillations for low-viscosity liquids, we show experimentally that the CaBER relaxation time $\tau_e$ inferred from the exponential thinning regime is in fact an apparent relaxation time that may increase significantly when increasing the plate diameter and the droplet volume. Similarly, we observe that $\tau_e$ increases with the plate diameter for the classical step-strain plate separation protocol of a commercial (Haake) CaBER device and increases with the nozzle diameter for a Dripping-onto-Substrate (DoS) method. This dependence on the flow history before the formation of the viscoelastic filament is in contradiction with polymer models such as Oldroyd-B that predict a filament thinning rate $1/3\tau$ ($\tau$ being the model's relaxation time) which is a material property independent of geometrical factors. We show that this is not due to artefacts such as solvent evaporation or polymer degradation and that it can only be rationalised by finite extensibility effects (FENE-P model) for a dilute polymer solution in a viscous solvent, but not for semi-dilute solutions in a low-viscosity solvent., Comment: 21 pages, 7 figures, presented at the ICR 2023 in Athens