1. One-step synthesis and fabrication of ZrMo2O8 nanostructures as advanced electrode material for energy storage applications.
- Author
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Rajkumar, S., Karthikeyan, M., Manohar, A., Dhineshkumar, S., and Princy Merlin, J.
- Subjects
SUPERCAPACITORS ,ENERGY storage ,SUPERCAPACITOR electrodes ,NANOSTRUCTURES ,ELECTRODES ,ELECTRODE potential ,ENERGY development - Abstract
[Display omitted] • ZrMo 2 O 8 prepared via simple chemical route. • The optimized ZrMo 2 O 8 electrode showed C s of 288C g
−1 at 1 Ag−1 with capacity retention of 92.5% upto 5000 GCD cycles at 1 Ag−1 . • ZrMo 2 O 8 nanostructure demonstrated its promising electrode material for supercapacitor application. Nanostructures of metal molybdates show great potential as high-performance electrode materials for the forthcoming development of energy storage devices. In present work, ZrMo 2 O 8 nanostructure was constructed using a simple chemical procedure and followed by examination with the aid of several spectral and analytical tools. The supercapacitive properties of ZrMo 2 O 8 electrode material were investigated using Cyclic voltammetry (CV), Galvanostatic charge–discharge (GCD) and Electrochemical Impedance Spectroscopy measurements (EIS). The as-prepared ZrMo 2 O 8 nanostructures as supercapacitor (SC) electrode material exhibited pseudocapacitive performance with notable value of 288C g−1 at 1 A/g, significant cycling stability and 92.5% capacity retention with the coulombic efficiency of 87.4% even after 5000 GCD cycles at 1 A/g. The morphological investigations indicated that the higher Specific capacity (C s) was primarily caused by the significant increase in active sites as well as active surface area. The Bode phase angle plot of ZrMo 2 O 8 exhibited a low frequency intercept, with emphasis at approximately −52° phase angle, indicating a superior redox signature. The results infered that ZrMo 2 O 8 nanostructures are promising candidates for high performance energy storage applications. [ABSTRACT FROM AUTHOR]- Published
- 2024
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