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© The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zhao, N., Oppo, D. W., Huang, K., Howe, J. N. W., Blusztajn, J., & Keigwin, L. D. Glacial-interglacial Nd isotope variability of North Atlantic Deep Water modulated by North American ice sheet. Nature Communications, 10, (2019): 5773, doi: 10.1038/s41467-019-13707-z., The Nd isotope composition of seawater has been used to reconstruct past changes in the contribution of different water masses to the deep ocean. In the absence of contrary information, the Nd isotope compositions of endmember water masses are usually assumed constant during the Quaternary. Here we show that the Nd isotope composition of North Atlantic Deep Water (NADW), a major component of the global overturning ocean circulation, was significantly more radiogenic than modern during the Last Glacial Maximum (LGM), and shifted towards modern values during the deglaciation. We propose that weathering contributions of unradiogenic Nd modulated by the North American Ice Sheet dominated the evolution of the NADW Nd isotope endmember. If water mass mixing dominated the distribution of deep glacial Atlantic Nd isotopes, our results would imply a larger fraction of NADW in the deep Atlantic during the LGM and deglaciation than reconstructed with a constant northern endmember., This study was supported by National Science Foundation grants (OCE 1335191 and OCE 1811305) to D.W.O. We thank Kathryn Pietro and Mary Carman for help with lab work, Steve Galer and Jerry McManus for helpful discussions. L.D.K. acknowledges the Grayce B. Kerr Fund for supporting research cruise KNR198. N.Z. acknowledges supports by a graduate internship from National Ocean Sciences Accelerator Mass Spectrometry facility and a post-doctoral scholarship from Max Planck Institute for Chemistry. K.-F.H. acknowledges funding from Taiwan MOST (MOST 104-2628-M-001-007-MY3).

A giant mass-transport complex was recently discovered in the eastern Arabian Sea, exceeding in volume all but one other known complex on passive margins worldwide. The complex, named the Nataraja Slide, was drilled by International Ocean Discovery Program (IODP) Expedition 355 in two locations where it is ~300 m (Site U1456) and ~200 m thick (Site U1457). The top of this mass-transport complex is defined by the presence of both reworked microfossil assemblages and deformation structures, such as folding and faulting. The deposit consists of two main phases of mass wasting, each consisting of smaller pulses, with generally fining-upward cycles, all emplaced just prior to 10.8 Ma based on biostratigraphy. The base of the deposit at each site is composed largely of matrix-supported carbonate breccia that is interpreted as the product of debris-flows. In the first phase, these breccias alternate with wellsorted calcarenites deposited from a high-energy current, coherent limestone blocks that are derived directly from the Indian continental margin, and a few clastic mudstone beds. In the second phase, at the top of the deposit, muddy turbidites dominate and become increasingly more siliciclastic. At Site U1456, where both phases are seen, a 20-m section of hemipelagic mudstone is present, overlain by a ~40-m-thick section of calcarenite and slumped interbedded mud and siltstone. Bulk sediment geochemistry, heavy-mineral analysis, clay mineralogy, isotope geochemistry, and detrital zircon U-Pb ages constrain the provenance of the clastic, muddy material to being reworked, Indus-derived sediment, with input from western Indian rivers (e.g., Narmada and Tapti rivers), and some material from the Deccan Traps. The carbonate blocks found within the breccias are shallow-water limestones from the outer western Indian continental shelf, which was oversteepened from enhanced clastic sediment delivery during the mid-Miocene. The final emplacement of the material was likely related

Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 20(3), (2019): 1485-1507, doi:10.1029/2018GC007985., In 2015 a geothermal exploration well was drilled on the island of Tutuila, American Samoa. The sample suite from the drill core provides 645 m of volcanic stratigraphy from a Samoan volcano, spanning 1.45 million years of volcanic history. In the Tutuila drill core, shield lavas with an EM2 (enriched mantle 2) signature are observed at depth, spanning 1.46 to 1.44 Ma. These are overlain by younger (1.35 to 1.17 Ma) shield lavas with a primordial “common” (focus zone) component interlayered with lavas that sample a depleted mantle component. Following ~1.15 Myr of volcanic quiescence, rejuvenated volcanism initiated at 24.3 ka and samples an EM1 (enriched mantle 1) component. The timing of the initiation of rejuvenated volcanism on Tutuila suggests that rejuvenated volcanism may be tectonically driven, as Samoan hotspot volcanoes approach the northern terminus of the Tonga Trench. This is consistent with a model where the timing of rejuvenated volcanism at Tutuila and at other Samoan volcanoes relates to their distance from the Tonga Trench. Notably, the Samoan rejuvenated lavas have EM1 isotopic compositions distinct from shield lavas that are geochemically similar to “petit spot” lavas erupted outboard of the Japan Trench and late stage lavas erupted at Christmas Island located outboard of the Sunda Trench. Therefore, like the Samoan rejuvenated lavas, petit spot volcanism in general appears to be related to tectonic uplift outboard of subduction zones, and existing geochemical data suggest that petit spots share similar EM1 isotopic signatures., Reviews from Kaj Hoernle and three anonymous reviewers are gratefully acknowledged. M. G. J. acknowledges support from the American Samoa Power Authority and National Science Foundation grants OCE‐1736984 and EAR‐1624840. The Tutuila drill core was the brainchild of Tim Bodell, without whom we would still have no stratigraphic record of Tutuila volcanism. The support of Utu Abe Malae and Matamua Katrina Mariner was instrumental to the project's success. We dedicate this paper to the memory of Abe Malae and his efforts to support science and education in American Samoa. Images of the entire drill core are available online (escholarship.org/uc/item/6gg6p61w). All data presented are either part of this study or previously published and are referenced in text., 2019-08-13

The Ayeyawady delta is the last Asian megadelta whose evolution has remained essentially unexplored so far. Unlike most other deltas across the world, the Ayeyawady has not yet been affected by dam construction, providing a unique view on largely natural deltaic processes benefiting from abundant sediment loads affected by tectonics and monsoon hydroclimate. To alleviate the information gap and provide a baseline for future work, here we provide a first model for the Holocene development of this megadelta based on drill core sediments collected in 2016 and 2017, dated with radiocarbon and optically stimulated luminescence, together with a reevaluation of published maps, charts and scientific literature. Altogether, these data indicate that Ayeyawady is a mud-dominated delta with tidal and wave influences. The sediment-rich Ayeyawady River built meander belt alluvial ridges with avulsive characters. A more advanced coast in the western half of the delta (i.e., the Pathein lobe) was probably favored by the more western location of the early course of the river. Radiogenic isotopic fingerprinting of the sediment suggests that the Pathein lobe coast does not receive significant sediment from neighboring rivers. However, the eastern region of the delta (i.e., Yangon lobe) is offset inland and extends east into the mudflats of the Sittaung estuary. Wave-built beach ridge construction during the late Holocene, similar to several other deltas across the Indian monsoon domain, suggests a common climatic control on monsoonal delta morphodynamics through variability in discharge, changes in wave climate or both. Correlation of the delta morphological and stratigraphic architecture information on land with the shelf bathymetry, as well as its tectonic, sedimentary and hydrodynamic characteristics, provides insight on the peculiar growth style of the Ayeyawady delta. The offset between the western Pathein lobe and the eastern deltaic coast appears to be driven by tectonic-hydrod

© The Author(s), 2018. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Science Advances 4 (2018): eaas8675, doi: 10.1126/sciadv.aas8675., The upper mantle, as sampled by mid-ocean ridge basalts (MORBs), exhibits significant chemical variability unrelated to mechanisms of melt extraction at ridges. We show that barium isotope variations in global MORBs vary systematically with radiogenic isotopes and trace element ratios, which reflects mixing between depleted and enriched MORB melts. In addition, modern sediments and enriched MORBs share similar Ba isotope signatures. Using modeling, we show that addition of ~0.1% by weight of sediment components into the depleted mantle in subduction zones must impart a sedimentary Ba signature to the overlying mantle and induce low-degree melting that produces the enriched MORB reservoir. Subsequently, these enriched domains convect toward mid-ocean ridges and produce radiogenic isotope variation typical of enriched MORBs. This mechanism can explain the chemical and isotopic features of enriched MORBs and provide strong evidence for pervasive sediment recycling in the upper mantle., This study was supported by NSF grants EAR-1119373 and EAR-1427310 to S.G.N.

© The Author(s), 2017. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Earth Surface Dynamics 5 (2017): 781-789, doi:10.5194/esurf-5-781-2017., Soil erosion plays a crucial role in transferring sediment and carbon from land to sea, yet little is known about the rhythm and rates of soil erosion prior to the most recent few centuries. Here we reconstruct a Holocene erosional history from central India, as integrated by the Godavari River in a sediment core from the Bay of Bengal. We quantify terrigenous fluxes, fingerprint sources for the lithogenic fraction and assess the age of the exported terrigenous carbon. Taken together, our data show that the monsoon decline in the late Holocene significantly increased soil erosion and the age of exported organic carbon. This acceleration of natural erosion was later exacerbated by the Neolithic adoption and Iron Age extensification of agriculture on the Deccan Plateau. Despite a constantly elevated sea level since the middle Holocene, this erosion acceleration led to a rapid growth of the continental margin. We conclude that in monsoon conditions aridity boosts rather than suppresses sediment and carbon export, acting as a monsoon erosional pump modulated by land cover conditions., This study was supported by grants from Woods Hole Oceanographic Institution, the National Science Foundation (OCE-0841736 and OCE-0623766) and Swiss National Science Foundation (“CAPS LOCK” 200021-140850 and “CAPS-LOCK2” 200021-163162).

Author Posting. © American Geophysical Union, 2017. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 18 (2017): 3946–3963, doi:10.1002/2017GC007071., The sources of terrestrial material delivered to the California margin over the past 7 Myr were assessed using 187Os/188Os, Nd, and Pb isotopes in hydrogenetic ferromanganese crusts from three seamounts along the central and southern California margin. From 6.8 to 4.5 (±0.5) Ma, all three isotope systems show more radiogenic values at Davidson Seamount, located near the base of the Monterey Canyon System, than in Fe-Mn crusts from the more remote Taney and Hoss Seamounts. At the Taney Seamounts, approximately 225 km farther offshore from Davidson Seamount, 187Os/188Os values, but not Pb and Nd isotope ratios, also deviate from the Cenozoic seawater curve toward more radiogenic values from 6.8 to 4.5 (±0.5) Ma. However, none of the isotope systems in Fe-Mn crusts deviate from seawater at Hoss Seamount located approximately 450 km to the south. The regional gradients in isotope ratios indicate that substantial input of dissolved and particulate terrestrial material into the Monterey Canyon System is responsible for the local deviations in the seawater Nd, Pb, and Os isotope compositions from 6.8 to 4.5 (±0.5) Ma. The isotope ratios recorded in Fe-Mn crusts are consistent with a southern Sierra Nevada or western Basin and Range provenance of the terrestrial material which was delivered by rivers to the canyon. The exhumation of the modern Monterey Canyon must have begun between 10 and 6.8 ± 0.5 Ma, as indicated by our data, the age of incised strata, and paleo-location of the Monterey Canyon relative to the paleo-coastline., Funding was provided by the United States Geological Survey Pacific Coastal and Marine Science Center Marine Minerals Group, the University of California Santa Cruz Scholarship for Re-Entry Women in Science, and the UCSC Earth and Planetary Science Department Waters Award., 2018-05-15