1. Effect of low concentration of impurity gases on the hydrogen absorption performance of uranium.
- Author
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Jiang, Wei, Pan, Qi-fa, Huang, Xu, Li, Gan, Fang, Yun, Kou, Hua-qin, and Tang, Tao
- Subjects
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GAS absorption & adsorption , *GAS mixtures , *SURFACE passivation , *HYDROGEN storage , *URANIUM , *CARBON dioxide - Abstract
The performance of uranium as a hydrogen storage material has attracted much attention. Herein, the hydrogen absorption properties of depleted uranium in impure hydrogen containing He, Ar, CH 4 , N 2 , CO, CO 2 and O 2 were studied by PVT method and XPS analysis. When these impurity gases were mixed in H 2 at low concentrations (0.1%∼1.5%), their behavior can be classified into three categories. The He, CH 4 and Ar were chemically inert to the activated uranium powder under room condition. These three gases inhibited the absorption kinetics during the whole stage by hindering the diffusion of H 2 molecules, showing a blanketing effect. The N 2 and O 2 did not affect the absorption kinetics but reduced the capacity by forming nitrides and oxides. The poisoning effect of N 2 was weaker than that of O 2. The CO and CO 2 not only affected the hydrogen absorption capacity, but also strongly inhibited the absorption kinetics. These two gases are chemically adsorbed on the uranium surface to form passivation layers, thus inhibiting the adsorption and dissociation of H 2 molecules and the diffusion of H atoms. The poisoning and retardation effect of CO 2 were much stronger than that of CO. The above conclusions are important to further study the reactivity of mixed gas with uranium, and can also be used as a reference for other hydrogen storage systems. [Display omitted] • The absorption of impure hydrogen by uranium was investigated. • Seven common impurity gases correspond to three kinds of mechanisms. • Blanketing effect inhibits the dynamics process. (He, CH 4 , Ar). • Poisoning effect reduces the hydrogen absorption capacity. (N 2 , O 2). • CO and CO 2 show poisoning & retardation effect. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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