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46P/Wirtanen is a Jupiter-family comet, probably originating from the Solar System's Kuiper belt, that now resides on a 5.4 year elliptical orbit. During its 2018 apparition, comet 46P passed unusually close to the Earth (within 0.08 au), presenting an outstanding opportunity for close-up observations of its inner coma. Here we present observations of HCN, H$^{13}$CN and HC$^{15}$N emission from 46P using the Atacama Compact Array (ACA). The data were analyzed using the SUBLIME non-LTE radiative transfer code to derive $^{12}$C/$^{13}$C and $^{14}$N/$^{15}$N ratios. The HCN/H$^{13}$CN ratio is found to be consistent with a lack of significant $^{13}$C fractionation, whereas the HCN/HC$^{15}$N ratio of $68\pm27$ (using our most conservative $1\sigma$ uncertainties), indicates a strong enhancement in $^{15}$N compared with the solar and terrestrial values. The observed $^{14}$N/$^{15}$N ratio is also significantly lower than the values of $\sim140$ found in previous comets, implying a strong $^{15}$N enrichment in 46P's HCN. This indicates that the nitrogen in Jupiter-family comets could reach larger isotopic enrichments than previously thought, with implications for the diversity of $^{14}$N/$^{15}$N ratios imprinted into icy bodies at the birth of the Solar System., Comment: Accepted for publication in PSJ, September 2024

We present the results of a molecular survey of long period comets C/2021 A1 (Leonard) and C/2022 E3 (ZTF). Comet C/2021 A1 was observed with the IRAM 30-m radio telescope in November-December 2021 before perihelion when it was closest to the Earth. We observed C/2022 E3 in January-February 2023 with the Odin 1-m space telescope and IRAM 30-m, shortly after its perihelion, and when it was closest to the Earth. Snapshots were obtained during 12-16 November 2021 period for comet C/2021 A1. Spectral surveys were undertaken over the 8-13 December 2021 period for comet C/2021 A1 (8, 16, and 61 GHz bandwidth in the 3 mm, 2 mm, and 1 mm window) and over the 3-7 February 2023 period for comet C/2022 E3 (25 and 61 GHz at 2 and 1mm). We report detections of 14 molecular species (HCN, HNC, CH3CN, HNCO, NH2CHO, CH3OH, H2CO, HCOOH, CH3CHO, H2S, CS, OCS, C2H5OH and aGg-(CH2OH)2 ) in both comets plus HC3N and CH2OHCHO marginally detected in C/2021 A1 and CO and H2O (with Odin detected in C/2022 E3. The spatial distribution of several species is investigated. Significant upper limits on the abundances of other molecules and isotopic ratios are also presented. The activity of comet C/2021 A1 did not vary significantly between 13 November and 13 December 2021. Short-term variability in the outgassing of comet C/2022 E3 on the order of +-20% is present and possibly linked to its 8h rotation period. Both comets exhibit rather low abundances relative to water for volatiles species such as CO (< 2%) and H2S (0.15%). Methanol is also rather depleted in comet C/2021 A1 (0.9%). Following their revised photo-destruction rates, HNCO and HCOOH abundances in comets have been reevaluated. Both molecules are relatively enriched in these two comets (0.2% relative to water). We cannot exclude that these species could be produced by the dissociation of ammonium salts., Comment: To be published in Astronomy & Astrophysics

Gas-phase molecules in cometary atmospheres (comae) originate primarily from (1) outgassing by the nucleus, (2) sublimation of icy grains in the near-nucleus coma, and (3) coma (photo-)chemical processes. However, the majority of cometary gases observed at radio wavelengths have yet to be mapped, so their production/release mechanisms remain uncertain. Here we present observations of six molecular species towards comet 46P/Wirtanen, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) during the comet's unusually close (~0.1 au) approach to Earth in December 2018. Interferometric maps of HCN, CH3OH, CH3CN, H2CO, CS and HNC were obtained at an unprecedented sky-projected spatial resolution of up to 25 km, enabling the nucleus and coma sources of these molecules to be accurately quantified. The HCN, CH3OH and CH3CN spatial distributions are consistent with production by direct outgassing from (or very near to) the nucleus, with a significant proportion of the observed CH3OH originating from sublimation of icy grains in the near-nucleus coma (at a scale-length $L_p=36\pm7$ km). On the other hand, H2CO, CS and HNC originate primarily from distributed coma sources (with $L_p$ values in the range 550-16,000 km), the identities of which remain to be established. The HCN, CH3OH and HNC abundances in 46P are consistent with the average values previously observed in comets, whereas the H2CO, CH3CN and CS abundances are relatively low., Comment: Accepted for publication in the Astrophysical Journal on 2023-06-17

29P/Schwassmann-Wachmann 1 is a distant Centaur/comet, showing persistent CO-driven activity and frequent outbursts. We used the Herschel space observatory in 2010, 2011, and 2013 to observe H$_2$O and NH$_3$ and to image the dust coma. Observations with the IRAM 30 m were undertaken in 2007, 2010, 2011, and 2021 to monitor the CO production rate and to search for HCN. Modeling was performed to constrain the size of the sublimating icy grains and to derive the dust production rate. HCN is detected for the first time in comet 29P (at 5$\sigma$ in the line area). H$_2$O is detected as well, but not NH$_3$. H$_2$O and HCN line shapes differ strongly from the CO line shape, indicating that these two species are released from icy grains. CO production rates are in the range (2.9-5.6) $\times$ 10$^{28}$ s$^{-1}$ (1400--2600 kg s$^{-1}$). A correlation between the CO production rate and coma brightness is observed, as is a correlation between CO and H$_2$O production. The correlation obtained between the excess of CO production and excess of dust brightness with respect to the quiescent state is similar to that established for the continuous activity of comet Hale-Bopp. The measured $Q$(H$_2$O)/$Q$(CO) and $Q$(HCN)/$Q$(CO) production rate ratios are 10.0 $\pm$ 1.5 % and 0.12 $\pm$ 0.03 %, respectively, averaging the April-May 2010 measurements ($Q$(H$_2$O) = (4.1 $\pm$ 0.6) $\times$ 10$^{27}$ s$^{-1}$, $Q$(HCN) = (4.8 $\pm$ 1.1) $\times$ 10$^{25}$ s$^{-1}$). We derive three independent and similar values of the effective radius of the nucleus, $\sim$ 31 $\pm$ 3 km. The inferred dust mass-loss rates during quiescent phases are in the range 30-120 kg s$^{-1}$, indicating a dust-to-gas mass ratio $<$ 0.1 during quiescent activity. We conclude that strong local heterogeneities exist on the surface of 29P, with quenched dust activity from most of the surface, but not in outbursting regions., Comment: 28 pages, 15 figures, A&A in press

The recently announced Oort-cloud comet C/2014 UN271 (Bernardinelli-Bernstein) is remarkable in at least three respects: (i) it was discovered inbound as far as ~29 au from the Sun (with prediscovery images up to ~34 au); (ii) it showed cometary activity already at almost 24 au; and (iii) its nuclear magnitude (Hr ~ 8.0) indicates an exceptionally large object. Detection of gases is expected in the upcoming years as the comet is heading towards a ~11 au perihelion in 2031. We used ALMA in extended configuration (resolution ~0.064") to measure the 1287 um (233 GHz) continuum flux of the comet. Observations were performed on August 8, 2021 at a 20.0 au distance from the Sun. The high spatial resolution was chosen in order to filter out any dust contribution. We detected the thermal emission of the object at ~10 sigma, with a flux of 0.128+/-0.012 mJy. Based on observational constraints and our theoretical estimates of the dust contribution, the entirety of the measured flux can be attributed to the nucleus. From NEATM modelling combined with the Hr magnitude, we determine a surface-equivalent diameter of 137+/-17 km and a red geometric albedo of 5.3+/-1.2 %. This confirms that 2014 UN271 is by far the largest Oort-cloud object ever found (almost twice as large as comet C/1995 O1 Hale-Bopp), and except for the Centaur 95P/Chiron which shows outburst-like activity, the largest known comet in the Solar System. On the other hand, the object albedo is typical of comets, adding credence for a "universal" comet nucleus albedo. With its distant perihelion and uniquely large size, 2014 UN271 is the prominent archetype of distant comets, whose activity is driven by hypervolatiles. Post-perihelion thermal measurements will permit to study possible albedo changes, such as a surface brightening compared to pre-perihelion, as was observed for Hale-Bopp., Comment: Accepted for publication in A & A Letters. Abstract slightly shortened to fit within word limit

We present the results of a molecular survey of comet 46P/Wirtanen undertaken with the IRAM 30-m and NOEMA radio telescopes in December 2018. Observations at IRAM 30-m during the 12-18 Dec. period comprise a 2 mm spectral survey covering 25 GHz and a 1 mm survey covering 62 GHz. The gas outflow velocity and kinetic temperature have been accurately constrained by the observations. We derive abundances of 11 molecules, some being identified remotely for the first time in a Jupiter-family comet, including complex organic molecules such as formamide, ethylene glycol, acetaldehyde, or ethanol. Sensitive upper limits on the abundances of 24 other molecules are obtained. The comet is found to be relatively rich in methanol (3.4 percent relative to water), but relatively depleted in CO, CS, HNC, HNCO, and HCOOH., Comment: 35 pages, 16 figures, to be published in Astronomy & Astrophysics

Aims. We aim to determine whether dissociative excitation of cometary neutrals by electron impact is the major source of far-ultraviolet (FUV) emissions at comet 67P/Churyumov-Gerasimenko in the southern hemisphere at large heliocentric distances, both during quiet conditions and impacts of corotating interaction regions observed in the summer of 2016. Methods. We combined multiple datasets from the Rosetta mission through a multi-instrument analysis to complete the first forward modelling of FUV emissions in the southern hemisphere of comet 67P and compared modelled brightnesses to observations with the Alice FUV imaging spectrograph. We modelled the brightness of OI1356, OI1304, Lyman-$\beta$, CI1657, and CII1335 emissions, which are associated with the dissociation products of the four major neutral species in the coma: CO$_2$, H$_2$O, CO, and O$_2$. The suprathermal electron population was probed by RPC/IES and the neutral column density was constrained by several instruments: ROSINA, MIRO and VIRTIS. Results. The modelled and observed brightnesses of the FUV emission lines agree closely when viewing nadir and dissociative excitation by electron impact is shown to be the dominant source of emissions away from perihelion. The CII1335 emissions are shown to be consistent with the volume mixing ratio of CO derived from ROSINA. When viewing the limb during the impacts of corotating interaction regions, the model reproduces brightnesses of OI1356 and CI1657 well, but resonance scattering in the extended coma may contribute significantly to the observed Lyman-$\beta$ and OI1304 emissions. The correlation between variations in the suprathermal electron flux and the observed FUV line brightnesses when viewing the comet's limb suggests electrons are accelerated on large scales and that they originate in the solar wind. This means that the FUV emissions are auroral in nature., Comment: 20 pages, 13 figures. Accepted for publication in Astronomy & Astrophysics

Comet Shoemaker-Levy 9 impacted Jupiter in July 1994, leaving its stratosphere with several new species, among them water vapor (H2O). With the aid of a photochemical model H2O can be used as a dynamical tracer in the jovian stratosphere. In this paper, we aim at constraining vertical eddy diffusion (Kzz) at the levels where H2O resides. We monitored the H2O disk-averaged emission at 556.936 GHz with the Odin space telescope between 2002 and 2019, covering nearly two decades. We analyzed the data with a combination of 1D photochemical and radiative transfer models to constrain vertical eddy diffusion in the stratosphere of Jupiter. The Odin observations show us that the emission of H2O has an almost linear decrease of about 40% between 2002 and 2019.We can only reproduce our time series if we increase the magnitude of Kzz in the pressure range where H2O diffuses downward from 2002 to 2019, i.e. from ~0.2 mbar to ~5 mbar. However, this modified Kzz is incompatible with hydrocarbon observations. We find that, even if allowance is made for the initially large abundances of H2O and CO at the impact latitudes, the photochemical conversion of H2O to CO2 is not sufficient to explain the progressive decline of the H2O line emission, suggestive of additional loss mechanisms. The Kzz we derived from the Odin observations of H2O can only be viewed as an upper limit in the ~0.2 mbar to ~5 mbar pressure range. The incompatibility between the interpretations made from H2O and hydrocarbon observations probably results from 1D modeling limitations. Meridional variability of H2O, most probably at auroral latitudes, would need to be assessed and compared with that of hydrocarbons to quantify the role of auroral chemistry in the temporal evolution of the H2O abundance since the SL9 impacts. Modeling the temporal evolution of SL9 species with a 2D model would be the next natural step., Comment: 9 pages, 8 figures, accepted in Astronomy and Astrophysics

Comets spend most of their lives at large distances from any star, during which time their interior compositions remain relatively unaltered. Cometary observations can therefore provide direct insight into the chemistry that occurred during their birth at the time of planet formation. To-date, there have been no confirmed observations of parent volatiles (gases released directly from the nucleus) of a comet from any planetary system other than our own. Here we present high-resolution, interferometric observations of 2I/Borisov, the first confirmed interstellar comet, obtained using the Atacama Large Millimeter/submillimeter Array (ALMA) on 15th-16th December 2019. Our observations reveal emission from hydrogen cyanide (HCN), and carbon monoxide (CO), coincident with the expected position of 2I/Borisov's nucleus, with production rates Q(HCN)=$(7.0\pm1.1)\times10^{23}$ s$^{-1}$ and Q(CO)=$(4.4\pm0.7)\times10^{26}$ s$^{-1}$. While the HCN abundance relative to water (0.06-0.16%) appears similar to that of typical, previously observed comets in our Solar System, the abundance of CO (35-105%) is among the highest observed in any comet within 2 au of the Sun. This shows that 2I/Borisov must have formed in a relatively CO-rich environment - probably beyond the CO ice-line in the very cold, outer regions of a distant protoplanetary accretion disk, as part of a population of small, icy bodies analogous to our Solar System's own proto-Kuiper Belt.

The D/H ratio in cometary water has been shown to vary between 1 and 3 times the Earth's oceans value, in both Oort cloud comets and Jupiter-family comets originating from the Kuiper belt. We present new sensitive spectroscopic observations of water isotopologues in the Jupiter-family comet 46P/Wirtanen carried out using the GREAT spectrometer aboard the Stratospheric Observatory for Infrared Astronomy (SOFIA). The derived D/H ratio of $(1.61 \pm 0.65) \times 10^{-4}$ is the same as in the Earth's oceans. Although the statistics are limited, we show that interesting trends are already becoming apparent in the existing data. A clear anti-correlation is seen between the D/H ratio and the active fraction, defined as the ratio of the active surface area to the total nucleus surface. Comets with an active fraction above 0.5 typically have D/H ratios in water consistent with the terrestrial value. These hyperactive comets, such as 46P/Wirtanen, require an additional source of water vapor in their coma, explained by the presence of subliming icy grains expelled from the nucleus. The observed correlation may suggest that hyperactive comets belong to a population of ice-rich objects that formed just outside the snow line, or in the outermost regions of the solar nebula, from water thermally reprocessed in the inner disk that was transported outward during the early disk evolution. The observed anti-correlation between the active fraction and the nucleus size seems to argue against the first interpretation, as planetesimals near the snow line are expected to undergo rapid growth. Alternatively, isotopic properties of water outgassed from the nucleus and icy grains may be different due to fractionation effects at sublimation. In this case, all comets may share the same Earth-like D/H ratio in water, with profound implications for the early solar system and the origin of Earth's oceans., Comment: 9 pages, 5 figures

The Atacama Large Millimeter/submillimeter Array (ALMA) is a powerful tool for high-resolution mapping of comets, but the main interferometer (comprised of 50x12-m antennas) is insensitive to the largest coma scales due to a lack of very short baselines. In this work, we present a new technique employing ALMA autocorrelation data (obtained simultaneously with the interferometric observations), effectively treating the entire 12-m array as a collection of single-dish telescopes. Using combined autocorrelation spectra from 28 active antennas, we recovered extended HCN coma emission from comet C/2012 S1 (ISON), resulting in a fourteen-fold increase in detected line brightness compared with the interferometer. This resulted in the first detection of rotational emission from H^13CN in this comet. Using a detailed coma radiative transfer model accounting for optical depth and non-LTE excitation effects, we obtained an H^12CN/H^13CN ratio of 88+-18, which matches the terrestrial value of 89, consistent with a lack of isotopic fractionation in HCN during comet formation in the protosolar accretion disk. The possibility of future discoveries in extended sources using autocorrelation spectroscopy from the main ALMA array is thus demonstrated.

We present a multi-wavelength study of comet C/2016 R2 (PanSTARRS). This comet was observed on 23-24 January 2018 with the IRAM 30m telescope, and in January to March 2018 with the Nan\c{c}ay radio telescope. Visible spectroscopy was performed in December 2017 and February 2018 with small amateur telescopes. We report on measurements of CO, CH3OH, H2CO and HCN production rates, and on the determination of the N2/CO abundance ratio. Several other species, especially OH, were searched for but not detected. The inferred relative abundances, including upper limits for sulfur species, are compared to those measured in other comets at about the same heliocentric distance of about 2.8 AU. The coma composition of comet C/2016 R2 is very different from all other comets observed so far, being rich in N2 and CO and dust poor. This suggests that this comet might belong to a very rare group of comets formed beyond the N2 ice line. Alternatively, comet C/2016 R2 (PanSTARRS) could be the fragment of a large and differentiated transneptunian object, with properties characteristic of volatile-enriched layers., Comment: 14 pages, 16 figures. Accepted for publication in Astronomy & Astrophysics

We present 2-5 $\mu$m spectroscopic observations of the dust coma of 67P/Churyumov-Gerasimenko obtained with the VIRTIS-H instrument onboard Rosetta during two outbursts that occurred on 2015, 13 September 13.6 h UT and 14 September 18.8 h UT at 1.3 AU from the Sun. Scattering and thermal properties measured before the outburst are in the mean of values measured for moderately active comets. The colour temperature excess (or superheat factor) can be attributed to submicrometre-sized particles composed of absorbing material or to porous fractal-like aggregates such as those collected by the Rosetta in situ dust instruments. The power law index of the dust size distribution is in the range 2-3. The sudden increase of infrared emission associated to the outbursts is correlated with a large increase of the colour temperature (from 300 K to up to 630 K) and a change of the dust colour at 2-2.5 $\mu$m from red to blue colours, revealing the presence of very small grains ($\leq$ 100 nm) in the outburst material. In addition, the measured large bolometric albedos ($\sim$ 0.7) indicate bright grains in the ejecta, which could either be silicatic grains, implying the thermal degradation of the carbonaceous material, or icy grains. The 3-$\mu$m absorption band from water ice is not detected in the spectra acquired during the outbursts, whereas signatures of organic compounds near 3.4 $\mu$m are observed in emission. The H$_2$O 2.7-$\mu$m and CO$_2$ 4.3-$\mu$m vibrational bands do not show any enhancement during the outbursts., Comment: Accepted for publication in the Monthly Notices of the Royal Astronomical Society

We present a summary of the campaign of remote observations that supported the European Space Agency's Rosetta mission. Telescopes across the globe (and in space) followed comet 67P/Churyumov-Gerasimenko from before Rosetta's arrival until nearly the end of mission in September 2016. These provided essential data for mission planning, large-scale context information for the coma and tails beyond the spacecraft, and a way to directly compare 67P with other comets. The observations revealed 67P to be a relatively `well behaved' comet, typical of Jupiter family comets and with activity patterns that repeat from orbit-to-orbit. Comparison between this large collection of telescopic observations and the in situ results from Rosetta will allow us to better understand comet coma chemistry and structure. This work is just beginning as the mission ends -- in this paper we present a summary of the ground-based observations and early results, and point to many questions that will be addressed in future studies., Comment: Author prepared version; final published version available at journal. 22 pages

Observations of the sungrazing comet C/2012 S1 (ISON) were carried out using the Atacama Large Millimeter/submillimeter Array (ALMA) at a heliocentric distance of 0.58-0.54 AU (pre-perihelion) on 2013 November 16-17. Temporally resolved measurements of the coma distributions of HNC, CH$_3$OH, H$_2$CO and dust were obtained over the course of about an hour on each day. During the period UT 10:10-11:00 on Nov. 16, the comet displayed a remarkable drop in activity, manifested as a $>42$% decline in the molecular line and continuum fluxes. The H$_2$CO observations are consistent with an abrupt, $\approx50$% reduction in the cometary gas production rate soon after the start of our observations. On Nov. 17, the total observed fluxes remained relatively constant during a similar period, but strong variations in the morphology of the HNC distribution were detected as a function of time, indicative of a clumpy, intermittent outflow for this species. Our observations suggest that at least part of the detected HNC originated from degradation of nitrogen-rich organic refractory material, released intermittently from confined regions of the nucleus. By contrast, the distributions of CH$_3$OH and H$_2$CO during the Nov. 17 observations were relatively uniform, consistent with isotropic outflow and stable activity levels for these species. These results highlight a large degree of variability in the production of gas and dust from comet ISON during its pre-perihelion outburst, consistent with repeated disruption of the nucleus interspersed with periods of relative quiescence., Comment: 9 pages. Accepted for publication in ApJ, February 2017

We present spatially and spectrally-resolved observations of CH$_3$OH emission from comet C/2012 K1 (PanSTARRS) using The Atacama Large Millimeter/submillimeter Array (ALMA) on 2014 June 28-29. Two-dimensional maps of the line-of-sight average rotational temperature ($T_{rot}$) were derived, covering spatial scales $0.3''-1.8''$ (corresponding to sky-projected distances $\rho\sim500$-2500 km). The CH$_3$OH column density distributions are consistent with isotropic, uniform outflow from the nucleus, with no evidence for extended sources of CH$_3$OH in the coma. The $T_{rot}(\rho)$ radial profiles show a significant drop within a few thousand kilometers of the nucleus, falling from about 60 K to 20 K between $\rho=0$ and 2500 km on June 28, whereas on June 29, $T_{rot}$ fell from about 120 K to 40 K between $\rho=$ 0 km and 1000 km. The observed $T_{rot}$ behavior is interpreted primarily as a result of variations in the coma kinetic temperature due to adiabatic cooling of the outflowing gas, as well as radiative cooling of the CH$_3$OH rotational levels. Our excitation model shows that radiative cooling is more important for the $J=7-6$ transitions (at 338 GHz) than for the $K=3-2$ transitions (at 252 GHz), resulting in a strongly sub-thermal distribution of levels in the $J=7-6$ band at $\rho\gtrsim1000$ km. For both bands, the observed temperature drop with distance is less steep than predicted by standard coma theoretical models, which suggests the presence of a significant source of heating in addition to the photolytic heat sources usually considered., Comment: Accepted for publication in ApJ, January 2017

Infrared observations of the coma of 67P/Churyumov-Gerasimenko were carried out from July to September 2015, i.e., around perihelion (13 August 2015), with the high-resolution channel of the VIRTIS instrument onboard Rosetta. We present the analysis of fluorescence emission lines of H$_2$O, CO$_2$, $^{13}$CO$_2$, OCS, and CH$_4$ detected in limb sounding with the field of view at 2.7-5 km from the comet centre. Measurements are sampling outgassing from the illuminated southern hemisphere, as revealed by H$_2$O and CO$_2$ raster maps, which show anisotropic distributions, aligned along the projected rotation axis. An abrupt increase of water production is observed six days after perihelion. In the mean time, CO$_2$, CH$_4$, and OCS abundances relative to water increased by a factor of 2 to reach mean values of 32%, 0.47%, and 0.18%, respectively, averaging post-perihelion data. We interpret these changes as resulting from the erosion of volatile-poor surface layers. Sustained dust ablation due to the sublimation of water ice maintained volatile-rich layers near the surface until at least the end of the considered period, as expected for low thermal inertia surface layers. The large abundance measured for CO$_2$ should be representative of the 67P nucleus original composition, and indicates that 67P is a CO$_2$-rich comet. Comparison with abundance ratios measured in the northern hemisphere shows that seasons play an important role in comet outgassing. The low CO$_2$/H$_2$O values measured above the illuminated northern hemisphere are not original, but the result of the devolatilization of the uppermost layers., Comment: Accepted for publication in the Monthly Notices of the Royal Astronomical Society

Observations of the Pluto-Charon system, acquired with the ALMA interferometer on June 12-13, 2015, have yielded a detection of the CO(3-2) and HCN(4-3) rotational transitions from Pluto, providing a strong confirmation of the presence of CO, and the first observation of HCN, in Pluto's atmosphere. The CO and HCN lines probe Pluto's atmosphere up to ~450 km and ~900 km altitude, respectively. The CO detection yields (i) a much improved determination of the CO mole fraction, as 515+/-40 ppm for a 12 ubar surface pressure (ii) clear evidence for a well-marked temperature decrease (i.e., mesosphere) above the 30-50 km stratopause and a best-determined temperature of 70+/-2 K at 300 km, in agreement with recent inferences from New Horizons / Alice solar occultation data. The HCN line shape implies a high abundance of this species in the upper atmosphere, with a mole fraction >1.5x10-5 above 450 km and a value of 4x10-5 near 800 km. The large HCN abundance and the cold upper atmosphere imply supersaturation of HCN to a degree (7-8 orders of magnitude) hitherto unseen in planetary atmospheres, probably due to the slow kinetics of condensation at the low pressure and temperature conditions of Pluto's upper atmosphere. HCN is also present in the bottom ~100 km of the atmosphere, with a 10-8 - 10-7 mole fraction; this implies either HCN saturation or undersaturation there, depending on the precise stratopause temperature. The HCN column is (1.6+/-0.4)x10^14 cm-2, suggesting a surface-referred net production rate of ~2x10^7 cm-2s-1. Although HCN rotational line cooling affects Pluto's atmosphere heat budget, the amounts determined in this study are insufficient to explain the well-marked mesosphere and upper atmosphere's ~70 K temperature. We finally report an upper limit on the HC3N column density (< 2x10^13 cm-2) and on the HC15N / HC14N ratio (< 1/125)., Comment: Revised version. Icarus, in press, Oct. 11, 2016. 57 pages, including 13 figures and 4 tables

The apparition of bright comets C/2012 F6 (Lemmon) and C/2014 Q2 (Lovejoy) in March-April 2013 and January 2015, combined with the improved observational capabilities of submillimeter facilities, offered an opportunity to carry out sensitive compositional and isotopic studies of the volatiles in their coma. We observed comet Lovejoy with the IRAM 30m telescope between 13 and 26 January 2015, and with the Odin submillimeter space observatory on 29 January - 3 February 2015. We detected 22 molecules and several isotopologues. The H$_2^{16}$O and H$_2^{18}$O production rates measured with Odin follow a periodic pattern with a period of 0.94 days and an amplitude of ~25%. The inferred isotope ratios in comet Lovejoy are $^{16}$O/$^{18}$O = 499 $\pm$ 24 and D/H = 1.4 $\pm$ 0.4 $\times 10^{-4}$ in water, $^{32}$S/$^{34}$S = 24.7 $\pm$ 3.5 in CS, all compatible with terrestrial values. The ratio $^{12}$C/$^{13}$C = 109 $\pm$ 14 in HCN is marginally higher than terrestrial and $^{14}$N/$^{15}$N = 145 $\pm$ 12 in HCN is half the Earth ratio. Several upper limits for D/H or 12C/13C in other molecules are reported. From our observation of HDO in comet C/2014 Q2 (Lovejoy), we report the first D/H ratio in an Oort Cloud comet that is not larger than the terrestrial value. On the other hand, the observation of the same HDO line in the other Oort-cloud comet, C/2012 F6 (Lemmon), suggests a D/H value four times higher. Given the previous measurements of D/H in cometary water, this illustrates that a diversity in the D/H ratio and in the chemical composition, is present even within the same dynamical group of comets, suggesting that current dynamical groups contain comets formed at very different places or times in the early solar system., Comment: Accepted for publication in Astronomy and Astrophysics

The Atacama Large Millimeter/submillimeter Array (ALMA) was used to obtain measurements of spatially and spectrally resolved CH$_3$OH emission from comet C/2012 K1 (PanSTARRS) on 28-29 June 2014. Detection of 12-14 emission lines of CH$_3$OH on each day permitted the derivation of spatially-resolved rotational temperature profiles (averaged along the line of sight), for the innermost 5000 km of the coma. On each day, the CH$_3$OH distribution was centrally peaked and approximately consistent with spherically symmetric, uniform outflow. The azimuthally-averaged CH$_3$OH rotational temperature ($T_{rot}$) as a function of sky-projected nucleocentric distance ($\rho$), fell by about 40 K between $\rho=0$ and 2500 km on 28 June, whereas on 29 June, $T_{rot}$ fell by about 50 K between $\rho=$0 km and 1500 km. A remarkable ($\sim50$ K) rise in $T_{rot}$ at $\rho=$1500-2500 km on 29 June was not present on 28 June. The observed variations in CH$_3$OH rotational temperature are interpreted primarily as a result of variations in the coma kinetic temperature due to adiabatic cooling, and heating through Solar irradiation, but collisional and radiative non-LTE excitation processes also play a role., Comment: Submitted to Astronomy in Focus, Volume 1. Based on work presented at the XXIXth IAU General Assembly, August 2015

Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this correlation because it was not easily detected in the interstellar medium although it proved to be rather abundant with respect to other O-bearing species in comet Hale-Bopp. Ethylene glycol thus appears, together with the related molecules glycolaldehyde CH$_{2}$OHCHO and ethanol CH$_{3}$CH$_{2}$OH, as a key species in the comparison of interstellar and cometary ices as well as in any discussion on the formation of cometary matter. We focus here on the analysis of ethylene glycol in the nearest and best studied hot core-like region, Orion-KL. We use ALMA interferometric data because high spatial resolution observations allow us to reduce the line confusion problem with respect to single-dish observations since different molecules are expected to exhibit different spatial distributions. Furthermore, a large spectral bandwidth is needed because many individual transitions are required to securely detect large organic molecules. Confusion and continuum subtraction are major issues and have been handled with care. We have detected the aGg' conformer of ethylene glycol in Orion-KL. The emission is compact and peaks towards the Hot Core close to the main continuum peak, about 2" to the south-west; this distribution is notably different from other O-bearing species. Assuming optically thin lines and local thermodynamic equilibrium, we derive a rotational temperature of 145 K and a column density of 4.6 10$^{15}$ cm$^{-2}$. The limit on the column density of the gGg' conformer is five times lower., Comment: 19 pages, 10 figures, A&A accepted

Results are presented from the first cometary observations using the Atacama Large Millimeter/Submillimeter Array (ALMA), including measurements of the spatially-resolved distributions of HCN, HNC, H$_2$CO and dust within the comae of two comets: C/2012 F6 (Lemmon) and C/2012 S1 (ISON), observed at heliocentric distances of 1.5 AU and 0.54 AU, respectively. These observations (with angular resolution $\approx0.5''$), reveal an unprecedented level of detail in the distributions of these fundamental cometary molecules, and demonstrate the power of ALMA for quantitative measurements of the distributions of molecules and dust in the inner comae of typical bright comets. In both comets, HCN is found to originate from (or within a few hundred km of) the nucleus, with a spatial distribution largely consistent with spherically-symmetric, uniform outflow. By contrast, the HNC distributions are clumpy and asymmetrical, with peaks at cometocentric radii $\sim$500-1000~km, consistent with release of HNC in collimated outflow(s). Compared to HCN, the H$_2$CO distribution in comet Lemmon is very extended. The interferometric visibility amplitudes are consistent with coma production of H$_2$CO and HNC from unidentified precursor material(s) in both comets. Adopting a Haser model, the H$_2$CO parent scale-length is found to be a few thousand km in Lemmon and only a few hundred km in ISON, consistent with destruction of the precursor by photolysis or thermal degradation at a rate which scales in proportion to the Solar radiation flux.

A spectral survey in the 1 mm wavelength range was undertaken in the long-period comets C/2012 F6 (Lemmon) and C/2013 R1 (Lovejoy) using the 30 m telescope of the Institut de radioastronomie millim\'etrique (IRAM) in April and November-December 2013. We report the detection of ethylene glycol (CH$_2$OH)$_2$ (aGg' conformer) and formamide (NH$_2$CHO) in the two comets. The abundances relative to water of ethylene glycol and formamide are 0.2-0.3% and 0.02% in the two comets, similar to the values measured in comet C/1995 O1 (Hale-Bopp). We also report the detection of HCOOH and CH$_3$CHO in comet C/2013 R1 (Lovejoy), and a search for other complex species (methyl formate, glycolaldehyde)., Comment: Accepted for publication as a Letter in Astronomy and Astrophysics

We aimed to measure the H2O and dust production rates in C/2006 W3 (Christensen) with the Herschel Space Observatory at a heliocentric distance of ~ 5 AU. We have searched for emission in the H2O and NH3 ground-state rotational transitions at 557 GHz and 572 GHz, simultaneously, with HIFI onboard Herschel on UT 1.5 September 2010. Photometric observations of the dust coma in the 70 and 160 {\mu}m channels were acquired with the PACS instrument on UT 26.5 August 2010. A tentative 4-{\sigma} H2O line emission feature was found in the spectra obtained with the HIFI wide-band and high-resolution spectrometers, from which we derive a water production rate of $2.0(5) \times 10^{27}$ molec. s$^{-1}$. A 3-{\sigma} upper limit for the ammonia production rate of <$1.5 \times 10^{27}$ molec. s$^{-1}$ is obtained taking into account the contribution from all hyperfine components. The blueshift of the water line detected by HIFI suggests preferential emission from the subsolar point. However, it is also possible that water sublimation occurs in small ice-bearing grains that are emitted from an active region on the nucleus surface at a speed of ~ 0.2 km s$^{-1}$. The dust thermal emission was detected in the 70 and 160 {\mu}m filters, with a more extended emission in the blue channel. The dust production rates, obtained for a dust size distribution index that explains the fluxes at the photocenters of the PACS images, lie in the range 70-110 kg s$^{-1}$. Scaling the CO production rate measured post-perihelion at 3.20 and 3.32 AU, these values correspond to a dust-to-gas production rate ratio in the range 0.3-0.4. The dust production rates derived in August 2010 are roughly one order of magnitude lower than in September 2009, suggesting that the dust-to-gas production rate ratio remained approximately constant during the period when the activity became increasingly dominated by CO outgassing., Comment: 13 pages, 9 figures

We present molecular observations carried out with the IRAM 30m telescope at wavelengths around 1.15 mm towards the Oort cloud comets C/2012 S1 (ISON) and C/2013 R1 (Lovejoy) when they were at 0.6 and 1 au, respectively, from the Sun. We detect HCN, HNC, and CH3OH in both comets, together with the ion HCO+ in comet ISON and a few weak unidentified lines in comet Lovejoy, one of which might be assigned to methylamine (CH3NH2). The monitoring of the HCN J = 3-2 line showed a tenfold enhancement in comet ISON on November 14.4 UT due to an outburst of activity whose exact origin is unknown, although it might be related to some break-up of the nucleus. The set of CH3OH lines observed was used to derive the kinetic temperature in the coma, 90 K in comet ISON and 60 K in comet Lovejoy. The HNC/HCN ratios derived, 0.18 in ISON and 0.05 in Lovejoy, are similar to those found in most previous comets and are consistent with an enhancement of HNC as the comet approaches the Sun. Phosphine (PH3) was also searched for unsuccessfully in both comets through its fundamental 1-0 transition, and 3 sigma upper limits corresponding to PH3/H2O ratios 4-10 times above the solar P/O elemental ratio were derived., Comment: Accepted for publication in A&A Letters. Preprint available at http://dx.doi.org/10.1051/0004-6361/201423639

HCl and HF are expected to be the main reservoirs of fluorine and chlorine wherever hydrogen is predominantly molecular. They are found to be strongly depleted in dense molecular clouds, suggesting freeze-out onto grains in such cold environments. We can then expect that HCl and HF were also the major carriers of Cl and F in the gas and icy phases of the outer solar nebula, and were incorporated into comets. We aimed to measure the HCl and HF abundances in cometary ices as they can provide insights on the halogen chemistry in the early solar nebula. We searched for the J(1-0) lines of HCl and HF at 626 and 1232 GHz, respectively, using the HIFI instrument on board the Herschel Space Observatory. HCl was searched for in comets 103P/Hartley 2 and C/2009 P1 (Garradd), whereas observations of HF were conducted in comet C/2009 P1. In addition, observations of H$_2$O and H$_2^{18}$O lines were performed in C/2009 P1 to measure the H$_2$O production rate. Three lines of CH$_3$OH were serendipitously observed in the HCl receiver setting. HCl is not detected, whereas a marginal (3.6-$\sigma$) detection of HF is obtained. The upper limits for the HCl abundance relative to water are 0.011% and 0.022%, for 103P and C/2009 P1, respectively, showing that HCl is depleted with respect to the solar Cl/O abundance by a factor more than 6$^{+6}_{-3}$ in 103P, where the error is related to the uncertainty in the chlorine solar abundance. The marginal HF detection obtained in C/2009 P1 corresponds to an HF abundance relative to water of (1.8$\pm$0.5) $\times$ 10$^{-4}$, which is approximately consistent with a solar photospheric F/O abundance. The observed depletion of HCl suggests that HCl was not the main reservoir of chlorine in the regions of the solar nebula where these comets formed. HF was possibly the main fluorine compound in the gas phase of the outer solar nebula., Comment: Accepted for publication in Astronomy & Astrophysics

Our goal was to characterize the distant gaseous and dust activity of comet C\2012 S1 (ISON), inbound, from observations of H2O, CO and the dust coma in the far-infrared and submillimeter domains. In this paper, we report observations undertaken with the Herschel Space Observatory on 8 & 13 March 2013 (rh = 4.54 - 4.47AU) and with the 30m telescope of Institut de Radioastronomie Millim\'etrique (IRAM) in March and April 2013 (rh = 4.45 - 4.18 AU). The HIFI instrument aboard Herschel was used to observe the H$_{2}$O $1_{10}-1_{01}$ line at 557 GHz, whereas images of the dust coma at 70 and 160 {\mu}m were acquired with the PACS instrument. Spectra acquired at the IRAM 30m telescope cover the CO J(2-1) line at 230.5 GHz. The spectral observations were analysed with excitation and radiative transfer models. A model of dust thermal emission taking into account a range of dust sizes is used to analyse the PACS maps. While H$_{2}$O was not detected in our 8 March 2013 observation, we derive a sensitive 3 $\sigma$ upper limit of QH$_{2}$O < 3.5 x 10$^{26}$ molecules/s for this date. A marginal 3.2 $\sigma$ detection of CO is found, corresponding to a CO production rate of QCO = 3.5 x 10$^{27}$ molecules/s. The Herschel PACS measurements show a clear detection of the coma and tail in both the 70 {\mu}m and 160 {\mu}m maps. Under the assumption of a 2 km radius nucleus, we infer dust production rates in the range 10 - 13 kg/s or 40 - 70 kg/s depending on whether a low or high gaseous activity from the nucleus surface is assumed. We constrain the size distribution of the emitted dust by comparing PACS 70 and 160 {\mu}m data, and considering optical data. Size indices between -4 and -3.6 are suggested. The morphology of the tail observed on 70 {\mu}m images can be explained by the presence of grains with ages older than 60 days., Comment: 6 pages, 5 figures, 3 tables. Accepted by A&A

Comet 103P/Hartley 2 made a close approach to the Earth in October 2010. It was the target of an extensive observing campaign and was visited by the Deep Impact spacecraft (mission EPOXI). We present observations of HCN and CH3OH emission lines conducted with the IRAM Plateau de Bure interferometer on 22-23, 28 October and 4, 5 November 2010 at 1.1, 1.9 and 3.4 mm wavelengths. The thermal emission from the dust coma and nucleus is detected simultaneously. Interferometric images with unprecedented spatial resolution are obtained. A sine-wave variation of the thermal continuum is observed in the 23 October data, that we associate with the nucleus thermal light curve. The nucleus contributes up to 30-55 % of the observed continuum. The large dust-to-gas ratio (in the range 2-6) can be explained by the unusual activity of the comet for its size, which allows decimeter size particles and large boulders to be entrained by the gas. The rotational temperature of CH3OH is measured. We attribute the increase from 35 to 46 K with increasing beam size (from 150 to 1500 km) to radiative processes. The HCN production rate displays strong rotation-induced variations. The HCN production curve, as well as those of CO2 and H2O measured by EPOXI, are interpreted with a geometric model which takes into account the rotation and the shape of the comet. The HCN and H2O production curves are in phase, showing common sources. The 1.7h delay, in average, of HCN and H2O with respect to the CO2 production curve suggests that HCN and H2O are mainly produced by subliming icy grains. The scale length of production of HCN is determined to be on the order of 500-1000 km, implying a mean velocity of 100-200 m/s for the icy grains producing HCN. The modulation of the CO2 prouction and of the velocity offset of the HCN lines are interpreted in terms of localized sources of gas on the nucleus surface., Comment: 22 pages, accepted for publication in Icarus

The 15N isotopologue abundance ratio measured today in different bodies of the solar system is thought to be connected to 15N-fractionation effects that would have occured in the protosolar nebula. The present study aims at putting constraints on the degree of 15N-fractionation that occurs during the prestellar phase, through observations of D, 13C and 15N-substituted isotopologues towards B1b. Both molecules from the nitrogen hydride family, i.e. N2H+ and NH3, and from the nitrile family, i.e. HCN, HNC and CN, are considered in the analysis. As a first step, we model the continuum emission in order to derive the physical structure of the cloud, i.e. gas temperature and H2 density. These parameters are subsequently used as an input in a non-local radiative transfer model to infer the radial abundances profiles of the various molecules. Our modeling shows that all the molecules are affected by depletion onto dust grains, in the region that encompasses the B1-bS and B1-bN cores. While high levels of deuterium fractionation are derived, we conclude that no fractionation occurs in the case of the nitrogen chemistry. Independently of the chemical family, the molecular abundances are consistent with 14N/15N~300, a value representative of the elemental atomic abundances of the parental gas. The inefficiency of the 15N-fractionation effects in the B1b region can be linked to the relatively high gas temperature ~17K which is representative of the innermost part of the cloud. Since this region shows signs of depletion onto dust grains, we can not exclude the possibility that the molecules were previously enriched in 15N, earlier in the B1b history, and that such an enrichment could have been incorporated into the ice mantles. It is thus necessary to repeat this kind of study in colder sources to test such a possibility., Comment: accepted in A&A

The line emission in the coma was measured in the comets C/2001 Q4 (NEAT) and C/2002 T7 (LINEAR), that were observed on five consecutive nights, 7-11 May 2004, at heliocentric distances of 1.0 and 0.7 AU, respectively, by means of high-resolution spectroscopy using the 10-m Submillimeter Telescope (SMT). We present a search for six parent- and product-volatile species (HCN, H2CO, CO, CS, CH3OH, and HNC) in both comets. Multiline observations of the CH3OH J = 5-4 series allow us to estimate the rotational temperature using the rotation diagram technique. We derive rotational temperatures of 54(9) K for C/2001 Q4 (NEAT) and 119(34) K for C/2002 T7 (LINEAR) that are roughly consistent with observations of other comets at similar distances from the Sun. The gas production rates of material are computed using a spherically symmetric molecular excitation code that includes collisions between neutrals and electrons. We find an HCN production rate of 2.96(5)e26 molec.s-1 for comet C/2001 Q4 (NEAT), corresponding to a mixing ratio with respect to H2O of 1.12(2)e-3. The mean HCN production rate during the observing period is 4.54(10)e26 molec.s-1 for comet C/2002 T7 (LINEAR), which gives a Q_HCN/Q_H2O mixing ratio of 1.51(3)e-3. With systematically lower mixing ratios in comet C/2001 Q4 (NEAT), production rate ratios of the observed species with respect to H2O lie within the typical ranges of dynamically new comets in both objects. We find a relative low abundance of CO in C/2001 Q4 (NEAT) compared to the observed range in other comets based on millimeter/submillimeter observations, and a significant upper limit on the CO production in C/2002 T7 (LINEAR) is derived. Depletion of CO suggests partial evaporation from the surface layers during previous visits to the outer Solar System and agrees with previous measurements of dynamically new comets., Comment: 20 pages, 18 figures. Minor changes to match the published version

Little is known about the physical properties of the nuclei of Oort cloud comets. Measuring the thermal emission of a nucleus is one of the few means for deriving its size and constraining some of its thermal properties. We attempted to measure the nucleus size of the Oort cloud comet C/2009 P1 (Garradd). We used the Plateau de Bure Interferometer to measure the millimetric thermal emission of this comet at 157 GHz (1.9 mm) and 266 GHz (1.1 mm). Whereas the observations at 266 GHz were not usable due to bad atmospheric conditions, we derived a 3-sigma upper limit on the comet continuum emission of 0.41 mJy at 157 GHz. Using a thermal model for a spherical nucleus with standard thermal parameters, we found an upper limit of 5.6 km for the radius. The dust contribution to our signal is estimated to be negligible. Given the water production rates measured for this comet and our upper limit, we estimated that Garradd was very active, with an active fraction of its nucleus larger than 50%., Comment: Accepted for publication in Astronomy & Astrophysics. 5 pages, 2 figures

We present Herschel observations of water isotopologues in the atmosphere of the Jupiter-family comet 45P/Honda-Mrkos-Pajdusakova. No HDO emission is detected, with a 3 sigma upper limit of 2.0 10-4 for the D/H ratio. This value is consistent with the earlier Herschel measurement in the Jupiter-family comet 103P/Hartley 2. The canonical value of 3 10-4 measured pre-Herschel in a sample of Oort-cloud comets can be excluded at a 4.5 sigma level. The observations presented here further confirm that a diversity of D/H ratios exists in the comet population and emphasize the need for additional measurements with future ground-based facilities, such as CCAT, in the post-Herschel era., Comment: To appear in The Astrophysical Journal Letters, 8 pages, 4 figures, 1 table

176P/LINEAR is a member of the new cometary class known as main-belt comets (MBCs). It displayed cometary activity shortly during its 2005 perihelion passage that may be driven by the sublimation of sub-surface ices. We have therefore searched for emission of the H2O 110-101 ground state rotational line at 557 GHz toward 176P/LINEAR with the Heterodyne Instrument for the Far Infrared (HIFI) on board the Herschel Space Observatory on UT 8.78 August 2011, about 40 days after its most recent perihelion passage, when the object was at a heliocentric distance of 2.58 AU. No H2O line emission was detected in our observations, from which we derive sensitive 3-sigma upper limits for the water production rate and column density of < 4e25 molec/s and of < 3e10 cm^{-2}, respectively. From the peak brightness measured during the object's active period in 2005, this upper limit is lower than predicted by the relation between production rates and visual magnitudes observed for a sample of comets by Jorda et al. (2008) at this heliocentric distance. Thus, 176P/LINEAR was likely less active at the time of our observation than during its previous perihelion passage. The retrieved upper limit is lower than most values derived for the H2O production rate from the spectroscopic search for CN emission in MBCs., Comment: 5 pages, 2 figures. Minor changes to match published version

We aim to determine the production rates of several parent and product volatiles and the 12C/13C isotopic carbon ratio in the long-period comet C/2004 Q2 (Machholz), which is likely to originate from the Oort Cloud. The line emission from several molecules in the coma was measured with high signal-to-noise ratio in January 2005 at heliocentric distance of 1.2 AU by means of high-resolution spectroscopic observations using the Submillimeter Telescope (SMT). We have obtained production rates of several volatiles (CH3OH, HCN, H13CN, HNC, H2CO, CO and CS) by comparing the observed and simulated line-integrated intensities. Furthermore, multiline observations of the CH3OH (7-6) series allow us to estimate the rotational temperature using the rotation diagram technique. We find that the CH3OH population distribution of the levels sampled by these lines can be described by a rotational temperature of 40 \pm 3 K. Derived mixing ratios relative to hydrogen cyanide are CO/CH3OH/H2CO/CS/HNC/H13CN/HCN = 30.9/24.6/4.8/0.57/0.031/0.013/1 assuming a pointing offset of 8" due to the uncertain ephemeris at the time of the observations and the telescope pointing error. The measured relative molecular abundances in C/2004 Q2 (Machholz) are between low- to typical values of those obtained in Oort Cloud comets, suggesting that it has visited the inner solar system previously and undergone thermal processing. The HNC/HCN abundance ratio of ~3.1% is comparable to that found in other comets, accounting for the dependence on the heliocentric distance, and could possibly be explained by ion-molecule chemical processes in the low-temperature atmosphere. From a tentative H13CN detection, the measured value of 97 \pm 30 for the H12CN/H13CN isotopologue pair is consistent with a telluric value., Comment: 14 pages with 11 figures, abridged abstract

The D/H ratio in cometary water is believed to be an important indicator of the conditions under which icy planetesimals formed and can provide clues to the contribution of comets to the delivery of water and other volatiles to Earth. Available measurements suggest that there is isotopic diversity in the comet population. The Herschel Space Observatory revealed an ocean-like ratio in the Jupiter-family comet 103P/Hartley 2, whereas most values measured in Oort-cloud comets are twice as high as the ocean D/H ratio. We present here a new measurement of the D/H ratio in the water of an Oort-cloud comet. HDO, H_2O, and H_2^18O lines were observed with high signal-to-noise ratio in comet C/2009 P1 (Garradd) using the Herschel HIFI instrument. Spectral maps of two water lines were obtained to constrain the water excitation. The D/H ratio derived from the measured H_2^16O and HDO production rates is 2.06+/-0.22 X 10**-4. This result shows that the D/H in the water of Oort-cloud comets is not as high as previously thought, at least for a fraction of the population, hence the paradigm of a single, archetypal D/H ratio for all Oort-cloud comets is no longer tenable. Nevertheless, the value measured in C/2009 P1 (Garradd) is significantly higher than the Earth's ocean value of 1.558 X 10**-4. The measured H_2^16O/H_2^18O ratio of 523+/-32 is, however, consistent with the terrestrial value., Comment: 6 pages with 4 figures and 1 table. Accepted for publication as a Letter in Astronomy & Astrophysics

Comet 17P/Holmes underwent a dramatic outburst in October 2007, caused by the sudden fragmentation of its nucleus and the production of a large quantity of grains scattering sunlight. We report on 90 GHz continuum observations carried out with the IRAM Plateau de Bure interferometer on 27.1 and 28.2 October 2007 UT, i.e., 4-5 days after the outburst. These observations probed the thermal radiation of large dust particles, and therefore provide the best constraints on the mass in the ejecta debris. The thermal emission of the debris was modelled and coupled to a time-dependent description of their expansion after the outburst. The analysis was performed in the Fourier plane. Visibilities were computed for the two observing dates and compared to the data to measure their velocity and mass. Optical data and 250-GHz continuum measurements published in the literature were used to further constrain the dust kinematics and size distribution. Two distinct dust components in terms of kinematic properties are identified in the data. The large-velocity component, with typical velocities V0 of 50-100 m/s for 1 mm particles, displays a steep size distribution with a size index estimated to q = -3.7 (\pm0.1), assuming a minimum grain size of 0.1 \mum. It corresponds to the fast expanding shell observed in optical images. The slowly-moving "core" component (V0 = 7-9 m/s) detected near the nucleus has a size index |q| < 3.4 and contains a higher proportion of large particles than the shell. The dust mass in the core is in the range 0.1-1 that of the shell. Using optical constants pertaining to porous grains (50% porosity) made of astronomical silicates mixed with water ice (48% in mass), the total dust mass Mdust injected by the outburst is estimated to 4-14 x 10**11 kg, corresponding to 3-9% the nucleus mass., Comment: 15 pages with 11 figures and 7 tables. Accepted for publication in Astronomy & Astrophysics

The Jupiter-family comet 10P/Tempel 2 was observed during its 2010 return with the Herschel Space Observatory. We present here the observation of the (J, K) = (1, 0)-(0, 0) transition of ammonia at 572 GHz in this comet with the Heterodyne Instrument for the Far Infrared (HIFI) of Herschel. We also report on radio observations of other molecules (HCN, CH3OH, H2S and CS) obtained during the 1999 return of the comet with the CSO telescope and the JCMT, and during its 2010 return with the IRAM 30-m telescope. Molecular abundances relative to water are 0.09%, 1.8%, 0.4%, and 0.08% for HCN, CH3OH, H2S, and CS, respectively. An abundance of 0.5% for NH3 is obtained, which is similar to the values measured in other comets. The hyperfine structure of the ammonia line is resolved for the first time in an astronomical source. Strong anisotropy in the outgassing is present in all observations from 1999 to 2010 and is modelled to derive the production rates., Comment: 6 pages and 8 figures. Accepted for publication in Astronomy & Astrophysics

We present unique spectroscopic radio observations of comets C/2002 X5 (Kudo-Fujikawa), C/2002 V1 (NEAT), and C/2006 P1 (McNaught), which came within $r_h ~ 0.2 AU of the Sun in 2003 and 2007. The molecules OH, HCN, HNC, CS, and CH3OH were detected in each of these comets when they were exposed to strong heating from the Sun. Both HC3N and HCO+ were detected in comets C/2002 X5 and C/2006 P1, respectively. We show that in these very productive comets close to the Sun screening of the photodissociation by the Sun UV radiation plays a non-negligible role. Acceleration of the gas expansion velocity and day-night asymmetry is also measured and modeled. The CS photodissociation lifetime was constrained to be about 2.5 x 10**-5 s-1 at r_h = 1 AU. The relative abundances are compared to values determined from more distant observations of C/2002 X5 or other comets. A high HNC/HCN production-rate ratio, in the range 10 to 30 % between 0.5 and 0.1 AU from the Sun, is measured. The trend for a significant enrichment in CS in cometary comae (CS/HCN proportional to r_h**-0.8) is confirmed in all three comets. The CH3OH/HCN production rate ratio decreases at low r_h. The HC3N/HCN production rate ratio in comet C/2002 X5 is four times higher than measured in any other comet., Comment: Accepted for publication in Astronomy & Astrophysics, 21 pages, 18 figures

Little is known about the physical properties of cometary nuclei. Apart from space mission targets, measuring the thermal emission of a nucleus is one of the few means to derive its size, independently of its albedo, and to constrain some of its thermal properties. This emission is difficult to detect from Earth but space telescopes (Infrared Space Observatory, Spitzer Space Telescope, Herschel Space Observatory) allow reliable measurements in the infrared and the sub-millimetre domains. We aim at better characterizing the thermal properties of the nucleus of comet 8P/Tuttle using multi-wavelentgh space- and ground-based observations, in the visible, infrared, and millimetre range. We used the Plateau de Bure Interferometer to measure the millimetre thermal emission of comet 8P/Tuttle at 240 GHz (1.25 mm) and analysed the observations with the shape model derived from Hubble Space Telescope observations and the nucleus size derived from Spitzer Space Telescope observations. We report on the first detection of the millimetre thermal emission of a cometary nucleus since comet C/1995 O1 Hale-Bopp in 1997. Using the two contact spheres shape model derived from Hubble Space Telescope observations, we constrained the thermal properties of the nucleus. Our millimetre observations are best match with: i) a thermal inertia lower than ~10 J K-1 m-2 s-1/2, ii) an emissivity lower than 0.8, indicating a non-negligible contribution of the colder sub-surface layers to the outcoming millimetre flux., Comment: 7 pages. Accepted for publication in Astronomy & Astrophysics

Based on long-slit infrared spectroscopic observations, it has been suggested that half of the carbon monoxide present in the atmosphere of comet C/1995 O1 (Hale-Bopp) close to perihelion was released by a distributed source in the coma, whose nature (dust or gas) remains unidentified. We re-assess the origin of CO in Hale-Bopp's coma from millimeter interferometric data and a re-analysis of the IR lines. Simultaneous observations of the CO J(1-0) (115 GHz) and J(2-1) (230 GHz) lines were undertaken with the IRAM interferometer in single-dish and interferometric modes. The diversity of angular resolutions (from 1700 to 42000 km diameter at the comet) is suitable to study the radial distribution of CO and detect the extended source observed in the infrared. We used excitation and radiative transfer models to simulate the observations. Various CO density distributions were considered, including 3D time-dependent hydrodynamical simulations which reproduce a CO rotating jet. The CO J(1-0) and J(2-1) observations can be consistently explained by a nuclear production of CO. Composite 50:50 nuclear/extended productions with characteristic scale lengths of CO parent L_p > 1500 km are rejected. Based on similar radiation transfer calculations, we show that the CO v = 1-0 ro-vibrational lines observed in comet Hale-Bopp at heliocentric distances less than 1.5 AU are severely optically thick. The broad extent of the CO brightness distribution in the infrared is mainly due to optical depth effects. Additional factors can be found in the complex structure of the CO coma, and non-ideal slit positioning caused by the anisotropy of dust IR emission. We conclude that both CO millimeter and infrared lines do not provide compelling evidence for a distributed source of CO in Hale-Bopp's atmosphere., Comment: Accepted for publication in Icarus (55 pages, 13 figures)

We report on the initial analysis of Herschel/HIFI carbon monoxide (CO) observations of the Martian atmosphere performed between 11 and 16 April 2010. We selected the (7-6) rotational transitions of the isotopes ^{13}CO at 771 GHz and C^{18}O at 768 GHz in order to retrieve the mean vertical profile of temperature and the mean volume mixing ratio of carbon monoxide. The derived temperature profile agrees within less than 5 K with general circulation model (GCM) predictions up to an altitude of 45 km, however, show about 12-15 K lower values at 60 km. The CO mixing ratio was determined as 980 \pm 150 ppm, in agreement with the 900 ppm derived from Herschel/SPIRE observations in November 2009., Comment: Accepted for publication in Astronomy and Astrophysics (special issue on HIFI first results); minor changes to match published version

We report on an initial analysis of Herschel/HIFI observations of hydrogen chloride (HCl), hydrogen peroxide (H_2O_2), and molecular oxygen (O_2) in the Martian atmosphere performed on 13 and 16 April 2010 (L_s ~ 77{\deg}). We derived a constant volume mixing ratio of 1400 +/- 120 ppm for O_2 and determined upper limits of 200 ppt for HCl and 2 ppb for H_2O_2. Radiative transfer model calculations indicate that the vertical profile of O_2 may not be constant. Photochemical models determine the lowest values of H_2O_2 to be around L_s ~ 75{\deg} but overestimate the volume mixing ratio compared to our measurements., Comment: Accepted for publication in Astronomy and Astrophysics (special issue on HIFI first results); minor changes to match published version

The high spectral resolution and sensitivity of Herschel/HIFI allows for the detection of multiple rotational water lines and accurate determinations of water production rates in comets. In this letter we present HIFI observations of the fundamental 110-101 (557 GHz) ortho and 111-000 (1113 GHz) para rotational transitions of water in comet 81P/Wild 2 acquired in February 2010. We mapped the extent of the water line emission with five point scans. Line profiles are computed using excitation models which include excitation by collisions with electrons and neutrals and solar infrared radiation. We derive a mean water production rate of $1.0 \times 10^{28}$ molecules s$^{-1}$ at a heliocentric distance of 1.61 AU about 20 days before perihelion, in agreement with production rates measured from the ground using observations of the 18-cm OH lines. Furthermore, we constrain the electron density profile and gas kinetic temperature, and estimate the coma expansion velocity by fitting the water line shapes., Comment: Accepted for publication in A&A (special issue on HIFI first results)

We report on the initial analysis of a Herschel/PACS full range spectrum of Neptune, covering the 51-220 micrometer range with a mean resolving power of ~ 3000, and complemented by a dedicated observation of CH4 at 120 micrometers. Numerous spectral features due to HD (R(0) and R(1)), H2O, CH4, and CO are present, but so far no new species have been found. Our results indicate that (i) Neptune's mean thermal profile is warmer by ~ 3 K than inferred from the Voyager radio-occultation; (ii) the D/H mixing ratio is (4.5+/-1) X 10**-5, confirming the enrichment of Neptune in deuterium over the protosolar value (~ 2.1 X 10**-5); (iii) the CH4 mixing ratio in the mid stratosphere is (1.5+/-0.2) X 10**-3, and CH4 appears to decrease in the lower stratosphere at a rate consistent with local saturation, in agreement with the scenario of CH4 stratospheric injection from Neptune's warm south polar region; (iv) the H2O stratospheric column is (2.1+/-0.5) X 10**14 cm-2 but its vertical distribution is still to be determined, so the H2O external flux remains uncertain by over an order of magnitude; and (v) the CO stratospheric abundance is about twice the tropospheric value, confirming the dual origin of CO suspected from ground-based millimeter/submillimeter observations., Comment: Accepted for publication in Astronomy & Astrophysics (special issue on Herschel first results)

We have obtained the first continuous disk averaged spectrum of Mars from 450 to 1550 Ghz using the Herschel-SPIRE Fourier Transform Spectrometer. The spectrum was obtained at a constant resolution of 1.4 GHz across the whole band. The flux from the planet is such that the instrument was operated in "bright source" mode to prevent saturation of the detectors. This was the first successful use of this mode and in this work we describe the method used for observing Mars together with a detailed discussion of the data reduction techniques required to calibrate the spectrum. We discuss the calibration accuracy obtained and describe the first comparison with surface and atmospheric models. In addition to a direct photometric measurement of the planet the spectrum contains the characteristic transitions of 12CO from J 5-4 to J 13-12 as well as numerous H2O transitions. Together these allow the comparison to global atmospheric models allowing the mean mixing ratios of water and 12CO to be investigated. We find that it is possible to match the observed depth of the absorption features in the spectrum with a fixed water mixing ratio of 1 x 10-4 and a 12CO mixing ratio of 9 x 10-4, Comment: Accepted for publication in Astronomy&Astrophysics, Herschel First Results special issue

High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres. We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 2_{12}-1_{01} (1669 GHz) ortho and 1_{11}-0_{00} (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 1_{10}-1_{01} at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7-2.8 x 10^{28} s^{-1} over the range r_h = 1.83-1.85 AU., Comment: 7 figures, v2: minor changes, updated version of arXiv:1005.2969v1. Accepted for publication in Astronomy and Astrophysics, Herschel special issue on Herschel First Science Results

Comet C/2006 W3 (Christensen) was observed in November 2009 at 3.3 AU from the Sun with Herschel. The PACS instrument acquired images of the dust coma in 70- and 160-micrometers filters, and spectra covering several H2O rotational lines. Spectra in the range 450-1550 GHz were acquired with SPIRE. The comet emission continuum from 70 to 672 micrometers was measured, but no lines were detected. The spectral energy distribution indicates thermal emission from large particles and provides a measure of the size distribution index and dust production rate. The upper limit to the water production rate is compared to the production rates of other species (CO, CH3OH, HCN, H2S, OH) measured with the IRAM 30-m and Nancay telescopes. The coma is found to be strongly enriched in species more volatile than water, in comparison to comets observed closer to the Sun. The CO to H2O production rate ratio exceeds 220%. The dust to gas production rate ratio is on the order of 1., Comment: Accepted for publication in Astronomy & Astrophysics (special issue on Herschel first results)