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Nanocomposite magnetic polymer electrolytes based on poly(vinyl alcohol) (PVA) complexed with lithium hydroxide (LiOH) and containing magnetite (Fe3O4) nanoparticles were prepared using an in situ method, in which the nanoparticles were grown in the host polymer electrolyte. Ion carriers were formed during nanoparticle growth from the previously added LiOH precursor. If a high concentration of LiOH was added, the remaining unreacted LiOH was distributed in the form of an amorphous complex around the Fe3O4 nanoparticles, thus preventing agglomeration of the nanoparticles by the host polymer. By addition of Fe3O4 the composite polymer electrolytes improved the ionic conductivity, resulting in a maximum conductivity of 1.81 × 10-3S·cm-1.The magnetic properties of the polymer electrolyte were investigated through magnetic susceptibility studies, and the material was predominantly ferromagnetic. [ABSTRACT FROM AUTHOR]

Competing Interests: Competing interests statement:The authors declare no competing interest.

Studying past ecosystems from ancient environmental DNA preserved in lake sediments (sedaDNA) is a rapidly expanding field. This research has mainly involved Holocene sediments from lakes in cool climates, with little known about the suitability of sedaDNA to reconstruct substantially older ecosystems in the warm tropics. Here, we report the successful recovery of chloroplast trnL (UAA) sequences (trnL-P6 loop) from the sedimentary record of Lake Towuti (Sulawesi, Indonesia) to elucidate changes in regional tropical vegetation assemblages during the lake's Late Quaternary paleodepositional history. After the stringent removal of contaminants and sequence artifacts, taxonomic assignment of the remaining genuine trnL-P6 reads showed that native nitrogen-fixing legumes, C 3 grasses, and shallow wetland vegetation (Alocasia) were most strongly associated with >1-million-year-old (>1 Ma) peats and silts (114-98.8 m composite depth; mcd), which were deposited in a landscape of active river channels, shallow lakes, and peat-swamps. A statistically significant shift toward partly submerged shoreline vegetation that was likely rooted in anoxic muddy soils (i.e., peatland forest trees and wetland C 3 grasses (Oryzaceae) and nutrient-demanding aquatic herbs (presumably Oenanthe javanica)) occurred at 76 mcd (~0.8 Ma), ~0.2 Ma after the transition into a permanent lake. This wetland vegetation was most strongly associated with diatom ooze (46-37 mcd), thought to be deposited during maximum nutrient availability and primary productivity. Herbs (Brassicaceae), trees/shrubs (Fabaceae and Theaceae), and C 3 grasses correlated with inorganic parameters, indicating increased drainage of ultramafic sediments and laterite soils from the lakes' catchment, particularly at times of inferred drying. Downcore variability in trnL-P6 from tropical forest trees (Toona), shady ground cover herbs (Zingiberaceae), and tree orchids (Luisia) most strongly correlated with sediments of a predominantly felsic signature considered to be originating from the catchment of the Loeha River draining into Lake Towuti during wetter climate conditions. However, the co-correlation with dry climate-adapted trees (i.e., Castanopsis or Lithocarpus) plus C 4 grasses suggests that increased precipitation seasonality also contributed to the increased drainage of felsic Loeha River sediments. This multiproxy approach shows that despite elevated in situ temperatures, tropical lake sediments potentially comprise long-term archives of ancient environmental DNA for reconstructing ecosystems, which warrants further exploration., (© 2024 The Authors. Geobiology published by John Wiley & Sons Ltd.)

The Inner Ambon Bay (IAB) is an important area for the economic development of the city of Ambon, one of only a few urban areas in eastern Indonesia. This study is intended to monitor the anthropogenic impact on IAB by employing combined rock magnetic and geochemical analyses on 20 samples collected from IAB and the surrounding rivers. Magnetic susceptibility values of samples in the IAB averaged 26.37× 10 -8  m 3 /kg, which is relatively high and comparable to that of contaminated coastal environments. Magnetic susceptibility correlated positively with certain metals such as Cr, Co, Ni, and Mn but negatively with Hg. Geochemical analyses showed that Hg and Ag contents were relatively high but pose only moderate risk to the environment based on the geo-accumulation index. Furthermore, the potential ecological risk index ( PERI ) showed that there were two points that showed moderate ecological risk. Multivariate statistical analysis (principal component analysis (PCA), Pearson's correlation coefficient (PCC), and hierarchical cluster analysis (HCA)) outlined that the metallic accumulation in the sediments of IAB was related to lithological, geological, and anthropogenic impacts. Therefore, oil spills and household waste are likely major reasons for anthropogenic pollution in the sediments of the IAB., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2024 The Authors.)

The intertropical convergence zone (ITCZ) plays a key role in regulating tropical hydroclimate and global water cycle through changes in its convection strength, latitudinal position, and width. The long-term variability of the ITCZ, along with the corresponding driving mechanisms, however, remains obscure, mainly because it is difficult to separate different ITCZ variables in paleoclimate proxy records. Here, we report a speleothem oxygen isotope (δ 18 O) record from southwestern Sulawesi, Indonesia, and compile it with other speleothem records from the Maritime Continent. Using the spatial gradient of speleothem δ 18 O along a transect across the ITCZ, we constrain ITCZ variabilities over the Maritime Continent during the past 30,000 y. We find that ITCZ convection strength overall intensified from the last glacial period to the Holocene, following changes in climate boundary conditions. The mean position of the regional ITCZ has moved latitudinally no more than 3° in the past 30,000 y, consistent with the deduction from the atmospheric energy framework. However, different from modern observations and model simulations for future warming, the ITCZ appeared narrower during both the late Holocene and most part of the last glacial period, and its expansion occurred during Heinrich stadials and the early-to-mid Holocene. We also find that during the last glacial and deglacial period, prominent millennial-scale ITCZ changes were closely tied to the variability of the Atlantic meridional overturning circulation (AMOC), whereas during the Holocene, they were predominantly modulated by the long-term variability of the Walker circulation.

Kalimantan Selatan is proud of the Martapura River's natural and cultural history. Martapura tributaries include Riam Kanan and Kiwa. The Martapura River is essential because it provides clean water and a livelihood for riverside residents. Human-caused river pollution grows with population density (also known as anthropogenic pollutants). This study characterizes surface sediment magnetic characteristics and heavy metal contents along the Riam Kanan, Riam Kiwa, and Martapura rivers. The purpose of this research is to evaluate the magnetic signal with respect to heavy metal contents found in surface sediments taken from rivers and to confirm the use of the rock magnetism method in environmental studies in the study area. Surface sediment samples were gathered and tested for magnetic, heavy metal, and mineralogical content. According to the findings, the pseudo-single domain (PSD) magnetite mineral predominates among the magnetic minerals that can be found in the surface sediments of the rivers Riam Kanan, Riam Kiwa, and Martapura. This substantially greater grain size may be due to magnetic particles produced by erosion along the river banks. The mass-specific magnetic susceptibility of surface sediments ranges from 103.11 to 1403.64 × 10 -8  m 3 /kg, with an average value of 355.67 × 10 -8  m 3 /kg due to the peatland environment. Magnetic susceptibility strongly negatively correlates with heavy contents like Cu, Zn, and Hg, according to Pearson correlation analysis. Due to this correlation, magnetic susceptibility may indicate heavy metal pollution in certain rivers. This current study demonstrates the novelty of the relationship between magnetic susceptibility and the contents of heavy metals in surface sediments from rivers in peatland and tropical environments by illustrating how the relationship affects the magnetic susceptibility of the sediments., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2023 The Authors. Published by Elsevier Ltd.)

Estuaries have very complex mechanisms because they are influenced by seawater intrusion, which causes enrichment of contaminants in the maximum turbidity area. Magnetic susceptibility measurements have been used for monitoring a wide variety of environments. However, there have been few studies of the magnetic properties of surface sediments from estuaries in volcanic environments in the tropics. This study investigates the magnetic properties and their correlations with the geochemistry of surface sediments in estuaries in volcanic areas and was conducted in the Krueng Aceh River, Indonesia. Measurements consist of magnetic susceptibility measurements, chemical analysis, and mineralogical analysis. Measurements of magnetic susceptibilities were performed using a Bartington MS2 instrument with an MS2B sensor using frequencies of 460 and 46 kHz. X-ray fluorescence (XRF) and energy-dispersive spectroscopy (EDS) were used to identify elements in the sediments. Scanning electron microscopy (SEM) analysis was used to analyze sediment grains. X-ray diffraction (XRD) analysis was used to determine mineral contents. For the first time, χ LF /χ FD ratios were found to be an obvious parameter for identifying areas of sediment traps and metal enrichment in the estuary turbidity maxima (ETM) zone. The magnetic properties carried by volcanic rock minerals consist of pigeonite and enstatite. These two minerals have not been previously considered as carriers of sediments with magnetic properties when monitoring heavy metal enrichment in urban rivers. These results provide an extension of the use of magnetic susceptibility measurements in environmental studies, particularly in estuary river environments in volcanic areas such as the Krueng Aceh River, Indonesia., (© 2022. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Deposition of ferruginous sediment was widespread during the Archaean and Proterozoic Eons, playing an important role in global biogeochemical cycling. Knowledge of organic matter mineralization in such sediment, however, remains mostly conceptual, as modern ferruginous analogs are largely unstudied. Here we show that in sediment of ferruginous Lake Towuti, Indonesia, methanogenesis dominates organic matter mineralization despite highly abundant reactive ferric iron phases like goethite that persist throughout the sediment. Ferric iron can thus be buried over geologic timescales even in the presence of labile organic carbon. Coexistence of ferric iron with millimolar concentrations of methane further demonstrates lack of iron-dependent methane oxidation. With negligible methane oxidation, methane diffuses from the sediment into overlying waters where it can be oxidized with oxygen or escape to the atmosphere. In low-oxygen ferruginous Archaean and Proterozoic oceans, therefore, sedimentary methane production was likely favored with strong potential to influence Earth's early climate.

This article presents rock texture and mineralogy, as well as major and trace elements of lava from Ijen Crater and Mount Blau, Ijen Volcanic Complex (IVC), East Java, Indonesia related to article entitled "Rock Magnetic, Petrography, and Geochemistry Studies of Lava at the Ijen Volcanic Complex (IVC), Banyuwangi, East Java, Indonesia" [1]. Six lava samples were taken from three lava flows that are the product of the eruption of the Ijen Crater and three lava samples from a lava flow that is the product of the eruption of Mount Blau. The samples were crushed and used for measuring major and trace elements using XRF method. Meanwhile, the thin sections of all samples were used to analyze rock texture and mineralogy. These data are invaluable in identifying the lithology, tectonic setting, and magmatism process through the analysis of total silica alkaline and Harker diagram. Other researchers can analyze the other diagrams and graphs to know in more detailed information as intended. On the other hand, the data can be used as a comparison for other lava products from different eruption sources., (© 2019 The Authors.)

This article presents magnetic mineral characteristics, trace metals, and REE geochemistry of river sediments that serve as inlets to Lake Limboto, Sulawesi, Indonesia related to article entitled "Lithogenic and anthropogenic components in surface sediments from Lake Limboto as shown by magnetic mineral characteristics, trace metals, and REE geochemistry" [1]. River sediments were obtained from three rivers, namely Alopohu, Bionga, and Talumelito. Sieved sediments were subjected to magnetic susceptibility measurements as well as geochemical analyses that include AAS analyses for trace metals and ICP-OES for REE. Extracted magnetic grains were also subjected to magnetic hysteresis analyses as well as XRD and SEM analyses. These data are invaluable in identifying the contribution of each river (and its catchment area) to the surface sediments of Lake Limboto.

Brantas River is a largest urban river supplying raw water and drainage in Jawa Timur Province, Indonesia. Dense population along the river is a threat of pollution due to anthropogenic pollutants. In this study, we characterize the magnetic properties and heavy metal contents of surface sediments in various locations along the Brantas River. This study aims to enhance our understanding of the relationship between magnetic parameters and heavy metal contents in surface sediments from river. Surface sediment samples were taken and measured by a series of magnetic measurements, mineralogical analysis and heavy metal contents. The results show that magnetic minerals in surface sediments of Brantas River are dominated by PSD magnetite mineral. This relatively coarser grain size can be caused by magnetic particles produced by erosion around the river. Surface sediments have very high mass-specific magnetic susceptibility varying from 844.0 to 7231.4 × 10 -8 m 3 kg -1 (on average of 3022.9 × 10 -8 m 3 kg -1 ) because influenced by the surrounding volcanic environment. Magnetic susceptibility can identify and classify enrichment of heavy metals. Based on the Pearson correlation analysis, magnetic susceptibility has strong positive correlation with the heavy metal contents of ferromagnetic elements such as Fe and Co so that it can potentially be used as an indicator of pollution of both these heavy metals in the Brantas River. This present work shows the novelty of the relationship between magnetic susceptibility and heavy metal contents in surface sediments from river in volcanic and tropical environment., (Copyright © 2019 Elsevier B.V. All rights reserved.)

This article presents measurement data using environmental magnetism method on the bulk surface sediments related to the research article entitled "Heavy metal contents and magnetic properties of surface sediments in volcanic and tropical environment from Brantas River, Jawa Timur Province, Indonesia" Mariyanto et al., 2019. Surface sediments were taken from 20 different locations along Brantas River. In the laboratory, a series of magnetic measurements was conducted on sediment samples i.e. magnetic susceptibility, ARM (Anhysteretic Remanent Magnetization) and IRM (Isothermal Remanent Magnetization). These environmental magnetism data were used to characterize bulk surface sediments in the study area.

Magnetic minerals, such as magnetite and hematite, have been reported to be present, in particular, leaves as biogenic particles. The magnetic minerals and properties of Ni hyperaccumulators have not previously been reported in the literature. This study aimed to characterize the magnetic properties of two Ni hyperaccumulating plant species, R. bengalensis and P. oxyhedra, which grow in an ultramafic region on Halmahera Island, Indonesia. For comparison, similar characterization was carried out on two non-hyperaccumulating plant species which grow in the same region. Concentrations of Ni, Fe, and Mn in the leaves of the hyperaccumulating plants were measured using atomic absorption spectroscopy (AAS) and their magnetic properties were characterized using measurements of magnetic susceptibility, low temperature magnetic susceptibility, and hysteresis curves. The results show that, compared to the non-hyperaccumulating plants, the Ni hyperaccumulating plants have higher concentrations of Ni and similar concentration of Fe. The magnetic susceptibilities of hyperaccumulating plants are positive, and those of non-hyperaccumulating plants are negative. This suggests that the abundance of Ni, rather than Fe, may control the magnetic properties of Ni hyperaccumulating plants. This probable connection between Ni concentration and plant magnetic properties could be advantageous for identifying hyperaccumulators, and should, therefore, be explored further.

The Indo-Pacific warm pool houses the largest zone of deep atmospheric convection on Earth and plays a critical role in global climate variations. Despite the region's importance, changes in Indo-Pacific hydroclimate on orbital timescales remain poorly constrained. Here we present high-resolution geochemical records of surface runoff and vegetation from sediment cores from Lake Towuti, on the island of Sulawesi in central Indonesia, that continuously span the past 60,000 y. We show that wet conditions and rainforest ecosystems on Sulawesi present during marine isotope stage 3 (MIS3) and the Holocene were interrupted by severe drying between ∼33,000 and 16,000 y B.P. when Northern Hemisphere ice sheets expanded and global temperatures cooled. Our record reveals little direct influence of precessional orbital forcing on regional climate, and the similarity between MIS3 and Holocene climates observed in Lake Towuti suggests that exposure of the Sunda Shelf has a weaker influence on regional hydroclimate and terrestrial ecosystems than suggested previously. We infer that hydrological variability in this part of Indonesia varies strongly in response to high-latitude climate forcing, likely through reorganizations of the monsoons and the position of the intertropical convergence zone. These findings suggest an important role for the tropical western Pacific in amplifying glacial-interglacial climate variability.

Leachate sludge samples were taken from two municipal solid waste sites of Jelekong and Sarimukti in Bandung, Indonesia. Their magnetic mineralogy and granulometry were analyzed to discriminate the sources of magnetic minerals using X-ray diffraction (XRD), scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy (SEM-EDX) and rock magnetism. SEM-EDX analyses infer that the main magnetic minerals in the leachate sludge are iron oxides. In terms of their morphology, the grains from Jelekong are mostly octahedral and angular, which are similar to the general shapes of magnetic grains from the local soils. The grains from Sarimukti, on the other hand, are dominated by imperfect spherule shapes suggesting the product of combustion processes. Hysteresis parameters verify that the predominant magnetic mineral in leachate sludge is low coercivity ferrimagnetic mineral such as magnetite (Fe(3)O(4)). Furthermore, comparisons of rock magnetic parameters show that the magnetic minerals of soil samples from Jelekong have higher degree of magnetic pedogenesis indicating higher proportion of superparamagnetic/ultrafine particles than those of soil samples from Sarimukti. The plot of susceptibilities ratio versus coercive force has a great potential to be used as a discriminating tool for determining the source of magnetic minerals., (2010 Elsevier B.V. All rights reserved.)