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Europa's ocean lies atop an interior made of metal and silicates. On the basis of gravity data from the Galileo mission, many argued that Europa's interior, like Earth, is differentiated into a metallic core and a mantle composed of anhydrous silicates. Some studies further assumed that Europa differentiated while (or soon after) it accreted, also like Earth. However, Europa probably formed at much colder temperatures, meaning that Europa plausibly ended accretion as a mixture containing water-ice and/or hydrated silicates. Here, we use numerical models to describe the thermal evolution of Europa's interior assuming low initial temperatures (~200 to 300 kelvin). We find that silicate dehydration can produce Europa's current ocean and icy shell. Rocks below the seafloor may remain cool and hydrated today. Europa's metallic core, if it exists, may have formed billions of years after accretion. Ultimately, we expect the chemistry of Europa's ocean to reflect protracted heating of the interior.

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability 1 . However, no unambiguous photochemical products have been detected in exoplanet atmospheres so far. Recent observations from the JWST Transiting Exoplanet Community Early Release Science Program 2,3 found a spectral absorption feature at 4.05 μm arising from sulfur dioxide (SO 2 ) in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M J ) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of around 1,100 K (ref.  4 ). The most plausible way of generating SO 2 in such an atmosphere is through photochemical processes 5,6 . Here we show that the SO 2 distribution computed by a suite of photochemical models robustly explains the 4.05-μm spectral feature identified by JWST transmission observations 7 with NIRSpec PRISM (2.7σ) 8 and G395H (4.5σ) 9 . SO 2 is produced by successive oxidation of sulfur radicals freed when hydrogen sulfide (H 2 S) is destroyed. The sensitivity of the SO 2 feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of about 10× solar. We further point out that SO 2 also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations., (© 2023. The Author(s).)

Pluto, Titan, and Triton make up a unique class of solar system bodies, with icy surfaces and chemically reducing atmospheres rich in organic photochemistry and haze formation. Hazes play important roles in these atmospheres, with physical and chemical processes highly dependent on particle sizes, but the haze size distribution in reducing atmospheres is currently poorly understood. Here we report observational evidence that Pluto's haze particles are bimodally distributed, which successfully reproduces the full phase scattering observations from New Horizons. Combined with previous simulations of Titan's haze, this result suggests that haze particles in reducing atmospheres undergo rapid shape change near pressure levels ~0.5 Pa and favors a photochemical rather than a dynamical origin for the formation of Titan's detached haze. It also demonstrates that both oxidizing and reducing atmospheres can produce multi-modal hazes, and encourages reanalysis of observations of hazes on Titan and Triton., (© 2022. The Author(s).)

The asteroid (16) Psyche may be the metal-rich remnant of a differentiated planetesimal, or it may be a highly reduced, metal-rich asteroidal material that never differentiated. The NASA Psyche mission aims to determine Psyche's provenance. Here we describe the possible solar system regions of origin for Psyche, prior to its likely implantation into the asteroid belt, the physical and chemical processes that can enrich metal in an asteroid, and possible meteoritic analogs. The spacecraft payload is designed to be able to discriminate among possible formation theories. The project will determine Psyche's origin and formation by measuring any strong remanent magnetic fields, which would imply it was the core of a differentiated body; the scale of metal to silicate mixing will be determined by both the neutron spectrometers and the filtered images; the degree of disruption between metal and rock may be determined by the correlation of gravity with composition; some mineralogy (e.g., modeled silicate/metal ratio, and inferred existence of low-calcium pyroxene or olivine, for example) will be detected using filtered images; and the nickel content of Psyche's metal phase will be measured using the GRNS., Competing Interests: Conflict of InterestNot applicable., (© The Author(s) 2022.)

The Galilean satellites exhibit a monotonic decrease in density (and increase in ice mass fraction) with distance from Jupiter (Pollack & Fanale 1982). Whether this is because of the background conditions when they formed (Lunine & Stevenson 1982; Canup & Ward 2002; Mosqueira & Estrada 2003a; Ronnet et al. 2017), the process of accretion itself (Dwyer et al. 2013), or later loss due to tidal heating (Canup & Ward 2009), has been in dispute for forty years. We find that a hitherto largely neglected process - vapor loss driven by accretional heating (Kuramoto & Matsui 1994) - can reproduce the observed density trend for accretion timescales ≳300 kyr, consistent with gas-starved satellite formation models (Canup & Ward 2002, 2006). In this model both Io and Europa develop an early surface liquid water ocean. Vapor escape from this ocean causes the water inventories of Io and Europa to be completely and mostly lost, respectively. Isotopic fractionation arising from vapor loss means that Europa will develop a higher D/H ratio compared with Ganymede and Callisto. We make predictions that can be tested with in situ measurements of D/H of potential Europa plumes (Roth et al. 2014) by the Europa Clipper spacecraft, or infrared spectroscopic determinations (Clark et al. 2019) of D/H at all three bodies.

The Cold Classical Kuiper Belt, a class of small bodies in undisturbed orbits beyond Neptune, is composed of primitive objects preserving information about Solar System formation. In January 2019, the New Horizons spacecraft flew past one of these objects, the 36-kilometer-long contact binary (486958) Arrokoth (provisional designation 2014 MU 69 ). Images from the flyby show that Arrokoth has no detectable rings, and no satellites (larger than 180 meters in diameter) within a radius of 8000 kilometers. Arrokoth has a lightly cratered, smooth surface with complex geological features, unlike those on previously visited Solar System bodies. The density of impact craters indicates the surface dates from the formation of the Solar System. The two lobes of the contact binary have closely aligned poles and equators, constraining their accretion mechanism., (Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.)

Telescopic observations of Kuiper Belt objects have enabled bulk density determinations for 17 objects. These densities vary systematically with size, perhaps suggesting systematic variations in bulk composition. We find this trend can be explained instead by variations in porosity arising from the higher pressures and warmer temperatures in larger objects. We are able to match the density of 14 of 17 KBOs within their 2 σ errors with a constant rock mass fraction of 70%, suggesting a compositionally homogeneous, rock-rich reservoir. Because early 26 Al would have removed too much porosity in small (~100 km) KBOs we find the minimum formation time to be 4 Myr after solar system formation. This suggests that coagulation, and not gravitational collapse, was the dominant mechanism for KBO formation. We also use this model to make predictions for the density of Makemake, 2007 OR 10 , and MU 69 .

The Kuiper Belt is a distant region of the outer Solar System. On 1 January 2019, the New Horizons spacecraft flew close to (486958) 2014 MU 69 , a cold classical Kuiper Belt object approximately 30 kilometers in diameter. Such objects have never been substantially heated by the Sun and are therefore well preserved since their formation. We describe initial results from these encounter observations. MU 69 is a bilobed contact binary with a flattened shape, discrete geological units, and noticeable albedo heterogeneity. However, there is little surface color or compositional heterogeneity. No evidence for satellites, rings or other dust structures, a gas coma, or solar wind interactions was detected. MU 69 's origin appears consistent with pebble cloud collapse followed by a low-velocity merger of its two lobes., (Copyright © 2019 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.)

The deep nitrogen-covered basin on Pluto, informally named Sputnik Planitia, is located very close to the longitude of Pluto's tidal axis and may be an impact feature, by analogy with other large basins in the Solar System. Reorientation of Sputnik Planitia arising from tidal and rotational torques can explain the basin's present-day location, but requires the feature to be a positive gravity anomaly, despite its negative topography. Here we argue that if Sputnik Planitia did indeed form as a result of an impact and if Pluto possesses a subsurface ocean, the required positive gravity anomaly would naturally result because of shell thinning and ocean uplift, followed by later modest nitrogen deposition. Without a subsurface ocean, a positive gravity anomaly requires an implausibly thick nitrogen layer (exceeding 40 kilometres). To prolong the lifetime of such a subsurface ocean to the present day and to maintain ocean uplift, a rigid, conductive water-ice shell is required. Because nitrogen deposition is latitude-dependent, nitrogen loading and reorientation may have exhibited complex feedbacks.