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Molecular deuteration is a powerful diagnostic tool for probing the physical conditions and chemical processes in astrophysical environments. In this work, we focus on formaldehyde deuteration in the protobinary system NGC\,1333 IRAS\,4A, located in the Perseus molecular cloud. Using high-resolution ($\sim$\,100\,au) ALMA observations, we investigate the [D$_2$CO]/[HDCO] ratio along the cavity walls of the outflows emanating from IRAS\,4A1. Our analysis reveals a consistent decrease in the deuteration ratio (from $\sim$\,60-20\% to $\sim$\,10\%) with increasing distance from the protostar (from $\sim$\,2000\,au to $\sim$\,4000\,au). Given the large measured [D$_2$CO]/[HDCO], both HDCO and D$_2$CO are likely injected by the shocks along the cavity walls into the gas-phase from the dust mantles, formed in the previous prestellar phase. We propose that the observed [D$_2$CO]/[HDCO] decrease is due to the density profile of the prestellar core from which NGC\,1333 IRAS\,4A was born. When considering the chemical processes at the base of formaldehyde deuteration, the IRAS\,4A's prestellar precursor had a predominantly flat density profile within 3000\,au and a decrease of density beyond this radius.

The exploration of outflows in protobinary systems presents a challenging yet crucial endeavour, offering valuable insights into the dynamic interplay between protostars and their evolution. In this study, we examine the morphology and dynamics of jets and outflows within the IRAS\,4A protobinary system. This analysis is based on ALMA observations of SiO(5--4), H$_2$CO(3$_{0,3}$--2$_{0,3}$), and HDCO(4$_{1,4}$--3$_{1,3}$) with a spatial resolution of $\sim$150\,au. Leveraging an astrochemical approach involving the use of diverse tracers beyond traditional ones has enabled the identification of novel features and a comprehensive understanding of the broader outflow dynamics. Our analysis reveals the presence of two jets in the redshifted emission, emanating from IRAS\,4A1 and IRAS\,4A2, respectively. Furthermore, we identify four distinct outflows in the region for the first time, with each protostar, 4A1 and 4A2, contributing to two of them. We characterise the morphology and orientation of each outflow, challenging previous suggestions of bends in their trajectories. The outflow cavities of IRAS\,4A1 exhibit extensions of 10$''$ and 13$''$ with position angles (PA) of 0$^{\circ}$ and -12$^{\circ}$, respectively, while those of IRAS\,4A2 are more extended, spanning 18$''$ and 25$''$ with PAs of 29$^{\circ}$ and 26$^{\circ}$. We propose that the misalignment of the cavities is due to a jet precession in each protostar, a notion supported by the observation that the more extended cavities of the same source exhibit lower velocities, indicating they may stem from older ejection events.

Methyl cyanide (CH$_3$CN) is one of the most abundant and widely spread interstellar complex organic molecules (iCOMs). Several studies found that, in hot corinos, methyl cyanide and methanol abundances are correlated suggesting a chemical link, often interpreted as a synthesis of them on the interstellar grain surfaces. In this article, we present a revised network of the reactions forming methyl cyanide in the gas-phase. We carried out an exhaustive review of the gas-phase CH$_3$CN formation routes, propose two new reactions and performed new quantum mechanics computations of several reactions. We found that 13 of the 15 reactions reported in the databases KIDA and UDfA have incorrect products and/or rate constants. The new corrected reaction network contains 10 reactions leading to methyl cyanide. We tested the relative importance of those reactions in forming CH$_3$CN using our astrochemical model. We confirm that the radiative association of CH${_3}{^+}$ and HCN, forming CH$_{3}$CNH$^{+}$, followed by the electron recombination of CH$_{3}$CNH$^{+}$, is the most important CH$_3$CN formation route in both cold and warm environments, notwithstanding that we significantly corrected the rate constants and products of both reactions. The two newly proposed reactions play an important role in warm environments. Finally, we found a very good agreement between the CH$_3$CN predicted abundances with those measured in cold ($\sim$10 K) and warm ($\sim$90 K) objects. Unexpectedly, we also found a chemical link between methanol and methyl cyanide via the CH$_{3}^{+}$ ion, which can explain the observed correlation between the CH$_3$OH and CH$_3$CN abundances measured in hot corinos., Comment: 24 pages, 19 figures, accepted in MNRAS

We report ALMA high-angular resolution (~ 50 au) observations of the binary system SVS13-A. More specifically, we analyse deuterated water (HDO) and sulfur dioxide (SO2) emission. The molecular emission is associated with both the components of the binary system, VLA4A and VLA4B. The spatial distribution is compared to that of formamide (NH2CHO), previously analysed in the system. Deuterated water reveals an additional emitting component spatially coincident with the dust accretion streamer, at a distance larger than 120 au from the protostars, and at blue-shifted velocities (> 3 km/s from the systemic velocities). We investigate the origin of the molecular emission in the streamer, in light of thermal sublimation temperatures calculated using updated binding energies (BE) distributions. We propose that the observed emission is produced by an accretion shock at the interface between the accretion streamer and the disk of VLA4A. Thermal desorption is not completely excluded in case the source is actively experiencing an accretion burst., Comment: Accepted for publication in Faraday Discussions 2023

We report a comprehensive study of the cyanopolyyne chemistry in the prototypical prestellar core L1544. Using the 100m Robert C. Byrd Green Bank Telescope (GBT) we observe 3 emission lines of HC$_3$N, 9 lines of HC$_5$N, 5 lines of HC$_7$N, and 9 lines of HC$_9$N. HC$_9$N is detected for the first time towards the source. The high spectral resolution ($\sim$ 0.05 km s$^{-1}$) reveals double-peak spectral line profiles with the redshifted peak a factor 3-5 brighter. Resolved maps of the core in other molecular tracers indicates that the southern region is redshifted. Therefore, the bulk of the cyanopolyyne emission is likely associated with the southern region of the core, where free carbon atoms are available to form long chains, thanks to the more efficient illumination of the interstellar field radiation. We perform a simultaneous modelling of the HC$_5$N, HC$_7$N, and HC$_9$N lines, to investigate the origin of the emission. To enable this analysis, we performed new calculation of the collisional coefficients. The simultaneous fitting indicates a gas kinetic temperature of 5--12 K, a source size of 80$\arcsec$, and a gas density larger than 100 cm$^{-3}$. The HC$_5$N:HC$_7$N:HC$_9$N abundance ratios measured in L1544 are about 1:6:4. We compare our observations with those towards the the well-studied starless core TMC-1 and with the available measurements in different star-forming regions. The comparison suggests that a complex carbon chain chemistry is active in other sources and it is related to the presence of free gaseous carbon. Finally, we discuss the possible formation and destruction routes in the light of the new observations., Comment: 16 pages, 7 figure, 3 tables

We present ALMA high-angular resolution ($\sim$ 50 au) observations of the Class I binary system SVS13-A. We report images of SVS13-A in numerous interstellar complex organic molecules: CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, CH$_{\rm 3}$CHO, CH$_{\rm 3}$OCH$_{\rm 3}$, and NH$_{\rm 2}$CHO. Two hot corinos at different velocities are imaged in VLA4A (V$_{sys}$= +7.7 km s$^{-1}$) and VLA4B (V$_{sys}$= +8.5 km s$^{-1}$). From a non-LTE analysis of methanol lines we derive a gas density of 3 $\times$ 10$^8$ cm$^{-3}$, and gas temperatures of 140 K and 170 K for VLA4A and VLA4B, respectively. For the other species the column densities are derived from a LTE analysis. Formamide, which is the only N-bearing species detected in our observations, is more prominent around VLA4A, while dimethyl ether, methanol and acetaldehyde are associated with both VLA4A and VLA4B. We derive in the two hot corinos abundance ratios of $\sim$ 1 for CH$_{\rm 3}$OH, $^{13}$CH$_{\rm 3}$OH, and CH$_{\rm 3}$OCH$_{\rm 3}$, $\sim$ 2 for CH$_{\rm 3}$CHO, and $\sim$ 4 for NH$_{\rm 2}$CHO. The present dataset supports a chemical segregation between the different species inside the binary system. The emerging picture is that of an onion-like structure of the two SVS13-A hot corinos, caused by the different binding energies of the species, also supported by ad hoc quantum chemistry calculations. In addition, the comparison between molecular and dust maps suggests that the interstellar complex organic molecules emission originates from slow shocks produced by accretion streamers impacting the VLA4A and VLA4B disks and enriching the gas-phase component., Comment: 20 pages, 14 figures

We studied the line emission from CH3CN and its deuterated isotopologue CH$_2$DCN towards the prototypical Class I object SVS13-A, where the deuteration of a large number of species has already been reported. Our goal is to measure the CH$_3$CN deuteration in a Class I protostar, for the first time, in order to constrain the CH$_3$CN formation pathways and the chemical evolution from the early prestellar core and Class 0 to the evolved Class I stages. We imaged CH2DCN towards SVS13-A using the IRAM NOEMA interferometer at 3mm in the context of the Large Program SOLIS (with a spatial resolution of 1.8"x1.2"). The NOEMA images have been complemented by the CH$_3$CN and CH$_2$DCN spectra collected by the IRAM-30m Large Program ASAI, that provided an unbiased spectral survey at 3mm, 2mm, and 1.3mm. The observed line emission has been analysed using LTE and non-LTE LVG approaches. The NOEMA/SOLIS images of CH2DCN show that this species emits in an unresolved area centered towards the SVS13-A continuum emission peak, suggesting that methyl cyanide and its isotopologues are associated with the hot corino of SVS13-A, previously imaged via other iCOMs. In addition, we detected 41 and 11 ASAI transitions of CH$_3$CN and CH2DCN, respectively, which cover upper level energies (Eup) from 13 to 442 K and from 18 K to 200 K, respectively. The derived [CH2DCN]/[CH3CN] ratio is $\sim$9\%. This value is consistent with those measured towards prestellar cores and a factor 2-3 higher than those measured in Class 0 protostars. Contrarily to what expected for other molecular species, the CH3CN deuteration does not show a decrease in SVS13-A with respect to measurements in younger prestellar cores and Class 0 protostars. Finally, we discuss why our new results suggest that CH3CN was likely synthesised via gas-phase reactions and frozen onto the dust grain mantles during the cold prestellar phase., Comment: 20 pages, 2 tables, 12 figures

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed., Comment: 27 pages, 21 figures, 2 Tables, Accepted for publication in ApJ

There is evidence that the star formation process is linked to the intricate net of filaments in molecular clouds, which may be also due to gas compression from external triggers. We studied the southern region of the Perseus NGC 1333 molecular cloud, known to be heavily shaped by similar external triggers, to shed light on the process that perturbed the filament where the Class 0 IRAS4 protostars lie. We use new IRAM-NOEMA observations of SiO and CH3OH, both known to trace violent events as shocks, toward IRAS 4A as part of the Large Program Seeds Of Life in Space (SOLIS). We detected three parallel elongated ($>$6000 au) structures, called fingers, with narrow line profiles (~1.5 $km s^{-1}$) peaked at the cloud systemic velocity, tracing gas with high density (5-20 $10^5 cm^{-3}$) and high temperature (80-160 K). They are chemically different, with the northern finger traced by both SiO and CH3OH ([CH3OH]/[SiO]~160-300), while the other two only by SiO ([CH3OH]/[SiO]$<$ 40). Among various possibilities, a train of three shocks, distanced by $>$5000 yr, would be consistent with the observations if a substantial fraction of silicon, frozen onto the grain mantles, is released by the shocks.We suggest that the shock train is due to an expanding gas bubble, coming behind NGC 1333 from the southwest and clashing against the filament, where IRAS 4A lies. Finally, we propose a solution to the two-decades long debate on the nature and origin of the widespread narrow SiO emission observed in the south part of NGC 1333, namely that it is due to unresolved trains of shocks., Comment: accepted to MNRAS, stac083

We have observed the very low-mass Class 0 protostar IRAS 15398-3359 at scales ranging from 50 au to 1800 au, as part of the ALMA Large Program FAUST. We uncover a linear feature, visible in H2CO, SO, and C18O line emission, which extends from the source along a direction almost perpendicular to the known active outflow. Molecular line emission from H2CO, SO, SiO, and CH3OH further reveals an arc-like structure connected to the outer end of the linear feature and separated from the protostar, IRAS 15398-3359, by 1200 au. The arc-like structure is blue-shifted with respect to the systemic velocity. A velocity gradient of 1.2 km/s over 1200 au along the linear feature seen in the H2CO emission connects the protostar and the arc-like structure kinematically. SO, SiO, and CH3OH are known to trace shocks, and we interpret the arc-like structure as a relic shock region produced by an outflow previously launched by IRAS 15398-3359. The velocity gradient along the linear structure can be explained as relic outflow motion. The origins of the newly observed arc-like structure and extended linear feature are discussed in relation to turbulent motions within the protostellar core and episodic accretion events during the earliest stage of protostellar evolution.

We present an overview of the ALMA chemical survey of disk-outflow sources in Taurus (ALMA-DOT), a campaign devoted to the characterization of the molecular emission from partly embedded, young stars. The project aims at better understanding the gaseous products that are delivered to planets by means of high-resolution maps of assorted lines probing disks at the time of the planet formation (less than 1 Myr). Nine different molecules are surveyed by our observations of six Class I/flat-spectrum sources. A series of accompanying articles analyze specific targets and molecules. Here we describe the sample and provide a general overview of the results, focusing on the spatial distribution, column densities, and abundance ratios of H$_2$CO, CS, and CN. The results of this work are a first step toward the characterization of the disk chemical evolution that need to be complemented by further observations of less exceptional disks and customized thermo-chemical modeling., Comment: Accepted for publication by A&A, 16 pages, 9 figures

Among all the interstellar complex organic molecules (iCOMs), acetaldehyde is one of the most widely detected species. The question of its formation route(s) is, therefore, of a major interest regarding astrochemical models. In this paper, we provide an extensive review of the gas-phase formation paths that were, or are, reported in the literature and the major astrochemical databases. Four different gas-phase formation routes stand out : (1) CH$_3$OCH$_3$ + H$^+$ / CH$_3$CHOH$^+$ + e$^-$, (2) C$_2$H$_5$ + O($^3$P), (3) CH$_3$OH + CH and (4) CH$_3$CH$_2$OH + OH / CH$_3$CHOH + O($^3$P). Paths (2) and (3) were not studied neither via laboratory or theoretical works in the low temperature and density regime valid for the ISM. Thus, we carried out new accurate quantum chemistry computations. A theoretical kinetics study at low temperatures (7-300 K), adopting the RRKM scheme, was also performed. We confirm that reaction (2) is efficient in forming acetaldehyde in the 7-300 temperature range (alpha = 1.21 x 10$^{-10}$ cm$^3$ s$^{-1}$ and beta = 0.16). On the contrary, our new computations disprove the formation of acetaldehyde through reaction (3) (alpha = 1.84, 0.67 x 10$^{-13}$ cm$^3$ s$^{-1}$ and beta = -0.07, -0.95). Path (1) was showed to be inefficient too by recent computations, while path (4) was formerly considered for glycolaldehyde formation, having acetaldehyde as a by-product. In conclusions, of the four above paths only two, the (2) and (4), are potentially efficient gas-phase reaction routes for the formation of acetaldehyde and we encourage astrochemical modellers to only consider them. Comparison with astronomical observations suggest that path (4) may actually play the major role.

There is mounting evidence that the composition and structure of planetary systems are intimately linked to their birth environments. During the past decade, several spectral surveys probed the chemistry of the earliest stages of star formation and of late planet-forming disks. However, very little is known about the chemistry of intermediate protostellar stages, i.e. Class I Young Stellar Objects (YSOs), where planet formation may have already begun. We present here the first results of a 3mm spectral survey performed with the IRAM-30m telescope to investigate the chemistry of a sample of seven Class I YSOs located in the Taurus star-forming region. These sources were selected to embrace the wide diversity identified for low-mass protostellar envelope and disk systems. We present detections and upper limits of thirteen small ($N_{\rm atoms}\leq3$) C, N, O, and S carriers - namely CO, HCO$^+$, HCN, HNC, CN, N$_2$H$^+$, C$_2$H, CS, SO, HCS$^+$, C$_2$S, SO$_2$, OCS - and some of their D, $^{13}$C, $^{15}$N, $^{18}$O, $^{17}$O, and $^{34}$S isotopologues. Together, these species provide constraints on gas-phase C/N/O ratios, D- and $^{15}$N-fractionation, source temperature and UV exposure, as well as the overall S-chemistry. We find substantial evidence of chemical differentiation among our source sample, some of which can be traced back to Class I physical parameters, such as the disk-to-envelope mass ratio (proxy for Class I evolutionary stage), the source luminosity, and the UV-field strength. Overall, these first results allow us to start investigating the astrochemistry of Class I objects, however, interferometric observations are needed to differentiate envelope versus disk chemistry., Comment: 27 pages, 17 figures, 4 tables, accepted for publication in ApJ

Optical coherence tomography angiography (OCTA) is a novel non-invasive imaging modality for the visualisation of microvasculature in vivo that has encountered broad adoption in retinal research. OCTA potential in the assessment of pathological conditions and the reproducibility of studies relies on the quality of the image analysis. However, automated segmentation of parafoveal OCTA images is still an open problem. In this study, we generate the first open dataset of retinal parafoveal OCTA images with associated ground truth manual segmentations. Furthermore, we establish a standard for OCTA image segmentation by surveying a broad range of state-of-the-art vessel enhancement and binarisation procedures. We provide the most comprehensive comparison of these methods under a unified framework to date. Our results show that, for the set of images considered, deep learning architectures (U-Net and CS-Net) achieve the best performance. For applications where manually segmented data is not available to retrain these approaches, our findings suggest that optimal oriented flux is the best handcrafted filter from those considered. Furthermore, we report on the importance of preserving network structure in the segmentation to enable deep vascular phenotyping. We introduce new metrics for network structure evaluation in segmented angiograms. Our results demonstrate that segmentation methods with equal Dice score perform very differently in terms of network structure preservation. Moreover, we compare the error in the computation of clinically relevant vascular network metrics (e.g. foveal avascular zone area and vessel density) across segmentation methods. Our results show up to 25% differences in vessel density accuracy depending on the segmentation method employed. These findings should be taken into account when comparing the results of clinical studies and performing meta-analyses.

The latest developments in astrochemistry have shown how some molecular species can be used as a tool to study the early stages of the solar-type star formation process. Among them, the more relevant species are the interstellar complex organic molecules (iCOMs) and the deuterated molecules. Their analysis give us information on the present and past history of protostellar objects. Among the protostellar evolutionary stages, Class I protostars represent a perfect laboratory in which to study the initial conditions for the planet formation process. Indeed, from a physical point of view, the Class I stage is the bridge between the Class 0 phase, dominated by the accretion process, and the protoplanetary disk phase, when planets form. Despite their importance, few observations of Class I protostars exist and very little is known about their chemical content. In this paper we review the (few) existing observations of iCOMs and deuterated species in Class I protostars. In addition, we present new observations of deuterated cyanoacetylene and thioformaldehyde towards the Class I protostar SVS13-A. These new observations allow us to better understand the physical and chemical structure of SVS13-A and compare the cyanoacetylene and thioformaldehyde deuteration with other sources in different evolutionary phases., Comment: 51 pages, 10 figures

The investigation of star forming regions have enormously benefited from the recent advent of the ALMA interferometer. More specifically, the unprecedented combination of high-sensitivity and high-angular resolution provided by ALMA allows one to shed light on the jet/disk systems associated with a Sun-like mass protostar. Also astrochemistry enjoyed the possibility to analyze complex spectra obtained using large bandwidths: several interstellar Complex Organic Molecules (iCOMs; C-bearing species with at least 6 atoms) have been imaged around protostars. This in turn boosted the study of the astrochemistry at work during the earliest phases of star formation paving the way to the chemical complexity in planetary systems where Life could emerge. There is mounting evidence that the observations of iCOMs can be used as unique tool to shed light, on Solar System scales (< 50 au), on the molecular content of protostellar disk. The increase of iCOMs abundances occur only under very selective physical conditions, such as those associated low-velocity shocks found where the infalling envelope is impacting the rotating accretion disk. The imaging of these regions with simpler molecules such as CO or CS is indeed paradoxically hampered by their high abundances and consequently high line opacities which do not allow the observers to disentangle all the emitting components at these small scales. In this respect, we review the state-of-the art of the ALMA analysis about the standard Sun-like star forming region in Orion named HH 212. We show (i) how all the physical components involved in the formation of a Sun-like star can be revealed only by observing different molecular tracers, and (ii) how the observation of iCOMs emission, observed to infer the chemical composition of star forming regions, can be used also as unique tracer to image protostellar disks on Solar System scales., Comment: To be published for ACS Earth and Space Chemistry

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars is of crucial importance because it highly depends on its formation mechanisms and the physical conditions during its moment of formation. We analyse dozens of transitions from deuterated methanol isotopologues coming from various existing observational datasets from the IRAM-PdBI and ALMA sub-mm interferometers to estimate the methanol deuteration surrounding three low-mass protostars on Solar System scales. A population diagram analysis allows us to derive a [CH$_2$DOH]/[CH$_3$OH] abundance ratio of 3-6 % and a [CH$_3$OD]/[CH$_3$OH] ratio of 0.4-1.6 % in the warm inner protostellar regions. These values are ten times lower than those derived with previous single-dish observations towards these sources but they are 10-100 times higher than the methanol deuteration measured in massive hot cores. Dust temperature maps obtained from Herschel and Planck observations show that massive hot cores are located in warmer molecular clouds than low-mass sources, with temperature differences of $\sim$10 K. Comparison with the predictions of the gas-grain astrochemical model GRAINOBLE shows that such a temperature difference is sufficient to explain the different deuteration observed in low- to high-mass sources, suggesting that the physical conditions of the molecular cloud at the origin of the protostars mostly govern the present observed deuteration of methanol. The methanol deuteration measured in this work is higher by a factor of 5 than the upper limit in methanol deuteration estimated in comet Hale-Bopp, implying that an important reprocessing of the organic material would have occurred in the solar nebula during the formation of the Solar System., Comment: 16 pages, 10 figures, accepted for publication in Astronomy & Astrophysics

Young stars exhibit short-term photometric variability caused by mass accretion events from circumstellar disks, the presence of dusty warps within the inner disks, starspots that rotate across the stellar surfaces, and flares. Long-term variability also occurs owing to starspot longevity and cycles, and from changes in stellar angular momenta and activity as the stars age. We propose to observe the Carina star-forming region in different bands with a cadence of 30 minutes every night for one week per year to clarify the nature of both the short-term and long-term variability of the thousands of young stars in this region. By obtaining well-sampled multicolor lightcurves of this dense young cluster, LSST would acquire the first statistically significant data on how these objects vary on both short and long timescales. This information will allow us to relate the observed variability to stellar properties such as mass, age, binarity, and to environmental properties such as location within or exterior to the H II region, and to the presence or absence of a circumstellar disk., Comment: Contribution in response of the Call for White Papers on LSST Cadence Optimization

We present polarimetric data of CW Tau and DG Tau, two well-known Class II disk/jet systems, obtained with the Atacama Large Millimeter/submillimeter Array at 870 $\mu$m and 0."2 average resolution. In CW Tau, the total and polarized emission are both smooth and symmetric, with polarization angles almost parallel to the minor axis of the projected disk. In contrast, DG Tau displays a structured polarized emission, with an elongated brighter region in the disk's near side and a belt-like feature beyond about 0."3 from the source. At the same time the total intensity is spatially smooth, with no features. The polarization pattern, almost parallel to the minor axis in the inner region, becomes azimuthal in the outer belt, possibly because of a drop in optical depth. The polarization fraction has average values of 1.2% in CW Tau and 0.4% in DG Tau. Our results are consistent with polarization from self-scattering of the dust thermal emission. Under this hypothesis, the maximum size of the grains contributing to polarization is in the range 100 - 150 $\mu$m for CW Tau and 50 - 70 $\mu$m for DG Tau. The polarization maps combined with dust opacity estimates indicate that these grains are distributed in a geometrically thin layer in CW Tau, representing a settling in the disk midplane. Meanwhile, such settling is not yet apparent for DG Tau. These results advocate polarization studies as a fundamental complement to total emission observations, in investigations of the structure and the evolution of protoplanetary disks., Comment: 8 pages, 5 figures. Accepted for publication in ApJ Letters

Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({\rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({\rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance., Comment: 19 pages, 18 figures. Accepted by ApJ