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1. An unprecedented hydride abstraction from tricarbonyl[ethyl exo-3-[1-4-η-1,3-cyclohexadien-5-yl]propionate]iron complex

Author

Ming Chang P. Yeh, Ming Yuan Wang, and Bi Ai Sheu

Subjects
chemistry.chemical_classification, Hydride, Sodium, Organic Chemistry, chemistry.chemical_element, Decane, Ring (chemistry), Biochemistry, Medicinal chemistry, chemistry.chemical_compound, chemistry, Hexafluorophosphate, Drug Discovery, Side chain, Propionate, Organic chemistry, Derivative (chemistry)
Abstract

The addition of triphenylcarbenium hexafluorophosphate to the title complex gives tricarbonyl(η5-cyclohexadienylium)iron hexafluorophosphate with a side chain at the C-1 position of the ring. Intramolecular cyclization of the cation using sodium- or calcium- hydride generates a hetero spiro[4.5]decane derivative.

Published
1998
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