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Accurate determination of mass-loss rates from massive stars is important to understanding stellar and galactic evolution and enrichment of the interstellar medium. Large-scale structure and variability in stellar winds have significant effects on mass-loss rates. Time-series observations provide direct quantification of such variability. Observations of this nature are available for some Galactic early supergiant stars but not yet for stars in lower metallicity environments such as the Magellanic Clouds. We utilise ultraviolet spectra from the Hubble Space Telescope ULLYSES program to demonstrate that the presence of structure in stellar winds of supergiant stars at low metallicities may be discerned from single-epoch spectra. We find evidence that, for given stellar luminosities and mean stellar wind optical depths, structure is more prevalent at higher metallicities. We confirm, at Large Magellanic Cloud (0.5 Z_solar), Small Magellanic Cloud (0.2 Z_solar) and lower (0.14 -- 0.1 Z_solar) metallicities, earlier Galactic results that there does not appear to be correlation between the degree of structure in stellar winds of massive stars and stellar effective temperature. Similar lack of correlation is found with regard to terminal velocity of stellar winds. Additional and revised values for radial velocities of stars and terminal velocities of stellar winds are presented. Direct evidence of temporal variability, on timescales of several days, in stellar wind at low metallicity is found. We illustrate that narrow absorption components in wind-formed profiles of Galactic OB stellar spectra remain common in early B supergiant spectra at low metallicities, providing means for better constraining hot, massive star mass-loss rates., Comment: 18 pages plus Appendices, 9 figures plus 37 figures in Appendices. Accepted by MNRAS

B supergiants (BSGs) are evolved stars with effective temperatures between 10 to 30 kK and are important to understand massive star evolution. Located on the edge of the line-driven wind regime, the study of their atmospheres is helpful to understand phenomena such as the bi-stability jump. Key UV features of their spectra have so far not been reproduced by models for types later than B1. Here, we aim to remedy this situation via spectral analysis that accounts for wind clumping and X-rays. In addition, we investigate the evolutionary status of our sample stars based on the obtained stellar parameters. We determined parameters via quantitative spectroscopy using CMFGEN and PoWR codes. The models were compared to UV and optical data of four BSGs: HD206165, HD198478, HD53138, and HD164353. We also study the evolutionary status of our sample using GENEC and MESA tracks. When including clumping and X-rays, we find good agreements between synthetic and observed spectra for our sample stars. For the first time, we reproduced key lines in the UV. For that, we require a moderately clumped wind (f_infty > ~0.5). We also infer relative X-ray luminosities of ~10^-7.5 to 10^-8 -- lower than the typical ratio of 10^-7. Moreover, we find a possible mismatch between evolutionary and spectroscopic masses, which could be related to the mass-discrepancy problem present in other OB stars. Our results provide evidence that X-rays and clumping are needed to describe the winds of cool BSGs. However, their winds seem less structured than in earlier type stars. This aligns with observational X-rays and clumping constraints as well as recent hydrodynamical simulations. The BSGs' evolutionary status appears diverse: some objects are potentially post-red supergiants or merger products. The wind parameters provide evidence for a moderate mass-loss rate increase around the bi-stability jump. Abstract abridged, Comment: 27 pages, 22 figures, accepted for publication in A&A