Search

One of the outstanding goals of the planetary science community is to measure the present-day atmospheric composition of planets and link this back to formation. As giant planets are formed by accreting gas, ices, and rocks, constraining the relative amounts of these components is critical to understand their formation and evolution. For most known planets, including the Solar System giants, this is difficult as they reside in a temperature regime where only volatile elements (e.g., C, O) can be measured, while refractories (e.g., Fe, Ni) are condensed to deep layers of the atmosphere where they cannot be remotely probed. With temperatures allowing for even rock-forming elements to be in the gas phase, ultra-hot Jupiter atmospheres provide a unique opportunity to simultaneously probe the volatile and refractory content of giant planets. Here we directly measure and obtain bounded constraints on the abundances of volatile C and O as well as refractory Fe and Ni on the ultra-hot giant exoplanet WASP-121b. We find that ice-forming elements are comparatively enriched relative to rock-forming elements, potentially indicating that WASP-121b formed in a volatile-rich environment much farther away from the star than where it is currently located. The simultaneous constraint of ice and rock elements in the atmosphere of WASP-121b provides insights into the composition of giant planets otherwise unattainable from Solar System observations., Comment: 24 pages, 9 figures, 2 tables, Accepted for publication in The Astronomical Journal

Attempts to probe the atmospheres of rocky planets around M dwarfs present both promise and peril. While their favorable planet-to-star radius ratios enable searches for even thin secondary atmospheres, their high activity levels and high-energy outputs threaten atmosphere survival. Here, we present the 0.6--2.85$\mu$m transmission spectrum of the 1.1 Earth-radius, ~340K rocky planet TRAPPIST-1c obtained over two JWST NIRISS/SOSS transit observations. Each of the two spectra displays 100--500 ppm signatures of stellar contamination. Despite being separated by 367 days, the retrieved spot and faculae properties are consistent between the two visits, resulting in nearly identical transmission spectra. Jointly retrieving for stellar contamination and a planetary atmosphere rules out with high confidence (>3-$\sigma$) not only clear hydrogen-dominated atmospheres, but even thin, 1-bar high-mean molecular weight atmospheres rich in H$_2$O, NH$_3$, or CO (at the 2-$\sigma$ level). We find that the only atmosphere scenarios which our spectrum cannot rule out are CH$_4$- or CO$_2$-rich atmospheres, which are both unlikely to be retained when considering the photodestruction of CH$_4$ and the susceptibility of even a CO$_2$-rich atmosphere to escape given the cumulative high-energy irradiation experienced by the planet. Our results further stress the importance of robustly accounting for stellar contamination when analyzing JWST observations of exo-Earths around M dwarfs, as well as the need for high-fidelity stellar models to search for the potential signals of thin secondary atmospheres., Comment: Minor typo corrections and figure axis adjustments compared to previous version

The TRAPPIST-1 system has been extensively observed with JWST in the near-infrared with the goal of measuring atmospheric transit transmission spectra of these temperate, Earth-sized exoplanets. A byproduct of these observations has been much more precise times of transit compared with prior available data from Spitzer, HST, or ground-based telescopes. In this note we use 23 new timing measurements of all seven planets in the near-infrared from five JWST observing programs to better forecast and constrain the future times of transit in this system. In particular, we note that the transit times of TRAPPIST-1h have drifted significantly from a prior published analysis by up to tens of minutes. Our newer forecast has a higher precision, with median statistical uncertainties ranging from 7-105 seconds during JWST Cycles 4 and 5. Our expectation is that this forecast will help to improve planning of future observations of the TRAPPIST-1 planets, whereas we postpone a full dynamical analysis to future work., Comment: Submitted to AAS journals, 4 pages, 1 figure

One of the main endeavors of the field of exoplanetary sciences is the characterization of exoplanet atmospheres on a population level. The current method of choice to accomplish this task is transmission spectroscopy, where the apparent radius of a transiting exoplanet is measured at multiple wavelengths in search of atomic and molecular absorption features produced by the upper atmosphere constituents. To extract the planetary radius from a transit light curve, it is necessary to account for the decrease in luminosity away from the center of the projected stellar disk, known as the limb darkening. Physically-motivated parametrizations of the limb darkening, in particular of the quadratic form, are commonly used in exoplanet transit light-curve fitting. Here, we show that such parametrizations can introduce significant wavelength-dependent biases in the transmission spectra currently obtained with all instrument modes of the JWST, and thus have the potential to affect atmospheric inferences. To avoid such biases, we recommend the use of standard limb-darkening parametrizations with wide uninformative priors that allow for non-physical stellar intensity profiles in the transit fits, and thus for a complete and symmetrical exploration of the parameter space. We further find that fitting the light curves at the native resolution results in errors on the measured transit depths that are significantly smaller compared to light curves that are binned in wavelength before fitting, thus potentially maximizing the amount of information that can be extracted from the data., Comment: Accepted for publication in The Astronomical Journal

The LHS 6343 system consists of a resolved M-dwarf binary with an evolved, negligibly irradiated brown dwarf, LHS 6343 C, orbiting the primary star. Such brown dwarf eclipsing binaries present rare and unique opportunities to calibrate sub-stellar evolutionary and atmosphere models since mass, radius, temperature and luminosity can be directly measured. We update this brown dwarf's mass (62.6+/-2.2 MJup) and radius (0.788+/-0.043 RJup) using empirical stellar relations and a Gaia DR3 distance. We use Hubble Space Telescope/WFC3 observations of an LHS 6343 C secondary eclipse to obtain a NIR emission spectrum, which matches to a spectral type of T1.5+/-1. We combine this spectrum with existing Kepler and Spitzer/IRAC secondary eclipse photometry to perform atmospheric characterization using the ATMO-2020, Sonora-Bobcat and BT-Settl model grids. ATMO-2020 models with strong non-equilibrium chemistry yield the best fit to observations across all modelled bandpasses while predicting physical parameters consistent with Gaia-dependant analogs. BT-Settl predicts values slightly more consistent with such analogs but offers a significantly poorer fit to the WFC3 spectrum. Finally, we obtain a semi-empirical measurement of LHS 6343 C's apparent luminosity by integrating its observed and modelled spectral energy distribution. Applying knowledge of the system's distance yields a bolometric luminosity of log(Lbol/Lsun) = -4.77+/-0.03 and, applying the Stefan-Boltzmann law for the known radius, an effective temperature of 1303+/-29 K. We also use the ATMO-2020 and Sonora-Bobcat evolutionary model grids to infer an age for LHS 6343 C of 2.86 +0.40-0.33 Gyr and 3.11 +0.50-0.38 Gyr respectively., Comment: Accepted for publication in ApJ

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $\mu$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $\mu$m in the 5-12 $\mu$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$\sigma$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $\mu$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range., Comment: Published in Nature

LHS 1140 b is the second-closest temperate transiting planet to the Earth with an equilibrium temperature low enough to support surface liquid water. At 1.730$\pm$0.025 R$_\oplus$, LHS 1140 b falls within the radius valley separating H$_2$-rich mini-Neptunes from rocky super-Earths. Recent mass and radius revisions indicate a bulk density significantly lower than expected for an Earth-like rocky interior, suggesting that LHS 1140 b could either be a mini-Neptune with a small envelope of hydrogen ($\sim$0.1% by mass) or a water world (9--19% water by mass). Atmospheric characterization through transmission spectroscopy can readily discern between these two scenarios. Here, we present two JWST/NIRISS transit observations of LHS 1140 b, one of which captures a serendipitous transit of LHS 1140 c. The combined transmission spectrum of LHS 1140 b shows a telltale spectral signature of unocculted faculae (5.8 $\sigma$), covering $\sim$20% of the visible stellar surface. Besides faculae, our spectral retrieval analysis reveals tentative evidence of residual spectral features, best-fit by Rayleigh scattering from an N$_2$-dominated atmosphere (2.3 $\sigma$), irrespective of the consideration of atmospheric hazes. We also show through Global Climate Models (GCM) that H$_2$-rich atmospheres of various compositions (100$\times$, 300$\times$, 1000$\times$solar metallicity) are ruled out to $>$10 $\sigma$. The GCM calculations predict that water clouds form below the transit photosphere, limiting their impact on transmission data. Our observations suggest that LHS 1140 b is either airless or, more likely, surrounded by an atmosphere with a high mean molecular weight. Our tentative evidence of an N$_2$-rich atmosphere provides strong motivation for future transmission spectroscopy observations of LHS 1140 b., Comment: 26 pages, 14 figures, 3 tables, accepted for publication in ApJL

This STScI Working Group (WG) was charged with soliciting community feedback and evaluating the strategic planning for exoplanet science with JWST and HST given the high quality of exoplanet observations, the significantly lengthened mission lifetime for JWST, and the pronounced expansion of the field over the last decade. We were charged with identifying key science themes, providing recommendations on issues associated with optimal timing and scale of resources, as well as providing a recommended DDT concept achievable with 500 hours of JWST time. We recommend a DDT concept to survey the atmospheres of rocky-M dwarf exoplanets. It is critical to quickly survey a wide sample of such targets to ascertain if they indeed host significant atmospheres, i.e., define the cosmic shoreline, and to identify high priority targets for future follow-up. It is important for this effort to occur early in the mission lifetime. In the context of strategic planning of exoplanet observations, it is useful to estimate the expected exoplanet observational commitment over JWST's lifetime. Given the current usage associated with exoplanets, extended over 20 cycles, it is anticipated that JWST will dedicate $\approx$30,000 hours to exoplanet observations. We recommend efforts to support GO-driven programs that will contribute to this unprecedented data product of JWST. Of the $\approx$30,000 hours of anticipated JWST full-mission time dedicated to exoplanets, we expect that 1/3 of it could, and perhaps inevitably would, form a comprehensive, high S/N, panchromatic, 10$^4$ hour atmospheric survey of planets. Such an observational sample would be a legacy archive that would address a broad range of science questions across various populations of planets. It would also bridge the direct imaging and transit communities and involve a multitude of techniques to detect and characterize exoplanets., Comment: 51 pages, 7 figures. Working Group details: https://outerspace.stsci.edu/display/HPR/Strategic+Exoplanet+Initiatives+with+HST+and+JWST

Studying and understanding the physical and chemical processes that govern hot Jupiters gives us insights on the formation of these giant planets. Having a constraint on the molecular composition of their atmosphere can help us pinpoint their evolution timeline. Namely, the metal enrichment and carbon-to-oxygen ratio can give us information about where in the protoplanetary disk a giant planet may have accreted its envelope, and subsequently, indicate if it went through migration. Here we present the first analysis of the atmosphere of the hot Jupiter HIP 65Ab. Using near-infrared high-resolution observations from the IGRINS spectrograph, we detect H$_2$O and CO absorption in the dayside atmosphere of HIP 65Ab. Using a high-resolution retrieval framework, we find a CO abundance of log(CO) = $-3.85^{+0.33}_{-0.36}$, which is slightly under abundant with expectation from solar composition models. We also recover a low water abundance of log(H$_2$O) = $-4.42\pm{0.18}$, depleted by 1 order of magnitude relative to a solar-like composition. Upper limits on the abundance of all other relevant major carbon- and oxygen-bearing molecules are also obtained. Overall, our results are consistent with a sub-stellar metallicity but slightly elevated C/O. Such a composition may indicate that HIP 65Ab accreted its envelope from beyond the water snowline and underwent a disk-free migration to its current location. Alternatively, some of the oxygen on HIP 65Ab could be condensed out of the atmosphere, in which case the observed gas-phase abundances would not reflect the true bulk envelope composition., Comment: Accepted for publication in AJ

Even though sub-Neptunes likely represent the most common outcome of planet formation, their natures remain poorly understood. In particular, planets near 1.5-2.5$\,R_\oplus$ often have bulk densities that can be explained equally well with widely different compositions and interior structures, resulting in grossly divergent implications for their formation. Here, we present the full 0.6-5.2$\,\mu \mathrm{m}$ JWST NIRISS/SOSS+NIRSpec/G395H transmission spectrum of the 2.2$\,R_\oplus$ TOI-270d ($4.78\,M_\oplus$, $T_\mathrm{eq}$=350-380 K), delivering unprecedented sensitivity for atmospheric characterization in the sub-Neptune regime. We detect five vibrational bands of CH$_4$ at 1.15, 1.4, 1.7, 2.3, and 3.3$\,\mu$m (9.4$\sigma$), the signature of CO$_2$ at 4.3$\,\mu$m (4.8$\sigma$), water vapor (2.5$\sigma$), and potential signatures of SO$_2$ at 4.0$\,\mu \mathrm{m}$ and CS$_2$ at 4.6$\,\mu\mathrm{m}$. Intriguingly, we find an overall highly metal-rich atmosphere, with a mean molecular weight of $5.47_{-1.14}^{+1.25}$. We infer an atmospheric metal mass fraction of $58_{-12}^{+8}\%$ and a C/O of $0.47_{-0.19}^{+0.16}$, indicating that approximately half the mass of the outer envelope is in high-molecular-weight volatiles (H$_2$O, CH$_4$, CO, CO$_2$) rather than H$_2$/He. We introduce a sub-Neptune classification scheme and identify TOI-270d as a "miscible-envelope sub-Neptune" in which H$_2$/He is well-mixed with the high-molecular-weight volatiles in a miscible supercritical metal-rich envelope. For a fully miscible envelope, we conclude that TOI-270d's interior is $90_{-4}^{+3}\,$wt$\,\%$ rock/iron, indicating that it formed as a rocky planet that accreted a few wt % of H$_2$/He, with the overall envelope metal content explained by magma-ocean/envelope reactions without the need for significant ice accretion. TOI-270d may well be an archetype of the overall population of sub-Neptunes., Comment: 25 pages, 12 figures

Previous attempts have been made to characterize the atmospheres of directly imaged planets at low-resolution (R$\sim$10s-100s), but the presence of clouds has often led to degeneracies in the retrieved atmospheric abundances with cloud opacity and temperature structure that bias retrieved compositions. In this study, we perform retrievals on the ultra-young ($\lesssim$ 5 Myr) directly imaged planet ROXs 42B b with both a downsampled low-resolution $JHK$-band spectrum from Gemini/NIFS and Keck/OSIRIS, and a high-resolution $K$-band spectrum from pre-upgrade Keck/NIRSPAO. Using the atmospheric retrieval framework of petitRADTRANS, we analyze both data sets individually and combined. We additionally fit for the stellar abundances and other physical properties of the host stars, a young M spectral type binary, using the SPHINX model grid. We find that the measured C/O, $0.50\pm0.05$, and metallicity, [Fe/H] = $-0.67\pm0.35$, for ROXs 42B b from our high-resolution spectrum agree with that of its host stars within 1$\sigma$. The retrieved parameters from the high-resolution spectrum are also independent of our choice of cloud model. In contrast, the retrieved parameters from the low-resolution spectrum show strong degeneracies between the clouds and the retrieved metallicity and temperature structure. When we retrieve on both data sets together, we find that these degeneracies are reduced but not eliminated, and the final results remain highly sensitive to cloud modeling choices. We conclude that high-resolution spectroscopy offers the most promising path for reliably determining atmospheric compositions of directly imaged companions independent of their cloud properties., Comment: Accepted to the Astronomical Journal, 25 pages, 12 figures, 3 tables

The hot-Neptune desert is one of the most sparsely populated regions of the exoplanet parameter space, and atmosphere observations of its few residents can provide insights into how such planets have managed to survive in such an inhospitable environment. Here, we present transmission observations of LTT 9779 b, the only known hot-Neptune to have retained a significant H/He-dominated atmosphere, taken with JWST NIRISS/SOSS. The 0.6-2.85$\mu$m transmission spectrum shows evidence for muted spectral features, rejecting a perfectly flat line at >5$\sigma$. We explore water and methane-dominated atmosphere scenarios for LTT 9779 b's terminator, and retrieval analyses reveal a continuum of potential combinations of metallicity and cloudiness. Through comparisons to previous population synthesis works and our own interior structure modelling, we are able to constrain LTT 9779 b's atmosphere metallicity to 20-850x solar. Within this range of metallicity, our retrieval analyses prefer solutions with clouds at mbar pressures, regardless of whether the atmosphere is water- or methane-dominated -- though cloud-free atmospheres with metallicities >500x solar cannot be entirely ruled out. By comparing self-consistent atmosphere temperature profiles with cloud condensation curves, we find that silicate clouds can readily condense in the terminator region of LTT 9779 b. Advection of these clouds onto the day-side could explain the high day-side albedo previously inferred for this planet and be part of a feedback loop aiding the survival of LTT 9779 b's atmosphere in the hot-Neptune desert., Comment: Accepted for publication in ApJL

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

The two-planet transiting system LHS 1140 has been extensively observed since its discovery in 2017, notably with $Spitzer$, HST, TESS, and ESPRESSO, placing strong constraints on the parameters of the M4.5 host star and its small temperate exoplanets, LHS 1140 b and c. Here, we reanalyse the ESPRESSO observations of LHS 1140 with the novel line-by-line framework designed to fully exploit the radial velocity content of a stellar spectrum while being resilient to outlier measurements. The improved radial velocities, combined with updated stellar parameters, consolidate our knowledge on the mass of LHS 1140 b (5.60$\pm$0.19 M$_{\oplus}$) and LHS 1140 c (1.91$\pm$0.06 M$_{\oplus}$) with unprecedented precision of 3%. Transits from $Spitzer$, HST, and TESS are jointly analysed for the first time, allowing us to refine the planetary radii of b (1.730$\pm$0.025 R$_{\oplus}$) and c (1.272$\pm$0.026 R$_{\oplus}$). Stellar abundance measurements of refractory elements (Fe, Mg and Si) obtained with NIRPS are used to constrain the internal structure of LHS 1140 b. This planet is unlikely to be a rocky super-Earth as previously reported, but rather a mini-Neptune with a $\sim$0.1% H/He envelope by mass or a water world with a water-mass fraction between 9 and 19% depending on the atmospheric composition and relative abundance of Fe and Mg. While the mini-Neptune case would not be habitable, a water-abundant LHS 1140 b potentially has habitable surface conditions according to 3D global climate models, suggesting liquid water at the substellar point for atmospheres with relatively low CO$_2$ concentration, from Earth-like to a few bars., Comment: 31 pages, 18 figures, accepted for publication in ApJL

The JWST Early Release Observations (ERO) included a NIRISS/SOSS (0.6-2.8$\,\mu$m) transit of the $\sim\,$850$\,$K Saturn-mass exoplanet HAT-P-18$\,$b. Initial analysis of these data reported detections of water, escaping helium, and haze. However, active K dwarfs like HAT-P-18 possess surface heterogeneities $-$ starspots and faculae $-$ that can complicate the interpretation of transmission spectra, and indeed, a spot-crossing event is present in HAT-P-18$\,$b's NIRISS/SOSS light curves. Here, we present an extensive reanalysis and interpretation of the JWST ERO transmission spectrum of HAT-P-18$\,$b, as well as HST/WFC3 and $\textit{Spitzer}$/IRAC transit observations. We detect H$_2$O (12.5$\,\sigma$), CO$_2$ (7.3$\,\sigma$), a cloud deck (7.4$\,\sigma$), and unocculted starspots (5.8$\,\sigma$), alongside hints of Na (2.7$\,\sigma$). We do not detect the previously reported CH$_4$ ($\log$ CH$_4$ $<$ -6 to 2$\,\sigma$). We obtain excellent agreement between three independent retrieval codes, which find a sub-solar H$_2$O abundance ($\log$ H$_2$O $\approx -4.4 \pm 0.3$). However, the inferred CO$_2$ abundance ($\log$ CO$_2$ $\approx -4.8 \pm 0.4$) is significantly super-solar and requires further investigation into its origin. We also introduce new stellar heterogeneity considerations by fitting for the active regions' surface gravities $-$ a proxy for the effects of magnetic pressure. Finally, we compare our JWST inferences to those from HST/WFC3 and $\textit{Spitzer}$/IRAC. Our results highlight the exceptional promise of simultaneous planetary atmosphere and stellar heterogeneity constraints in the era of JWST and demonstrate that JWST transmission spectra may warrant more complex treatments of the transit light source effect.

Over the last decade, precise exoplanet transmission spectroscopy has revealed the atmospheres of dozens of exoplanets, driven largely by observatories like the Hubble Space Telescope. One major discovery has been the ubiquity of atmospheric aerosols, often blocking access to exoplanet chemical inventories. Tentative trends have been identified, showing that the clarity of planetary atmospheres may depend on equilibrium temperature. Previous work has often grouped dissimilar planets together in order to increase the statistical power of any trends, but it remains unclear from observed transmission spectra whether these planets exhibit the same atmospheric physics and chemistry. We present a re-analysis of a smaller, more physically similar sample of 15 exo-Neptune transmission spectra across a wide range of temperatures (200-1000 K). Using condensation cloud and hydrocarbon haze models, we find that the exo-Neptune population is best described by low cloud sedimentation efficiency ($\mathrm{f_{sed}}\sim0.1$) and high metallicity ($100\times$ Solar). There is an intrinsic scatter of $\sim0.5$ scale height, perhaps evidence of stochasticity in these planets' formation processes. Observers should expect significant attenuation in transmission spectra of Neptune-size exoplanets, up to 6 scale heights for equilibrium temperatures between 500 and 800 K. With JWST's greater wavelength sensitivity, colder (<500 K) planets should be high-priority targets given their clearer atmospheres, and the need to distinguish between the "super-puffs" and more typical gas-dominated planets., Comment: Published in ApJL. 11 pages, 3 figures, 4 tables

We present the first analysis of JWST near-infrared spectroscopy of stellar flares from TRAPPIST-1 during transits of rocky exoplanets. Four flares were observed from 0.6--2.8 $\mu$m with NIRISS and 0.6--3.5 $\mu$m with NIRSpec during transits of TRAPPIST-1b, f, and g. We discover P$\alpha$ and Br$\beta$ line emission and characterize flare continuum at wavelengths from 1--3.5 $\mu$m for the first time. Observed lines include H$\alpha$, P$\alpha$-P$\epsilon$, Br$\beta$, He I $\lambda$0.7062$\mu$m, two Ca II infrared triplet (IRT) lines, and the He I IRT. We observe a reversed Paschen decrement from P$\alpha$-P$\gamma$ alongside changes in the light curve shapes of these lines. The continuum of all four flares is well-described by blackbody emission with an effective temperature below 5300 K, lower than temperatures typically observed at optical wavelengths. The 0.6--1 $\mu$m spectra were convolved with the TESS response, enabling us to measure the flare rate of TRAPPIST-1 in the TESS bandpass. We find flares of 10$^{30}$ erg large enough to impact transit spectra occur at a rate of 3.6$\substack{+2.1 \\ -1.3}$ flare d$^{-1}$, $\sim$10$\times$ higher than previous predictions from K2. We measure the amount of flare contamination at 2 $\mu$m for the TRAPPIST-1b and f transits to be 500$\pm$450 and 2100$\pm$400 ppm, respectively. We find up to 80% of flare contamination can be removed, with mitigation most effective from 1.0--2.4 $\mu$m. These results suggest transits affected by flares may still be useful for atmospheric characterization efforts., Comment: 29 pages, 17 figures, 3 tables, accepted to The Astrophysical Journal

Recent work on the characterization of small exoplanets has allowed us to accumulate growing evidence that the sub-Neptunes with radii greater than $\sim2.5\,R_\oplus$ often host H$_2$/He-dominated atmospheres both from measurements of their low bulk densities and direct detections of their low mean-molecular-mass atmospheres. However, the smaller sub-Neptunes in the 1.5-2.2 R$_\oplus$ size regime are much less understood, and often have bulk densities that can be explained either by the H$_2$/He-rich scenario, or by a volatile-dominated composition known as the "water world" scenario. Here, we report the detection of water vapor in the transmission spectrum of the $1.96\pm0.08$ R$_\oplus$ sub-Neptune GJ9827d obtained with the Hubble Space Telescope. We observed 11 HST/WFC3 transits of GJ9827d and find an absorption feature at 1.4$\mu$m in its transit spectrum, which is best explained (at 3.39$\sigma$) by the presence of water in GJ9827d's atmosphere. We further show that this feature cannot be caused by unnoculted star spots during the transits by combining an analysis of the K2 photometry and transit light-source effect retrievals. We reveal that the water absorption feature can be similarly well explained by a small amount of water vapor in a cloudy H$_2$/He atmosphere, or by a water vapor envelope on GJ9827d. Given that recent studies have inferred an important mass-loss rate ($>0.5\,$M$_\oplus$/Gyr) for GJ9827d making it unlikely to retain a H-dominated envelope, our findings highlight GJ9827d as a promising water world candidate that could host a volatile-dominated atmosphere. This water detection also makes GJ9827d the smallest exoplanet with an atmospheric molecular detection to date., Comment: Published in ApJL, 11 pages, 6 figures

TRAPPIST-1 is a nearby system of seven Earth-sized, temperate, rocky exoplanets transiting a Jupiter-sized M8.5V star, ideally suited for in-depth atmospheric studies. Each TRAPPIST-1 planet has been observed in transmission both from space and from the ground, confidently rejecting cloud-free, hydrogen-rich atmospheres. Secondary eclipse observations of TRAPPIST-1 b with JWST/MIRI are consistent with little to no atmosphere given the lack of heat redistribution. Here we present the first transmission spectra of TRAPPIST-1 b obtained with JWST/NIRISS over two visits. The two transmission spectra show moderate to strong evidence of contamination from unocculted stellar heterogeneities, which dominates the signal in both visits. The transmission spectrum of the first visit is consistent with unocculted starspots and the second visit exhibits signatures of unocculted faculae. Fitting the stellar contamination and planetary atmosphere either sequentially or simultaneously, we confirm the absence of cloud-free hydrogen-rich atmospheres, but cannot assess the presence of secondary atmospheres. We find that the uncertainties associated with the lack of stellar model fidelity are one order of magnitude above the observation precision of 89 ppm (combining the two visits). Without affecting the conclusion regarding the atmosphere of TRAPPIST-1 b, this highlights an important caveat for future explorations, which calls for additional observations to characterize stellar heterogeneities empirically and/or theoretical works to improve model fidelity for such cool stars. This need is all the more justified as stellar contamination can affect the search for atmospheres around the outer, cooler TRAPPIST-1 planets for which transmission spectroscopy is currently the most efficient technique., Comment: 26 pages, 11 figures, accepted for publication in The Astrophysical Journal Letters

Carbon monoxide was recently reported in the atmosphere of the hot Jupiter WASP-39b using the NIRSpec PRISM transit observation of this planet, collected as part of the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) Program. This detection, however, could not be confidently confirmed in the initial analysis of the higher resolution observations with NIRSpec G395H disperser. Here we confirm the detection of CO in the atmosphere of WASP-39b using the NIRSpec G395H data and cross-correlation techniques. We do this by searching for the CO signal in the unbinned transmission spectrum of the planet between 4.6 and 5.0 $\mu$m, where the contribution of CO is expected to be higher than that of other anticipated molecules in the planet's atmosphere. Our search results in a detection of CO with a cross-correlation function (CCF) significance of $6.6 \sigma$ when using a template with only ${\rm ^{12}C^{16}O}$ lines. The CCF significance of the CO signal increases to $7.5 \sigma$ when including in the template lines from additional CO isotopologues, with the largest contribution being from ${\rm ^{13}C^{16}O}$. Our results highlight how cross-correlation techniques can be a powerful tool for unveiling the chemical composition of exoplanetary atmospheres from medium-resolution transmission spectra, including the detection of isotopologues., Comment: Accepted for publication in The Astrophysical Journal Letters

Ultra-hot Jupiters are tidally locked with their host stars dividing their atmospheres into a hot dayside and a colder nightside. As the planet moves through transit, different regions of the atmosphere rotate into view revealing different chemical regimes. High-resolution spectrographs can observe asymmetries and velocity shifts, and offer the possibility for time-resolved spectroscopy. In this study, we search for other atoms and molecules in the planet`s transmission spectrum and investigate asymmetric signals. We analyse and combine eight transits of the ultra-hot Jupiter WASP-189 b taken with the HARPS, HARPS-N, ESPRESSO and MAROON-X high-resolution spectrographs. Using the cross-correlation technique, we search for neutral and ionised atoms, and oxides and compare the obtained signals to model predictions. We report significant detections for H, Na, Mg, Ca, Ca+, Ti, Ti+, TiO, V, Cr, Mn, Fe, Fe+, Ni, Sr, Sr+, and Ba+. Of these, Sr, Sr+, and Ba+ are detected for the first time in the transmission spectrum of WASP-189 b. In addition, we robustly confirm the detection of titanium oxide based on observations with HARPS and HARPS-N using the follow-up observations performed with MAROON-X and ESPRESSO. By fitting the orbital traces of the detected species by means of time-resolved spectroscopy using a Bayesian framework, we infer posterior distributions for orbital parameters as well as lineshapes. Our results indicate that different species must originate from different regions of the atmosphere to be able to explain the observed time dependence of the signals. Throughout the course of the transit, most signal strengths are expected to increase due to the larger atmospheric scale height at the hotter trailing terminator. For some species, however, the signals are instead observed to weaken due to ionisation for atoms and their ions, or the dissociation of molecules on the dayside., Comment: 38 pages, 34 figures, published in A&A on October 24, 2023

The abundance of refractory elements in giant planets can provide key insights into their formation histories. Due to the Solar System giants' low temperatures, refractory elements condense below the cloud deck limiting sensing capabilities to only highly volatile elements. Recently, ultra-hot giant exoplanets have allowed for some refractory elements to be measured showing abundances broadly consistent with the solar nebula with titanium likely condensed out of the photosphere. Here we report precise abundance constraints of 14 major refractory elements on the ultra-hot giant planet WASP-76b that show distinct deviations from proto-solar, and a sharp onset in condensation temperature. In particular, we find nickel to be enriched, a possible sign of the accretion of a differentiated object's core during the planet's evolution. Elements with condensation temperatures below 1,550 K otherwise closely match those of the Sun before sharply transitioning to being strongly depleted above 1,550 K, well explained by nightside cold-trapping. We further unambiguously detect vanadium oxide on WASP-76b, a molecule long hypothesized to drive atmospheric thermal inversions, and also observe a global east-west asymmetry in its absorption signals. Overall, our findings indicate that giant planets have a mostly stellar-like refractory elemental content and suggest that temperature sequences of hot Jupiter spectra can show abrupt transitions wherein a mineral species is either present, or completely absent if a cold-trap exists below its condensation temperature., Comment: Published online in Nature on June 14, 2023

The newly operational JWST offers the potential to study the atmospheres of distant worlds with precision that has not been achieved before. One of the first exoplanets observed by JWST in the summer of 2022 was WASP-96 b, a hot-Saturn orbiting a G8 star. As part of the Early Release Observations program, one transit of WASP-96 b was observed with NIRISS/SOSS to capture its transmission spectrum from 0.6-2.85 microns. In this work, we utilise four retrieval frameworks to report precise and robust measurements of WASP-96 b's atmospheric composition. We constrain the logarithmic volume mixing ratios of multiple chemical species in its atmosphere, including: H$_2$O = $-3.59 ^{+ 0.35 }_{- 0.35 }$, CO$_2$ = $-4.38 ^{+ 0.47 }_{- 0.57 }$ and K = $-8.04 ^{+ 1.22 }_{- 1.71 }$. Notably, our results offer a first abundance constraint on potassium in WASP-96 b's atmosphere, and important inferences on carbon-bearing species such as CO$_2$ and CO. Our short wavelength NIRISS/SOSS data are best explained by the presence of an enhanced Rayleigh scattering slope, despite previous inferences of a clear atmosphere - although we find no evidence for a grey cloud deck. Finally, we explore the data resolution required to appropriately interpret observations using NIRISS/SOSS. We find that our inferences are robust against different binning schemes. That is, from low $R = 125$ to the native resolution of the instrument, the bulk atmospheric properties of the planet are consistent. Our systematic analysis of these exquisite observations demonstrates the power of NIRISS/SOSS to detect and constrain multiple molecular and atomic species in the atmospheres of hot giant planets., Comment: 12 pages, 5 Figures. Accepted for publication in MNRAS. Companion paper to Radica et al., 2023

Carbon monoxide (CO) is predicted to be the dominant carbon-bearing molecule in giant planet atmospheres, and, along with water, is important for discerning the oxygen and therefore carbon-to-oxygen ratio of these planets. The fundamental absorption mode of CO has a broad double-branched structure composed of many individual absorption lines from 4.3 to 5.1 $\mathrm{\mu}$m, which can now be spectroscopically measured with JWST. Here we present a technique for detecting the rotational sub-band structure of CO at medium resolution with the NIRSpec G395H instrument. We use a single transit observation of the hot Jupiter WASP-39b from the JWST Transiting Exoplanet Community Early Release Science (JTEC ERS) program at the native resolution of the instrument ($R \,{\sim} 2700$) to resolve the CO absorption structure. We robustly detect absorption by CO, with an increase in transit depth of 264 $\pm$ 68 ppm, in agreement with the predicted CO contribution from the best-fit model at low resolution. This detection confirms our theoretical expectations that CO is the dominant carbon-bearing molecule in WASP-39b's atmosphere, and further supports the conclusions of low C/O and super-solar metallicities presented in the JTEC ERS papers for WASP-39b., Comment: 11 pages, 5 figures, accepted for publication in ApJL

Precise measurements of chemical abundances in planetary atmospheres are necessary to constrain the formation histories of exoplanets. A recent study of WASP-127b, a close-in puffy sub-Saturn orbiting its solar-type host star in 4.2 d, using HST and Spitzer revealed a feature-rich transmission spectrum with strong excess absorption at 4.5 um. However, the limited spectral resolution and coverage of these instruments could not distinguish between CO and/or CO2 absorption causing this signal, with both low and high C/O ratio scenarios being possible. Here we present near-infrared (0.9--2.5 um) transit observations of WASP-127 b using the high-resolution SPIRou spectrograph, with the goal to disentangle CO from CO2 through the 2.3 um CO band. With SPIRou, we detect H2O at a t-test significance of 5.3 sigma and observe a tentative (3 sigma) signal consistent with OH absorption. From a joint SPIRou + HST + Spitzer retrieval analysis, we rule out a CO-rich scenario by placing an upper limit on the CO abundance of log10[CO]<-4.0, and estimate a log10[CO2] of -3.7^(+0.8)_(-0.6), which is the level needed to match the excess absorption seen at 4.5um. We also set abundance constraints on other major C-, O-, and N-bearing molecules, with our results favoring low C/O (0.10^(+0.10)_(-0.06)), disequilibrium chemistry scenarios. We further discuss the implications of our results in the context of planet formation. Additional observations at high and low-resolution will be needed to confirm these results and better our understanding of this unusual world., Comment: 23 pages, 13 figures, Submitted for publication in the Monthly Notice of the Royal Astronomical Society

The population of planets smaller than approximately $1.7~R_\oplus$ is widely interpreted as consisting of rocky worlds, generally referred to as super-Earths. This picture is largely corroborated by radial-velocity (RV) mass measurements for close-in super-Earths but lacks constraints at lower insolations. Here we present the results of a detailed study of the Kepler-138 system using 13 Hubble and Spitzer transit observations of the warm-temperate $1.51\pm0.04~R_\oplus$ planet Kepler-138 d ($T_{\mathrm{eq, A_B=0.3}}$~350 K) combined with new Keck/HIRES RV measurements of its host star. We find evidence for a volatile-rich "water world" nature of Kepler-138 d, with a large fraction of its mass contained in a thick volatile layer. This finding is independently supported by transit timing variations, RV observations ($M_d=2.1_{-0.7}^{+0.6}~M_\oplus$), as well as the flat optical/IR transmission spectrum. Quantitatively, we infer a composition of $11_{-4}^{+3}$\% volatiles by mass or ~51% by volume, with a 2000 km deep water mantle and atmosphere on top of a core with an Earth-like silicates/iron ratio. Any hypothetical hydrogen layer consistent with the observations ($<0.003~M_\oplus$) would have swiftly been lost on a ~10 Myr timescale. The bulk composition of Kepler-138 d therefore resembles those of the icy moons rather than the terrestrial planets in the solar system. We conclude that not all super-Earth-sized planets are rocky worlds, but that volatile-rich water worlds exist in an overlapping size regime, especially at lower insolations. Finally, our photodynamical analysis also reveals that Kepler-138 c ($R_c=1.51 \pm 0.04~R_\oplus$, $M_c=2.3_{-0.5}^{+0.6}~M_\oplus$) is a slightly warmer twin of Kepler-138 d, i.e., another water world in the same system, and we infer the presence of Kepler-138 e, a likely non-transiting planet at the inner edge of the habitable zone., Comment: Published in Nature Astronomy. 4 main figures, 10 extended data figures, 13 supplementary figures. 4 tables

A star's obliquity with respect to its planetary system can provide us with insight into the system's formation and evolution, as well as hinting at the presence of additional objects in the system. However, M dwarfs, which are the most promising targets for atmospheric follow-up, are underrepresented in terms of obliquity characterization surveys due to the challenges associated with making precise measurements. In this paper, we use the extreme-precision radial velocity spectrograph MAROON-X to measure the obliquity of the late M dwarf TRAPPIST-1. With the Rossiter-McLaughlin effect, we measure a system obliquity of $-2^{+17}_{-19}$ degrees and a stellar rotational velocity of 2.1 $\pm$ 0.3 km s$^{-1}$. We were unable to detect stellar surface differential rotation, and we found that a model in which all planets share the same obliquity was favored by our current data. We were unable to make a detection of the signatures of the planets using Doppler tomography, which is likely a result of the both the slow rotation of the star and the low SNR of the data. Overall, TRAPPIST-1 appears to have a low obliquity, which could imply that the system has a low primordial obliquity. It also appears to be a slow rotator, which is consistent with past characterizations of the system and estimates of the star's rotation period. The MAROON-X data allow for a precise measurement of the stellar obliquity through the Rossiter-McLaughlin effect, highlighting the capabilities of MAROON-X and its ability to make high-precision RV measurements around late, dim stars., Comment: 18 pages, 6 figures, submitted to AJ

The Kepler and TESS missions revealed a remarkable abundance of sub-Neptune exoplanets. Despite this abundance, our understanding of the nature and compositional diversity of sub-Neptunes remains limited, to a large part because atmospheric studies via transmission spectroscopy almost exclusively aimed for low-density sub-Neptunes and even those were often affected by high-altitude clouds. The recent TESS discovery of the hot, dense TOI-824b ($2.93\,R_\oplus$ and $18.47\,M_\oplus$) opens a new window into sub-Neptune science by enabling the study of a dense sub-Neptune via secondary eclipses. Here, we present the detection of TOI-824b's hot day side via Spitzer secondary eclipse observations in the $3.6$ and $4.5\,\mathrm{\mu m}$ channels, combined with a reanalysis of its interior composition. The measured eclipse depths (142$^{+57}_{-52}$ and 245$^{+75}_{-77}$ ppm) and brightness temperatures (1463$^{+183}_{-196}$ and 1484$^{+180}_{-202}$ K) indicate a poor heat redistribution ($f>$ 0.49) and a low Bond albedo (A$_{B}<$ 0.26). We conclude that TOI-824b could be an "exposed Neptune mantle": a planet with a Neptune-like water-rich interior that never accreted a hydrogen envelope or that subsequently lost it. The hot day-side temperature is then naturally explained by a high-metallicity envelope re-emitting the bulk of the incoming radiation from the day side. TOI-824b's density is also consistent with a massive rocky core that accreted up to 1% of hydrogen, but the observed eclipse depths favor our high-metallicity GCM simulation to a solar-metallicity GCM simulation with a likelihood ratio of 7:1. The new insights into TOI-824b's nature suggest that the sub-Neptune population may be more diverse than previously thought, with some of the dense hot sub-Neptunes potentially not hosting a hydrogen-rich envelope as generally assumed for sub-Neptunes., Comment: Accepted for publication in The Astrophysical Journal, 14 pages, 5 figures

Transmission spectroscopy provides insight into the atmospheric properties and consequently the formation history, physics, and chemistry of transiting exoplanets. However, obtaining precise inferences of atmospheric properties from transmission spectra requires simultaneously measuring the strength and shape of multiple spectral absorption features from a wide range of chemical species. This has been challenging given the precision and wavelength coverage of previous observatories. Here, we present the transmission spectrum of the Saturn-mass exoplanet WASP-39b obtained using the SOSS mode of the NIRISS instrument on the JWST. This spectrum spans $0.6 - 2.8 \mu$m in wavelength and reveals multiple water absorption bands, the potassium resonance doublet, as well as signatures of clouds. The precision and broad wavelength coverage of NIRISS-SOSS allows us to break model degeneracies between cloud properties and the atmospheric composition of WASP-39b, favoring a heavy element enhancement ("metallicity") of $\sim 10 - 30 \times$ the solar value, a sub-solar carbon-to-oxygen (C/O) ratio, and a solar-to-super-solar potassium-to-oxygen (K/O) ratio. The observations are best explained by wavelength-dependent, non-gray clouds with inhomogeneous coverage of the planet's terminator., Comment: 48 pages, 12 figures, 2 tables. Under review at Nature

Photochemistry is a fundamental process of planetary atmospheres that regulates the atmospheric composition and stability. However, no unambiguous photochemical products have been detected in exoplanet atmospheres to date. Recent observations from the JWST Transiting Exoplanet Early Release Science Program found a spectral absorption feature at 4.05 $\mu$m arising from SO$_2$ in the atmosphere of WASP-39b. WASP-39b is a 1.27-Jupiter-radii, Saturn-mass (0.28 M$_J$) gas giant exoplanet orbiting a Sun-like star with an equilibrium temperature of $\sim$1100 K. The most plausible way of generating SO$_2$ in such an atmosphere is through photochemical processes. Here we show that the SO$_2$ distribution computed by a suite of photochemical models robustly explains the 4.05 $\mu$m spectral feature identified by JWST transmission observations with NIRSpec PRISM (2.7$\sigma$) and G395H (4.5$\sigma$). SO$_2$ is produced by successive oxidation of sulphur radicals freed when hydrogen sulphide (H$_2$S) is destroyed. The sensitivity of the SO$_2$ feature to the enrichment of the atmosphere by heavy elements (metallicity) suggests that it can be used as a tracer of atmospheric properties, with WASP-39b exhibiting an inferred metallicity of $\sim$10$\times$ solar. We further point out that SO$_2$ also shows observable features at ultraviolet and thermal infrared wavelengths not available from the existing observations., Comment: 39 pages, 14 figures, accepted to be published in Nature

Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is a fundamental step towards constraining the dominant chemical processes at work and, if in equilibrium, revealing planet formation histories. Transmission spectroscopy provides the necessary means by constraining the abundances of oxygen- and carbon-bearing species; however, this requires broad wavelength coverage, moderate spectral resolution, and high precision that, together, are not achievable with previous observatories. Now that JWST has commenced science operations, we are able to observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here we report time-series observations of the transiting exoplanet WASP-39b using JWST's Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and short-wavelength photometric light curves span 2.0 - 4.0 $\mu$m, exhibit minimal systematics, and reveal well-defined molecular absorption features in the planet's spectrum. Specifically, we detect gaseous H$_2$O in the atmosphere and place an upper limit on the abundance of CH$_4$. The otherwise prominent CO$_2$ feature at 2.8 $\mu$m is largely masked by H$_2$O. The best-fit chemical equilibrium models favour an atmospheric metallicity of 1-100$\times$ solar (i.e., an enrichment of elements heavier than helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred high metallicity and low C/O ratio may indicate significant accretion of solid materials during planet formation or disequilibrium processes in the upper atmosphere., Comment: 35 pages, 13 figures, 3 tables, Nature, accepted

Measuring the abundances of carbon and oxygen in exoplanet atmospheres is considered a crucial avenue for unlocking the formation and evolution of exoplanetary systems. Access to an exoplanet's chemical inventory requires high-precision observations, often inferred from individual molecular detections with low-resolution space-based and high-resolution ground-based facilities. Here we report the medium-resolution (R$\sim$600) transmission spectrum of an exoplanet atmosphere between 3-5 $\mu$m covering multiple absorption features for the Saturn-mass exoplanet WASP-39b, obtained with JWST NIRSpec G395H. Our observations achieve 1.46x photon precision, providing an average transit depth uncertainty of 221 ppm per spectroscopic bin, and present minimal impacts from systematic effects. We detect significant absorption from CO$_2$ (28.5$\sigma$) and H$_2$O (21.5$\sigma$), and identify SO$_2$ as the source of absorption at 4.1 $\mu$m (4.8$\sigma$). Best-fit atmospheric models range between 3 and 10x solar metallicity, with sub-solar to solar C/O ratios. These results, including the detection of SO$_2$, underscore the importance of characterising the chemistry in exoplanet atmospheres, and showcase NIRSpec G395H as an excellent mode for time series observations over this critical wavelength range., Comment: 44 pages, 11 figures, 3 tables. Resubmitted after revision to Nature

Transiting exoplanets orbiting young nearby stars are ideal laboratories for testing theories of planet formation and evolution. However, to date only a handful of stars with age <1 Gyr have been found to host transiting exoplanets. Here we present the discovery and validation of a sub-Neptune around HD 18599, a young (300 Myr), nearby (d=40 pc) K star. We validate the transiting planet candidate as a bona fide planet using data from the TESS, Spitzer, and Gaia missions, ground-based photometry from IRSF, LCO, PEST, and NGTS, speckle imaging from Gemini, and spectroscopy from CHIRON, NRES, FEROS, and Minerva-Australis. The planet has an orbital period of 4.13 d, and a radius of 2.7Rearth. The RV data yields a 3-sigma mass upper limit of 30.5Mearth which is explained by either a massive companion or the large observed jitter typical for a young star. The brightness of the host star (V~9 mag) makes it conducive to detailed characterization via Doppler mass measurement which will provide a rare view into the interior structure of young planets., Comment: submitted to MNRAS

Photometric and spectral variability of brown dwarfs probes heterogeneous temperature and cloud distribution and traces the atmospheric circulation patterns. We present a new 42-hr Hubble Space Telescope (HST) Wide Field Camera 3 G141 spectral time series of VHS 1256$-$1257 b, a late L-type planetary-mass companion that has been shown to have one of the highest variability amplitudes among substellar objects. The light curve is rapidly evolving and best-fit by a combination of three sine waves with different periods and a linear trend. The amplitudes of the sine waves and the linear slope vary with wavelength, and the corresponding spectral variability patterns match the predictions by models invoking either heterogeneous clouds or thermal profile anomalies. Combining these observations with previous HST monitoring data, we find that the peak-to-valley flux difference is $33\pm2$% with an even higher amplitude reaching 38% in the $J$ band, the highest amplitude ever observed in a substellar object. The observed light curve can be explained by maps that are composed of zonal waves, spots, or a mixture of the two. Distinguishing the origin of rapid light curve evolution requires additional long-term monitoring. Our findings underscore the essential role of atmospheric dynamics in shaping brown dwarf atmospheres and highlight VHS 1256$-$1257 b as one of the most favorable targets for studying atmospheres, clouds, and atmospheric circulation of planets and brown dwarfs., Comment: Accepted for publicaton in AJ. 18 pages main text, 13 figures

Carbon dioxide (CO2) is a key chemical species that is found in a wide range of planetary atmospheres. In the context of exoplanets, CO2 is an indicator of the metal enrichment (i.e., elements heavier than helium, also called "metallicity"), and thus formation processes of the primary atmospheres of hot gas giants. It is also one of the most promising species to detect in the secondary atmospheres of terrestrial exoplanets. Previous photometric measurements of transiting planets with the Spitzer Space Telescope have given hints of the presence of CO2 but have not yielded definitive detections due to the lack of unambiguous spectroscopic identification. Here we present the detection of CO2 in the atmosphere of the gas giant exoplanet WASP-39b from transmission spectroscopy observations obtained with JWST as part of the Early Release Science Program (ERS). The data used in this study span 3.0 to 5.5 {\mu}m in wavelength and show a prominent CO2 absorption feature at 4.3 {\mu}m (26{\sigma} significance). The overall spectrum is well matched by one-dimensional, 10x solar metallicity models that assume radiative-convective-thermochemical equilibrium and have moderate cloud opacity. These models predict that the atmosphere should have water, carbon monoxide, and hydrogen sulfide in addition to CO2, but little methane. Furthermore, we also tentatively detect a small absorption feature near 4.0 {\mu}m that is not reproduced by these models., Comment: 27 pages, 6 figures, Accepted for publication in Nature, data and models available at https://doi.10.5281/zenodo.6959427

The increasing numbers of rocky, terrestrial exoplanets known to orbit nearby stars (especially M dwarfs) has drawn increased attention to the possibility of studying these planets' surface properties, and atmospheric compositions & escape histories. Here we report the detection of the secondary eclipse of the terrestrial exoplanet GJ1252b using the Spitzer Space Telescope's IRAC2 4.5 micron channel. We measure an eclipse depth of 149(+25/-32) ppm, corresponding to a day-side brightness temperature of 1410(+91/-125) K and consistent with the prediction for no atmosphere. Comparing our measurement to atmospheric models indicates that GJ1252b has a surface pressure of <10 bar, substantially less than Venus. Assuming energy-limited escape, even a 100 bar atmosphere would be lost in <1 Myr, far shorter than estimated age of 3.9+/-0.4 Gyr. The expected mass loss could be overcome by mantle outgassing, but only if the mantle's carbon content were >7% by mass - over two orders of magnitude greater than that found in Earth. We therefore conclude that GJ1252b has no significant atmosphere. Model spectra with granitoid or feldspathic surface composition, but with no atmosphere, are disfavored at >2 sigma. The eclipse occurs just +1.4(+2.8/-1.0) min after orbital phase 0.5, indicating e cos omega=+0.0025(+0.0049/-0.0018), consistent with a circular orbit. Tidal heating is therefore likely to be negligible to GJ1252b's global energy budget. Finally, we also analyze additional, unpublished TESS transit photometry of GJ1252b which improves the precision of the transit ephemeris by a factor of ten, provides a more precise planetary radius of 1.180+/-0.078 R_E, and rules out any transit timing variations with amplitudes <1 min., Comment: ApJL in press. 16 pages, 12 figures, 10 eclipses, 1 bandpass. Models will be available at journal website

Exploring the properties of exoplanets near or inside the radius valley provides insights on the transition from the rocky super-Earths to the larger, hydrogen-rich atmosphere mini-Neptunes. Here, we report the discovery of TOI-1452 b, a transiting super-Earth ($R_{\rm p} = 1.67 \pm 0.07$ R$_{\oplus}$) in an 11.1--day temperate orbit ($T_{\rm eq} = 326 \pm 7$ K) around the primary member ($H = 10.0$, $T_{\rm eff} = 3185 \pm 50$ K) of a nearby visual binary M dwarf. The transits were first detected by TESS, then successfully isolated between the two $3.2^{\prime\prime}$ companions with ground-based photometry from OMM and MuSCAT3. The planetary nature of TOI-1452 b was established through high-precision velocimetry with the near-infrared SPIRou spectropolarimeter as part of the ongoing SPIRou Legacy Survey. The measured planetary mass ($4.8 \pm 1.3$ M$_{\oplus}$) and inferred bulk density ($5.6^{+1.8}_{-1.6}$ g/cm$^3$) is suggestive of a rocky core surrounded by a volatile-rich envelope. More quantitatively, the mass and radius of TOI-1452 b, combined with the stellar abundance of refractory elements (Fe, Mg and Si) measured by SPIRou, is consistent with a core mass fraction of $18\pm6$ % and a water mass fraction of $22^{+21}_{-13}$%. The water world candidate TOI-1452 b is a prime target for future atmospheric characterization with JWST, featuring a Transmission Spectroscopy Metric similar to other well-known temperate small planets such as LHS 1140 b and K2-18 b. The system is located near Webb's northern Continuous Viewing Zone, implying that is can be followed at almost any moment of the year., Comment: Published in The Astronomical Journal

We present high-resolution dayside thermal emission observations of the exoplanet KELT-20b/MASCARA-2b using the MAROON-X spectrograph. Applying the cross-correlation method with both empirical and theoretical masks and a retrieval analysis, we confirm previous detections of Fe\,\textsc{i} emission lines and we detect Ni\,\textsc{i} for the first time in the planet (at 4.7$\sigma$ confidence). We do not see evidence for additional species in the MAROON-X data, including notably predicted thermal inversion agents TiO and VO, their atomic constituents Ti\,\textsc{i} and V\,\textsc{i}, and previously claimed species Fe\,\textsc{ii} and Cr\,\textsc{i}. We also perform a joint retrieval with existing \textit{Hubble Space Telescope}/WFC3 spectroscopy and \textit{Spitzer}/IRAC photometry. This allows us to place bounded constraints on the abundances of Fe\,\textsc{i}, H$_2$O, and CO, and to place a stringent upper limit on the TiO abundance. The results are consistent with KELT-20b having a solar to slightly super-solar composition atmosphere in terms of the bulk metal enrichment, and the carbon-to-oxygen and iron-to-oxygen ratios. However, the TiO volume mixing ratio upper limit (10$^{-7.6}$ at 99\% confidence) is inconsistent with this picture, which, along with the non-detection of Ti\,\textsc{i}, points to sequestration of Ti species, possibly due to nightside condensation. The lack of TiO but the presence of a large H$_2$O emission feature in the WFC3 data is challenging to reconcile within the context of 1D self-consistent, radiative-convective models., Comment: 14 pages, 9 figures, 2 tables

After a successful launch, the James Webb Space Telescope is preparing to undertake one of its principal missions, the characterization of the atmospheres of exoplanets. The Single Object Slitless Spectroscopy (SOSS) mode of the Near Infrared Imager and Slitless Spectrograph (NIRISS) is the only observing mode that has been specifically designed for this objective. It features a wide simultaneous spectral range (0.6--2.8\,\micron) through two spectral diffraction orders. However, due to mechanical constraints, these two orders overlap slightly over a short range, potentially introducing a ``contamination'' signal in the extracted spectrum. We show that for a typical box extraction, this contaminating signal amounts to 1\% or less over the 1.6--2.8\,\micron\ range (order 1), and up to 1\% over the 0.85--0.95\,\micron\ range (order 2). For observations of exoplanet atmospheres (transits, eclipses or phase curves) where only temporal variations in flux matter, the contamination signal typically biases the results by order of 1\% of the planetary atmosphere spectral features strength. To address this problem, we developed the Algorithm to Treat Order ContAmination (ATOCA). By constructing a linear model of each pixel on the detector, treating the underlying incident spectrum as a free variable, ATOCA is able to perform a simultaneous extraction of both orders. We show that, given appropriate estimates of the spatial trace profiles, the throughputs, the wavelength solutions, as well as the spectral resolution kernels for each order, it is possible to obtain an extracted spectrum accurate to within 10\,ppm over the full spectral range., Comment: Submitted to PASP. 22 pages, 12 figures

$\texttt{Eureka!}$ is a data reduction and analysis pipeline for exoplanet time-series observations, with a particular focus on JWST data. Over the next 1-2 decades, JWST will pursue four main science themes: Early Universe, Galaxies Over Time, Star Lifecycle, and Other Worlds. Our focus is on providing the astronomy community with an open source tool for the reduction and analysis of time-series observations of exoplanets in pursuit of the fourth of these themes, Other Worlds. The goal of $\texttt{Eureka!}$ is to provide an end-to-end pipeline that starts with uncalibrated FITS files and ultimately yields precise exoplanet spectra. The pipeline has a modular structure with six stages, and each stage uses a "Eureka! Control File" (ECF) to allow for easy control of the pipeline's behavior. Stage 5 also uses a "Eureka! Parameter File" (EPF) to control the fitted parameters. We provide template ECFs for the MIRI, NIRCam, NIRISS, and NIRSpec instruments on JWST and the WFC3 instrument on the Hubble Space Telescope (HST). These templates give users a good starting point for their analyses, but $\texttt{Eureka!}$ is not intended to be used as a black box tool, and users should expect to fine-tune some settings for each observation in order to achieve optimal results. At each stage, the pipeline creates intermediate figures and outputs that allow users to compare $\texttt{Eureka!}$'s performance using different parameter settings or to compare $\texttt{Eureka!}$ with an independent pipeline. The ECF used to run each stage is also copied into the output folder from each stage to enhance reproducibility. Finally, while $\texttt{Eureka!}$ has been optimized for exoplanet observations (especially the latter stages of the code), much of the core functionality could also be repurposed for JWST time-series observations in other research domains thanks to $\texttt{Eureka!}$'s modularity., Comment: 6 pages, 1 figure, published in JOSS

We present a uniform analysis of transit observations from the Hubble Space Telescope and Spitzer Space Telescope of two warm gas giants orbiting K-type stars - WASP-29b and WASP-80b. The transmission spectra, which span 0.4-5.0 $\mu$m, are interpreted using a suite of chemical equilibrium PLATON atmospheric retrievals. Both planets show evidence of significant aerosol opacity along the day-night terminator. The spectrum of WASP-29b is flat throughout the visible and near-infrared, suggesting the presence of condensate clouds extending to low pressures. The lack of spectral features hinders our ability to constrain the atmospheric metallicity and C/O ratio. In contrast, WASP-80b shows a discernible, albeit muted H$_2$O absorption feature at 1.4 $\mu$m, as well as a steep optical spectral slope that is caused by fine-particle aerosols and/or contamination from unocculted spots on the variable host star. WASP-80b joins the small number of gas-giant exoplanets that show evidence for enhanced atmospheric metallicity: the transmission spectrum is consistent with metallicities ranging from $\sim$30-100 times solar in the case of cloudy limbs to a few hundred times solar in the cloud-free scenario. In addition to the detection of water, we infer the presence of CO$_2$ in the atmosphere of WASP-80b based on the enhanced transit depth in the Spitzer 4.5 $\mu$m bandpass. From a complementary analysis of Spitzer secondary eclipses, we find that the dayside emission from WASP-29b and WASP-80b is consistent with brightness temperatures of $937 \pm 48$ and $851 \pm 14$ K, respectively, indicating relatively weak day-night heat transport and low Bond albedo., Comment: Published in AJ, 26 pages, 13 figures. Updated to reflect proof changes

After observing WASP-12 in the second year of the primary mission, the Transiting Exoplanet Survey Satellite (TESS) revisited the system in late 2021 during its extended mission. In this paper, we incorporate the new TESS photometry into a reanalysis of the transits, secondary eclipses, and phase curve. We also present a new $K_s$-band occultation observation of WASP-12b obtained with the Palomar/Wide-field Infrared Camera instrument. The latest TESS photometry spans three consecutive months, quadrupling the total length of the TESS WASP-12 light curve and extending the overall time baseline by almost two years. Based on the full set of available transit and occultation timings, we find that the orbital period is shrinking at a rate of $-29.81 \pm 0.94$ ms yr$^{-1}$. The additional data also increase the measurement precision of the transit depth, orbital parameters, and phase-curve amplitudes. We obtain a secondary eclipse depth of $466 \pm 35$ ppm, a $2\sigma$ upper limit on the nightside brightness of 70 ppm, and a marginal $6\overset{\circ}{.}2 \pm 2\overset{\circ}{.}8$ eastward offset between the dayside hotspot and the substellar point. The voluminous TESS dataset allows us to assess the level of atmospheric variability on timescales of days, months, and years. We do not detect any statistically significant modulations in the secondary eclipse depth or day-night brightness contrast. Likewise, our measured $K_s$-band occultation depth of $2810 \pm 390$ ppm is consistent with most $\sim$2.2 $\mu$m observations in the literature., Comment: 16 pages, 9 figures, 3 tables. Published in AJ

We report observations of the recently discovered warm Neptune TOI-674 b (5.25 \rearth{}, 23.6 \mearth{}) with the Hubble Space Telescope's Wide Field Camera 3 instrument. TOI-674 b is in the Neptune desert, an observed paucity of Neptune-size exoplanets at short orbital periods. Planets in the desert are thought to have complex evolutionary histories due to photoevaporative mass loss or orbital migration, making identifying the constituents of their atmospheres critical to understanding their origins. We obtained near-infrared transmission spectroscopy of the planet's atmosphere with the G141 grism. After extracting, detrending, and fitting the spectral lightcurves to measure the planet's transmission spectrum, we used the petitRADTRANS atmospheric spectral synthesis code to perform retrievals on the planet's atmosphere to identify which absorbers are present. These results show moderate evidence for increased absorption at 1.4 $\mu$m due to water vapor at 2.9$\sigma$ (Bayes factor = 15.8), as well as weak evidence for the presence of clouds at 2.2$\sigma$ (Bayes factor = 4.0). TOI-674 b is a strong candidate for further study to refine the water abundance, which is poorly constrained by our data. We also incorporated new TESS short-cadence optical photometry, as well as Spitzer/IRAC data, and re-fit the transit parameters for the planet. We find the planet to have the following transit parameters: $R_p/R_* = 0.1135\pm0.0006$, $T_0 = 2458544.523792\pm0.000452$ BJD, and $P = 1.977198\pm0.00007$ d. These measurements refine the planet radius estimate and improve the orbital ephemerides for future transit spectroscopy observations of this highly intriguing warm Neptune., Comment: Accepted to the Astronomical Journal. 20 pages, 17 figures

We validate the presence of a two-planet system orbiting the 0.15--1.4 Gyr K4 dwarf TOI 560 (HD 73583). The system consists of an inner moderately eccentric transiting mini-Neptune (TOI 560 b, $P = 6.3980661^{+0.0000095}_{-0.0000097}$ days, $e=0.294^{+0.13}_{-0.062}$, $M= 0.94^{+0.31}_{-0.23}M_{Nep}$) initially discovered in the Sector 8 \tess\ mission observations, and a transiting mini-Neptune (TOI 560 c, $P = 18.8805^{+0.0024}_{-0.0011}$ days, $M= 1.32^{+0.29}_{-0.32}M_{Nep}$) discovered in the Sector 34 observations, in a rare near-1:3 orbital resonance. We utilize photometric data from \tess\, \textit{Spitzer}, and ground-based follow-up observations to confirm the ephemerides and period of the transiting planets, vet false positive scenarios, and detect the photo-eccentric effect for TOI 560 b. We obtain follow-up spectroscopy and corresponding precise radial velocities (RVs) with the iSHELL spectrograph at the NASA Infrared Telescope Facility and the HIRES Spectrograph at Keck Observatory to validate the planetary nature of these signals, which we combine with published PFS RVs from Magellan Observatory. We detect the masses of both planets at $> 3-\sigma$ significance. We apply a Gaussian process (GP) model to the \tess\ light curves to place priors on a chromatic radial velocity GP model to constrain the stellar activity of the TOI 560 host star, and confirm a strong wavelength dependence for the stellar activity demonstrating the ability of NIR RVs in mitigating stellar activity for young K dwarfs. TOI 560 is a nearby moderately young multi-planet system with two planets suitable for atmospheric characterization with James Webb Space Telescope (JWST) and other upcoming missions. In particular, it will undergo six transit pairs separated by $<$6 hours before June 2027., Comment: AAS Journals, Accepted for publication