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Best current expressions for the vibrational relaxation times of oxygen and nitrogen in the atmosphere are used to compute total absorption. The resulting graphs of total absorption as a function of frequency for different humidities should be used in lieu of the graph published earlier by Evans et al (1972).

The various mechanisms which contribute to sound absorption in the atmosphere are identified and a technique for computing the contribution from each is presented. The similarities between sound absorption, laser fluorescence measurements, and the opto-acoustic effect are discussed. Finally, experimental sound absorption results are compared to predictions to test the microscopic energy transfer approach.

The absorption of sound in air at frequencies from 4 to 100 kHz in 1/12 octave intervals, for temperatures from 255.4 K (0 F) to 310.9 K (100 F) in 5.5 K (10 F) intervals, and at 10% relative-humidity increments between 0% and saturation has been measured. The values of free-field absorption have been analyzed to determine the relaxation frequency of oxygen for each of the 92 combinations of temperature and relative humidity studied and the results are compared to an empirical expression. The relaxation frequencies of oxygen have been analyzed to determine the microscopic energy-transfer rates.

At audible frequencies, the vibrational relaxation of nitrogen contributes significantly to the absorption of sound in still air. The accurate measurement of the humidity dependence of the relaxation frequency of nitrogen, as yet, has eluded careful measurement due to the difficulty in measuring small absorption at low frequencies. Recently, equipment has been constructed for measuring sound absorption in air as a function of humidity over the frequency range from 4 to 100 kHz. In the experiment described here, the temperature and humidity range of this equipment has been extended so that it can be used to study the relaxation absorption in nitrogen at temperatures from 311 K to 418 K. The results indicate that, over this temperature range, the frequency of maximum absorption in moist nitrogen, f, can be given by f/P = 260 x h, Hz/atm, where h is the percent mole fraction of water, and P is the pressure in atm. To the accuracy of the measurements reported here, f is independent of temperature over the range of temperatures at which the measurements were made.

Equipment had been constructed for measuring sound absorption in the frequency range from 4 to 100 kHz in a large tube 25.4 cm in diameter and 4.8-m long. The technique employs a large moveable solid-dielectric capacitance transducer that completely fills the tube cross section and generates pulses of plane waves. An identical transducer terminates the other end of the tube and serves as a microphone to detect and reflect the sound pulses. Measurements in argon, nitrogen, and air indicate that the attenuation of the sound pulses differs by less than 1% from values calculated for the zero-order mode for frequencies up to 44 times the cutoff frequency for the first 'nonplane' mode. Above that frequency, the measured values are less than those predicted by theory by an amount that is approximately proportional to the wavelength to the -3.1 power. In a smaller tube of similar construction, the high-frequency deviation from theory is absent.

Pure tone sound absorption coefficients were measured at 1/12 octave intervals from 4 to 100 KHz at 5.5K temperature intervals between 255.4 and 310.9 K and at 10 percent relative humidity increments between 0 percent and saturation in a large cylindrical tube (i.d., 25.4 cm; length, 4.8 m). Special solid-dielectric capacitance transducers, one to generate bursts of sound waves and one to terminate the sound path and detect the tone bursts, were constructed to fit inside the tube. The absorption was measured by varying the transmitter receiver separation from 1 to 4 m and observing the decay of multiple reflections or change in amplitude of the first received burst. The resulting absorption was compared with that from a proposed procedure for computing sound absorption in still air. Absorption of bands of noise was numerically computed by using the pure tone results. The results depended on spectrum shape, on filter type, and nonlinearly on propagation distance. For some of the cases considered, comparison with the extrapolation of ARP-866A showed a difference as large as a factor of 2. However, for many cases, the absorption for a finite band was nearly equal to the pure tone absorption at the center frequency of the band. A recommended prediction procedure is described for 1/3 octave band absorption coefficients.

Experimental measurements of sound absorption in air, measurements of ultrasonic absorption in H2O/O2 mixtures at 500 K, and experimental measurements in mixtures of H2O with other impurities have been analyzed to determine the energy transfer rates in mixtures of O2 and H2O as a function of temperature. A set of energy transfer rate coefficients was found that give results consistent with all the experimental data examined and with vibrational energy transfer theory. The rotational relaxation time for H2O/O2 mixtures was determined from the 500 K ultrasonic measurements.