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We investigate the impact of CO$_2$ on TRAPPIST-1 e, f and g during the magma ocean stage. These potentially habitable rocky planets are currently the most accessible for astronomical observations. A constraint on the volatile budget during the magma ocean stage is a link to planet formation and also needed to judge their habitability. We perform simulations with 1-100 terrestrial oceans (TO) of H$_2$O with and without CO$_2$ and for albedos 0 and 0.75. The CO$_2$ mass is scaled with initial H$_2$O by a constant factor between 0.1 and 1. The magma ocean state of rocky planets begins with a CO$_2$-dominated atmosphere but can evolve into a H$_2$O dominated state, depending on initial conditions. For less than 10 TO initial H$_2$O, the atmosphere tends to desiccate and the evolution may end with a CO$_2$ dominated atmosphere. Otherwise, the final state is a thick (>1000 bar) H$_2$O-CO$_2$ atmosphere. Complete atmosphere desiccation with less than 10 TO initial H$_2$O can be significantly delayed for TRAPPIST-1e and f, when H$_2$O has to diffuse through a CO$_2$ atmosphere to reach the upper atmosphere, where XUV photolysis occurs. As a consequence of CO$_2$ diffusion-limited water loss, the time of mantle solidification for TRAPPIST-1 e, f, and g can be significantly extended compared to a pure H$_2$O evolution by up to 40 Myrs for albedo 0.75 and by up to 200 Mrys for albedo 0. The addition of CO$_2$ further results in a higher water content in the melt during the magma ocean stage. Our compositional model adjusted for the measured metallicity of TRAPPIST-1 yields for the dry inner planets (b, c, d) an iron fraction of 27 wt-%. For TRAPPIST-1 e, this iron fraction would be compatible with a (partly) desiccated evolution scenario and a CO$_2$ atmosphere with surface pressures of a few 100 bar. A comparative study between TRAPPIST-1 e and the inner planets may yield the most insights about formation and evolution scenarios., Comment: 36 pages, 28 figues, accepted by A&A 9/12/2024

Lightning has been suggested to play a role in triggering the occurrence of bio-ready chemical species. Future missions (PLATO, ARIEL, HWO, LIFE) and ground-based ELTs will investigate the atmospheres of potentially habitable exoplanets. We aim to study the effect of lightning on the atmospheric chemistry, how it affects false-positive and false-negative biosignatures, and if its effect would be observable on an exo-Earth and on TRAPPIST-1 planets. We use a combination of laboratory experiments, photochemical and radiative transfer modelling. With spark discharge experiments in N2-CO2-H2 gas mixtures, representing a range of possible rocky-planet atmospheres, we investigate the production of potential lightning signatures (CO, NO), possible biosignature gases (N2O, NH3, CH4), and important prebiotic precursors (HCN, Urea). Photochemical simulations are conducted for oxygen-rich and anoxic atmospheres for rocky planets in the habitable zones of the Sun and TRAPPIST-1 for a range of lightning flash rates. Synthetic spectra are calculated using SMART to study the atmosphere's reflectance, emission, and transmission spectra. Lightning enhances the spectral features of NO, NO2, and, in some cases, CO; CH4 and C2H6 may be enhanced indirectly. Lightning at a flash rate slightly higher than on modern Earth can mask the ozone features of an oxygen-rich, biotic atmosphere, making it harder to detect the biosphere. Lightning flash rates at least ten times higher than on modern Earth can mask the presence of ozone in the anoxic, abiotic atmosphere of a planet orbiting a late M dwarf, reducing the potential for a false-positive life-detection. The threshold lightning rates to eliminate oxygen and ozone false positive biosignatures on planets orbiting ultra-cool dwarfs is up to ten times higher than the modern flash rate, suggesting that lightning cannot always prevent these false-positive scenarios., Comment: Accepted for publication in Astronomy & Astrophysics. 30 pages, 22 figures (including appendix)

Bioavailable nitrogen is thought to be a requirement for the origin and sustenance of life. Before the onset of biological nitrogen fixation, abiotic pathways to fix atmospheric N2 must have been prominent to provide bioavailable nitrogen to Earth's earliest ecosystems. Lightning has been shown to produce fixed nitrogen as nitrite and nitrate in both modern atmospheres dominated by N2 and O2 and atmospheres dominated by N2 and CO2 analogous to the Archaean Earth. However, a better understanding of the isotopic fingerprints of lightning-generated fixed nitrogen is needed to assess the role of this process on the early Earth. Here, we present results from spark discharge experiments in N2-CO2 and N2-O2 gas mixtures. Our experiments suggest that lightning-driven nitrogen fixation may have been similarly efficient in the Archaean atmosphere, compared to modern times. Measurements of the isotopic ratio {\delta}15N of the discharge-produced nitrite and nitrate in solution show very low values of -6 to -15 permil after equilibration with the gas phase with a calculated endmember composition of -17 permil. These results are much lower than most {\delta}15N values documented from the sedimentary rock record, which supports the development of biological nitrogen fixation earlier than 3.2 Ga. However, some Paleoarchean records (3.7 Ga) may be consistent with lightning-derived nitrogen input, highlighting the potential role of this process for the earliest ecosystems., Comment: Accepted manuscript. Version of record published in Nature Geoscience. 29 pages (main text, methods, supplementary material), 5 figures + 4 supplementary figures

The Trappist-1 system contains seven roughly Earth-sized planets locked in a multi-resonant orbital configuration, which has enabled precise measurements of the planets' masses and constrained their compositions. Here we use the system's fragile orbital structure to place robust upper limits on the planets' bombardment histories. We use N-body simulations to show how perturbations from additional objects can break the multi-resonant configuration by either triggering dynamical instability or simply removing the planets from resonance. The planets cannot have interacted with more than ${\sim 5\%}$ of an Earth mass (${M_\oplus}$) in planetesimals -- or a single rogue planet more massive than Earth's Moon -- without disrupting their resonant orbital structure. This implies an upper limit of ${10^{-4}}$ to ${10^{-2} M_\oplus}$ of late accretion on each planet since the dispersal of the system's gaseous disk. This is comparable to or less than the late accretion on Earth after the Moon-forming impact, and demonstrates that the Trappist-1 planets' growth was complete in just a few million years, roughly an order of magnitude faster than Earth's. Our results imply that any large water reservoirs on the Trappist-1 planets must have been incorporated during their formation in the gaseous disk., Comment: Published in Nature Astronomy (Nov 25, 2021). This is the authors' version including Methods and Supplementary Info

Hot Jupiters provide valuable natural laboratories for studying potential contributions of high-energy radiation to prebiotic synthesis in the atmospheres of exoplanets. In this fourth paper of the MOVES (Multiwavelength Observations of an eVaporating Exoplanet and its Star) programme, we study the effect of different types of high-energy radiation on the production of organic and prebiotic molecules in the atmosphere of the hot Jupiter HD 189733b. Our model combines X-ray and UV observations from the MOVES programme and 3D climate simulations from the 3D Met Office Unified Model to simulate the atmospheric composition and kinetic chemistry with the STAND2019 network. Also, the effects of galactic cosmic rays and stellar energetic particles are included. We find that the differences in the radiation field between the irradiated dayside and the shadowed nightside lead to stronger changes in the chemical abundances than the variability of the host star's XUV emission. We identify ammonium (NH4+) and oxonium (H3O+) as fingerprint ions for the ionization of the atmosphere by both galactic cosmic rays and stellar particles. All considered types of high-energy radiation have an enhancing effect on the abundance of key organic molecules such as hydrogen cyanide (HCN), formaldehyde (CH2O), and ethylene (C2H4). The latter two are intermediates in the production pathway of the amino acid glycine (C2H5NO2) and abundant enough to be potentially detectable by JWST., Comment: 15 pages, 11 figures, 4 tables

Recent observations of the potentially habitable planets TRAPPIST-1 e, f, and g suggest that they possess large water mass fractions of possibly several tens of wt% of water, even though the host star's activity should drive rapid atmospheric escape. These processes can photolyze water, generating free oxygen and possibly desiccating the planet. After the planets formed, their mantles were likely completely molten with volatiles dissolving and exsolving from the melt. In order to understand these planets and prepare for future observations, the magma ocean phase of these worlds must be understood. To simulate these planets, we have combined existing models of stellar evolution, atmospheric escape, tidal heating, radiogenic heating, magma ocean cooling, planetary radiation, and water-oxygen-iron geochemistry. We present MagmOc, a versatile magma ocean evolution model, validated against the rocky Super-Earth GJ 1132b and early Earth. We simulate the coupled magma ocean-atmospheric evolution of TRAPPIST-1 e, f, and g for a range of tidal and radiogenic heating rates, as well as initial water contents between 1 and 100 Earth oceans. We also reanalyze the structures of these planets and find they have water mass fractions of 0-0.23, 0.01-0.21, and 0.11-0.24 for planets e, f, and g, respectively. Our model does not make a strong prediction about the water and oxygen content of the atmosphere of TRAPPIST-1 e at the time of mantle solidification. In contrast, the model predicts that TRAPPIST-1 f and g would have a thick steam atmosphere with a small amount of oxygen at that stage. For all planets that we investigated, we find that only 3-5% of the initial water will be locked in the mantle after the magma ocean solidified., Comment: Accepted for publication in Astrobiology, 24 pages, 9 figures, 7 tables

We describe a software package called VPLanet that simulates fundamental aspects of planetary system evolution over Gyr timescales, with a focus on investigating habitable worlds. In this initial release, eleven physics modules are included that model internal, atmospheric, rotational, orbital, stellar, and galactic processes. Many of these modules can be coupled simultaneously to simulate the evolution of terrestrial planets, gaseous planets, and stars. The code is validated by reproducing a selection of observations and past results. VPLanet is written in C and designed so that the user can choose the physics modules to apply to an individual object at runtime without recompiling, i.e., a single executable can simulate the diverse phenomena that are relevant to a wide range of planetary and stellar systems. This feature is enabled by matrices and vectors of function pointers that are dynamically allocated and populated based on user input. The speed and modularity of VPLanet enables large parameter sweeps and the versatility to add/remove physical phenomena to assess their importance. VPLanet is publicly available from a repository that contains extensive documentation, numerous examples, Python scripts for plotting and data management, and infrastructure for community input and future development., Comment: 75 pages, 34 figures, 10 tables, accepted to the Proceedings of the Astronomical Society of the Pacific. Source code, documentation, and examples available at https://github.com/VirtualPlanetaryLaboratory/vplanet

We present WASP-43b climate simulations with deep wind jets (down to 700~bar) that are linked to retrograde (westward) flow at the equatorial day side for $p<0.1$~bar. Retrograde flow inhibits efficient eastward heat transport and naturally explains the small hotspot shift and large day-night-side gradient of WASP-43b ($P_{\text{orb}}=P_{\text{rot}}=0.8135$~days) observed with Spitzer. We find that deep wind jets are mainly associated with very fast rotations ($P_{\text{rot}}=P_{\text{orb}}\leq 1.5$~days) which correspond to the Rhines length smaller than $2$ planetary radii. We also diagnose wave activity that likely gives rise to deviations from superrotation. Further, we show that we can achieve full steady state in our climate simulations by imposing a deep forcing regime for $p>10$~bar: convergence time scale $\tau_{\text{conv}}=10^6-10^8$~s to a common adiabat, as well as linear drag at depth ($p\geq 200$~bar), which mimics to first order magnetic drag. Lower boundary stability and the deep forcing assumptions were also tested with climate simulations for HD~209458b ($P_{\text{orb}}=P_{\text{rot}}=3.5$~days). HD~209458b simulations always show shallow wind jets (never deeper than 100~bar) and unperturbed superrotation. If we impose a fast rotation ($P_{\text{orb}}=P_{\text{rot}}=0.8135$~days), also the HD~209458b-like simulation shows equatorial retrograde flow at the day side. We conclude that the placement of the lower boundary at $p=200$~bar is justified for slow rotators like HD~209458b, but we suggest that it has to be placed deeper for fast-rotating, dense hot Jupiters ($P_{\text{orb}}\leq 1.5$~days) like WASP-43b. Our study highlights that the deep atmosphere may have a strong influence on the observable atmospheric flow in some hot Jupiters., Comment: Accepted by MNRAS (36 pages with Appendix)