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Difficulties in dating Mississippi Valley–type (MVT) mineral deposits and the often closely associated dolomitization have led to controversy regarding their origin. We report the first radiometric ages for the Gorno mining district in northern Italy, an example of the Alpine subclass of MVT deposits. U-Pb ages of hydrothermal carbonates pre- and postdating the ore-forming event show that base-metal mineralization occurred shortly after the deposition of the Carnian host rocks. This implies that the Gorno ore deposits formed at shallow burial depth prior to the Early Jurassic western Tethys rifting phase. Contemporaneous Triassic magmatism and extensional tectonics likely contributed to the high geothermal heat fluxes required to drive the mineralizing system. Our study reinforces the need for reliable geochronological data for metallogenic models and warns against a general application of classic North American MVT models to similar deposits worldwide.

Secondo Franchi (1859-1932) was one of the most important geologists of the Regio Ufficio Geologico of Italy. In collaboration with his colleagues of the Turin office, starting from 1888 Franchi surveyed in detail the Western Alps to contribute to the new Geological Map of Italy at the 1:100,000 scale. Franchi's studies contributed to the definition of a still largely accepted chronostratigraphic framework for the Alpine successions, and to the recognition of previously overlooked folding and faulting phases in the Western Alps. Eleven of Franchi's field notebooks are kept in the Library of Istituto Superiore per la Protezione e la Ricerca Ambientale in Rome. These notebooks are richly illustrated with geological sections and landscape sketches and represent an invaluable firsthand resource for the analysis of Franchi's mapping methods and interpretive procedures. This paper analyses Franchi's contribution to the geological knowledge of some specific localities of the Western Alps, integrating excerpts from his original field notebooks and published works.

The 'Ornamental Stones of Piemonte Region' geo-lithological map at 1:250,000 scale aims at reviewing the ornamental stone heritage of Piemonte at the regional scale. The map derives from a thorough revision of the available literature, integrated with some unpublished original data. The map shows the location of the main quarries of ornamental stones of the region, selected on the basis of their historical, cultural and architectonic relevance. A geo-lithological basemap was produced, deriving it from a basic Geological Map of Piemonte, available at the same scale. The large varieties of lithotypes of Piemonte have been resumed, in the new map, into 21 classes, which all the ornamental stones have been assigned to. The Main Map is enriched by some significant examples of using the ornamental stones in historical buildings, and it is supported by a supplementary data base containing essential information about the quarry sites and the quarried material.

This contribution describes a geodatabase structure designed to manage a large amount of geo-environmental data for the "Gronda di Genova" highway by-pass tunnels in Liguria region (Italy). In particular, an innovative dataset structure founded on an explicit conceptual model was designed to represent the distribution of petrofacies containing Natural Occurring Asbestos (NOA), and their minero-chemical composition. This in order to assess the environmental risk (air dispersion of fibers) due to the tunnel excavation in the asbestos-bearing rocks. Problems related to the GIS (shp) - AutoCAD (layer) conversion have been also considered for delivering the graphic layout of the project and are here discussed.

The presence of naturally occurring asbestos (NOA) in many areas worldwide requires an enhanced geological risk evaluation to ensure workplace safety from asbestos during large construction projects. Due to the complexity of the geological risk definition, health and safety regulations for working with asbestos-bearing materials are often not enforceable in NOA settings. Therefore, to correctly estimate the risk of NOA in these scenarios, new procedures are urgently needed to provide (1) a detailed geological model representative of the possible presence of the asbestos, (2) representative sampling, and (3) a reliable quantitative determination of asbestos content in rocks. This work aims to discuss the improvements on the two latter points specifically developed during the design of the “Gronda di Genova” project, a 50-km-long tunnel bypass partially designed in the NOA-bearing meta-ophiolites of the Ligurian Alps and ophiolites of the northern Apennines in Italy. Implementation of Gy's theory on sampling was used to maintain statistical validity during sample processing from the primary sample to the analytical sample and is here described. The scanning electron microscopy/energy dispersive spectroscopy procedure for the quantification of NOA was improved with an error analysis delivering the minimum number of fibers to be measured to achieve the best analytical results.

Asbestos may constitute a severe health risk when meta-ophiolites are excavated for large infrastructural projects. For public acceptance, a reliable estimation of the content of Naturally Occurring Asbestos (NOA) is necessary for the design of construction sites, workers' safety and spoil management. In the framework of a research project supporting the final design of a highway tunnel system in NW Italy, SEM-EDS (Scanning Electron Microscopy – Energy-Dispersive Spectrometry) quantitative analyses were performed to provide a direct NOA content estimation by counting and weighing the asbestos fibers in the rocks, after a chemical and geometrical characterization. The direct NOA content estimation was compared with an indirect estimation obtained through a fracture network modeling based on a structural survey on a selected outcrop and statistical analysis of a relative digital image. The fracture intensity, inferred from the fracture network model, was multiplied by coefficients deriving from the semi-quantitative estimation of the geological relations between asbestos mineral occurrence and fracture size, thickness and distribution. A good agreement between the indirect NOA estimation and the average result of the SEM-EDS analysis was obtained. Thus, the statistical analysis of the fracture network may represent a valuable support to the SEM-EDS quantitative analysis based on mineral fibers counting. However, the quality of the indirect NOA estimation depends on the postulates for inferring the coefficients describing the distribution and occurrence of the asbestos minerals within the fractures. This Note discusses the above-mentioned issues, as well as those concerning the procedure for a representative sampling of NOA-bearing rocks and fractures.

Naturally-Occurring Asbestos (NOA) may constitute a severe health risk when metamorphic rocks are excavated for large infrastructure projects. For public acceptance, a reliable assessment of the content of NOA is necessary for the design of the construction site, workers’ safety, and spoil management. Direct measurements of NOA content can be made by SEM-EDS analyses on an adequate number of samples. Such measurements are sufficiently precise but questions about the representativity of the samples may arise, especially when the rock units are structurally and lithologically complex. Therefore, in order to corroborate the direct assessments, alternative and indirect assessments can be performed by measuring the fracture volumetric porosity, provided that almost all the NOA is deposited as veins in the fractures of the rock mass. Statistical sampling and inference procedures can be applied to derive such an index. In this paper, an indirect assessment of NOA is reported and compared with the assessment obtained by direct measurements. The application is to a metamorphic rock formation through which a tunnel is to be driven as part of the ”Gronda di Genova” highway development in Genoa, Italy. Even though significant approximations are made, the indirect assessment is relatively close to the direct measurement.

In SW Piemonte the Western Alps arc ends off in a narrow, E-W trending zone, where some geological domains of the Alps converged. Based on a critical review of available data, integrated with new field data, it is concluded that the southern termination of Western Alps recorded the Oligocene-Miocene activity of a regional transfer zone (southwestern Alps Transfer, SWAT) already postulated in the literature, which should have allowed, since early Oligocene, the westward indentation of Adria, while the regional shortening of SW Alps and tectonic transport toward the SSW (Dauphinois foreland) was continuing. This transfer zone corresponds to a system of deformation units and km-scale shear zones (Gardetta-Viozene Zone, GVZ). The GVZ/SWAT developed externally to the Penninic Front (PF), here corresponding to the Internal Briançonnais Front (IBF), which separates the Internal Briançonnais domain, affected by major tectono-metamorphic transformations, from the External Briançonnais, subjected only to anchizonal metamorphic conditions. The postcollisional evolution of the SW Alps axial belt units was recorded by the Oligocene to Miocene inner syn-orogenic basin (Tertiary Piemonte Basin, TPB), which rests also on the Ligurian units stacked within the adjoining Apennines belt in southern Piemonte. The TPB successions were controlled by transpressive faults propagating (to E and NE) from the previously formed Alpine belt, as well as by the Apennine thrusts that were progressively stacking the Ligurian units, resting on the subducting Adriatic continental margin, with the TPB units themselves. This allows correlation between Alps and Apennines kinematics, in terms of age of the main geologic events, interference between the main structural systems and tectonic control exerted by both tectonic belts on the same syn-orogenic basin.

The greenstone industry of Valgrana/Tetto Chiappello was studied with an archaeo-typological and mineral/petrographic approach (functional study, XRPD, polarized light microscopy and SEM-EDS), to infer the provenance of the raw materials and the role of this site in the general greenstone circulation during Neolithic. Most artifacts (mainly cutting-edge tools) are made of sensu stricto greenstones (≈ 80%), especially mixed Na-pyroxenite and eclogite in roughly equal amounts. The abundance of roughouts and broken tools, with evident use-wear traces, suggests that these implements were possibly used even before (or sometimes without) pre-shaping. Based on mineralogical and morphological ‘markers’, a dual mechanism of raw materials supplying was hypothesized for Valgrana: most tools were retrieved from the closer areas of the southern Monviso ‘massif’ (few dozens of km far, as the crow flies), though a subordinate supply channel was probably represented by commercial trades with other settlements, thus allowing the stocking of raw materials and/or artifacts also from the more distant Voltri ‘massif’ (70-to-80 km far). For what concerns the provisioning mode, a ‘secondary high-ground supplying’ mainly operated in Valgrana, according to which the raw materials were retrieved from greenstone boulders dismantled by erosion and rolled down along the Monviso ‘massif’ mountainsides; however, it cannot be excluded that direct extraction from primary outcrops may also have occurred. In the operative chain, Valgrana can be identified as a subordinate sedentary ‘satellite site’, in which specialized workers took care of raw materials gathering and preliminary tool processing – to be continued and concluded elsewhere.

In the Maritime Alps (NW Italy - SE France), the Middle Triassic-Berriasian platform carbonates of the Provençal Domain are locally affected by an intense hydrothermal dolomitization. This dolomitization resulted from a large-scale hydrothermal circulation related to deep-rooted faults, and is indirect evidence of a significant earliest Cretaceous fault activity in this part of the Alpine Tethys European palaeomargin. New carbonate U-Pb dating and geochemical (stable isotope and noble gases on inclusion-hosted water, 87Sr/86Sr, clumped isotopes) data allowed a better understanding of the timing and mechanisms of the hydrothermal circulation. Hydrothermal fluids probably originated from seawater, which was involved in a deep circulation within the underlying crystalline basement, undergoing heating to more than 200°C and substantial compositional modification by prolonged interaction with basement rocks. Thin cement rims rich in carbonaceous material, locally alternated with hydrothermal dolomite cements, are interpreted as remnants of ephemeral microbial communities that could colonize the upper part of hydrothermal conduits during periods of reduced hot fluid flow and contemporaneous downward seawater infiltration.

For a reliable evaluation of the geo-environmental risk due to naturally occurring asbestos (NOA) during rock excavation of large infrastructure projects, a proper procedure is needed. First, it is necessary to provide a detailed geological model tailored to the NOA-related issues that should drive the rock sampling procedures in order to obtain a representative sampling. The sampling procedures should take into account lithological variability and relative spatial distributions of the rock units. The geological model for NOA should be thus constrained by the main NOA petrofacies occurring in a given geotectonic context, which take into consideration both the mineralogical and structural features, and the identification of NOA homogeneous zones in which the NOA petrofacies are distributed. In this paper, some geo-environmental problems faced during the excavation, in meta-ophiolites, of a long highway tunnel are described. The geological model of the complex setting of the tunnel area (northern Italy, Alps-Apennines junction) is described, focusing on how the NOA-related problems were addressed to allow reliable and detailed estimations of NOA contents for each NOA homogeneous zone and the relevant tunnel layout segment.

Naturally-Occurring Asbestos (NOA) may constitute a severe health risk when metamorphic rocks are excavated for large infrastructure projects. For public acceptance, a reliable assessment of the content of NOA is necessary for the design of the construction site, workers' safety, and spoil management. Direct measurements of NOA content can be made by SEM-EDS analyses on an adequate number of samples. Such measurements are sufficiently precise but questions about the representativity of the samples may arise, especially when the rock units are structurally and lithologically complex. Therefore, in order to corroborate the direct assessments, alternative and indirect assessments can be performed by measuring the fracture volumetric porosity, provided that almost all the NOA is deposited as veins in the fractures of the rock mass. Statistical sampling and inference procedures can be applied to derive such an index. In this paper, an indirect assessment of NOA is reported and compared with the assessment obtained by direct measurements. The application is to a metamorphic rock formation through which a tunnel is to be driven as part of the "Gronda di Genova" highway development in Genoa, Italy. Even though significant approximations are made, the indirect assessment is relatively close to the direct measurement.

Realization of large geo-engineering projects in rocks containing naturally occurring asbestos (NOA) must address several crucial geo-environmental issues, including the design of the construction site, the enforcement of health protection measures and the environmentally responsible spoil management. This leads to a compelling need to develop effective and standard procedures to evaluate the distribution and concentration of NOA in rock volumes. NOA petrofacies are here proposed as an innovative tool to evaluate the asbestos distribution and concentration in complex geological settings. NOA petrofacies are fundamental asbestos-bearing rock types, consisting in recurrent lithological and structural features controlling asbestos occurrence. Here we describe and discuss how the NOA petrofacies approach was utilized in a geo-environmental study for the evaluation of asbestos content in a complex meta-ophiolite suite, which will be crossed by the “Gronda di Genova” highway by-pass project (Genoa, NW Italy). NOA petrofacies were used to predict the distribution and relative abundance of NOA in geologically homogeneous zones characterized by the occurrence of specific NOA minerals.

An unusual occurrence of asbestiform sepiolite, filling veins in the antigorite serpentinites of the Voltri Unit exposed in a borrow pit (now reclaimed) in the Deiva forest, near Sassello, NW Italy, was investigated with an in-depth analytical approach aimed at studying its crystal-chemistry and structure and evaluating its possible hazards for human health. Optical microscopy and scanning electron microscopy (energy-dispersive spectroscopy mode) proved that these sepiolite fibres, apparently up to several cm long, are made up of bundles of thinner fibrils (or laths: average length > 100 µm; thickness ≈ 80 nm), with a composition consistent to that reported in the literature. The dehydration process was monitored through thermo-gravimetric analyses and Fourier-transform infrared spectroscopy, performed at increasingT; the latter, in particular, showed the presence of moderate amounts of aliphatic hydrocarbons – not yet identified thoroughly – associated with the sample. The crystal structure refinement with the Rietveld method showed no relevant difference from the literature models, although a peculiar distribution of zeolitic H2O molecules was observed. The geological context suggests that the Sassello sepiolite precipitated from hydrothermal fluids, which were saturated in Mg and silica by the interaction of the host serpentinites. The same setting favoured formation of abiotic hydrocarbons, by means of the Fischer–Tropsch reaction. The extremely long and flexible fibrils (length/width aspect ratio >> 3) of this sepiolite specimen could represent a serious hazard for human health if air dispersed and inhaled; also, its atypical association with hydrocarbons (only reported once previously) might even favour further fragmentation in thinner units.

In the SW Alps, at the NE margin of the Argentera Massif, the occurrence of isolated bodies of silicate-bearing marbles (Valdieri Marble), laterally passing to non-metamorphic Mesozoic limestones of the Dauphinois succession, appears enigmatic, since their origin cannot be related to the regional metamorphism. The stratigraphic, geometric, petrographic, and geochemical features of the Valdieri Marble indicate that it originated from the upflow of hydrothermal fluids which deeply recrystallised the limestone and provoked the abundant neoblastesis of silicate minerals, at an estimated crystallisation temperature of ca. 350 °C. This paper provides for the first time an absolute U/Pb age, comprised between 30 and 31.6 Ma (early Oligocene), for the Valdieri Marble, which is affected by a syn-genetic shear foliation in turn crosscut by the main Alpine tectonic foliations. The hydrothermal fluids that formed the Valdieri Marble migrated along low-angle shear zones, mostly parallel to the sedimentary primary bedding, which were downward connected with high-angle master faults of the “Alpine SW transfer”, a main Oligocene–early Miocene transcurrent shear zone at the southern termination of the Western Alps. The localized heat flow sustaining the hydrothermal system could be related to the early Oligocene thermal event, well documented by magmatic activity in the Western and Central Alps.

The Provençal and Dauphinois Mesozoic successions cropping out at the southeastern margin of the Argentera Massif (Maritime Alps, NW Italy) were deposited at the transition between the Provençal platform and the Dauphinois basin, marked in the study area by a partly preserved Mesozoic palaeoescarpment. These successions show important lateral variations occurring over relatively short distances, probably related to syndepositional tectonics. Different stratigraphic intervals of the pelagic-hemipelagic Dauphinois succession contain resedimented deposits, made up of both intra- and extrabasinal material, which provide a twofold evidence of syndepositional tectonics indicating both tectonically-triggered gravitational processes and a tectonically-driven evolution of the source areas. Two stages of syndepositional tectonics have been recognized: the first in the earliest Cretaceous, which is related to the deposition of carbonate breccias in the Dauphinois succession and to hydrothermal dolomitization of the Middle Triassic-Jurassic Provençal carbonates, and the second in the Late Cretaceous, which triggered the deposition of different detrital lithozones in the Upper Cretaceous Puriac Limestone. The cited evidence indicates that syndepositional tectonics continued to influence the evolution of the Alpine Tethys European passive margin long after the Late Triassic-Early Jurassic syn-rift stage, which caused the differentiation between the Dauphinois basin and the Provençal platform., Rivista Italiana di Paleontologia e Stratigrafia (Research In Paleontology and Stratigraphy), V. 123, N. 3 (2017)