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Adhesive bond is the weakest part of carbon fiber reinforced composites (CFRP) force‐bearing structure. Therefore, enhancing the strength of the adhesive bond is key to improve force‐bearing structure. In this study, adhesive strength of the common CFRP T‐joint was enhanced by aminated carbon nanotubes (CNT). To begin with, shear tensile strength of single‐lap‐joint laminated composites with various CNT content was verified, which peaked at 0.5 wt%. It was indicated that the adhesive bond of deltoid is the weakest area in a T‐joint. CNT was applied in the deltoid of composite T‐joint and pull‐off test was conducted to investigate the progress from the initiation and evolution of damage as well as the final failure. The aminated CNT employed in this study formed an effective load transmission through physical engagement and chemical bonding; the addition of 0.5 wt% CNT effectively enhanced tensile strength and toughness, improving mechanical property of the adhesive bond. This study provides a solution to enhance the adhesive area of CFRP load‐bearing structure with CNT, consequently improve the load‐bearing strength of composite. Highlights: Aminated CNT is substantially improve the adhesive strength of CFRP T‐joint.Tensile strength and toughness of T‐joint deltoid was optimized by 0.5 wt% CNT.Effective load transmission through physical engagement and chemical bonding. [ABSTRACT FROM AUTHOR]

Nitric oxide (NO), as a critical transcellular messenger, participates in a variety of physiological and pathological processes. However, its real-time detection still faces challenges due to its short half-life and trace amounts. Here, MWCNTs@COF-366-Co was prepared by in situ growth of a cobalt porphyrin-based covalent organic framework (COF-366-Co) on multi-walled carbon nanotubes (MWCNTs), and a unique biosensing platform for ultrasensitive real-time NO determination was established. Remarkably, MWCNTs@COF-366-Co contains plenty of atomically arranged M–N4 active sites for electrocatalysis, which provides more efficient electron transfer pathways and resolves the random arrangement issue of active sites. COF-366-Co with a high surface area contains a large number of exposed active M–N4 sites, providing faster NO transport/diffusion and more efficient electron transfer pathways. Due to the synergy of atomic-level periodic structural features of COF-366-Co and high conductivity of MWCNTs, the MWCNTs@COF-366-Co electrochemical biosensor exhibited excellent NO determination performance in a wide range from 0.09 to 400 μM, with high sensitivity (8.9 μA μM−1 cm−2) and a low limit of detection (16 nM). Moreover, the biosensor has been successfully used to sensitively monitor NO molecules released from human umbilical vein endothelial cells (HUVECs). This research not only designed a multifunctional intelligent biosensor platform, but also provided a broad prospect for continuous dynamic monitoring of the activity of living cells and their released metabolites. [ABSTRACT FROM AUTHOR]

L-shaped stiffened composite panels provide an efficient structure for engineering applications. However, they often produce delamination in the preparation and service process due to a series of factors. To study the effect of different types of delamination on the compressive strength of stiffened composite panels, ABAQUS finite element software was used in combine with the progressive damage subroutine user-defined field variable (USDFLD), and the finite element model was established based on cohesive theory to realize the prediction of the progressive failure process and strength of the stiffened composite panels. The results showed that the delamination of a stringer had a greater impact on the strength of the stiffened composite panels than did the debonding between the skin panel and a stringer and the delamination of the skin panel. The debonding delamination and delamination of a stringer exhibited delamination growth near the damage position during static compression, but delamination of the skin panel exhibited no delamination growth. The experimental results were in good agreement with the finite element simulation results, which verified the validity of the finite element model. [ABSTRACT FROM AUTHOR]

The thermal conductivities of single-layer BC3 (SLBC) sheets and their responses to environmental temperature, vacancy defects and external strain have been studied and compared with those of single-layer C3N (SLCN) sheets by molecular dynamics (MD) simulations. We found that SLBC and SLCN are isotropic in the basal plane and that their predicted thermal conductivities for infinite length sheets are 488.54 W m−1 K−1 and 799.87 W m−1 K−1, respectively. Despite many similar features in the structures of these materials, SLBC exhibits a lower thermal conductivity than SLCN due to stronger flexural acoustic phonon-defect scattering rates and weaker interatomic bonding stiffnesses. The vibrational density of states (VDOS) are calculated in both structures to elucidate their thermal conductivity differences. SLBC exhibits a more substantial redshift phenomenon in the high- and low-frequency domains than SLCN. In addition, the thermal conductivities of these materials exhibit decreasing trends in response to increases in temperature and defect ratio, and the temperature effect in SLBC is more substantial than that in SLCN, while the defect effect in SLBC is less substantial than that in SLCN. The influences of uniaxial compressive and tensile strains on the thermal conductivities of these materials are analysed separately. These two deformation modes cause different effects on the thermal transport behaviours of SLBC and SLCN: the effect of uniaxial compressive strain is slightly negative, while the effect of uniaxial tensile strain is initially positive and then negative. Moreover, the biaxial strains result in a more severe reduction in thermal conductivity than the uniaxial strains. Remarkably, the impact of uniaxial and biaxial tensile strains on thermal transport was stronger in SLBC than in SLCN. We propose that SLBC nanomembranes are promising candidates for various thermal applications. [ABSTRACT FROM AUTHOR]

The thermal conductivities of single-layer BC 3 (SLBC) sheets and their responses to environmental temperature, vacancy defects and external strain have been studied and compared with those of single-layer C 3 N (SLCN) sheets by molecular dynamics (MD) simulations. We found that SLBC and SLCN are isotropic in the basal plane and that their predicted thermal conductivities for infinite length sheets are 488.54 W m -1 K -1 and 799.87 W m -1 K -1 , respectively. Despite many similar features in the structures of these materials, SLBC exhibits a lower thermal conductivity than SLCN due to stronger flexural acoustic phonon-defect scattering rates and weaker interatomic bonding stiffnesses. The vibrational density of states (VDOS) are calculated in both structures to elucidate their thermal conductivity differences. SLBC exhibits a more substantial redshift phenomenon in the high- and low-frequency domains than SLCN. In addition, the thermal conductivities of these materials exhibit decreasing trends in response to increases in temperature and defect ratio, and the temperature effect in SLBC is more substantial than that in SLCN, while the defect effect in SLBC is less substantial than that in SLCN. The influences of uniaxial compressive and tensile strains on the thermal conductivities of these materials are analysed separately. These two deformation modes cause different effects on the thermal transport behaviours of SLBC and SLCN: the effect of uniaxial compressive strain is slightly negative, while the effect of uniaxial tensile strain is initially positive and then negative. Moreover, the biaxial strains result in a more severe reduction in thermal conductivity than the uniaxial strains. Remarkably, the impact of uniaxial and biaxial tensile strains on thermal transport was stronger in SLBC than in SLCN. We propose that SLBC nanomembranes are promising candidates for various thermal applications.