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Contemporary quantum devices are reaching new limits in size and complexity, allowing for the experimental exploration of emergent quantum modes. However, this increased complexity introduces significant challenges in device tuning and control. Here, we demonstrate autonomous tuning of emergent Majorana zero modes in a minimal realization of a Kitaev chain. We achieve this task using cross-platform transfer learning. First, we train a tuning model on a theory model. Next, we retrain it using a Kitaev chain realization in a two-dimensional electron gas. Finally, we apply this model to tune a Kitaev chain realized in quantum dots coupled through a semiconductor-superconductor section in a one-dimensional nanowire. Utilizing a convolutional neural network, we predict the tunneling and Cooper pair splitting rates from differential conductance measurements, employing these predictions to adjust the electrochemical potential to a Majorana sweet spot. The algorithm successfully converges to the immediate vicinity of a sweet spot (within 1.5 mV in 67.6% of attempts and within 4.5 mV in 80.9% of cases), typically finding a sweet spot in 45 minutes or less. This advancement is a stepping stone towards autonomous tuning of emergent modes in interacting systems, and towards foundational tuning machine learning models that can be deployed across a range of experimental platforms.

Majorana zero modes (MZMs) are non-Abelian excitations predicted to emerge at the edges of topological superconductors. One proposal for realizing a topological superconductor in one dimension involves a chain of spinless fermions, coupled through $p$-wave superconducting pairing and electron hopping. This concept is also known as the Kitaev chain. A minimal two-site Kitaev chain has recently been experimentally realized using quantum dots (QDs) coupled through a superconductor. In such a minimal chain, MZMs are quadratically protected against global perturbations of the QD electrochemical potentials. However, they are not protected from perturbations of the inter-QD couplings. In this work, we demonstrate that extending the chain to three sites offers greater protection than the two-site configuration. The enhanced protection is evidenced by the stability of the zero-energy modes, which is robust against variations in both the coupling amplitudes and the electrochemical potential variations in the constituent QDs. While our device offers all the desired control of the couplings it does not allow for superconducting phase control. Our experimental observations are in good agreement with numerical simulated conductances with phase averaging. Our work pioneers the development of longer Kitaev chains, a milestone towards topological protection in QD-based chains.

The recent realization of a two-site Kitaev chain featuring "poor man's Majorana" states demonstrates a path forward in the field of topological superconductivity. Harnessing the potential of these states for quantum information processing, however, requires increasing their robustness to external perturbations. Here, we form a two-site Kitaev chain using proximitized quantum dots hosting Yu-Shiba-Rusinov states. The strong hybridization between such states and the superconductor enables the creation of poor man's Majorana states with a gap larger than $70 \mathrm{~\mu eV}$. It also greatly reduces the charge dispersion compared to Kitaev chains made with non-proximitized quantum dots. The large gap and reduced sensitivity to charge fluctuations will benefit qubit manipulation and demonstration of non-abelian physics using poor man's Majorana states., Comment: 45 pages, 14 figures

The proximity effect of superconductivity on confined states in semiconductors gives rise to various bound states such as Andreev bound states (ABSs), Andreev molecules and Majorana zero modes. While such bound states do not conserve charge, their Fermion parity is a good quantum number. One way to measure parity is to convert it to charge first, which is then sensed. In this work, we sense the charge of ABSs and Andreev molecules in an InSb-Al hybrid nanowire using an integrated quantum dot operated as a charge sensor. We show how charge sensing measurements can resolve the even and odd states of an Andreev molecule, without affecting the parity. Such an approach can be further utilized for parity measurements of Majorana zero modes in Kitaev chains based on quantum dots.

With the development of quantum technology, hybrid devices that combine superconductors (S) and semiconductors (Sm) have attracted great attention due to the possibility of engineering structures that benefit from the integration of the properties of both materials. However, until now, none of the experiments have reported good control of band alignment at the interface, which determines the strength of S-Sm coupling and the proximitized superconducting gap. Here, we fabricate hybrid devices in a generic way with argon milling to modify the interface while maintaining its high quality. First, after the milling the atomically connected S-Sm interfaces appear, resulting in a large induced gap, as well as the ballistic transport revealed by the multiple Andreev reflections and quantized above-gap conductance plateaus. Second, by comparing transport measurement with Schr\"odinger-Poisson (SP) calculations, we demonstrate that argon milling is capable of varying the band bending strength in the semiconducting wire as the electrons tend to accumulate on the etched surface for longer milling time. Finally, we perform nonlocal measurements on advanced devices to demonstrate the coexistence and tunability of crossed Andreev reflection (CAR) and elastic co-tunneling (ECT) -- key ingredients for building the prototype setup for realization of Kitaev chain and quantum entanglement probing. Such a versatile method, compatible with the standard fabrication process and accompanied by the well-controlled modification of the interface, will definitely boost the creation of more sophisticated hybrid devices for exploring physics in solid-state systems., Comment: 41 pages, 16 figures

Quantum devices based on InSb nanowires (NWs) are a prime candidate system for realizing and exploring topologically-protected quantum states and for electrically-controlled spin-based qubits. The influence of disorder on achieving reliable topological regimes has been studied theoretically, highlighting the importance of optimizing both growth and nanofabrication. In this work we investigate both aspects. We developed InSb nanowires with ultra-thin diameters, as well as a new gating approach, involving few-layer graphene (FLG) and Atomic Layer Deposition (ALD)-grown AlOx. Low-temperature electronic transport measurements of these devices reveal conductance plateaus and Fabry-P\'erot interference, evidencing phase-coherent transport in the regime of few quantum modes. The approaches developed in this work could help mitigate the role of material and fabrication-induced disorder in semiconductor-based quantum devices., Comment: 14 pages, 5 figures

Tunneling spectroscopy is widely used to examine the subgap spectra in semiconductor-superconductor nanostructures when searching for Majorana zero modes (MZMs). Typically, semiconductor sections controlled by local gates at the ends of hybrids serve as tunnel barriers. Besides detecting states only at the hybrid ends, such gate-defined tunnel probes can cause the formation of non-topological subgap states that mimic MZMs. Here, we develop an alternative type of tunnel probes to overcome these limitations. After the growth of an InSb-Al hybrid nanowire, a precisely controlled in-situ oxidation of the Al shell is performed to yield a nm-thick Al oxide layer. In such thin isolating layer, tunnel probes can be arbitrarily defined at any position along the hybrid nanowire by shadow-wall angle-deposition of metallic leads. This allows us to make multiple tunnel probes along single nanowire hybrids and to successfully identify Andreev bound states (ABSs) of various spatial extension residing along the hybrids., Comment: 38 pags, 5 figures

A short superconducting segment can couple attached quantum dots via elastic co-tunneling (ECT) and crossed Andreev reflection (CAR). Such coupled quantum dots can host Majorana bound states provided that the ratio between CAR and ECT can be controlled. Metallic superconductors have so far been shown to mediate such tunneling phenomena, albeit with limited tunability. Here we show that Andreev bound states formed in semiconductor-superconductor heterostructures can mediate CAR and ECT over mesoscopic length scales. Andreev bound states possess both an electron and a hole component, giving rise to an intricate interference phenomenon that allows us to tune the ratio between CAR and ECT deterministically. We further show that the combination of intrinsic spin-orbit coupling in InSb nanowires and an applied magnetic field provides another efficient knob to tune the ratio between ECT and CAR and optimize the amount of coupling between neighboring quantum dots.

Semiconducting nanowire Josephson junctions represent an attractive platform to investigate the anomalous Josephson effect and detect topological superconductivity by studying Josephson supercurrent. However, an external magnetic field generally suppresses the supercurrent through hybrid nanowire junctions and significantly limits the field range in which the supercurrent phenomena can be studied. In this work, we investigate the impact of the length of InSb-Al nanowire Josephson junctions on the supercurrent resilience against magnetic fields. We find that the critical parallel field of the supercurrent can be considerably enhanced by reducing the junction length. Particularly, in 30 nm-long junctions supercurrent can persist up to 1.3 T parallel field - approaching the critical field of the superconducting film. Furthermore, we embed such short junctions into a superconducting loop and obtain the supercurrent interference at a parallel field of 1 T. Our findings are highly relevant for multiple experiments on hybrid nanowires requiring a magnetic field-resilient supercurrent., Comment: 17 pages, 5 figures in main text. 22 pages, 10 figures in supporting information

Majorana bound states constitute one of the simplest examples of emergent non-Abelian excitations in condensed matter physics. A toy model proposed by Kitaev shows that such states can arise at the ends of a spinless $p$-wave superconducting chain. Practical proposals for its realization require coupling neighboring quantum dots in a chain via both electron tunneling and crossed Andreev reflection. While both processes have been observed in semiconducting nanowires and carbon nanotubes, crossed-Andreev interaction was neither easily tunable nor strong enough to induce coherent hybridization of dot states. Here we demonstrate the simultaneous presence of all necessary ingredients for an artificial Kitaev chain: two spin-polarized quantum dots in an InSb nanowire strongly coupled by both elastic co-tunneling and crossed Andreev reflection. We fine-tune this system to a sweet spot where a pair of Poor Man's Majorana states is predicted to appear. At this sweet spot, the transport characteristics satisfy the theoretical predictions for such a system, including pairwise correlation, zero charge and stability against local perturbations. While the simple system presented here can be scaled to simulate a full Kitaev chain with an emergent topological order, it can also be used imminently to explore relevant physics related to non-Abelian anyons., Comment: Authors' version of the accepted manuscript

In most naturally occurring superconductors, electrons with opposite spins are paired up to form Cooper pairs. This includes both conventional $s$-wave superconductors such as aluminum as well as high-$T_\text{c}$, $d$-wave superconductors. Materials with intrinsic $p$-wave superconductivity, hosting Cooper pairs made of equal-spin electrons, have not been conclusively identified, nor synthesized, despite promising progress. Instead, engineered platforms where $s$-wave superconductors are brought into contact with magnetic materials have shown convincing signatures of equal-spin pairing. Here, we directly measure equal-spin pairing between spin-polarized quantum dots. This pairing is proximity-induced from an $s$-wave superconductor into a semiconducting nanowire with strong spin-orbit interaction. We demonstrate such pairing by showing that breaking a Cooper pair can result in two electrons with equal spin polarization. Our results demonstrate controllable detection of singlet and triplet pairing between the quantum dots. Achieving such triplet pairing in a sequence of quantum dots will be required for realizing an artificial Kitaev chain., Comment: Authors' version of the accepted manuscript

Utilizing dispersive gate sensing (DGS), we investigate the spin-orbit field ($\textbf{B}_{SO}$) orientation in a many-electron double quantum dot (DQD) defined in an InSb nanowire. While characterizing the inter-dot tunnel couplings, the measured dispersive signal depends on the electron charge occupancy, as well as on the amplitude and orientation of the external magnetic field. The dispersive signal is mostly insensitive to the external field orientation when a DQD is occupied by a total odd number of electrons. For a DQD occupied by a total even number of electrons, the dispersive signal is reduced when the finite external magnetic field aligns with the effective $\textbf{B}_{SO}$ orientation. This fact enables the identification of $\textbf{B}_{SO}$ orientations for different DQD electron occupancies. The $\textbf{B}_{SO}$ orientation varies drastically between charge transitions, and is generally neither perpendicular to the nanowire nor in the chip plane. Moreover, $\textbf{B}_{SO}$ is similar for pairs of transitions involving the same valence orbital, and varies between such pairs. Our work demonstrates the practicality of DGS in characterizing spin-orbit interactions in quantum dot systems, without requiring any current flow through the device.

We systematically study three-terminal InSb-Al nanowire devices by using radio-frequency reflectometry. Tunneling spectroscopy measurements on both ends of the hybrid nanowires are performed while systematically varying the chemical potential, magnetic field and junction transparencies. Identifying the lowest-energy state allows for the construction of lowest- and zero-energy state diagrams, which show how the states evolve as a function of the aforementioned parameters. Importantly, comparing the diagrams taken for each end of the hybrids enables the identification of states which do not coexist simultaneously, ruling out a significant amount of the parameter space as candidates for a topological phase. Furthermore, altering junction transparencies filters out zero-energy states sensitive to a local gate potential. Such a measurement strategy significantly reduces the time necessary to identify a potential topological phase and minimizes the risk of falsely recognizing trivial bound states as Majorana zero modes., Comment: Main text: 12 pages, 9 figures. SupplementaryMaterials: 12 pages, 14 figures

Indium antimonide (InSb) nanowires are used as building blocks for quantum devices because of their unique properties, i.e., strong spin-orbit interaction and large Land\'e g-factor. Integrating InSb nanowires with other materials could potentially unfold novel devices with distinctive functionality. A prominent example is the combination of InSb nanowires with superconductors for the emerging topological particles research. Here, we combine the II-VI cadmium telluride (CdTe) with the III-V InSb in the form of core-shell (InSb-CdTe) nanowires and explore potential applications based on the electronic structure of the InSb-CdTe interface and the epitaxy of CdTe on the InSb nanowires. We determine the electronic structure of the InSb-CdTe interface using density functional theory and extract a type-I band alignment with a small conduction band offset ($\leq$ 0.3 eV). These results indicate the potential application of these shells for surface passivation or as tunnel barriers in combination with superconductors. In terms of the structural quality of these shells, we demonstrate that the lattice-matched CdTe can be grown epitaxially on the InSb nanowires without interfacial strain or defects. These epitaxial shells do not introduce disorder to the InSb nanowires as indicated by the comparable field-effect mobility we measure for both uncapped and CdTe-capped nanowires.

The lowest-energy excitations of superconductors do not carry an electric charge, as their wave function is equally electron-like and hole-like. This fundamental property is not easy to study in electrical measurements that rely on the charge to generate an observable signal. The ability of a quantum dot to act as a charge filter enables us to solve this problem and measure the quasiparticle charge in superconducting-semiconducting hybrid nanowire heterostructures. We report measurements on a three-terminal circuit, in which an injection lead excites a non-equilibrium quasiparticle distribution in the hybrid system, and the electron or hole component of the resulting quasiparticles is detected using a quantum dot as a tunable charge and energy filter. The results verify the chargeless nature of the quasiparticles at the gap edge and reveal the complete relaxation of injected charge and energy in a proximitized nanowire, resolving open questions in previous three-terminal experiments.

We demonstrate the use of radio-frequency (rf) resonators to measure the capacitance of nano-scale semiconducting devices in field-effect transistor configurations. The rf resonator is attached to the gate or the lead of the device. Consequently, tuning the carrier density in the conducting channel of the device affects the resonance frequency, quantitatively reflecting its capacitance. We test the measurement method on InSb and InAs nanowires at dilution-refrigerator temperatures. The measured capacitances are consistent with those inferred from the periodicity of the Coulomb blockade of quantum dots realized in the same devices. In an implementation of the resonator using an off-chip superconducting spiral inductor we find sensitivity values reaching down to 75~zF/$\sqHz$ at 1~kHz measurement bandwidth, and noise down to 0.45~aF at 1~Hz bandwidth. We estimate the sensitivity of the method for a number of other implementations. In particular we predict typical sensitivity of about 40~zF/$\sqHz$ at room temperature with a resonator comprised of off-the-shelf components. Of several proposed applications, we demonstrate two: the capacitance measurement of several identical 80~nm-wide gates with a single resonator, and the field-effect mobility measurement of an individual nanowire with the gate capacitance measured in-situ.

We study a Cooper-pair transistor realized by two Josephson weak links that enclose a superconducting island in an InSb-Al hybrid nanowire. When the nanowire is subject to a magnetic field, isolated subgap levels arise in the superconducting island and, due to the Coulomb blockade,mediate a supercurrent by coherent co-tunneling of Cooper pairs. We show that the supercurrent resulting from such co-tunneling events exhibits, for low to moderate magnetic fields, a phase offset that discriminates even and odd charge ground states on the superconducting island. Notably,this phase offset persists when a subgap state approaches zero energy and, based on theoretical considerations, permits parity measurements of subgap states by supercurrent interferometry. Such supercurrent parity measurements could, in a new series of experiments, provide an alternative approach for manipulating and protecting quantum information stored in the isolated subgap levels of superconducting islands.

Kitaev chain is a theoretical model of a one-dimensional topological superconductor with Majorana zero modes at the two ends of the chain. With the goal of emulating this model, we build a chain of three quantum dots in a semiconductor nanowire. We observe Andreev bound states in each of the three dots and study their magnetic field and gate voltage dependence. Theory indicates that triple dot states acquire Majorana polarization when Andreev states in all three dots reach zero energy in a narrow range of magnetic field. In our device Andreev states in one of the dots reach zero energy at a lower field than in other two, placing the Majorana regime out of reach. Devices with greater uniformity or with independent control over superconductor-semiconductor coupling should can realize the Kitaev chain with high yield. Due to its overall tunability and design flexibility the quantum dot system remains promising for quantum simulation of interesting models and in particular for modular topological quantum devices., Comment: Full data and code are available on Zenodo https://zenodo.org/communities/frolovlab/

Semiconducting-superconducting nanowires attract widespread interest owing to the possible presence of non-abelian Majorana zero modes, which hold promise for topological quantum computation. However, the search for Majorana signatures is challenging because reproducible hybrid devices with desired nanowire lengths and material parameters need to be reliably fabricated to perform systematic explorations in gate voltages and magnetic fields. Here, we exploit a fabrication platform based on shadow walls that enables the in-situ, selective and consecutive depositions of superconductors and normal metals to form normal-superconducting junctions. Crucially, this method allows to realize devices in a single shot, eliminating fabrication steps after the synthesis of the fragile semiconductor/superconductor interface. At the atomic level, all investigated devices reveal a sharp and defect-free semiconducting-superconducting interface and, correspondingly, we measure electrically a hard induced superconducting gap. While our advancement is of crucial importance for enhancing the yield of complex hybrid devices, it also offers a straightforward route to explore new material combinations for hybrid devices.

The realization of a topological qubit calls for advanced techniques to readily and reproducibly engineer induced superconductivity in semiconductor nanowires. Here, we introduce an on-chip fabrication paradigm based on shadow walls that offers substantial advances in device quality and reproducibility. It allows for the implementation of novel quantum devices and ultimately topological qubits while eliminating many fabrication steps such as lithography and etching. This is critical to preserve the integrity and homogeneity of the fragile hybrid interfaces. The approach simplifies the reproducible fabrication of devices with a hard induced superconducting gap and ballistic normal-/superconductor junctions. Large gate-tunable supercurrents and high-order multiple Andreev reflections manifest the exceptional coherence of the resulting nanowire Josephson junctions. Our approach enables, in particular, the realization of 3-terminal devices, where zero-bias conductance peaks emerge in a magnetic field concurrently at both boundaries of the one-dimensional hybrids.

Signatures of Majorana zero modes (MZMs), which are the building blocks for fault-tolerant topological quantum computing, have been observed in semiconductor nanowires (NW) with strong spin-orbital-interaction (SOI), such as InSb and InAs NWs with proximity-induced superconductivity. Realizing topological superconductivity and MZMs in this most widely-studied platform also requires eliminating spin degeneracy, which is realized by applying a magnetic field to induce a helical gap. However, the applied field can adversely impact the induced superconducting state in the NWs and also places geometric restrictions on the device, which can affect scaling of future MZM-based quantum registers. These challenges could be circumvented by integrating magnetic elements with the NWs. With this motivation, in this work we report the first experimental investigation of spin transport across InSb NWs, which are enabled by devices with ferromagnetic (FM) contacts. We observe signatures of spin polarization and spin-dependent transport in the quasi-one-dimensional ballistic regime. Moreover, we show that electrostatic gating tunes the observed magnetic signal and also reveals a transport regime where the device acts as a spin filter. These results open an avenue towards developing MZM devices in which spin degeneracy is lifted locally, without the need of an applied magnetic field. They also provide a path for realizing spin-based devices that leverage spin-orbital states in quantum wires., Comment: 30 pages, 12 figures