1. Electronic structure and glass forming ability in early and late transition metal alloys
- Author
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Babić, E., Ristić, R., Figueroa, I. A., Pajić, D., Skoko, Ž., and Zadro, K.
- Subjects
Condensed Matter - Materials Science - Abstract
A correlation between the change in magnetic susceptibility ({\Delta}\c{hi}exp) upon crystallization of Cu-Zr, Hf metallic glasses (MG) with their glass forming ability (GFA) observed recently is found to apply to Cu-Ti and Zr-Ni alloys, too. In particular, a small {\Delta}\c{hi}exp , which reflects similar electronic structures, ES, of glassy and corresponding crystalline alloys, corresponds to high GFA. Here, we studied {\Delta}\c{hi}exp in five Cu-Ti and four Cu-Zr and Ni-Zr MGs. The fully crystalline final state of all alloys was verified from X-ray diffraction patterns. The variation of GFA with composition in Cu-Ti, Cu-Zr and Cu-Hf MGs was established from the variation of the corresponding critical casting thickness, dc. Due to the absence of data for dc in Ni-Zr MGs their GFA was described by using empirical criteria, such as the reduced glass transition temperature. A very good correlation between {\Delta}\c{hi}exp and dc (and/or other criteria for GFA) was observed for all alloys studied. The correlation between the ES and GFA showed up best for Cu-Zr and NiZr2 alloys where direct data for the change in ES ({\Delta}ES) upon crystallization are available. The applicability of the {\Delta}\c{hi}exp ({\Delta}ES) criterion for high GFA (which provides a simple way to select the compositions with high GFA) to other metal-metal MGs (including ternary and multicomponent bulk MGs) is briefly discussed., Comment: 29 pages, 6 figures
- Published
- 2017
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