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Sustainably grown biomass is a promising alternative to produce fuels and chemicals and reduce the dependency on fossil energy sources. However, the efficient conversion of lignocellulosic biomass into biofuels and bioproducts often requires extensive testing of components and reaction conditions used in the pretreatment, saccharification, and bioconversion steps. This restriction can result in a significant and unwieldy number of combinations of biomass types, solvents, microbial strains, and operational parameters that need to be characterized, turning these efforts into a daunting and time-consuming task. Here we developed a high-throughput feedstocks-to-fuels screening platform to address these challenges. The result is a miniaturized semi-automated platform that leverages the capabilities of a solid handling robot, a liquid handling robot, analytical instruments, and a centralized data repository, adapted to operate as an ionic-liquid-based biomass conversion pipeline. The pipeline was tested by using sorghum as feedstock, the biocompatible ionic liquid cholinium phosphate as pretreatment solvent, a one-pot process configuration that does not require ionic liquid removal after pretreatment, and an engineered strain of the yeast Rhodosporidium toruloides that produces the jet-fuel precursor bisabolene as a conversion microbe. By the simultaneous processing of 48 samples, we show that this configuration and reaction conditions result in sugar yields (~70%) and bisabolene titers (~1500 mg/L) that are comparable to the efficiencies observed at larger scales but require only a fraction of the time. We expect that this Feedstocks-to-Fuels pipeline will become an effective tool to screen thousands of bioenergy crop and feedstock samples and assist process optimization efforts and the development of predictive deconstruction approaches.

Our reliance on agriculture for sustenance, healthcare, and resources has been essential since the dawn of civilization. However, traditional agricultural practices are no longer adequate to meet the demands of a burgeoning population amidst climate-driven agricultural challenges. Microalgae emerge as a beacon of hope, offering a sustainable and renewable source of food, animal feed, and energy. Their rapid growth rates, adaptability to non-arable land and non-potable water, and diverse bioproduct range, encompassing biofuels and nutraceuticals, position them as a cornerstone of future resource management. Furthermore, microalgaes ability to capture carbon aligns with environmental conservation goals. While microalgae offers significant benefits, obstacles in cost-effective biomass production persist, which curtails broader application. This review examines microalgae compared to other host platforms, highlighting current innovative approaches aimed at overcoming existing barriers. These approaches include a range of techniques, from gene editing, synthetic promoters, and mutagenesis to selective breeding and metabolic engineering through transcription factors.

The development of microalgae‐based biofuels has emerged as a promising solution to address the pressing global challenges of climate change, resource scarcity, and the need for renewable energy sources. Microalgae possess unique capabilities that make them an attractive feedstock for biofuel production, including their ability to capture and sequester carbon dioxide, their efficient use of water and land resources, and the potential for them to utilize waste streams as nutrient sources. This paper provides a comprehensive overview of the environmental and economic implications of microalgae‐derived fuels, highlighting the key benefits and remaining challenges. The integration of synthetic biology to enhance microalgae strains, optimize cultivation and processing, and diversify revenue streams is explored as a means to address the economic barriers to large‐scale commercialization. As research and development in this field continue to progress, the future prospects of microalgae‐based biofuels are discussed, underscoring their potential to reshape the global energy landscape towards a more sustainable and economically viable future. [ABSTRACT FROM AUTHOR]

A process combining aldol condensation and hydrogenation of bio‐based cyclopentanone (CPO) in a one‐pot reaction is proposed. Cu‐based bifunctional catalysts obtained from hydrotalcite‐type precursors were found highly active in mild reaction conditions (i.e., 130–170 °C), producing valuable bicyclic (C10) and tricyclic (C15) aliphatic alcohols/ketones with interesting application as sustainable aviation fuel (SAF) precursors with enhanced properties. The presence of surficial strong basic sites active in aldol condensation, together with the formation of highly dispersed copper nanoparticles able to catalyze C═C and C═O hydrogenation (TOF of 0.06–0.16 s−1), assured high catalytic efficiency and fine control of the products nature and distribution. From the optimization of both catalysts formulation and reaction conditions it was found that, properly tuning the Cu content, it is possible to drive products distribution towards the production of bicyclic (C10) aliphatic alcohol with high selectivity (75% at total CPO conversion, when Cu = 10 wt %, at 170 °C, 1.0 MPa of H2) and short reaction time (4 h). The optimized catalyst formulation showed impressive stability over multiple reaction/regeneration cycles, demonstrating the high potential of the proposed catalytic process for future applications in sustainable biofuels production. [ABSTRACT FROM AUTHOR]

In the strategy to combat climate change that has been caused by the world's overdependence on fossil fuels, current research is focusing on the decarbonisation of the energy sector through the production of renewable cleaner energy, such as biofuels. Spent coffee grounds (SCGs), the waste stream of the coffee brewing industry, are a potential feedstock for the production of valuable products, including biofuels. However, the environmental implications for the valorisation of this valuable waste need to be investigated. This study assesses the environmental impacts of six biomass‐to‐fuel processing technologies using SCGs as a feedstock, with the aim of identifying the most environmentally friendly technology. A cradle‐to‐gate life‐cycle assessment (LCA) was conducted on fast pyrolysis, fermentation, anaerobic digestion (AD), hydrothermal liquefaction (HTL), gasification, and biodiesel production. The mass and energy balances obtained from Aspen Plus simulations served as the life‐cycle inventory data. Using the ReCiPe 2016 midpoint (H) and Eco‐Indicator 99 as the assessment methods, potential environmental impacts were calculated in OpenLCA software. Electricity generation and carbon dioxide emissions were the biggest contributors of environmental impacts. For each category, the maximum result was set to 100% and the results of the other variants were displayed in relation to this result. AD, with the smallest total weighted score (160), was the most environmentally friendly biomass‐to‐fuel processing route, while HTL, with the biggest total weighted score (893), was the worst. A sensitivity analysis indicated that the environmental performance of biofuel production from SCGs was highly influenced by energy input flows and the source of energy generation. [ABSTRACT FROM AUTHOR]

Reducing maritime greenhouse gas (GHG) emissions is challenging. As efforts to address climate change are gaining momentum, reducing the environmental impact becomes crucial for maritime short-to-medium-term sustainability. The International Maritime Organisation (IMO) has adopted Life Cycle Assessment (LCA) guidelines for estimating GHG emissions associated with alternative fuels. This paper proposes an examination of the latest IMO-adopted LCA guidelines, comparing them with existing methodologies used for the transport sector. By scrutinising these guidelines, the paper aims to provide a better understanding of the evolving landscape for GHG emission estimation within the maritime sector. The paper presents a case study that applies the newly established LCA guidelines to a promising alternative fuel pathway, i.e., waste-wood-derived pyrolysis oil. Pyrolysis oil offers an attractive option, leveraging waste materials to generate a sustainable energy source. The environmental impact of pyrolysis oils is quantified according to the IMO LCA guidelines, offering insights into its viability as a cleaner alternative as marine fuel. The results show the large potential for GHG savings offered by this pathway: upgraded pyrolysis oil can deliver significant GHG savings, and this contribution is linearly dependent of its energy share when blended with standard Heavy Fuel Oil. [ABSTRACT FROM AUTHOR]

Energy security and the transition to a thriving lowcarbon economy are essential for a developing nation like India. We examined the life-cycle greenhouse gas emissions (GHG) and environmental impact of bioethanol production from jute and kenaf feedstock. It was observed that net GHG emissions from crop production and bio-refinery from jute and kenaf ethanol were 3.45 and 5.88 g MJ-1 respectively. This result is much lower than any other feedstock like sugarcane bagasse, corn stover, rice straw and wheat straw. Life cycle assessment revealed that ethanol produced from jute and kenaf biomass can reduce GHG emissions by 78-81% when compared with petrol. Bioethanol has the least negative effects (rice straw > sugarcane bagasse > wheat straw > corn stover > jute, kenaf) on the environment and resource depletion. It might deliver 60% of the ethanol requirement annually and may prove to be a workable technology for meeting ethanol-to-petrol blend targets. [ABSTRACT FROM AUTHOR]

The development of aviation biofuels is a key strategy for reducing carbon emissions in the aviation industry. This study aimed to establish a surrogate model for aviation biofuels using a hybrid approach that combined explicit equations with an artificial neural network (ANN). The low heating value was calculated using an explicit equation, whereas the ANN predicted changes in density, viscosity, surface tension with temperature, and the distillation curve of the surrogate model. An optimization algorithm was then employed to identify suitable substitutes, which consisted of 11.44% n‐decane, 43.43% n‐dodecane, 43.11% n‐tetradecane, and 2.02% methylcyclohexane. The maximum error between the physical properties of the surrogate components and the measured biofuels did not exceed 7%. The ignition delay time of the substitute components matched that of real aviation biofuels at an equivalence ratio of 1.0 and a pressure of 10 bar. [ABSTRACT FROM AUTHOR]

D-xylose is the second most abundant monosaccharide found in lignocellulose and is of biotechnological importance for producing second-generation ethanol and other high-value chemical compounds. D-xylose conversion to ethanol is promoted by microbial fermentation, mainly by bacteria, yeasts, or filamentous fungi. Among yeasts, species belonging to the CTG(Ser1) or CTG(Ala) clade display a remarkable ability to ferment D-xylose to ethanol and other compounds; however, these yeasts are not employed on an industrial scale given their poor fermentative performance compared to that of conventional yeasts, such as Saccharomyces cerevisiae, and because of the lack of a molecular toolbox for the development of new strains tailored to fermentation stress tolerance and performance. Thus, the purpose of this review was to evaluate the major genetic engineering tools (e.g., transformation markers and techniques, vectors, regulatory sequences, and gene editing techniques) available for the most studied yeasts of the CTG(Ser1) clade, such as Scheffersomyces , Spathaspora , Candida , and Yamadazyma species, and the CTG(Ala) clade, representative Pachysolen tannophilus. Furthermore, we systematized state-of-the-art molecular developments and perspectives to design D-xylose-fermenting yeast strains. • Review of genetic tools in CTG(Ser1) and CTG(Ala) yeasts for bioethanol production. • CTG codon reassignment impairs the use of conventional genetic engineering tools. • CTG(Ser1) yeasts can use genetic tools from clinically important Candida strains for research. [ABSTRACT FROM AUTHOR]

Asterarcys quadricellularis strain AQYS21, a green microalga isolated from the brackish waters near Manseong-ri Black Sand Beach in Korea, shows considerable potential as a source of bioactive compounds and biofuels. Therefore, this study analyzed the morphological, molecular, and biochemical characteristics of this strain; optimized its cultivation conditions; and evaluated its suitability for biodiesel production. Morphological analysis revealed characteristics typical of the Asterarcys genus: spherical to ellipsoidal cells with pyrenoid starch plates and mucilage-embedded coenobia. Additionally, features not previously reported in other A. quadricellularis strains were observed. These included young cells with meridional ribs and an asymmetric spindle-shaped form with one or two pointed ends. Molecular analysis using small-subunit rDNA and tufA sequences confirmed the identification of the strain AQYS21. This strain showed robust growth across a wide temperature range, with optimal conditions at 24 °C and 88 µmol m−2s−1 photon flux density. It was particularly rich in ω-3 α-linolenic acid and palmitic acid. Furthermore, its biodiesel properties indicated its suitability for biodiesel formulations. The biomass of this microalga may serve as a viable feedstock for biodiesel production and a valuable source of ω-3 fatty acids. These findings reveal new morphological characteristics of A. quadricellularis, enhancing our understanding of the species. [ABSTRACT FROM AUTHOR]

Innovations are crucial for the transition to a sustainable bioeconomy. They are embedded in and linked to complex value chains, but these interrelationships have not received much attention in the empirical literature yet. Using current typologies of four bioeconomic innovation types and six value chain models, this case study analyzes detailed data from 11 companies in Argentina to identify the drivers of sustainable innovations, their linkage to different value chain characteristics, and the main innovation types. The results show that certain factors such as supply and demand, interindustry cooperation and R&D, diversification strategies, personal values and the search for sustainable solutions particularly shape certain types of innovation. The structure and governance of the value chains influence the type of sustainable innovation. Innovations take place at different levels, and in succession, they complement each other and can thus make the bioeconomy more sustainable. Therefore, appropriate policies to promote the bioeconomy in Argentina and beyond should consider the type of value chains and specific innovation systems involved. [ABSTRACT FROM AUTHOR]

An integrated thermochemical-biochemical Biomass-to-Liquid (BtL) pathway for the production of aviation and maritime liquid fuels from biogenic residues is introduced. The presence of a semi-commercially proven technology like Dual Fluidized Bed Gasification (DFBG) ensures extended fuel flexibility, syngas of high quality, complete fuel conversion, and optimal heat integration while avoiding CAPEX (Capital Expenditure) intensive equipment like air separation unit. Then, a two-stage biochemical route is proposed: initially syngas fermentation (anaerobic) into acetate and subsequently acetate fermentation (aerobic) into targeted triglycerides (TAGs) that will be finally purified and hydrotreated to form the desired drop-in biofuels. The tolerance of the bacteria to syngas contaminants minimizes the gas cleaning requirements. Moreover, the low-pressure requirements (1–10 bar) along with the mild operating temperatures (30–60 °C) reduce drastically the capital and operational cost of the process. The biological process of syngas fermentation inherently has limited side products, a fact that reduces the risk of deactivation of hydrotreatment catalysts. Heat and mass balances are calculated for the proposed concept via full-scale process simulations in Aspen Plus™ assuming a thermal input of 200 MWth with crushed bark as feedstock. Three different operational scenarios are examined mainly through overall performance indicators such as carbon utilization (CU) and energetic fuel efficiency (EFE). Competitive performance compared to technologies that exploit similar feedstock (i.e., biogenic residues) was noticed, since values in the range of 22–27% and 31–37% were obtained for the CU and EFE, respectively. The aim of this study is to determine the appropriate key process specifications and assess the potential of the proposed concept compared to other competitive technologies. [ABSTRACT FROM AUTHOR]

The automotive industry must mitigate climate change by reducing vehicle carbon emissions and promoting sustainable transportation through technical solutions and innovations. Biofuels are seen as a solution to reduce CO2 emissions, but they may affect fuel performance and emissions. Second-generation biogasoline mixed with ethanol has proven that it can be introduced as a drop-in fuel with the same performance and tailpipe emissions at the same level as fossil fuels. However, particulate matter (PM) emissions are significantly higher than fossil fuels. This study aims to experimentally investigate the effect of port and direct fuel injections on the PM emissions in a boosted spark ignition (SI) engine fuelled by Euro 6 standard biofuel with a 99 octane number blended with 20% ethanol compared to a fossil fuel baseline. The single-cylinder SI engine was equipped with two fuel injectors, a direct injector and a port fuel injector, and operated with externally boosted air. The split injection ratio was adjusted from 100% direct injection (DI) to 100% port fuel injection (PFI) to investigate the combustion characteristics and particulate emissions (PM) at different engine loads and speeds. The results indicate that by changing 100% DI to 80% PFI, PM emissions numbers between particle sizes of 23 and 1000 nm were dropped by 96.56% at a low load operation of 4.6 bar IMEP for the 99 RON E20 biogasoline and by 84% for the 95 RON E10 fossil fuel while maintaining the same indicated thermal efficiency and a similar level of other emissions. However, at a higher load above 10 bar IMEP, it was found that full DI operation reduced particulate numbers (PN) by 64% and 38% for 99 RON E20 biogasoline and 95 RON E10 fossil fuel at 20 bar IMEP, respectively, and enabled more stable operation at 3000 rpm with higher load operation regions. [ABSTRACT FROM AUTHOR]

The development of integrated biorefineries and the greater utilization of biomass resources to reduce dependence on fossil fuel‐derived products require research emphasis not just on conversion strategies but also on improving separations associated with biorefining. A significant roadblock towards developing biorefineries is the lack of effective separation techniques evidenced by the relative deficiency of literature in this area. Additionally, high conversion yields may only be realized if effective separations generate feedstock of sufficient purity – this makes research into biomass conversion strategies all the more critical. In this review, the challenges associated with biomass separations are discussed, followed by an overview of the most appropriate separation strategies for processing biomass. One of the unit operations most appealing for biorefining, membrane separations (MS), is then considered along with a review of the recent literature utilizing this technique in biomass processing. [ABSTRACT FROM AUTHOR]

Biofuel production has emerged as a leading contender in the quest for renewable energy solutions, offering a promising path toward a greener future. This comprehensive state-of-the-art review delves into the current landscape of biofuel production, exploring its potential as a viable alternative to conventional fossil fuels. This study extensively examines various feedstock options, encompassing diverse sources such as plants, algae, and agricultural waste, and investigates the technological advancements driving biofuel production processes. This review highlights the environmental benefits of biofuels, emphasizing their capacity to significantly reduce greenhouse gas emissions compared to those of fossil fuels. Additionally, this study elucidates the role of biofuels in enhancing energy security by decreasing reliance on finite fossil fuel reserves, thereby mitigating vulnerabilities to geopolitical tensions and price fluctuations. The economic prospects associated with biofuel production are also elucidated, encompassing job creation, rural development, and the potential for additional revenue streams for farmers and landowners engaged in biofuel feedstock cultivation. While highlighting the promise of biofuels, the review also addresses the challenges and considerations surrounding their production. Potential issues such as land use competition, resource availability, and sustainability implications are critically evaluated. Responsible implementation, including proper land-use planning, resource management, and adherence to sustainability criteria, is emphasized as critical for the long-term viability of biofuel production. Moreover, the review underscores the importance of ongoing research and development efforts aimed at enhancing biofuel production efficiency, feedstock productivity, and conversion processes. Technological advancements hold the key to increasing biofuel yields, reducing production costs, and improving overall sustainability. This review uniquely synthesizes the latest advancements across the entire spectrum of biofuel production, from feedstock selection to end-use applications. It addresses critical research gaps by providing a comprehensive analysis of emerging technologies, sustainability metrics, and economic viability of various biofuel pathways. Unlike previous reviews, this work offers an integrated perspective on the interplay between technological innovation, environmental impact, and socio-economic factors in biofuel development, thereby providing a holistic framework for future research and policy directions in renewable energy. [ABSTRACT FROM AUTHOR]

Straight soybean and diesel oil blends are proposed as alternatives for electricity generation in isolated regions. The compression ignition engine is considered the prime mover and has the attractive potential to distribute electricity generation for supply in isolated regions, as well as for small applications demanded by the agro-industrial sector. The heat release rate evaluation of straight soybean blends is the main focus of this paper. A single-cylinder compression ignition engine with a nominal power of 14.7 kW/2200 rpm fueled with blends of 50% and 80% v/v straight soybean oil with commercial diesel oil was tested on a dynamometer bench. The heat release rate and ignition delay were determined from in-cylinder pressure measurements using zero-dimensional modeling. The experimental results showed a promising performance and coherent behavior with the physicochemical fuel properties and load conditions tested. The highest fraction of vegetable oil led to a combustion delay, characterized by high diffusive and residual combustion phases, although the fuel oxygen content favored the combustion. Finally, this work allowed observation of the development of the heat release rate of straight soybean blends in a diesel engine, understanding the influence of the fuel properties and in-cylinder gas properties on the combustion process. [ABSTRACT FROM AUTHOR]

The widespread use of glyphosate as broad-spectrum herbicide has caused detrimental effects on phytoplankton communities. In the present study, the effects of glyphosate (4 mg/L) on the physiology of a resistant microalga, Chlorella sorokiniana UUIND6, were examined in both indoor and outdoor cultivation systems to correlate the findings with aquatic ecology. Notably, outdoor ponds had higher dissolved oxygen (17 mg/L) than indoor ponds, resulting in a 30% reduction in algal growth, with volumetric productivity of 0.068 g/L/D, which were 1.5-fold lower than indoor cultures. Furthermore, indoor cultures had 1.7-fold higher lipid productivity and carbohydrate productivity than outdoor cultures. To acclimatize to changing outdoor conditions, the alga modulated its cell membrane fluidity and permeability by increasing saturated fatty acids with a concomitant decrease in monosaturated fatty acids and phospholipids. The study identified C. sorokiniana as a potential candidate for outdoor cultivation for bioproduct production. [ABSTRACT FROM AUTHOR]

The growth in population, economic expansion, and urban dynamism has collectively driven a surge in the use of public and private transport, resulting in increased energy consumption in this sector. Consequently, the transport sector requires an energy transition to meet mobility demands, foster economic growth, and achieve emission reduction. The main objective of this article is to systematically review the literature on energy transition in transportation, categorizing research, identifying barriers, and providing analysis to guide future steps, with a special focus on developing countries. The methodology used in this study follows a sequence for a systematic review based on an evidence-informed approach and specific guidelines for systematic reviews, exploring the concepts, methodologies, and policies within the context of the energy transition, considering transport modes and geographical scope. The findings indicate that electricity is the predominant energy source in this transition, although its prevalence varies by transport mode. Biofuels present an alternative, primarily contributing to emission reduction associated with fossil fuel use. Natural gas emerges as a cost-effective option for heavy transport, while hydrogen represents another alternative, with the challenge of developing recharging infrastructure. Determinants of this transition include recharging infrastructure, tax and nontax incentives, public policies, the generation of electric power from renewable sources, and the management of battery life cycles from mineral extraction to disposal. [ABSTRACT FROM AUTHOR]

Aim Ammonium chloride (NH4Cl) is one of the nitrogen sources for microalgal cultivation. An excessive amounts of NH4Cl are toxic for microalgae. However, combining mixotrophic conditions and excessive quantities of NH4Cl positively affects microalgal biomass and lipid production. In this study, we investigated the impact of NH4Cl on the growth, biomass, and triglyceride (TAG) content of the green microalga Chlamydomonas reinhardtii especially under mixotrophic conditions. Methods and results Under photoautotrophic conditions (without organic carbon supplementation), adding 25 mM NH4Cl had no significant effect on microalgal growth or TAG content. However, under mixotrophic condition (with acetate supplementation), NH4Cl interfered with microalgal growth while inducing TAG content. To explore these effects further, we conducted a two-step cultivation process and found that NH4Cl reduced microalgal growth, but induced total lipid and TAG content, especially after 4-day cultivation. The photosynthesis performances showed that NH4Cl completely inhibited oxygen evolution on day 4. However, NH4Cl slightly reduced the F v/ F m ratio indicating that the NH4Cl supplementation directly affects microalgal photosynthesis. To investigate the TAG induction effect by NH4Cl, we compared the protein expression profiles of microalgae grown mixotrophically with and without 25 mM NH4Cl using a proteomics approach. This analysis identified 1782 proteins, with putative acetate uptake transporter GFY5 and acyl-coenzyme A oxidase being overexpressed in the NH4Cl-treated group. Conclusion These findings suggested that NH4Cl supplementation may stimulate acetate utilization and fatty acid synthesis pathways in microalgae cells. Our study indicated that NH4Cl supplementation can induce microalgal biomass and lipid production, particularly when combined with mixotrophic conditions. [ABSTRACT FROM AUTHOR]

Finding alternatives to fossil fuels is extremely important for economic and environmental considerations. Biomass pyrolysis stands out as an efficient method for generating fuels and chemical intermediates. This study explored the influence of wood particle size (ranging from 1 to 3 cm) and pyrolysis temperature (ranging from about 300 to 480 °C) on the process. Characterization of wood residues utilized energy-dispersive X-ray (EDX) and field emission scanning electron microscopy (FE-SEM) to comprehend surface morphology and resultant biochar structure. Results revealed a significant temperature-dependent impact on pyrolysis product concentrations. Biomass composition analysis indicates lignin, hemicellulose, extractive contents, and cellulose percentages at 11.23%, 39%, 2.15%, and 47.62% mass/mass, respectively. Reduction in particle size to less than 2 mm enhances heat transfer, elevating overall bio-oil production. Major bio-oil components comprise phenolics, acids, alcohols, aldehydes, and ketones. Optimal conditions are identified at a wood particle size of 1 cm and a heating temperature of 480 °C. For every 1.0 kg of wood biomass residues, bio-oil, syngas, and biochar yields are 0.38 kg, 0.22 kg, and 0.4 kg, respectively. Notably, the agreement between Aspen Plus simulation and experimental findings underscored the robustness of the study. [ABSTRACT FROM AUTHOR]

Nickel catalysts promoted with Mo and supported on silica were studied for renewable diesel production from triglyceride biomass, through the selective deoxygenation process. The catalysts were prepared by wet co-impregnation of the SiO2 with different Ni/(Ni + Mo) atomic ratios (0/0.84/0.91/0.95/0.98/1) and a total metal content equal to 50%. They were characterized by XRD, XPS, N2 physisorption, H2-TPR, and NH3-TPD. Evaluation of the catalysts for the transformation of sunflower oil to renewable (green) diesel took place in a high-pressure semi-batch reactor, under solvent-free conditions. A very small addition of Mo, namely the synergistic Ni/(Ni + Mo) atomic ratio equal to 0.95, proved to be the optimum one for a significant enhancement of the catalytic performance of the metallic Ni/SiO2 catalyst, achieving 98 wt.% renewable diesel production. This promoting action of Mo has been attributed to the significant increase of the metallic Ni active phase surface area, the suitable regulation of surface acidity, the acceleration of the hydro-deoxygenation pathway (HDO), the creation of surface oxygen vacancies, and the diminution of coke formation provoked by Mo addition. [ABSTRACT FROM AUTHOR]

The expansion of sugarcane, a tropical high‐yielding feedstock, will likely reshape the Southeastern United States (SE US) bioenergy landscape. However, the sustainability of sugarcane, particularly as it displaces grazed pastures, is highly uncertain. Here, we investigated how pasture conversion to sugarcane in subtropical Florida impacts net ecosystem CO2 exchange (NEE) and net ecosystem carbon (C) balance (NECB). Measurements were made over three full growth cycles (> 3 years) in sugarcane—plant cane, PC; first ratoon cane, FRC; second ratoon cane, SRC—and in improved (IM) and semi‐native (SN) pastures, which make up ca. 37% of agricultural land in the region. Immediately following conversion, PC was a stronger net source of CO2 than pastures, indicating the importance of CO2 losses related to land disturbance. Sugarcane, however, shifted to a strong net sink of CO2 after first regrowth, and overall sugarcane was a stronger net CO2 sink than pastures. Both stand age and low water availability during cane emergence and tillering substantially decreased its potential gross CO2 uptake. Accounting for all C gains and removals (i.e., NECB), greater frequency of burn events and repeated harvest increased removals and overall made sugarcane a stronger C source relative to pastures despite substantial C inputs from the previous land use and a stronger CO2 sink strength. Time since conversion substantially reduced C losses from sugarcane, and the NECB of SRC was similar to that of IM pasture but lower than that of SN pasture, indicating a rapid shift in the NECB of cane. We conclude that the C‐balance implications following conversion will depend on the proportion of IM versus SN pastures converted to sugarcane. Furthermore, our findings suggest that no‐burn harvest management strategies will be critical to the development of a sustainable bioenergy landscape in SE US. [ABSTRACT FROM AUTHOR]

The objectives of this study are to investigate the possibility of utilizing sugar beet for biogas production with a high methane content. For the last three hundred years, it has been an important source of sugar, particularly in Europe and other temperate regions of the world, but changes in modern agriculture, world trade and economics have led to a decline in the use of sugar beet as a raw material for sugar factories. As sugar is an important product and an important ingredient for many industries, sugar beet will continue to be grown in many countries for strategic reasons. Nevertheless, this plant has become an interesting source for many new byproducts and technologies. The sugar beet root not only has a sugar content of about 20%, but also contains an abundance of pectin, cellulose, hemicellulose and other materials that are used for the production of textiles and biodegradable materials such as bioplastics. Due to global warming and the rise in average temperatures in many regions of the world, the energy sector will rely on biofuels such as bioethanol and biogas. Many countries are acquiring automotive technology based on the use of ethanol. Biogas with a high methane content can be produced through the use of sugar beet fermentation technology. This is also an acceptable alternative and a way to move to more environmentally friendly energy sources. Many regions of the world have problems with saline soils. Since sugar beets has a high tolerance to salt, they can be grown on these soils to improve fertility and other soil properties and create a more suitable environment for plant and human life. The sugar beet grown on these soils can be used as animal feed or as a raw material for various industries to produce paper, bioplastics or biogas and ethanol. Byproducts of the sugar industry such as molasses and beet pulp can be used for several purposes. Molasses is an environmentally friendly product derived from sugar manufacturing process from beat and are being utilized for several byproducts. Intercropping sugar beet with other crops has many advantages. Sugar beet products as feed for dairy cows has increased the quantity and quality of milk. Sugar beet has found its place in the circular economy and in many new technological byproducts. Many countries have launched programs to breed and develop new products of using sugar beet. [ABSTRACT FROM AUTHOR]

This review explores the potential of green synthesised SBA-15 nanomaterials in biodiesel production, focusing on their promising application despite their lack of direct use in this field. The growing global demand for sustainable and renewable energy sources has intensified interest in biodiesel as a cleaner alternative to fossil fuels. Biodiesel, derived from renewable biomass sources such as agricultural residues and waste cooking oils, offers significant environmental benefits, including reduced greenhouse gas emissions. Traditional SBA-15 synthesis involves hazardous chemicals, but green synthesis methods using biomass-derived silica present an eco-friendly approach. This review examines the unique structural properties of SBA-15, such as its high surface area and uniform pore structure, which could improve biodiesel production when used as a catalyst. While the green-synthesised SBA-15 has not yet been applied directly in biodiesel production, this article proposes its potential utility and emphasises the need for future research to validate its effectiveness. This novel approach of directly using SBA-15 as a catalyst emphasises its potential to improve biodiesel production sustainability and efficiency, contributing to waste management and renewable energy goals. These findings underscore the scientific value of SBA-15 in the advancement of biofuel technology and highlight its potential for industrial applications.Article Highlights: Examines biomass waste as a viable and renewable resource for silica extraction. Evaluates green synthesis approaches for producing SBA-15 from renewable sources. Consider the prospective use of green-synthesised SBA-15 in the advancement of biodiesel production technologies. [ABSTRACT FROM AUTHOR]

Depleting fossil fuel resources and increasing energy demand have intensified the emphasis on biofuel production cyanobacteria. In this study, 19 cyanobacterial filamentous strains were isolated from various regions of Pakistan, including the northern areas and the University of the Punjab, Lahore. Sudan black, Nile red, and BODIPY staining, together with CLSM, fluorimetry, FTIR, growth in different nitrate concentrations, and GC techniques, were used to confirm and measure the lipid and diesel contents within isolated cyanobacterial filaments. Oscillatoria sp. strain CFF-6 showed a significantly higher yield (biodiesel/biomass=35.6%). Leptolyngbya sp. strain CFF-18 showed a higher yield (biodiesel/biomass=17.1%) compared to other Leptolyngbya strains. FAME (Fatty Acid Methyl Ester) analysis was also performed. Oscillatoria are better biodiesel producers in comparison to other filamentous strains. [ABSTRACT FROM AUTHOR]

Fossil fuels are primary sources for energy production. Increased dependence on fossil fuels has resulted in increased environmental issues demanding alternative sources. Bioenergy is becoming a popular alternative energy source due to its positive environmental impact and the availability of renewable sources. However, the availability of renewable energy sources in the energy sector currently contributes to about 14%. Biofuels are preferred due to its sustainability, eco‐friendly approach, and low‐cost raw materials, making it an efficient technique for energy production. This article provides the fundamental and applied concepts for on conversion processes of biomass to biofuels, such as combustion, pyrolysis, fermentation, gasification, and anaerobic digestion along with their role in the green economy. Different physical characteristics of biomass resources are important and contribute to determining their potential for producing biofuels. Herein, LCA, its techno‐economic importance, and the role of biomass in green economy are explained. Varying compositions and properties of different types of biomass resources, including lignocellulosic feedstocks, agriculture and forest residue, municipal solid waste, food waste, and animal manure as potential biomass resources, have been discussed. The article explains the strengths and weaknesses of different thermochemical conversion techniques and their current input toward scalar applications and commercialization. [ABSTRACT FROM AUTHOR]

This review offers a comprehensive overview of synthetic fuels as promising alternatives to conventional fossil fuels. The carbon-neutral potential of synthetic fuels when produced using renewable energy and captured CO2, offering significant opportunities to mitigate CO2 emissions, is discussed. Moreover, the efficiency of synthetic fuels is presented, as they do not require dedicated agricultural land or substantial water resources, addressing concerns related to the land-use change and water scarcity associated with traditional biofuels. The economic viability of synthetic fuels is explored, highlighting the advancements in technology and decreased renewable-energy costs, coupled with their independence from food crops, mitigating concerns about potential impacts on food prices. Major investments by industry leaders such as Porsche, Highly Innovative Fuels Global, and ExxonMobil, totalling $1 billion, aimed at achieving an annual production of 550 million litres by 2026, are covered in detail. This study is further extended by emphasizing the scalability of synthetic fuel production through modular processes, enabling tailored facilities to meet regional demands and contribute to a decentralized and resilient energy infrastructure. Additionally, the 'drop-in' nature of synthetic fuels that are seamlessly compatible with existing fuel storage, pipelines, and pumps, facilitating a smooth transition without requiring extensive infrastructure changes, is highlighted. Challenges such as the current high cost of synthetic fuel production are acknowledged, necessitating supportive government policies and incentives for widespread adoption. Overall, synthetic fuels have emerged as promising contenders in the pursuit of sustainable and adaptable energy solutions, with tangible benefits for the environment, economy, and existing energy infrastructure. [ABSTRACT FROM AUTHOR]

Logistics is becoming more cost competitive while customers and regulatory bodies pressure businesses to disclose their carbon footprints, creating interest in alternative fuels as a decarbonization strategy. This paper provides a thematic review of the role of alternative fuels in sustainable air, land, and sea logistics, their challenges, and potential mitigations. Through an extensive literature survey, we determined that biofuels, synthetic kerosene, natural gas, ammonia, alcohols, hydrogen, and electricity are the primary alternative fuels of interest in terms of environmental sustainability and techno-economic feasibility. In air logistics, synthetic kerosene from hydrogenated esters and fatty acids is the most promising route due to its high technical maturity, although it is limited by biomass sourcing. Electrical vehicles are favorable in road logistics due to cheaper green power and efficient vehicle designs, although they are constrained by recharging infrastructure deployment. In sea logistics, liquified natural gas is advantageous owing to its supply chain maturity, but it is limited by methane slip control and storage requirements. Overall, our examination indicates that alternative fuels will play a pivotal role in the logistics networks of the future. [ABSTRACT FROM AUTHOR]

Pongame oiltree (Millettia pinnata) is one of the medicinal plants that are grown in humid subtropical climate zones. The seeds are the major source of furanoflavonoids karanjin and pongamol that exhibit anticancerous, antimicrobial, antipesticidal, antilarval, anti-oxidant, and anti-inflammatory properties. The seed oil also possesses antimicrobial properties due to the presence of unsaturated fatty acids namely linoleic, oleic, and linolenic acids. However, there is limited understanding of the mechanisms of action of Millettia pinnata seeds bioactive compounds. Thus, the review aims to describe the comprehensive information with special emphasis on seed and seed oil, the phytochemistry of compounds, the detailed pharmacological potential of phytocompounds, and their role in agri-food industries. As well, the bioactivity of seed and seed oil is explained in detail with their bioactive mechanisms. Millettia pinnata seed and seed oil contain a diverse range of phytochemicals, which vary based on factors such as geographic location, climate, and extraction method. The bioactive mechanisms of the phytochemicals in Millettia pinnata seed and seed oil are diverse, with some compounds acting by modulating key enzymes and signaling pathways, while others act by inducing cell death or inhibiting cell proliferation. Millettia pinnata seed and seed oil have potential applications in the agri-food industry, including as food additives and ingredients, and for their potential to improve the shelf life and nutritional value of food products. Overall, the detailed description of the bioactive mechanisms of the phytochemicals in these compounds adds to the current understanding of their potential therapeutic applications. This review explores its diverse phytocompounds, including karanjin and pongamol, known for insecticidal and medicinal properties. The plant's alkaloids contribute to anti-inflammatory and antimicrobial effects. Pongamia oil has applications in skin care and even cancer treatment, with additional antibacterial and insecticidal benefits. This cost-effective oil finds uses in cosmetics. This review discusses seed composition, therapeutic uses, Ayurvedic applications, and the plant's role in various activities, from anti-quorum sensing to antioxidation and anti-inflammation. It underscores the plant's promising future in pharmaceuticals and agriculture. [ABSTRACT FROM AUTHOR]

ABSTRACT Many countries accelerate climate change by using fossil fuels like coal, gas, and petroleum to power their energy production systems and boost economic growth, which in turn releases large amounts of greenhouse gases (GHG). Recently, biofuels (BIO) have gained significant global attention for their potential to decarbonize the economy and reduce dependence on petroleum by replacing fossil fuels. This study examines the effect of biofuel consumption and innovation in non‐fossil fuels on the load capacity factor (LCF) in the United States spanning from 1981 to 2020. The empirical outcomes verify the validity of the load capacity curve (LCC) theory. In addition, biofuel consumption has a favourable impact on LCF. The findings further demonstrate that innovation in non‐fossil fuel technologies has no significant impact on the LCF. Based on these outcomes, the US government should increase the share of BIO as an energy component in the energy mix to replace fossil fuels. As a result, BIO have significant potential for the United States to meet its low‐carbon goal by efficiently reducing GHG. [ABSTRACT FROM AUTHOR]

Incompatible with the pioneering role of the transportation sector in greenhouse gas (GHG) emissions, this research mainly deals with GHG emissions from the transport sector. In this context, the study looks at the four leading European Union (EU) countries (i.e., Germany, France, Italy, and Spain), investigates emissions from their sub‐types of the transport sector (i.e., aviation, rail, and road), uses environmental transport taxes (ETAX) as the main explanatory variable in the bivariate modeling, and considers biofuel consumption (BIO) as a control factor in the multivariate modeling. The study uses monthly data between 2004 and 2022, bivariate and multivariate quantile‐on‐quantile regression as well, and Granger causality‐in‐quantiles as the main approaches. The results demonstrate that (i) ETAX is completely inefficient on aviation and road transport GHG emissions; (ii) ETAX curbs rail transport GHG emissions in France at only middle quantiles; (iii) with the moderating impact of BIO, ETAX becomes effective in declining aviation, rail, and road transport GHG emissions (iv) BIO has a certainly reversing impact on the nexus between ETAX and transport sector GHG emissions. Overall, the study highlights that ETAX has a stand‐alone ineffective impact in curbing transport sector GHG emissions, but BIO has a certain moderating contribution in this manner. Thus, the study strongly recommends taking further actions, such as more use of BIO as in the case of this study, to support ETAX practices in combating GHG emissions for the EU countries. [ABSTRACT FROM AUTHOR]

In recent decades, microalgae have been getting attention as one sustainable and promising feedstock for biofuel production. Algal biomass can be a viable and long-term alternative for biofuel generation and has the capability to replace petroleum or diesel. According to technological economic models, algal biomass can become economically comparable to petroleum due to lowering carbon energy indices. This review entails the process, mechanism, comparative studies, challenges, and various reports involved in algal-based biofuel production. It also discusses the revolutionizing potential or option of algal biofuel, particularly in the transportation sector. Several advantages of algal biofuel over fossil fuels have been discussed, such as renewable, clean, low-cost, and commercial viability. Biofuels can be used as the primary fuel in motors or as a supplement. Sustainable issues regarding renewable biofuel have been addressed, which reduces greenhouse gas emissions. The preparation of biofuel from three basic components, which are lipids, carbohydrates, and proteins, is also discussed. Algae biomass can be used as an energy source for vehicular engines or as an additive to traditional fuels, such as by blending ethanol from sugar biomass with gasoline, offering a sustainable solution for both green product manufacturing and renewable energy requirements. In the aspect of carbon neutrality, algal biomass can be converted intobiofuels, including biomethane, bioethanol, and biohydrogen. The variety of available research and updated mechanisms represent a clear-cut idea for the suitability of industrial-scale biofuel production using selected algal strains. Finally, this review will be helpful to researchers who are working to improve production efficiency, reduce production costs, and realize industrial-scale production. [ABSTRACT FROM AUTHOR]

This study aims to conduct an applied and innovative investigation to enhance the energy quality of wood residues through hydrothermal carbonization pretreatment. For this purpose, the treatment was carried out at three different temperatures: 180, 220, and 240 °C under autogenous pressure. The in natura material and the hydrochars were characterized, and thermogravimetric analyses were performed in an O2 atmosphere with heating rates of 2.5, 5, 10, and 20 °C min−1. The global activation energy for natura biomass combustion was determined to be 112.49 kJ.mol−1. On the other hand, the hydrothermal carbonization process promoted a reduction in this value for the 94.85 kJ.mol−1. The conversion function for the in natura biomass was characterized as 1 - α , order 1, while the hydrochars was 2(1−α) [−ln(1−α)] (1⁄2), Avrami-Erofe'ev I. Triple kinetic parameters were ascertained, and the conversion curves along with their respective derivatives were modeled, exhibiting minimal deviations between theoretical and experimental data. This facilitated the mathematical representation of the reaction processes and allowed for a comprehensive comparison of the results. [ABSTRACT FROM AUTHOR]

Hydrogen mobility embodies a promising solution to address the challenges posed by traditional fossil fuel-based vehicles. The use of hydrogen in small heavy-duty road vehicles based on internal combustion engines (ICEs) may be appealing for two fundamental reasons: Direct electrification seems less promising in heavy-duty transport systems, and fuel cell-based hydrogen vehicle implementation may not proceed at the expected pace due to higher investment costs compared to ICEs. On the other hand, hydrogen combustion is gaining attractiveness and relies on robust and cheap technologies, but it is not the only renewable solution. In this framework, this work presents a methodology to assess the Well-to-Wheel primary energy consumption and CO2 emissions of small heavy-duty vehicles. The methodology is applied in a real case study, namely a passenger coach traveling on a 100 km mission in non-optimized conditions. Therefore, the suitability of hydrogen is compared with standard diesel and other alternative diesel-type fuels (biodiesel and synthetic diesel types). Hydrogen shows competitivity with standard diesel from the point of view of CO2 emission reduction (−29%) while it hides a higher primary energy consumption (+40%) based on the current power-to-hydrogen efficiency declared by electrolyzer manufacturers. Nonetheless, HVO brings the highest benefits both from the point of view of primary energy consumption and emission reduction, namely −35% and 464–634 kgCO2/100km avoided compared to hydrogen. Moreover, the availability of HVO—like other biofuels—does not depend on carbon from CO2 capture and sequestration systems. [ABSTRACT FROM AUTHOR]

This article presents the initial processes of changing ship fuels aimed at reducing emissions of carbon dioxide and other greenhouse gases. A significant reduction in GHG emissions is only possible by using carbon-free fuels. The process of reducing CO2 emissions was forced by legal regulations introduced in recent years by the International Maritime Organization and the Parliament of the European Union. The year 2050 was set as the target year for achieving the intended goals, but intermediate goals should be achieved already in 2030 and 2040. This article attempts to analyze the ongoing changes in the fuel market in maritime transport on the way to achieving the threshold of climate neutrality with this form of transport. A number of hopes related to this were indicated but also so were obstacles that may slow down this process. In 2023, there was an increased interest among shipowners in adapting ship engines to burn more ecological ship fuels. However, it is far from our expectations. Meeting the gradually increasing emission limits through imposed regulations was possible in the years 2020–2023 by using dual-fuel engines in which gaseous fuels, mainly LNG and LPG, were used for long periods of operation. The next step is the use of biofuels or synthetic fuels, which, however, will not meet the requirements after 2030. Interest is moving towards the use of ammonia and, ultimately, after 2040, hydrogen. The aim of this article is to analyze the ongoing processes and assess the directions of changes that justify the sense of the actions taken. [ABSTRACT FROM AUTHOR]

In this study, the giant reed (Arundo donax L.) was used as a substrate for bioethanol production. To study and optimize the effect of bioethanol production parameters, including sodium hydroxide (NaOH) concentration (3–9, w/w%), temperature (60–180 °C), and pretreatment duration (30–120 min), on bioethanol concentration, and theoretical bioethanol yield, response surface methodology (RSM) based on the Box–Behnken design (BBD) was used. Alkaline pretreatment with NaOH was done on the substrate and all the samples were subjected to an enzymatic degradation experiment under conditions of loading 30 FPU cellulase/g dry biomass and then converted to bioethanol by Saccharomyces cerevisiae yeast. The results showed significant effects of the variables on bioethanol production, except for the effects of temperature on theoretical bioethanol yield. The optimal conditions for producing bioethanol under alkaline pretreatment conditions are a NaOH concentration of 3.0%, a temperature of 60 °C, and a pretreatment duration of 30 min which identified the optimal conditions of bioethanol concentration (3.19 g/L), and theoretical bioethanol yield (25.62%). These results contribute to supporting the potential of giant reed biomass as a suitable raw material for bioethanol production. [ABSTRACT FROM AUTHOR]

Bamboo is a perennial rapid-growing plant that is given preference for renewable biosources for biofuels and bio-based chemical conversion. Bamboos are rich in cellulose and have highly recalcitrant biomass due to high lignin. Bamboo is abundantly available in Northeastern India and can be utilized as a feedstock biofuels. Here, we evaluated the pretreatment of bamboo residues Dendrocalamus strictus with different concentrations of alkali, hydrogen peroxide, and alkaline hydrogen peroxide and its influence on biomass digestibility for enhancement of sugar recovery with Celic C cellulase enzyme blend. Enzymatic hydrolysis data indicated untreated raw biomass showed a digestibility of 40% after 48 h of incubation. The biomass pretreated with alkali showed a maximum digestibility of 61% obtained from 10% loaded with 0.5% w/v NaOH. Pretreatment of the bamboo with H2O2 shows a maximum digestibility of 75% from biomass loaded with 1% w/v of H2O2. Combinational pretreatment of alkaline hydrogen peroxide showed a maximum efficiency of biomass digestibility of 83% attained from biomass loaded with 1% w/v NaOH-H2O2. Crystallinity index (CrI) analysis showed that CrI increased from 64% to 70.75% in pretreated biomass. FTIR and SEM analysis show changes in functional groups, morphology, and surface of biomass in pretreated biomass. Compositional analysis shows that 68% of lignin removal is obtained from alkaline hydrogen peroxide pretreatment. Cellulose content increased from 52% to 65%, and hemicellulose decreased from 18.6% to 8.6%. Results indicated that the potential possibility of bamboo waste biomass as feedstock for biorefinery products and alkaline hydrogen peroxide pretreatment methods is an efficient strategy for sugar recovery for bioethanol production. [ABSTRACT FROM AUTHOR]

Environmental justice and climate justice activists routinely find themselves participating in state-led processes to determine energy futures and the built environment that follows. At stake is reproducing worlds of enclosure in the name of resilience, sustainability, innovation, carbon neutrality, and just transitions. This narrative performs a close reading of environmental justice activists' participation in California's Low Carbon Fuel Standard (LCFS) alongside the landscape of San Joaquin Valley's lagoons of effluvia. I draw on extensive fieldwork with environmental justice activists, decolonial theories on worlding, and the theory of agonism to present interventions that interrupt state-led imaginaries to instead multiply worlds within worlds. [ABSTRACT FROM AUTHOR]

The growing interest in microalgae is driven by their potential in various bioindustries, such as biofuel production, bioremediation, and the generation of high-value biomolecules. This paper aims to systematically review the state of research on bioprospecting microalgae, their applications, and recognize trends. This study employs an exploratory and descriptive research approach, using bibliometric methods to analyze scientific production and identify emerging trends in bioprospecting microalgae research. The analysis reveals exponential publication growth, with multidisciplinary sources indicating a strong applied focus. Leading countries in this research field benefit from clear technology transfer policies, and the prevalent terms "production" and "biomass" underscore the industrial relevance. Key research areas include biofuels and bioremediation, with a combined emphasis that is often studied in cultivation and biomass production. Bioactive compounds derived from microalgae are a current trend for industrial, medical, and food applications. Although the potential for CO2 capture is acknowledged, direct studies are limited. This systematic review provides a comprehensive overview of current trends and identifies opportunities and challenges in microalgae research, highlighting its significance for sustainable development and industrial applications. [ABSTRACT FROM AUTHOR]

Typically, citrus waste is composted on land by producers or used as livestock feed. However, the biorefinery approach offers a sustainable and economically viable solution for managing and valorizing these agricultural residues. This review examines research from the period 2014 to 2024. Citrus waste can be utilized initially by extracting the present phytochemicals and subsequently by producing value-added products using it as a raw material. The phytochemicals reported as extracted include essential oils (primarily limonene), pectin, polyphenolic components, micro- and nano-cellulose, proteins, and enzymes, among others. The components produced from the waste include bioethanol, biogas, volatile acids, biodiesel, microbial enzymes, and levulinic acid, among others. The review indicates that citrus waste has technical, economic, and environmental potential for utilization at the laboratory scale and, in some cases, at the pilot scale. However, research on refining pathways, optimization, and scalability must continue to be an active field of investigation. [ABSTRACT FROM AUTHOR]

Elephant grass (EG), or Pennisetum purpureum, is gaining attention as a robust renewable biomass source for energy production amidst growing global energy demands and the push for alternatives to fossil fuels. This review paper explores the status of EG as a sustainable bioenergy resource, integrating various studies to present a comprehensive analysis of its potential in renewable energy markets. Methods employed include assessing the efficiency and yield of biomass conversion methods such as pretreatment for bioethanol production, biomethane yields, direct combustion, and pyrolysis. The analysis also encompasses a technoeconomic evaluation of the economic viability and scalability of using EG for energy production, along with an examination of its environmental impacts, focusing on its water and carbon footprint. Results demonstrate that EG has considerable potential for sustainable energy practices due to its high biomass production and ecological benefits such as carbon sequestration. Despite challenges in cost competitiveness with traditional energy sources, specific applications like small-scale combined heat and power (CHP) systems and charcoal production show economic promise. Conclusively, EG presents a viable option for biomass energy, potentially playing a pivotal role in the biomass sector as the energy landscape shifts towards more sustainable solutions; although, technological and economic barriers need further addressing. [ABSTRACT FROM AUTHOR]

This work determines the deactivation mechanisms of Cu/ZSM-5 catalysts used for the conversion of 2,3-butanediol to butene as part of an alcohol-to-jet route. The deactivation of the catalyst, reflected by a drop in the rate of the limiting hydrogenation step by over 90% in 24 h at a weight hourly space velocity of 5.92 h−1, proceeds via both the agglomeration of copper particles and the obstruction of copper surfaces due to carbonaceous deposits, although the former has less impact on the decrease in the hydrogenation rate. To reduce the detrimental effect of carbonaceous deposits on catalytic activity, ZMS-5 is modified through desilication of the HZSM-5 support with NaOH and CsOH solutions to generate a hierarchical structure with mesopores. The catalyst with the CsOH-treated support generates the highest overall yield of desired olefin products and experiences the slowest deactivation. This is a result of the lower Brønsted acidity and larger mesopores found in the CsOH-treated catalyst, leading to the slower formation of carbonaceous deposits and the faster diffusion of their precursors out of the pores. [ABSTRACT FROM AUTHOR]

In the current era there are huge quantities of waste organic matter available, creating a big burden to the environment. To address these issues, researchers started to apply effective and microbial induced biotechnological processes that can mitigate these waste matters. In this context, different nature of microbial systems are involved in hydrolysing the waste organic material into fermentable sugar. These can be easily consumed by specific microbial systems like Saccharomyces cerevisiae MTCC 3821 and Clostridium acetobutylicum that produced bioethanol and biobutanol, respectively. Saccharomyces cerevisiae was cultured in specific media and incubated at rotary shaker with 150 rpm at 30°C for 72 to 96 hours. Ethanol concentrations from different waste matters were found in the range of 1.2-1.5 g.L-1. Ethanol synthesis was done by shake flask experiment with addition of glucose (50 g.L-1) to waste organic hydrolyzed solution. Non-glucose media produced less than 3 g.L-1 ethanol but glucose media produced 4.5 g.L-1. Next, Clostridium acetobutylicum was grown in culture media containing waste organics as sole carbon substrate with pH 7 and then was incubated in anaerobic conditions at 35°C for 72 hours, produced butanol (0.7 to 1.25 g.L-1). This research work promoted biofuels synthesis by keeping a waste mitigation strategy. [ABSTRACT FROM AUTHOR]

Population growth has generated an enormous increase in demand for energy and chemicals to supply goods and services and to maintain quality of life. Oil, coal, and natural gas are the primary sources of the chemicals and energy that directly impact the economy. However, the reserves of these resources are continuously reducing. New alternatives have emerged, including biotechnological tools such as microbial consortia (MC) to produce biofuels, chemicals such as organic acids, and processed foods. The diversity of MC as a biotechnological tool allows it to be used in complex substrates, opening the possibility of using other solid waste to implement consolidated bioprocesses (CPs). This review presents an overview of the uses of MC and CP for producing biofuels using different feedstocks. [ABSTRACT FROM AUTHOR]

A report on the Pithecellobium dulce tree is provided in this review. The main characteristics of the tree, its chemical composition, traditional applications and future application in the bioenergy area are addressed. Pithecellobium dulce is a leguminous tree characterized by being fast growing, nitrogen fixing and largely available. In addition, it is distinguished by growing in different types of soils from acid to alkaline and with little water. This review could serve as a scientific basis to promote and carry out new research work focused on individual and comprehensive use for various bioenergetic processes, from the different parts that make up the P. dulce tree such as its leaves, pods, branches, flowers, fruit and seeds. Among the bioenergetic processes that could be developed are the production of bioethanol, biodiesel, biogas, heterogeneous catalysts, biochar, activated carbon and nanoparticles, among other applications. [ABSTRACT FROM AUTHOR]

The economic competitiveness of 2G-bioethanol technology should improve through the improvement of the sugar release and the valorization of by-products, especially lignin. Thus, an integrated scheme with corncob was developed to produce ethanol using low dosages of cellulases and value-added products from the semi-simultaneous saccharification and fermentation (SSSF) residue. Enzymatic hydrolysis and SSSF of acid pretreated corncob (< 20 mesh and > 20 mesh) were carried out under cellulase dosages of 5, 10, and 15 FPU/g in the absence and presence of polyethylene glycol 1500 (PEG 1500). The SSSF residue was used to obtain lignosulfonate via sulfomethylation reaction and phenolic acids via alkaline hydrolysis using 4% (w/v) sodium hydroxide and 0–5% (v/v) hydrogen peroxide. Pretreated corncob < 20 mesh allowed the reduction of cellulase dosage to 5 FPU/g without compromising sugar release. The addition of PEG 1500 boosted sugar release, reaching 56.73 g/L glucose under 20% (w/v) solids. The maximum ethanol production of 31.64 g/L was obtained using 5 FPU/g cellulases, 2% (w/w) PEG 1500, and 20% (w/v) solids (gradual addition). FTIR confirmed the preparation of lignosulfonate from SSSF residue, and the surfactant showed good stabilization performance in oil/water systems (emulsification index≈30%). High yields of p-coumaric acid (8045.3 mg/100 g) and ferulic acid (1429.4 mg/100 g) were obtained in alkaline hydrolysis with 5% (v/v) hydrogen peroxide. Based on these findings, corncob is versatile and can create a biorefinery with high economic potential. [ABSTRACT FROM AUTHOR]

Countries are looking to reduce their agricultural sector's carbon footprint while encouraging economic and environmental sustainability. One proposed method of making agriculture more sustainable while maintaining farm incomes is through the production of bioenergy feedstocks. We examine the spatial aspect of the production of renewable energy feedstocks in Ireland. Two feedstocks are looked at—grass silage and short‐rotation coppice (SRC) willow. Spatial microsimulation analysis is utilised to assess the spatial suitability for alternative land uses, simulating land‐use change to compare economic returns with the current agricultural use. A farm‐based carbon subsidy is modelled based on avoided agricultural emissions and carbon sequestered. We find that midlands counties, especially those in the north midlands, have the highest proportion of land where feedstocks would be more profitable than the current agricultural use. Counties on the western seaboard have the lowest proportion of land where feedstocks would give greater returns. The amount of land where feedstocks are more profitable increases as greater carbon subsidies are provided. Of the two feedstocks assessed, SRC willow cultivation is more profitable than grass silage production. The overwhelming majority of land where producing feedstocks would be more profitable has cattle farming as its current use. [ABSTRACT FROM AUTHOR]

Canola (Brassica napus L. and B. rapa L. [Brassicales: Brassicaceae]) is a major oilseed crop grown globally as a source of vegetable oil, animal feed and biofuel feedstock. The global demand for canola oil as a biofuel feedstock has increased due to recent regulations in the European Union, United States, and Canada. In North America, canola production is centered on the northern Great Plains where it is challenged by two highly destructive flea beetle species, the crucifer (Phyllotreta cruciferae Goeze, 1777) and the striped (Phyllotreta striolata Fabricius, 1803) flea beetles. In the spring, adult P. cruciferae and P. striolata begin feeding on canola seedlings, creating a 'shot hole' appearance, which can reduce the plant's photosynthetic capacity leading to uneven plant emergence and growth, reduced plant stand density, and reduced seed yield. Losses resulting from flea beetles are estimated in the tens of millions of dollars annually. At present, the principle means for flea beetle control are insecticides applied as systemic seed treatments and/or subsequent foliar sprays. The continued use of these products is being questioned due to environmental concerns and acquisition of resistance. As such, significant research effort is being directed toward the development of an integrated pest management system for these abundant and hard to manage pests of canola. Here, we review the ecology, pest status, and management of flea beetles in North America and discuss future research needed to promote flea beetle management and sustainable canola production. [ABSTRACT FROM AUTHOR]