1. Low-temperature annealing of radiation-induced defects in carbon nanotube bundles
- Author
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R.M. Rudenko, I.Y. Uvarova, I.S. Rogutski, I. I. Yaskovets, B. A. Danilchenko, and E.A. Voitsihovska
- Subjects
Materials science ,Liquid helium ,Annealing (metallurgy) ,Mechanical Engineering ,Nanotechnology ,02 engineering and technology ,General Chemistry ,Activation energy ,Carbon nanotube ,Atmospheric temperature range ,021001 nanoscience & nanotechnology ,01 natural sciences ,Fluence ,Electronic, Optical and Magnetic Materials ,law.invention ,Condensed Matter::Materials Science ,law ,Chemical physics ,0103 physical sciences ,Materials Chemistry ,Electron beam processing ,Graphite ,Electrical and Electronic Engineering ,010306 general physics ,0210 nano-technology - Abstract
The annealing of radiation-induced defects in carbon nanotube bundles below room temperature has been investigated experimentally. Significant feature of this study is that electron irradiation (with an energy 1 MeV and fluence up to 1016 el/cm2) was carried out at liquid helium temperature. A detailed analysis of the resistance change over a wide temperature range (7–300 K) enables us to prove partial annealing of irradiation-induced defects at moderate temperatures. It is shown that such an annealing follows a first-order reaction in whole investigated temperature range. While at temperatures below 40 K, annealing is nonactivation, tunneling process; at higher temperatures (100 − 300 K) it becomes activated, with activation energy of ~ 0.05 eV. The value of discovered activation energy is close to the migration energy of interstitial carbon atom in graphite. Probably, observed annealing of radiation-induced defects in carbon nanotube bundles is also caused by the migration of interstitial carbon atoms between single nanotubes below room temperature.
- Published
- 2017