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The superior optical extinction characteristics of noble metal nanoparticles have long been considered for enhancing the solar energy absorption in light-harvesting devices. The energy captured through a plasmon resonance mechanism can potentially be transferred to a surrounding semiconductor matrix in the form of excitons or charge carriers, offering a promising light-sensitization strategy. Of particular interest is the plasmon near-field energy conversion, which is predicted to yield substantial gains in the photocarrier generation. Such a short-range interaction, however, is often inhibited by processes of backward electron and energy transfer, which obscure its net benefit. Here, we employ sample-transmitted excitation photoluminescence spectroscopy to determine the quantum efficiency for the plasmon-induced energy transfer (ET) in assemblies of Au nanoparticles and CdSe nanocrystals. The present technique distinguishes the Au-to-CdSe ET contribution from metal-induced quenching processes, thus enabl...