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High-energy radiation from stars impacts planetary atmospheres deeply affecting their chemistry, providing departures from chemical equilibrium. While the upper atmospheric layers are dominated by ionizations induced by extreme ultraviolet radiation, deeper into the atmosphere molecular abundances are controlled by a characteristic X-ray dominated chemistry, mainly driven by an energetic secondary electron cascade. In this work, we aim at identifying molecular photochemically induced fingerprints in the transmission spectra of a giant planet atmosphere. We have developed a numerical code capable of synthesizing transmission spectra with arbitrary spectral resolution, exploiting updated infrared photoabsorption cross sections. Chemical mixing ratios are computed using a photochemical model, tailored to investigate high energy ionization processes. We find that in case of high levels of stellar activity, synthetic spectra in both low and high resolutions show significant, potentially observable out-of-equilibrium signatures arising mainly from CO, CH$_4$, C$_2$H$_2$, and HCN., Comment: The paper has been accepted for publication in The Planetary Science Journal (PSJ)

We aim at extracting the transmission spectrum of the HI Balmer lines of the ultra-hot Jupiter (UHJ) KELT-20b/MASCARA-2b from observations and to further compare the results with what obtained through forward modelling accounting for non-local thermodynamic equilibrium (NLTE) effects. We extract the line profiles from six transits obtained with the HARPS-N high-resolution spectrograph attached to the Telescopio Nazionale Galileo telescope. We compute the temperature-pressure (TP) profile employing the helios code in the lower atmosphere and the Cloudy NLTE code in the middle and upper atmosphere. We further use Cloudy to compute the theoretical planetary transmission spectrum in LTE and NLTE for comparison with observations. We detected the Halpha (0.79+/-0.03%; 1.25 Rp), Hbeta (0.52+/-0.03%; 1.17 Rp), and Hgamma (0.39+/-0.06%; 1.13 Rp) lines, while we detected the Hdelta line at almost 4 sigma (0.27+/-0.07%; 1.09 Rp). The models predict an isothermal temperature of about2200 K at pressures >10^-2 bar and of about 7700 K at pressures <10^-8 bar, with a roughly linear temperature rise in between. In the middle and upper atmosphere, the NLTE TP profile is up to about 3000 K hotter than in LTE. The synthetic transmission spectrum derived from the NLTE TP profile is in good agreement with the observed HI Balmer line profiles, validating our obtained atmospheric structure. Instead, the synthetic transmission spectrum derived from the LTE TP profile leads to significantly weaker absorption compared to the observations. Metals appear to be the primary agents leading to the temperature inversion in UHJs and the impact of NLTE effects on them increases the magnitude of the inversion. We find that the impact of NLTE effects on the TP profile of KELT-20b/MASCARA-2b is larger than for the hotter UHJ KELT-9b, and thus NLTE effects might be relevant also for planets cooler than KELT-20b/MASCARA-2b., Comment: Accepted for publication in Astronomy and Astrophysics

The Milky Way Galaxy is literally teeming with exoplanets; thousands of planets have been discovered, with thousands more planet candidates identified. Terrestrial-like planets are quite common around other stars, and are expected to be detected in large numbers in the future. Such planets are the primary targets in the search for potentially habitable conditions outside the solar system. Determining the atmospheric composition of exoplanets is mandatory to understand their origin and evolution, as atmospheric processes play crucial roles in many aspects of planetary architecture. In this work we construct and exploit a 1D radiative transfer model based on the discrete-ordinates method in plane-parallel geometry. Radiative results are linked to a convective flux that redistributes energy at any altitude producing atmospheric profiles in radiative-convective equilibrium. The model has been applied to a large number (6250) of closely dry synthetic \ce{CO2} atmospheres, and the resulting pressure and thermal profiles have been interpreted in terms of parameter variability. Although less accurate than 3D general circulation models, not properly accounting for e.g., clouds and atmospheric and ocean dynamics, 1D descriptions are computationally inexpensive and retain significant value by allowing multidimensional parameter sweeps with relative ease., Comment: 12 pages, 9 figures, accepted for publication in MNRAS

The X-ray luminosities of T Tauri stars are about two to four orders of magnitude higher than the luminosity of the contemporary Sun. As these stars are born in clusters, their disks are not only irradiated by their parent star but also by an X-ray background field produced by the cluster members. We aim to quantify the impact of X-ray background fields produced by young embedded clusters on the chemical structure of disks. Further, we want to investigate the importance of the dust for X-ray radiative transfer in disks. We present a new X-ray radiative transfer module for the radiation thermo-chemical disk code ProDiMo, which includes X-ray scattering and absorption by both the gas and dust component. For the X-ray radiative transfer, we consider irradiation by the star and by X-ray background fields. To study the impact of X-rays on the chemical structure of disks we use the well-established disk ionization tracers N2H+ and HCO+. For evolved dust populations, X-ray opacities are mostly dominated by the gas; only for photon energies $E\gtrsim5-10\,$keV, dust opacities become relevant. Consequently, the local disk X-ray radiation field is only affected in dense regions close to the disk midplane. X-ray background fields can dominate the local X-ray disk ionization rate for disk radii $r\gtrsim20\,$au. However, the N2H+ and HCO+ column densities are only significantly affected in case of low cosmic-ray ionization rates, or if the background flux is at least a factor of ten higher than the flux level expected for clusters typical for the solar vicinity. Observable signatures of X-ray background fields in low-mass star-formation regions, like Taurus, are only expected for cluster members experiencing a strong X-ray background field. For the majority of the cluster members, the X-ray background field has only little impact on the disk chemical structure., Comment: 16 pages, 12 figures, accepted for publication in A&A

Anomalies in the abundance measurements of short lived radionuclides in meteorites indicate that the protosolar nebulae was irradiated by a high amount of energetic particles (E$\gtrsim$10 MeV). The particle flux of the contemporary Sun cannot explain these anomalies. However, similar to T Tauri stars the young Sun was more active and probably produced enough high energy particles to explain those anomalies. We want to study the interaction of stellar energetic particles with the gas component of the disk and identify possible observational tracers of this interaction. We use a 2D radiation thermo-chemical protoplanetary disk code to model a disk representative for T Tauri stars. We use a particle energy distribution derived from solar flare observations and an enhanced stellar particle flux proposed for T Tauri stars. For this particle spectrum we calculate the stellar particle ionization rate throughout the disk with an accurate particle transport model. We study the impact of stellar particles for models with varying X-ray and cosmic-ray ionization rates. We find that stellar particle ionization has a significant impact on the abundances of the common disk ionization tracers HCO$^+$ and N$_2$H$^+$, especially in models with low cosmic-ray ionization rates. In contrast to cosmic rays and X-rays, stellar particles cannot reach the midplane of the disk. Therefore molecular ions residing in the disk surface layers are more affected by stellar particle ionization than molecular ions tracing the cold layers/midplane of the disk. Spatially resolved observations of molecular ions tracing different vertical layers of the disk allow to disentangle the contribution of stellar particle ionization from other competing ionization sources. Modeling such observations with a model like the one presented here allows to constrain the stellar particle flux in disks around T Tauri stars., Comment: 15 pages, 11 figures, 5 tables. Accepted for publication in A&A

The physical properties of brown dwarf discs, in terms of their shapes and sizes, are still largely unexplored by observations. To what extent brown dwarf discs are similar to scaled-down T Tauri discs is currently unknown, and this work is a step towards establishing a relationship through the eventual modelling of future observations. We use observations of the brown dwarf disc $\rho$ Oph 102 to infer a fiducial model around which we build a small grid of brown dwarf disc models, in order to model the CO, HCN, and HCO+ line fluxes and the chemistry which drives their abundances. These are the first brown dwarf models to be published which relate detailed, 2D radiation thermochemical disc models to observational data. We predict that moderately extended ALMA antenna configurations will spatially resolve CO line emission around brown dwarf discs, and that HCN and HCO+ will be detectable in integrated flux, following our conclusion that the flux ratios of these molecules to CO emission are comparable to that of T Tauri discs. These molecules have not yet been observed in sub-mm wavelengths in a brown dwarf disc, yet they are crucial tracers of the warm surface-layer gas and of ionization in the outer parts of the disc. We present the prediction that if the physical and chemical processes in brown dwarf discs are similar to those that occur in T Tauri discs -- as our models suggest -- then the same diagnostics that are used for T Tauri discs can be used for brown dwarf discs (such as HCN and HCO+ lines that have not yet been observed in the sub-mm), and that these lines should be observable with ALMA. Through future observations, either confirmation (or refutation) of these ideas about brown dwarf disc chemistry will have strong implications for our understanding of disc chemistry, structure, and subsequent planet formation in brown dwarf discs., Comment: Accepted for publication in A&A. 11 pages, 10 figures, 3 tables

Mid-IR water lines from protoplanetary disks around T Tauri stars have a detection rate of 50\%. Models have identified multiple physical properties of disks such as dust-to-gas mass ratio, dust size power law distribution, disk gas mass, disk inner radius, and disk scale height as potential explanation for the current detection rate. We search for a connection between mid-IR water line fluxes and the strength of the 10~$\mu$m silicate feature. We analyse observed water line fluxes from three blends and compute the 10~$\mu$m silicate feature strength from Spitzer spectra. We use a series of published models, exploring disk dust and gas properties, and the effects of different stars. The models also show that the increasing stellar luminosity enhance simultaneously the strength of this dust feature and the water lines fluxes. No correlation is found between the observed mid-IR water lines and the 10~$\mu$m silicate. Our sample shows the same difference in the peak strength between amorphous and crystalline silicates that was noted in earlier studies, but our models do not support this intrinsic difference in silicate peak strength. Individual properties of our model series are not able to reproduce the most extreme observations, suggesting that more complex dust properties are required. A parametrized settling prescription is able to boost the peak strength by a factor 2 for the standard model. Water line fluxes are unrelated to the composition of the dust. The pronounced regular trends seen in the model results are washed out in the data due to the larger diversity in stellar and disk properties compared to our model series. The disks with with weaker mid-IR water line fluxes are depleted in gas or enhanced in dust in the inner 10~au. In the case of gas depleted disks, settling produces very strong 10~$\mu$m silicate features, with strong peak strength.