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We introduce a universal framework for boundary transfer matrices, inspired by Sklyanin's two-row transfer matrix approach for quantum integrable systems with boundary conditions. The main examples arise from quantum symmetric pairs of finite and affine type. As a special case we recover a construction by Kolb in finite type. We review recent work on universal solutions to the reflection equation and highlight several open problems in this field., Comment: 30 pages

Barocalorics (BCs) are emerging as promising alternatives to vapour-phase refrigerants, which are problematic as they exacerbate climate change when they inevitably leak into the atmosphere. However, the commercialisation of BC refrigerants is significantly hindered by hysteresis in the solid-solid phase transition that would be exploited in a refrigeration cycle. Here, we provide new insight into the hysteresis that is a critical step towards the rational design of viable BCs. By studying the archetypal BC plastic crystal, neopentyl glycol (NPG), we observe for the first time the liberation of the hydroxyl rotational modes that unlock the hydrogen bonding network. We use high-resolution inelastic fixed-window neutron scattering studies in combination with quasielastic neutron scattering (QENS) measurements to build a comprehensive microscopic understanding of the NPG phase transition. Hysteresis previously observed in calorimetric studies of NPG is now observed directly as hysteresis in molecular rotational modes, and hence in the formation and disruption of hydrogen bonding. Furthermore, by tracking the thermal activation of three main reorientation modes, we suggest that their fractional excitations may resolve an outstanding discrepancy between measured and calculated entropy change. These results allow for direct study of the molecular dynamics that govern the thermal hysteresis of small molecule energy materials. They will be broadly applicable, as many promising BC material families possess first-order transitions involving molecular reorientations.

This paper provides an empirical overview of the impact and practices of paying Article Processing Charges (APCs) by four nationally categorized groups of researchers in Argentina, Brazil, Mexico, and South Africa. The data was collected from 13,577 researchers through an online questionnaire. The analysis compares the practice of publishing in journals that charge APCs across different dimensions, including country, discipline, gender, and age of the researchers. The paper also focuses on the maximum amount APC paid and the methods and strategies researchers use to cover APC payments, such as waivers, research project funds, payment by coauthors, and the option to publish in closed access, where possible. Different tendencies were identified among the different disciplines and the national systems examined. Findings show that Argentine researchers apply for waivers most frequently and often use personal funds or international coauthors for APCs, with younger researchers less involved in APC payments. In contrast, Brazil, South Africa, and Mexico have more older researchers, yet younger researchers still publish more in APC journals. South African researchers lead in APC publications, likely due to better funding access and read and publish agreements. This study lays the groundwork for further analysis of gender asymmetries, funding access, and views on the commercial Open Access model of scientific dissemination., Comment: 33 pages, 6 figures, 12 tables

We study the evolution of populations of binary stars within massive cluster-forming regions. We simulate the formation of young massive star clusters within giant molecular clouds with masses ranging from 2 x 10$^{4}$ to 3.2 x 10$^{5}$ M$_{\odot}$. We use Torch, which couples stellar dynamics, magnetohydrodynamics, star and binary formation, stellar evolution, and stellar feedback through the AMUSE framework. We find that the binary fraction decreases during cluster formation at all molecular cloud masses. The binaries' orbital properties also change, with stronger and quicker changes in denser, more massive clouds. Most of the changes we see can be attributed to the disruption of binaries wider than 100 au, although the close binary fraction also decreases in the densest cluster-forming region. The binary fraction for O stars remains above 90%, but exchanges and dynamical hardening are ubiquitous, indicating that O stars undergo frequent few-body interactions early during the cluster formation process. Changes to the populations of binaries are a by-product of hierarchical cluster assembly: most changes to the binary population take place when the star formation rate is high and there are frequent mergers between sub-clusters in the cluster-forming region. A universal primordial binary distribution based on observed inner companions in the Galactic field is consistent with the binary populations of young clusters with resolved stellar populations, and the scatter between clusters of similar masses could be explained by differences in their formation history., Comment: 15 pages, 8 figures, 3 tables. Submitted to ApJ

High-harmonic generation (HHG) is a nonlinear process in which a material sample is irradiated by intense laser pulses, causing the emission of high harmonics of the incident light. HHG has historically been explained by theories employing a classical electromagnetic field, successfully capturing its spectral and temporal characteristics. However, recent research indicates that quantum-optical effects naturally exist, or can be artificially induced, in HHG. Even though the fundamental equations of motion for quantum electrodynamics (QED) are well-known, a unifying framework for solving them to explore HHG is missing. So far, numerical solutions employed a wide range of basis-sets and untested approximations. Based on methods originally developed for cavity polaritonics, here we formulate a numerically accurate QED model consisting of a single active electron and a single quantized photon mode. Our framework can in principle be extended to higher electronic dimensions and multiple photon modes to be employed in ab initio codes. We employ it as a model of an atom interacting with a photon mode and predict a characteristic minimum structure in the HHG yield vs. phase-squeezing. We find that this phenomenon, which can be used for novel ultrafast quantum spectroscopies, is partially captured by a multi-trajectory Ehrenfest dynamics approach, with the exact minima position sensitive to the level of theory. On the one hand, this motivates using multi-trajectory approaches as an alternative for costly exact calculations. On the other hand, it suggests an inherent limitation of the multi-trajectory formalism, indicating the presence of entanglement. Our work creates a road-map for a universal formalism of QED-HHG that can be employed for benchmarking approximate theories, predicting novel phenomena for advancing quantum applications, and for the measurements of entanglement and entropy., Comment: 10 pages, 7 figures

We report the first ab initio, non-relativistic QED method that couples light and matter self-consistently beyond the electric dipole approximation and without multipolar truncations. This method is based on an extension of the Maxwell-Pauli-Kohn-Sham approach to a full minimal coupling Hamiltonian, where the space- and time-dependent vector potential is coupled to the matter system, and its back-reaction to the radiated fields is generated by the full current density. The implementation in the open-source Octopus code is designed for massively-parallel multiscale simulations considering different grid spacings for the Maxwell and matter subsystems. Here, we show the first applications of this framework to simulate renormalized Cherenkov radiation of an electronic wavepacket, magnetooptical effects with non-chiral light in non-chiral molecular systems, and renormalized plasmonic modes in a nanoplasmonic dimer. We show that in some cases the beyond-dipole effects can not be captured by a multipolar expansion Hamiltonian in the length gauge. Finally, we discuss further opportunities enabled by the framework in the field of twisted light and orbital angular momentum, inelastic light scattering and strong field physics., Comment: 31 pages, 9 figures, supporting information appended

Sub-picosecond optical laser processing of metals is actively utilized for modification of a heated surface layer. But for deeper modification of different materials a laser in the hard x-ray range is required. Here, we demonstrate that a single 9-keV x-ray pulse from a free-electron laser can form a um-diameter cylindrical cavity with length of ~1 mm in LiF surrounded by shock-transformed material. The plasma-generated shock wave with TPa-level pressure results in damage, melting and polymorphic transformations of any material, including transparent and non-transparent to conventional optical lasers. Moreover, cylindrical shocks can be utilized to obtain a considerable amount of exotic high-pressure polymorphs. Pressure wave propagation in LiF, radial material flow, formation of cracks and voids are analyzed via continuum and atomistic simulations revealing a sequence of processes leading to the final structure with the long cavity. Similar results can be produced with semiconductors and ceramics, which opens a new pathway for development of laser material processing with hard x-ray pulses.

Mass segregation is seen in many star clusters, but whether massive stars form in the center of a cluster or migrate there dynamically is still debated. N-body simulations have shown that early dynamical mass segregation is possible when sub-clusters merge to form a dense core with a small crossing time. However, the effect of gas dynamics on both the formation and dynamics of the stars could inhibit the formation of the dense core. We aim to study the dynamical mass segregation of star cluster models that include gas dynamics and self-consistently form stars from the dense substructure in the gas. Our models use the Torch framework, which is based on AMUSE and includes stellar and magnetized gas dynamics, as well as stellar evolution and feedback from radiation, stellar winds, and supernovae. Our models consist of three star clusters forming from initial turbulent spherical clouds of mass $10^{4,5,6}\rm~M_\odot$ and radius $11.7\rm~pc$ that have final stellar masses of $3.6\times10^3\rm~M_\odot$, $6.5\times10^4\rm~M_\odot$, and $8.9\times10^5\rm~M_\odot$, respectively. There is no primordial mass segregation in the model by construction. All three clusters become dynamically mass segregated at early times via collapse confirming that this mechanism occurs within sub-clusters forming directly out of the dense substructure in the gas. The dynamics of the embedded gas and stellar feedback do not inhibit the collapse of the cluster. We find that each model cluster becomes mass segregated within $2~$Myr of the onset of star formation, reaching the levels observed in young clusters in the Milky Way. However, we note that the exact values are highly time-variable during these early phases of evolution. Massive stars that segregate to the center during core collapse are likely to be dynamically ejected, a process that can decrease the overall level of mass segregation again., Comment: Submitted to A&A. 8 pages, 4 figures

Front-end polarization modulation enables improved polarization measurement stability by modulating the targeted signal above the low-frequency $1/f$ drifts associated with atmospheric and instrumental instabilities and diminishes the impact of instrumental polarization. In this work, we present the design and characterization of a new 60-cm diameter Reflective Half-Wave Plate (RHWP) polarization modulator for the 90 GHz band telescope of the Cosmology Large Angular Scale Surveyor (CLASS) project. The RHWP consists of an array of parallel wires (diameter $50~\mathrm{\mu m}$, $175~\mathrm{\mu m}$ pitch) positioned $0.88~\mathrm{mm}$ from an aluminum mirror. In lab tests, it was confirmed that the wire resonance frequency ($f_\mathrm{res}$) profile is consistent with the target, $139~\mathrm{Hz}

We present the theoretical derivation and numerical implementation of the linear response equations for relativistic quantum electrodynamical density functional theory (QEDFT). In contrast to previous works based on the Pauli-Fierz Hamiltonian, our approach describes electrons interacting with photonic cavity modes at the four-component Dirac-Kohn-Sham level, derived from fully relativistic QED through a series of established approximations. Moreover, we show that a new type of spin-orbit-like (SO) cavity-mediated interaction appears under the relativistic description of the coupling of matter with quantized cavity modes. Benchmark calculations performed for atoms of group 12 elements (Zn, Cd, Hg) demonstrate how a relativistic treatment enables the description of exciton polaritons which arise from the hybridization of formally forbidden singlet-triplet transitions with cavity modes. For atoms in cavities tuned on resonance with a singlet-triplet transition we discover a significant interplay between SO effects and coupling to an off-resonant intense singlet-singlet transition. This dynamic relationship highlights the crucial role of ab initio approaches in understanding cavity quantum electrodynamics. Finally, using the mercury porphyrin complex as an example, we show that relativistic linear response QEDFT provides computationally feasible first-principles calculations of polaritonic states in large heavy element-containing molecules of chemical interest., Comment: 29 pages, 5 figures, supplemental material, v2: Corrected references to the Supplemental Material

Background: Computer models for simulating cardiac electrophysiology are valuable tools for research and clinical applications. Traditional reaction-diffusion (RD) models used for these purposes are computationally expensive. While eikonal models offer a faster alternative, they are not well-suited to study cardiac arrhythmias driven by reentrant activity. The present work extends the diffusion-reaction eikonal alternant model (DREAM), incorporating conduction velocity (CV) restitution for simulating complex cardiac arrhythmias. Methods: The DREAM modifies the fast iterative method to model cyclical behavior, dynamic boundary conditions, and frequency-dependent anisotropic CV. Additionally, the model alternates with an approximated RD model, using a detailed ionic model for the reaction term and a triple-Gaussian to approximate the diffusion term. The DREAM and monodomain models were compared, simulating reentries in 2D manifolds with different resolutions. Results: The DREAM produced similar results across all resolutions, while experiments with the monodomain model failed at lower resolutions. CV restitution curves obtained using the DREAM closely approximated those produced by the monodomain simulations. Reentry in 2D slabs yielded similar results in vulnerable window and mean reentry duration for low CV in both models. In the left atrium, most inducing points identified by the DREAM were also present in the high-resolution monodomain model. DREAM's reentry simulations on meshes with an average edge length of 1600$\mu$m were 40x faster than monodomain simulations at 200$\mu$m. Conclusion: This work establishes the mathematical foundation for using the accelerated DREAM simulation method for cardiac electrophysiology. Cardiac research applications are enabled by a publicly available implementation in the openCARP simulator., Comment: 39 pages, 9 figures

Small Angle-X-ray Scattering Tensor Tomography (SAS-TT) is a relatively new, but powerful technique for studying the multiscale architecture of hierarchical structures, which is of particular interest for life science applications. Currently, the technique is very demanding on synchrotron beamtime, which limits its applications, especially for cases requiring a statistically relevant amount of sample. This study reports the first SAS-TT measurement at a macromolecular X-ray crystallography beamline, PX-I at the SLS, with an improvement in data acquisition time from 96 h/Mvoxel in the pilot experiments to 6 h/Mvoxel, defining a new standard for fast SAS-TT and allowing the measurement of a full tomogram in 1.2 hours. Measurements were performed on the long and lenticular process of the incus bone, one of the three human auditory ossicles. The main orientation and degree of alignment of the mineralised collagen fibrils are characterised, as well as the size and shape of the mineral particles which show relevant variations in different tissue locations. The study reveals three distinct regions of high fibril alignment, most likely important pathways of sound throughout the ossicular chain, and highlights the potential of the technique to aid in future developments in middle ear reconstructive surgery.

Mosaic crystals, with their high integrated reflectivities, are widely-employed in spectrometers used to diagnose high energy density systems. X-ray Thomson scattering (XRTS) has emerged as a powerful diagnostic tool of these systems, providing in principle direct access to important properties such as the temperature via detailed balance. However, the measured XRTS spectrum is broadened by the spectrometer instrument function (IF), and without careful consideration of the IF one risks misdiagnosing system conditions. Here, we consider in detail the IF of 40 $\mu$m and 100 $\mu$m mosaic HAPG crystals, and how the broadening varies across the spectrometer in an energy range of 6.7-8.6 keV. Notably, we find a strong asymmetry in the shape of the IF towards higher energies. As an example, we consider the effect of the asymmetry in the IF on the temperature inferred via XRTS for simulated 80 eV CH plasmas, and find that the temperature can be overestimated if an approximate symmetric IF is used. We therefore expect a detailed consideration of the full IF will have an important impact on system properties inferred via XRTS in both forward modelling and model-free approaches., Comment: 19 pages, 13 figures

We investigate the stellar and nebular properties of 9 H II regions in the spiral galaxy M101 with far-ultraviolet (FUV; ~900-2000 \r{A}) and optical (~3200-10000 \r{A}) spectra. We detect significant C III] 1907,1909 nebular emission in 7 regions, but O III] 1666 only in the lowest-metallicity region. We produce new analytic functions of the carbon ICF as a function of metallicity in order to perform a preliminary C/O abundance analysis. The FUV spectra also contain numerous stellar emission and P-Cygni features that we fit with luminosity-weighted combinations of single-burst Starburst99 and BPASS models. We find that the best-fit Starburst99 models closely match the observed very-high-ionization P-Cygni features, requiring very-hot, young (~< 3 Myr), metal-enriched massive stars. The youngest stellar populations are strongly correlated with broad He II emission, nitrogen Wolf-Rayet (WR) FUV and optical spectral features, and enhanced N/O gas abundances. Thus, the short-lived WR phase may be driving excess emission in several N P-Cygni wind features (955 \r{A}, 991 \r{A}, 1720 \r{A}) that bias the stellar continuum fits to higher metallicities relative to the gas-phase metallicities. Accurate characterization of these H II regions requires additional inclusion of WR stars in the stellar population synthesis models. Our FUV spectra demonstrate that the ~900-1200 \r{A} FUV can provide a strong test-bed for future WR atmosphere and evolution models., Comment: 24 ages, 12 figures, accepted to ApJ

Two main mechanisms have classically been proposed for the formation of runaway stars. In the binary supernova scenario (BSS), a massive star in a binary explodes as a supernova, ejecting its companion. In the dynamical ejection scenario, a star is ejected during a strong dynamical encounter between multiple stars. We propose a third mechanism for the formation of runaway stars: the subcluster ejection scenario (SCES), where a subset of stars from an infalling subcluster is ejected out of the cluster via a tidal interaction with the contracting gravitational potential of the assembling cluster. We demonstrate the SCES in a star-by-star simulation of the formation of a young massive cluster from a $10^6\rm~M_\odot$ gas cloud using the Torch framework. This star cluster forms hierarchically through a sequence of subcluster mergers determined by the initial turbulent, spherical conditions of the gas. We find that these mergers drive the formation of runaway stars in our model. Late-forming subclusters fall into the central potential, where they are tidally disrupted, forming tidal tails of runaway stars that are distributed highly anisotropically. Runaways formed in the same SCES have similar ages, velocities, and ejection directions. Surveying observations, we identify several SCES candidate groups with anisotropic ejection directions. The SCES is capable of producing runaway binaries: two wide dynamical binaries in infalling subclusters were tightened through ejection. This allows for another velocity kick via subsequent via a subsequent BSS ejection. An SCES-BSS ejection is a possible avenue for the creation of hypervelocity stars unbound to the Galaxy. We expect nonspherical initial gas distributions to increase the number of calculated runaway stars. The observation of groups of runaway stars formed via the SCES can thus reveal the assembly history of their natal clusters., Comment: 11 pages, 10 figures. Accepted for publication in A&A. Abstract abridged for arXiv

Open software ecosystems are beneficial for customers; they benefit from 3rd party services and applications, e.g. analysis of data using apps, developed and deployed by other companies or open-source communities. One significant advantage of this approach is that other customers may benefit from these newly developed applications as well. Especially software ecosystems utilizing container technologies are prone to certain risks. Docker, in particular, is more vulnerable to attacks than hypervisor based virtualisation as it directly operates on the host system. Docker is a popular representative of containerisation technology which offers a lightweight architecture in order to facilitate the set-up and creation of such software ecosystems. Popular Infrastructure as a Service cloud service providers, like Amazon Web Services or Microsoft Azure, jump on the containerisation bandwagon and provide interfaces for provisioning and managing containers. Companies can benefit from that change of technology and create software ecosystems more efficiently. In this paper, we present a new concept for significant security improvements for cloud-based software ecosystems using Docker for 3rd party app integration. Based on the security features of Docker we describe a secure integration of applications in the cloud environment securely. Our approach considers the whole software lifecycle and includes sandbox testing of potentially dangerous 3rd party apps before these became available to the customers., Comment: 7 pages

A promising strategy to address the pressing challenges with wildfire, particularly in the wildland-urban interface (WUI), involves developing new approaches for preventing and controlling wildfire within wildlands. Among sprayable fire-retardant materials, water-enhancing gels have emerged as exceptionally effective for protecting civil infrastructure. They possess favorable wetting and viscoelastic properties that reduce the likelihood of ignition, maintaining strong adherence to a wide array of surfaces after application. Although current water-enhancing hydrogels effectively maintain surface wetness by creating a barricade, they rapidly desiccate and lose efficacy under high heat and wind typical of wildfire conditions. To address this limitation, we developed unique biomimetic hydrogel materials from sustainable cellulosic polymers crosslinked by colloidal silica particles that exhibit ideal viscoelastic properties and facile manufacturing. Under heat activation, the hydrogel transitions into a highly porous and thermally insulative silica aerogel coating in situ, providing a robust protective layer against ignition of substrates, even when the hydrogel fire suppressant becomes completely desiccated. By confirming the mechanical properties, substrate adherence, and enhanced substrate protection against fire, these heat-activatable biomimetic hydrogels emerge as promising candidates for next-generation water-enhancing fire suppressants. These advancements have the potential to dramatically improve our ability to protect homes and critical infrastructure during wildfire., Comment: 21 pages, 4 figures

Quantum networks require quantum nodes with coherent optical interfaces and multiple stationary qubits. In terms of optical properties, semiconductor quantum dots are highly compelling, but their adoption as quantum nodes has been impaired by the lack of auxiliary qubits. Here, we demonstrate a functional quantum register in a semiconductor quantum dot leveraging the dense, always-present nuclear spin ensemble. We prepare 13,000 host nuclear spins into a single many-body dark state to operate as the register logic state $|0\rangle$. The logic state $|1\rangle$ is defined as a single nuclear magnon excitation, enabling controlled quantum-state transfer between the electron spin qubit and the nuclear magnonic register. Using 130-ns SWAP gates, we implement a full write-store-retrieve-readout protocol with 68.6(4)% raw overall fidelity and a storage time of 130(16) $\mu$s in the absence of dynamical decoupling. Our work establishes how many-body physics can add step-change functionality to quantum devices, in this case transforming quantum dots into multi-qubit quantum nodes with deterministic registers.

A central spin qubit interacting coherently with an ensemble of proximal spins can be used to engineer entangled collective states or a multi-qubit register. Making full use of this many-body platform requires tuning the interaction between the central spin and its spin register. GaAs quantum dots offer a model realization of the central spin system where an electron qubit interacts with multiple ensembles of $\sim 10^{4}$ nuclear spins. In this work, we demonstrate tuning of the interaction between the electron qubit and the nuclear many-body system in a GaAs quantum dot. The homogeneity of the GaAs system allows us to perform high-precision and isotopically selective nuclear sideband spectroscopy, which reveals the single-nucleus electronic Knight field. Together with time-resolved spectroscopy of the nuclear field, this fully characterizes the electron-nuclear interaction for a priori control. An algorithmic feedback sequence selects the nuclear polarization precisely, which adjusts the electron-nuclear exchange interaction in situ via the electronic g-factor anisotropy. This allows us to tune directly the activation rate of a collective nuclear excitation (magnon) and the coherence time of the electron qubit. Our method is applicable to similar central-spin systems and enables the programmable tuning of coherent interactions in the many-body regime., Comment: 9 pages, 5 figures, and Supplementary Materials

Improved polarization measurements at frequencies below 70 GHz with degree-level angular resolution are crucial for advancing our understanding of the Galactic synchrotron radiation and the potential polarized anomalous microwave emission and ultimately benefiting the detection of primordial $B$ modes. In this study, we present sensitivity-improved 40 GHz polarization maps obtained by combining the CLASS 40 GHz and WMAP $Q$-band data through a weighted average in the harmonic domain. The decision to include WMAP $Q$-band data stems from similarities in the bandpasses. Leveraging the accurate large-scale measurements from WMAP $Q$ band and the high-sensitivity information from CLASS 40 GHz band at intermediate scales, the noise level at $\ell\in[30, 100]$ is reduced by a factor of $2-3$ in the map space. A pixel domain analysis of the polarized synchrotron spectral index ($\beta_s$) using WMAP $K$ band and the combined maps (mean and 16/84th percentile across the $\beta_s$ map: $-3.08_{-0.20}^{+0.20}$) reveals a stronger preference for spatial variation (PTE for a uniform $\beta_s$ hypothesis smaller than 0.001) than the results obtained using WMAP $K$ and $Ka$ bands ($-3.08_{-0.14}^{+0.14}$). The cross-power spectra of the combined maps follow the same trend as other low-frequency data, and validation through simulations indicates negligible bias introduced by the combination method (sub-percent level in the power spectra). The products of this work are publicly available on $\mathtt{LAMBDA}$., Comment: 19 pages, 16 figures, 1 table, accepted for publication in ApJ

Optimizing grain boundary characteristics in polycrystalline materials can improve their properties. Many processing methods have been developed for grain boundary manipulation, including the use of intense radiation in certain applications. In this work, we used X-ray free electron laser pulses to irradiate single-crystalline bismuth selenide (Bi2Se3) and observed grain boundary formation and subsequent grain rotation in response to the X-ray radiation. Our observations with simultaneous transmission X-ray microscopy and X-ray diffraction demonstrate how intense X- ray radiation can rapidly change size and texture of grains., Comment: 37 pages, 11 figures including 6 supplemental figures

Using a novel ultrahigh resolution ($\Delta E \sim 0.1\,$eV) setup to measure electronic features in x-ray Thomson scattering (XRTS) experiments at the European XFEL in Germany, we have studied the collective plasmon excitation in aluminium at ambient conditions, which we can measure very accurately even at low momentum transfers. As a result, we can resolve previously reported discrepancies between ab initio time-dependent density functional theory simulations and experimental observations. The demonstrated capability for high-resolution XRTS measurements will be a game changer for the diagnosis of experiments with matter under extreme densities, temperatures, and pressures, and unlock the full potential of state-of-the-art x-ray free electron laser (XFEL) facilities to study planetary interior conditions, to understand inertial confinement fusion applications, and for material science and discovery.

Let $\mathfrak{g}$ be a symmetrizable Kac-Moody algebra, $U_q(\mathfrak{g})$ its quantum group, and $U_q(\mathfrak{k}) \subset U_q(\mathfrak{g})$ a quantum symmetric pair subalgebra determined by a Lie algebra automorphism $\theta$. We introduce a category $W_\theta$ of weight $U_q(\mathfrak{k})$-modules, which is acted upon by the category of weight $U_q(\mathfrak{g})$-modules via tensor products. We construct a universal tensor K-matrix $\mathbb{K}$ (that is, a solution of a reflection equation) in a completion of $U_q(\mathfrak{k}) \otimes U_q(\mathfrak{g})$. This yields a natural operator on any tensor product $M \otimes V$, where $M\in W_\theta$ and $V\in \mathcal{O}_\theta$, that is $V$ is a $U_q(\mathfrak{g})$-module in category $\mathcal{O}$ satisfying an integrability property determined by $\theta$. $W_\theta$ is equipped with a structure of a bimodule category over $\mathcal{O}_\theta$ and the action of $\mathbb{K}$ is encoded by a new categorical structure, which we call a boundary structure on $W_\theta$. This generalizes a result of Kolb which describes a braided module structure on finite-dimensional $U_q(\mathfrak{k})$-modules when $\mathfrak{g}$ is finite-dimensional. We apply our construction to the case of an affine Lie algebra, where it yields a formal tensor K-matrix valued in the endomorphisms of the tensor product of any module in $W_\theta$ and any finite-dimensional module over the corresponding quantum affine algebra. This formal series is normalized to a trigonometric K-matrix if the factors in the tensor product are both finite-dimensional irreducible modules over the quantum affine algebra., Comment: 52 pages. Minor revision: Appendix A added; bibliography updated and expanded; minor changes to the introduction

The functionality of materials is determined by their composition and microstructure, that is, the distribution and orientation of crystalline grains, grain boundaries and the defects within them. The characterisation of the material's microstructure is therefore critical for materials applications such as catalysis, energy storage and buildings. Until now, characterization techniques that map the distribution of grains, their orientation, and the presence of defects have either been limited to surface investigations, to spatial resolutions of a few hundred nanometres, or to systems of thickness around one hundred nanometres, thus requiring destructive sample preparation for measurements and preventing the study of system-representative volumes or the investigation of materials under operational conditions. Here, we present X-ray linear dichroic orientation tomography, a quantitative, non-invasive technique that allows for an intra- and inter-granular characterisation of extended polycrystalline and amorphous materials in three dimensions (3D). We present the detailed characterisation of a polycrystalline sample of vanadium pentoxide (V2O5), a key catalyst in the production of sulfuric acid. In addition to determining the nanoscale composition, we map the crystal orientation throughout the polycrystalline sample with 73 nm spatial resolution. We identify grains, as well as twist, tilt, and twin grain boundaries. We further observe the creation and annihilation of topological defects promoted by the presence of volume crystallographic defects in 3D. Our method's non-destructive and spectroscopic nature opens the door to in-operando combined chemical and microstructural investigations of functional materials, including energy and mechanical materials in existing industries, as well as quantum materials for future technologies.

The ForMAX beamline at the MAX IV Laboratory provides multiscale and multimodal structural characterization of hierarchical materials in the nm to mm range by combining small- and wide-angle x-ray scattering with full-field microtomography. The modular design of the beamline is optimized for easy switching between different experimental modalities. The beamline has a special focus on the development of novel, fibrous materials from forest resources, but it is also well suited for studies within, e.g., food science and biomedical research., Comment: Accepted for publication in J. Synchrotron Rad

The mode of star formation that results in the formation of globular clusters and young massive clusters is difficult to constrain through observations. We present models of massive star cluster formation using the Torch framework, which uses AMUSE to couple distinct multi-physics codes that handle star formation, stellar evolution and dynamics, radiative transfer, and magnetohydrodynamics. We upgrade Torch by implementing the N-body code PeTar, thereby enabling Torch to handle massive clusters forming from $10^6\rm\, M_\odot$ clouds with $\ge10^5$ individual stars. We present results from Torch simulations of star clusters forming from $10^4, 10^5$, and $10^6\rm M_\odot$ turbulent, spherical gas clouds (named M4, M5, M6) of radius $R=11.7$ pc. We find that star formation is highly efficient and becomes more so at higher cloud mass and surface density. For M4, M5, and M6 with initial surface densities $2.325\times 10^{1,2,3}\rm\, M_\odot\, pc^{-2}$, after a free-fall time of $t_{ff}=6.7,2.1,0.67$ Myr, we find that $\sim30\%$, 40%, and 60% of the cloud mass has formed into stars, respectively. The final integrated star formation efficiency is $32\%,\, 65\%$, and 85\% for M4, M5, and M6. Observations of nearby clusters similar to M4 have similar integrated star formation efficiencies of $\leq30\%$. The M5 and M6 models represent a different regime of cluster formation that is more appropriate for the conditions in starburst galaxies and gas-rich galaxies at high redshift, and that leads to a significantly higher efficiency of star formation. We argue that young massive clusters build up through short efficient bursts of star formation in regions that are sufficiently dense ($\ge 10^2 \rm\,M_\odot\,pc^{-2}$) and massive ($\ge10^5\rm\, M_\odot$). In such environments, the dynamical time of the cloud becomes short enough that stellar feedback cannot act quickly enough to slow star formation., Comment: Submitted to A&A

Here, using low-temperature optical scanning tunneling microscopy (STM), we investigate inelastic light scattering (ILS) in the vicinity of a single-atom quantum point contact (QPC). A vibration mode localized at the single Ag adatom on the Ag(111) surface is resolved in the ILS spectrum, resulting from tip-enhanced Raman scattering (TERS) by the atomically-confined plasmonic field in the STM junction. Furthermore, we trace how TERS from the single adatom evolves as a function of the gap distance. The exceptional stability of the low-temperature STM allows to examine distinctly different electron transport regimes of the picocavity, namely in the tunneling and quantum point contact (QPC) regimes. This measurement shows that the vibration mode localized at the adatom and its TERS intensity exhibits a sharp change upon the QPC formation, indicating that the atomic-level structure has a crucial impact on the plasmonic properties. To gain microscopic insights into picocavity optomechanics, we scrutinize the structure and plasmonic field in the STM junction using time-dependent density functional theory. The simulations reveal that atomic-scale structural relaxation at the single-atom QPC results in a discrete change of the plasmonic field strength, volume, and distribution as well as the vibration mode localized at the single atom. These findings give a qualitative explanation for the experimental observations. Furthermore, we demonstrate that strong ILS is a characteristic feature of QPC by continuously forming, breaking, and reforming the atomic contact, and how the plasmonic resonance evolves throughout the non-tunneling, tunneling, and QPC regimes., Comment: 23 pages, 5 figures

This paper focuses on the impact of introducing a Group Dynamics Training Activity (GDTA) on learners' reported engagement during the course. The context is a university Common European Framework of Reference for languages (CEFR) B2 French language online course over the course of two semesters. Data was collected in the form of online surveys during the semester prior to the introduction of the GDTA and during the semester when it was administered. This case study uses quantitative analysis of Likert-scale question responses and qualitative analysis of open fields in the questionnaires using a content analysis methodology. Results indicate that the GDTA had a positive impact on learners, particularly on the social and cognitive dimension of learner engagement. [For the complete volume, "Intelligent CALL, Granular Systems and Learner Data: Short Papers from EUROCALL 2022 (30th, Reykjavik, Iceland, August 17-19, 2022)," see ED624779.]

Mobile Instant Messaging (MIM) applications have come into focus as potential tools to improve English language instruction, and teachers can engage more students from different backgrounds in English as a Foreign Language (EFL) classes thanks to MIM apps' distinctive features, like WhatsApp. Most of the reported studies on the use of WhatsApp in the teaching of foreign languages were performed in university or adult learning environments. The present study explores how social and emotional engagement manifest themselves in a popular instant messaging application group (WhatsApp) used by teenagers learning EFL. A focus group, a Likert scale survey, and a transcript of the WhatsApp chat were the three main sources from which data was gathered. Members' interaction records were retrieved and inductive thematic analysis was used to examine them. These findings suggest that WhatsApp provided communicative opportunities to all students, including those who did not fully engage. However, further research with a larger number of students in different contexts is necessary. [For the complete volume, "Intelligent CALL, Granular Systems and Learner Data: Short Papers from EUROCALL 2022 (30th, Reykjavik, Iceland, August 17-19, 2022)," see ED624779.]

We present direct observations of acoustic waves in warm dense matter. We analyze wave-number- and energy-resolved x-ray spectra taken from warm dense methane created by laser heating a cryogenic liquid jet. X-ray diffraction and inelastic free-electron scattering yield sample conditions of 0.3$\pm$0.1 eV and 0.8$\pm$0.1 g/cm$^3$, corresponding to a pressure of $\sim$13 GPa. Inelastic x-ray scattering was used to observe the collective oscillations of the ions. With a highly improved energy resolution of $\sim$50 meV, we could clearly distinguish the Brillouin peaks from the quasielastic Rayleigh feature. Data at different wave numbers were utilized to derive a sound speed of 5.9$\pm$0.5 km/s, marking a high-temperature data point for methane and demonstrating consistency with Birch's law in this parameter regime., Comment: 7 pages, 4 figures

Group IV vacancy color centers in diamond are promising spin-photon interfaces with strong potential for applications for photonic quantum technologies. Reliable methods for controlling and stabilizing their charge state are urgently needed for scaling to multi-qubit devices. Here, we manipulate the charge state of silicon vacancy (SiV) ensembles by combining luminescence and photo-current spectroscopy. We controllably convert the charge state between the optically active SiV$^-$ and dark SiV$^{2-}$ with MHz rates and 90% contrast by judiciously choosing the local potential applied to in-plane surface electrodes and the laser excitation wavelength. We observe intense SiV$^-$ photoluminescence under hole-capture, measure the intrinsic conversion time from the dark SiV$^{2-}$ to the bright SiV$^-$ to be 36.4(6.7)ms and demonstrate how it can be enhanced by a factor of $10^5$ via optical pumping. Moreover, we obtain new information on the defects that contribute to photo-conductivity, indicating the presence of substitutional nitrogen and divacancies., Comment: 5 figures

Deterministic photon sources allow long-term advancements in quantum optics. A single quantum emitter embedded in a photonic resonator or waveguide may be triggered to emit one photon at a time into a desired optical mode. By coherently controlling a single spin in the emitter, multi-photon entanglement can be realized. We demonstrate a deterministic source of three-qubit entanglement based on a single electron spin trapped in a quantum dot embedded in a planar nanophotonic waveguide. We implement nuclear spin narrowing to increase the spin dephasing time to $T_2^* \simeq 33$ ns, which enables high-fidelity coherent optical spin rotations, and realize a spin-echo pulse sequence for sequential generation of high-fidelity spin-photon and spin-photon-photon entanglement. The emitted photons are highly indistinguishable, which is a key requirement for subsequent photon fusions to realize larger entangled states. This work presents a scalable deterministic source of multi-photon entanglement with a clear pathway for further improvements, offering promising applications in photonic quantum computing or quantum networks.