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Hypothesis: Passive low ice-adhesion surfaces are frequently composed of soft materials; however, soft materials potentially present durability issues, which could be overcome by fabricating composite surfaces with patterned rigid and soft areas. Here we propose the innovative concept of discontinuity-enhanced icephobic surfaces, where the stress concentration at the edge between rigid and soft areas, i.e. where discontinuities in elasticity are located, facilitates ice detachment. Experiments: Composite model surfaces were fabricated with controlled rigid-soft ratios and discontinuity line lengths. The ice adhesion values were measured while recording the ice/substrate interface, to unravel the underpinning ice detachment mechanism. The experiments were complemented by numerical simulations that provided a better understanding of the ice detachment mechanism. Findings: It was found that when a surface contains rigid and soft areas, stress is concentrated at the edge between soft and hard areas, i.e. at the discontinuity line, rather than all over the soft or rigid areas. An unexpected non-unidirectional crack propagation was observed for the first time and elucidated. When rigid and deformable materials are present, the crack occurs on the discontinuity line and propagates first on rigid and then on soft areas. Moreover, it was demonstrated that an increase in discontinuities promotes crack initiation and leads to a reduction of ice adhesion.

Hypothesis: Investigating solid-liquid interactions to determine advancing and receding contact angles, and consequently contact angle hysteresis, is crucial for understanding material wetting properties. A reliable, automated, and possibly open-source tool is desirable, to standardize and automatize the measurement and make it user-independent. Experiments: This study introduces an open-source software, DropenVideo, as an extension of Dropen. DropenVideo automates frame-by-frame video analysis for the advancing and receding contact angle determination, by considering needle presence, contrast tuning, and compensating for missing drop edge data. Contact angles are calculated using convolution mask, circle, and polynomial fittings. An innovative feature in DropenVideo is the automatic protocol for identifying advancing and receding contact angles: (i) the advancing contact angle is determined as the average value during drop inflation; and (ii) the receding contact angle is determined from the frame of incipient motion during drop deflation. Findings: Exploring the application of DropenVideo across a range of complex surfaces as representative test cases, we highlight existing challenges in interpreting wetting measurements by addressing different wetting scenarios. Our study demonstrates that employing frame-by-frame automatic analysis of contact angle measurement videos using DropenVideo significantly mitigates the potential risks of subjective bias associated with manual interpretation and enhances the precision of identified wetting characteristics.

Icephobic materials and systems are highly desired in regions and seasons where daily life activities are hindered by the presence of ice. The combination of icephobic materials with active de-icing systems, known as hybrid systems, is a promising way to optimize efficiency in ice removal, while reducing power consumption. However, the development of hybrid systems is limited by their lifespan and the incompatibility of most icephobic materials with the operating mode of the active system. Here we present a hybrid system comprising a gradient polymer coating deposited with initiated chemical vapor deposition and a resonant piezoelectric de-icing system. The de-icing performance is evaluated in an icing wind tunnel, where the system is capable of detaching ice blocks in less than 1 s, regardless the ice type and covered area. An in-depth ice detachment study confirms that ice adhesion reduction is an intrinsic property of the coating, independent from external factors. The nanometric nature of the coating enables efficient operation of the resonant de-icing systems. The coating shows outstanding durability against the de-icing cycles, abrasion, water erosion, and delamination. The results showcase the hybrid systems potential in real-world applications to contrast icing.A hybrid system for de-icing made of gradient polymer coatings, deposited on aluminum coupled with an electromechanical system, is demonstrated as an effective and durable strategy for reducing drastically ice adhesion. The system is capable of detaching ice blocks over the coating in less than 1 s, regardless of the ice type and covered area.image (c) 2024 WILEY-VCH GmbH

The working curve informs resin properties and print parameters for stereolithography, digital light processing, and other photopolymer additive manufacturing (PAM) technologies. First demonstrated in 1992, the working curve measurement of cure depth vs radiant exposure of light is now a foundational measurement in the field of PAM. Despite its widespread use in industry and academia, there is no formal method or procedure for performing the working curve measurement, raising questions about the utility of reported working curve parameters. Here, an interlaboratory study (ILS) is described in which 24 individual laboratories performed a working curve measurement on an aliquot from a single batch of PAM resin. The ILS reveals that there is enormous scatter in the working curve data and the key fit parameters derived from it. The measured depth of light penetration Dp varied by as much as 7x between participants, while the critical radiant exposure for gelation Ec varied by as much as 70x. This significant scatter is attributed to a lack of common procedure, variation in light engines, epistemic uncertainties from the Jacobs equation, and the use of measurement tools with insufficient precision. The ILS findings highlight an urgent need for procedural standardization and better hardware characterization in this rapidly growing field.

Materials against ice formation and accretion are highly desirable for different industrial applications and daily activities affected by icing. Although several concepts have been proposed, no material has so far shown wide-ranging icephobic features, enabling durability and manufacturing on large scales. Herein, we present gradient polymers made of 1,3,5,7-tetravinyl-1,3,5,7-tetramethylcyclotetrasiloxane (V4D4) and 1H,1H,2H,2H-perfluorodecyl acrylate (PFDA) deposited in one step via initiated chemical vapor deposition (iCVD) as an effective coating to mitigate ice accretion and reduce ice adhesion. The gradient structures easily overcome adhesion, stability, and durability issues of traditional fluorinated coatings. The coatings show promising icephobic performance by reducing ice adhesion, depressing the freezing point, delaying drop freezing, and inhibiting ice nucleation and frost propagation. Icephobicity correlates with surface energy discontinuities at the surface plane resulting from the random orientation of the fluorinated groups of PFDA, as confirmed by grazing-incidence X-ray diffraction measurements. The icephobicity could be further improved by tuning the surface crystallinity rather than surface wetting, as samples with random crystal orientation show the lowest ice adhesion despite high contact angle hysteresis. The iCVD-manufactured coatings show promising results, indicating the potential for ice control on larger scales and various applications.

Understanding water drop impact on meshes is valuable to design passive systems for atmospheric water collection. By investigating water drop impact on hydrophobic and superhydrophobic surfaces, here, we identify the different drop impact outcomes and build outcome maps within the pertinent parameter spaces, based on Weber number and contact angles. Furthermore, we quantitatively evaluate critical factors such as the captured volume and spray characteristics of the penetrating liquid and also measure the drop rebound time, reporting that full rebound occurs on superhydrophobic meshes surfaces even at high We numbers, as the Cassie-Baxter wetting state is maintained.

Soft materials are a promising alternative to design and fabricate passive de-icing systems, considering the low ice adhesion strength values reported in the literature. Nevertheless, the interwoven effects of surface and mechanical properties have been not elucidated in terms of their individual contribution to the ice adhesion performance. In this work, the wetting and mechanical properties of soft PDMS with different lubricant content were analyzed by using different strategies: sessile drop, indentation and rheology experiments. The collected information is used to understand its relation with the shear ice adhesion results. First of all, the visualization of fracture events and its synchronization with the adhesion force measurement by ice push tests allowed to identify three different de-icing mechanisms depending on the size of the ice block: (i) Single detachment, (ii) stick-slip and (iii) interfacial slippage. The outcome depends both on the surface and on the size of the ice block. An increasing amount of lubricant decreases the force necessary for the initial ice detachment, which is an advantage in single detachment regime, where the small ice blocks are completely separated at the end of the experiments. When bigger ice blocks are considered, the silanol dangling ends molecules that migrated to the interface due to the contact with water, promotes the reattachment of the ice block, inducing a change from the stick-slip to the interfacial slippage mechanism, where the ice is more likely to remain attached after the de-icing experiment. More in details, on one hand advancing and receding contact angle measurements indicated the importance of considering the migration of low surface energy uncrosslinked chains to the interface during contact with water, leading to lubrication of the ice-substrate interface. This implies that two materials with different lubricant amounts may present similar contact angles after exposure to water (time scale 10 s). However

The interest in the development of icephobic surfaces has pushed towards the definition of standardized processes and parameters to assess ice adhesion, with the ambition of identifying an equivalent method to contact angle measurements used to assess wetting properties. Although most studies focus on the average ice adhesion strength, measured as the force per unit area required to detach ice, much less attention is paid to interfacial toughness, perhaps as its measurement is challenging. In this article, we provide a conceptual framework to correctly measure both ice adhesion strength and interfacial toughness, even using a simple push test method, laying the ground for a complete and comprehensive assessment of surface icephobicity.

Icephobic materials can prevent or reduce ice formation, e.g. by ensuring easy detachment, a desirable property for those applications where ice accumulation is critical to human safety. Herein, we develop a chitosan electrolyte hydrogel to create a bio-based surface with low ice adhesion. The chitosan electrolyte hydrogel is physically crosslinked and infused with salted water at concentrations from 4.5 to 30 g/L, including that of seawater (23 g/L). Depending on salt content in the hydrogel, we could obtain very low ice adhesion down to 140 kPa (at – 10°C). We hypothesize that the chitosan electrolyte hydrogel exploits the colligative properties of water avoiding the ice nucleation at the ice-hydrogel interface. To confirm the hypothesis, we investigate the chitosan electrolyte hydrogel structure by contact angles analysis, DSC, TGA, FTIR, XRD, and by rheometry for mechanical properties. We quantify the presence of non-freezing water, which creates a lubricating liquid water layer at the ice-hydrogel interface, affecting the ice detachment mechanism and lowering ice adhesion. In conclusion, the proposed chitosan electrolyte hydrogel presents a bio-based and cost-efficient strategy for ice detachment across various icing scenarios for systems operating in humid marine environments, such as offshore platforms and ships.

Hypothesis Soft materials are promising candidates for designing passive de-icing systems. It is unclear whether low adhesion on soft surfaces is due to elasticity or lubrication, and how these properties affect the ice detachment mechanism. This study presents a systematic analysis of ice adhesion on soft materials with different lubricant content to better understand the underpinning interaction. Experiments The wetting and mechanical properties of soft polydimethylsiloxane with different lubricant content were thoroughly characterized by contact angle, indentation, and rheology measurements. The collected information was used to understand the relationship with the ice adhesion results, obtained by using different ice block sizes. Findings Three different de-icing mechanisms were identified: (i) single detachment occurs when small ice blocks are considered, and the ice completely detaches in a single event. In the case of larger ice blocks, the reattachment of the ice block is promoted by either: (ii) stick–slip or, (iii) interfacial slippage, depending on the lubricant content. It was confirmed that the ice adhesion strength is not a material property, since it depends on the ice block size. As such, differently than on hard surfaces, where wetting primarily determines the icephobic performance, also elasticity and lubrication need to be considered on soft surfaces.

Controlling surface morphology is one of the main strategies used to tune surface hydrophobic and icephobic properties. Taking advantage of coating growth by initiated chemical vapor deposition, random and ordered wrinkles were induced on a thin film of polyperfluorodecyl acrylate (pPFDA) deposited on polydimethylsiloxane (PDMS) to simultaneously modify surface chemistry and morphology. A range of wrinkles of different wavelengths were studied, and how the wrinkle characteristics change with varying coating thickness. Ordered wrinkles enhanced hydrophobicity more when compared to random wrinkles, with a noticeable effect for coating thickness on the order of hundreds of nanometers. An insight into the mechanism of surface wrinkling and its effect on freezing delay is also provided, and promising results were found on ordered wrinkles, where a freezing delay was observed.

Chitosan and its derivatives are interesting biopolymers for different field of analytical chemistry, especially in separation techniques. The present study was aimed at testing chitosan water soluble derivatives as dynamic coating agents for application to capillary electrophoresis. In particular, chitosan was modified following three different chemical reactions (nucleophilic substitution, reductive amination, and condensation) to introduce differences in charge and steric hindrance, and to assess the effect of these physico-chemical properties in capillary electrophoresis. The effects were tested on the capillary electrophoretic separation of the glycoforms of human transferrin, an important iron-transporting serum protein, one of which, namely disialo-transferrin (CDT), is a biomarker of alcohol abuse. Chitosan derivatives were characterized by using NMR and 1H NMR, HP-SEC-TDA, DLS, and rheology. The use of these compounds as dynamic coatings in the electrolyte running buffer in capillary electrophoresis was tested assessing the peak resolution of the main glycoforms of human transferrin and particularly of disialo-transferrin. The results showed distinct changes of the peak resolution produced by the different derivatives. The best results in terms of peak resolution were achieved using polyethylene glycol (PEG)-modified chitosan, which, in comparison to a reference analytical approach, provided an almost baseline resolution of disialo-transferrin from the adjacent peaks.

Polymeric nanofilms have been widely utilized in diverse cutting-edge technologies, yet accurately determining their elastic moduli remains challenging. Here we demonstrate that interfacial nanoblisters, which are produced by simply immersing substrate-supported nanofilms in water, represent natural platforms for assessing the mechanical properties of polymeric nanofilms using the sophisticated nanoindentation method. Nevertheless, high-resolution, quantitative force spectroscopy studies reveal that the indentation test must be performed on an effective freestanding region around the nanoblister apex and meanwhile under an appropriate loading force, to obtain load-independent, linear elastic deformations. The nanoblister stiffness increases with either decreasing its size or increasing its covering film thickness, and such size effects can be adequately rationalized by an energy-based theoretical model. The proposed model also enables an exceptional determination of the film elastic modulus. Given that interfacial blistering is a frequently occurring phenomenon for polymeric nanofilms, we envision that the presented methodology would stimulate broad applications in relevant fields.

Hypothesis: Characterizing the microstructure of an ice/surface interface and its effect on the icephobic behavior of surfaces remains a significant challenge. Introducing X-ray Computed Tomography (XCT) can provide unprecedented insights into the internal (porosity) and interfacial structures, i.e. wetting regime, between (super)hydrophobic surfaces and ice by visualizing these optically inaccessible regions. Experiments: Frozen droplets with controlled volume were deposited on top of metallic and polymeric substrates with different levels of wettability. Different modes of XCT (3D and 4D) were utilized to obtain information on the internal and interfacial structure of the ice/surface system. The results were supplemented by conventional surface analysis techniques, including optical profilometry and contact angle measurements. Findings: Using XCT on ice/surface systems, the 3D and 4D (imaging with temporal resolution) structural information can be visualized. From these datasets, qualitative and quantitative results were obtained, not only for characterizing the interface but also for analyzing the entire droplet/surface system, e.g., measurement of porosity size, shape, and location. These results highlight the potential of XCT in the characterization of both droplets and substrates and proves that the technique can aid to develop hydrophobic surfaces for use as icephobic materials.

Chitosan is a marine-origin polysaccharide obtained from the deacetylation of chitin, the main component of crustaceans’ exoskeleton, and the second most abundant in nature. Although this biopolymer has received limited attention for several decades right after its discovery, since the new millennium chitosan has emerged owing to its physicochemical, structural and biological properties, multifunctionalities and applications in several sectors. This review aims at providing an overview of chitosan properties, chemical functionalization, and the innovative biomaterials obtained thereof. Firstly, the chemical functionalization of chitosan backbone in the amino and hydroxyl groups will be addressed. Then, the review will focus on the bottom-up strategies to process a wide array of chitosan-based biomaterials. In particular, the preparation of chitosan-based hydrogels, organic–inorganic hybrids, layer-by-layer assemblies, (bio)inks and their use in the biomedical field will be covered aiming to elucidate and inspire the community to keep on exploring the unique features and properties imparted by chitosan to develop advanced biomedical devices. Given the wide body of literature that has appeared in past years, this review is far from being exhaustive. Selected works in the last 10 years will be considered.

Several additive manufacturing (AM) technologies are nowadays available for layer-by-layer fabrication of complex parts, allowing reduction of costs and waste compared to conventional manufacturing technologies. Among all AM technologies, digital light processing (DLP), an advanced version of stereolithography (SLA), is emerging for manufacturing 3D objects using liquid photopolymers and suspensions (e.g. including ceramic and metal particles) as feedstock. In case of supsensions, the printed object can be thermally treated for debinding and sintering, producing ceramic and metal objects. DLP takes the advantage of a digital light projector, which selectively polymerizes the feedstock, printing each layer with a single exposure, thus eliminating the scanning time required in SLA. The technology can be adopted for several applications in the field of biomedical, automobile, aerospace, and electronics due to the technological advancement in projection-based manufacturing technology and the development of innovative materials in form of elastomers, shape memory polymers, and suspensions (ceramics, metals, composites, and nanocomposites). For successful manufacturing, feedstocks need to be thoroughly characterized for optimal printing. Therefore, this work presents a systematic study to characterize both pure photopolymers and suspensions, discussing two radiation-independent characteristic parameters of photopolymers, the critical energy (Ec) and the penetration depth (Dp). This also includes some of the basic theoretical aspects of light-matter interaction that can guide the manufacturing process development and optimization. Based on such findings, we present a “printing window”, identifying the boundaries for minimum and maximum radiation exposure for optimized polymerization and thus providing guidelines for the optimal printing conditions of each individual feedstock.

Mitigating icing hazards is of interest for many technological applications. One solution is to employ low ice adhesion coatings, either passively or in combination with active de-icing systems. Nevertheless, comparing different low ice adhesion surfaces can be challenging. Studies generally report the average shear stress, calculated as the ratio of applied force to the ice-substrate contact area; however, the fracture mechanism at the ice-substrate interface is rarely reported. There are two fracture mechanisms that can occur at the interface: stress-dominated and toughness-dominated. Average shear stress is only meaningful when performing adhesion tests in a stress-dominated regime; otherwise, interface stresses are underestimated and misleading. This study presents a new understanding of ice adhesion mechanisms combining experimental and numerical methods, demonstrating how the traditional ice adhesion reporting method can lead to errors up to 400%. Using a simple fracture model, the study shows that the stress-dominated fracture regime in the horizontal push test is favored by smaller ice diameter and greater ice thickness, and is also affected by the load force position. The identification of the two fracture regimes is required for the correct understanding and reproducibility of ice adhesion results, enabling better design and characterization of icephobic coatings and materials.

Understanding the underlying hydrodynamics and developing strategies to control bouncing droplets on superhydrophobic surfaces are of fundamental and practical significance. While recent efforts have mainly focused on regulating the contact time of bouncing droplets, less attention was given to manipulating droplet rebound from the perspective of energy optimization, which determines the long-term successive dynamics. Here, we investigate the impact of water droplets on superhydrophobic cones at low Weber numbers, where ideally complete rebounds arise. In sharp contrast to flat superhydrophobic surfaces, an impinging droplet on a cone-shaped superhydrophobic surface undergoes almost inversion-symmetric spreading and retracting processes with prolonged contact time, and more strikingly, it rebounds with a higher restitution coefficient. Such enhanced droplet rebound is beyond the prediction of existing theoretical models, in which the viscous boundary layer was recognized as the dominant channel of energy dissipation and, thus, an increase in the contact time would result in a lower restitution coefficient; nevertheless, numerical simulations have confirmed the increase in the restitution coefficient. The quantitative energy and flow field analyses of our numerical results reveal that the suppression of the boundary layer in early impact and the weakening of the viscous flow near the moving edge in the subsequent impact phases, which were not accounted for yet in existing theoretical models, are the causes for the enhancement of droplet rebound on superhydrophobic cones.

Chitosan films have attracted increased attention in the field of sensors because of chitosan’s unique chemico-physical properties, including high adsorption capacity, filmability and transparency. A chitosan film sensor was developed through the dispersion of an ammonia specific reagent (Nessler’s reagent) into a chitosan film matrix. The chitosan film sensor was characterized to assess the film’s properties by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). A gas diffusion device was prepared with the chitosan film sensor, enabling the collection and detection of ammonia vapor from biological samples. The chitosan film sensor color change was correlated with the ammonia concentration in samples of human serum and artificial urine. This method enabled facile ammonia detection and concentration measurement, making the sensor useful not only in clinical laboratories, but also for point-of-care devices and wherever there is limited access to modern laboratory facilities.

The substitution of perfluorinated substances (PFAS) as chemical applied in anti-adhesive and hydrophobic applications has become an urgent need, due to raising concerns for their potential hazard. In this framework, chitosan-based coatings represent a promising alternative because of their properties of non-toxicity, biodegradability, and sustainability as raw materials. Our work developed modified chitosan-based coatings, with a fine-tuning of transparency and superhydrophobicity (Figure 1). Chitosan-based fluorine-free superhydrophobic coatings were obtained via functionality modification through esterification and amidation reaction with stearoyl chloride, followed by freeze-drying and coating deposition using a novel solvent-free approach followed by thermal treatment. A full characterization of the modified-chitosan was performed to assess its chemico-physical properties and confirmed the functionality modification. The application of an innovative and sustainable deposition method demonstrates to be effective in tuning the coating properties of transparency and superhydrophobicity, combining durability under physical abrasion.

Protein analysis by capillary electrophoresis is an established benchmark technique, where electrophoretic separation performances are frequently affected by protein adsorption on capillary walls. The protein-wall interaction can be suppressed or mitigated by the application of the so-called dynamic coating agents. In this study, the potential of chitosan derivatives as dynamic coating was investigated, targeting the separation of the carbohydrate deficient transferrin (CDT), a relevant biomarker in forensic analyses to detect chronic alcohol abuse. To this aim, chitosan was derivatized through different chemical reactions, including nucleophilic substitution, reductive amination, and condensation reaction, to provide different characteristics to the dynamic coatings. After chemical and physical characterization, chitosan derivatives were tested as dynamic coating additives in the buffer separation solution of CDT. Evidence of the improvement in the CDT separation efficiency were found applying PEGmodified chitosan via nucleophilic substitution.

Controlling water transport and management is crucial for continuous and reliable system operation in harsh weather conditions. Passive strategies based on nonwetting surfaces are desirable, but so far, the implementation of superhydrophobic coatings into real-world applications has been limited by durability issues and, in some cases, lack of compliance with environmental regulations. Inspired by surface patterning observed on living organisms, in this study we have developed durable surfaces based on contrast wettability for capillary-driven water transport and management. The surface fabrication process combines a hydrophobic coating with hard-anodized aluminum patterning, using a scalable femtosecond laser microtexturing technique. The concept targets heavy-duty engineering applications; particularly in aggressive weather conditions where corrosion is prevalent and typically the anodic aluminum oxide-based coating is used to protect the surface from corrosion, the concept has been validated on anodic aluminum oxide coated aluminum alloy substrates. Such substrates with contrast wettable characteristics show long-term durability in both natural and lab-based artificial UV and corrosion tests where superhydrophobic coatings tend to degrade.

Additive manufacturing technologies are developed and utilized to manufacture complex, lightweight, functional, and non-functional components with optimized material consumption. Among them, vat polymerization-based digital light processing (DLP) exploits the polymerization of photocurable resins in the layer-by-layer production of three-dimensional objects. With the rapid growth of the technology in the last few years, DLP requires a rational design framework for printing process optimization based on the specific material and printer characteristics. In this work, we investigate the curing of pure photopolymers, as well as ceramic and metal suspensions, to characterize the material properties relevant to the printing process, such as penetration depth and critical energy. Based on the theoretical framework offered by the Beer–Lambert law for absorption and on experimental results, we define a printing space that can be used to rationally design new materials and optimize the printing process using digital light processing. The proposed methodology enables printing optimization for any material and printer combination, based on simple preliminary material characterization tests to define the printing space. Also, this methodology can be generalized and applied to other vat polymerization technologies.

One of the current greatest challenges in materials science and technology is the development of safe- and sustainable-by-design coatings with enhanced functionalities, e.g. to substitute fluorinated substances raising concerns for their potential hazard on human health. Bio-based polymeric coatings represent a promising route with a high potential. In this study, we propose an innovative sustainable method for fabricating coatings based on chitosan with modified functionality, with a fine-tuning of coating properties, namely transparency and superhydrophobicity. The process consists in two main steps: i) fluorine-free modification of chitosan functional groups with stearoyl chloride and freeze-drying to obtain a superhydrophobic powder, ii) coating deposition using a novel solvent-free approach through a thermal treatment. The modified chitosan is characterized to assess its chemico-physical properties and confirm the functionality modification with fatty acid tails. The deposition method enables tuning the coating properties of transparency and superhydrophobicity, maintaining good durability.

Additive manufacturing is a layer-by-layer strategy enabling the advanced design and fabrication of complex 3D objects and structures, overcoming geometry limitations and reducing waste production compared to conventional technologies. Among various additive manufacturing technologies, digital light processing (DLP), is an additive manufacturing technology used to print photopolymer parts, using a projected light source to cure an entire layer at once. Initially developed for pure resins, recent advances have demonstrated the potential of DLP in the polymerization of ceramic and metal-loaded suspensions, enabling the fabrication of ceramic and metal components after proper debinding and sintering. Such flexibility increases the potential of DLP for different applications, ranging from dental implants and bone scaffolds to smart biomaterials for soft robotics, smart wearables, and microfluidic devices. The review provides an overview of DLP technology and its recent advances; specifically, the review covers the photopolymer properties, the ceramic and metallic feedstock preparation, and the light-matter interaction mechanism underpinning the printing and post-processing steps. Finally, a description of the current application is provided and complemented with future perspectives.