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Hemp shiv has been widely used as a plant aggregate incorporated into natural building composites such as hemp-lime due to its low thermal conductivity and high moisture buffer value. The aim of this research is to study the intrinsic physical parameters such as the porosity and cell wall structure of hemp shiv, which are responsible for the favourable thermal and hygric properties of hemp shiv. Scanning electron microscope observations of hemp shiv revealed microstructural features. A computed tomography (CT) scan improved the vizualization of pore shape and pore connectivity in three dimensions. The vessels exhibit little variation in size and there is no clear pore arrangement with a diffuse-porous distribution. The vessels are mostly solitary although some small groups of adjacent vessels exhibit shared cell walls between them. The vessels are approximately 50 to 100 µm in diameter and are surrounded by relatively thick fibre cells. These thick-walled fibres are located between the vessels with a diameter ranging from 1µm to 2µm. The pore frequency of hemp shiv (generally only measured on diffuse-porous woods) is around 20.8 vessels/mm2. The porosity of hemp shiv has been studied by a combination of mercury intrusion porosimetry (MIP) and CT scanning. Average accessible porosity of hemp shiv is 76.67 ± 2.03 % measured by MIP measurement and from 50% to 75% measured by CT, depending on the threshold and resolution., Academic Journal of Civil Engineering, Vol 35 No 2 (2017): Special Issue - ICBBM 2017

Significantly decreasing energy consumption in buildings requires more air-tight construction combined with much higher insulation levels. A potential unintended consequence of this approach has been deterioration in the indoor air quality, resulting from significantly reduced ventilation rates and the accumulation of airborne pollutants, and this has proven to be a bottleneck to successful implementation of legislation. The use of natural bio-based insulation materials has increased in recent years, largely driven by concerns over the embodied energy and whole-life environmental impact of insulation materials. This has led to their increased use, typically within breathable wall constructions. A breathable wall construction allows the insulation material to directly contribute to the indoor air quality. Volatile Organic Compounds (VOCs) having boiling points within the range 60-280 °C contribute to the indoor air contamination in buildings, and at certain concentrations can contribute to building-related illnesses. This paper presents some findings from the early stages of a phased experimental study to explore use of bio-based insulation materials, including hemp-lime and sheep’s wool, to reduce VOCs from the room atmosphere. There are many different volatile organic compounds and this study will consider the Total Volatile Organic Compound (TVOC) emissions expressed as toluene, as well as the formaldehyde emissions separately. Insulation specimens with nominal dimensions 200 x 60 x 50 mm were prepared and placed in horizontally mounted cylindrical chambers. Air maintained at 23 °C (±2 °C) and 50 % (±5 %) RH was fed in coaxially to one end of the cylinder. The exhaust air was sampled for VOCs and for formaldehyde following 3 and 28 day of exposure. The results of this paper will help inform the design of holistic indoor environments that consider more than just the hygrothermal properties of insulation materials., Academic Journal of Civil Engineering, Vol 33 No 2 (2015): Special Issue - ICBBM 2015