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International audience; We present first fiber Bragg grating (FBG) inscribed in polarization maintaining (PM) optical fiber with artificially anisotropic core achieved by an appropriate distribution of discrete germanium-doped areas in nanoscale. We proved that this FBG reveals unique properties. Its single-resonance spectral shape, strain and temperature sensitivities are similar to that for grating written in cylindrically symmetrical optical fiber, which indicates that it behaves as the grating fabricated in a non-PM fiber, whereas it is written in the fiber that preserves the orthogonal polarization components of the mode. Moreover, due to the relatively low birefringence of the fiber, the FBG is insensitive to the excited polarization state and twist, and only a negligible shift of the spectrum is noticeable with no changes in its shape. Thus, FBG inscribed in ZEBRA fiber is a kind of hybrid structure that can be used for all-fiber lasers that generate polarized wave, as well as for polarization fiber sensors and components with spectral insensitivity to random or intentional twist.

International audience; Silica-based optical fibers made by Modified Chemical Vapor Deposition (MCVD) technique have been doped with different concentrations of germanium (Ge). After characterization of the thermoluminescence (TL) process in each of these fibers, their real-time responses were studied by radioluminescence (RL) under X-rays. First, the same counterintuitive trend was observed for the intensity of the two phenomena as a function of the Ge content, namely the decrease in TL and RL signals with increasing Ge content. This behavior was explained by the existence of thermally disconnected traps. Then, the RL response as a function of the dose-rate of the fiber doped with 1% Ge was judiciously chosen and investigated in detail. The results show that up to Total Ionizing Dose (TID) of 1.9 kGy(SiO 2 ), this response is not only insensitive to the accumulated dose effect but also exhibits an afterglow decay at the end of the radiation much faster than that of a Ce-doped fiber, a very useful feature where irradiations are repetitive as in the medical field of flash-therapy. In addition to the medical field where the Ge-doped fiber seems to be quite suitable, slightly larger core diameters would also allow this same fiber to meet the challenge of high sensitivity in the environmental radiation monitoring around nuclear power plants or radioactive waste storage areas.

Oral; International audience

International audience; We report a bending-insensitive multi-core fiber (MCF) for lensless endoscopy imaging with modified fiber geometry that enables optimal light coupling in and out of the individual cores. In a previously reported bending insensitive MCF (twisted MCF), the cores are twisted along the length of the MCF allowing for the development of flexible thin imaging endoscopes with potential applications in dynamic and freely moving experiments. However, for such twisted MCFs the cores are seen to have an optimum coupling angle which is proportional to their radial distance from the center of the MCF. This brings coupling complexity and potentially degrades the endoscope imaging capabilities. In this study, we demonstrate that by introducing a small section (1 cm) at two ends of the MCF, where all the cores are straight and parallel to the optical axis one can rectify the above coupling and output light issues of the twisted MCF, enabling the development of bend-insensitive lensless endoscopes.

International audience

International audience; We report the first three photon micro-endoscope enabling imaging of unlabeled biological tissues. It is based on a double clad antiresonant hollow-core fiber which is designed to make the endoscope highly multimodal (2PEF, 3PEF, SHG, THG, CARS).

International audience; We present a novel fiber-optic component, a “tapered multicore fiber (MCF)”, designed for integration into ultraminiaturized endoscopes for minimally invasive two-photon point-scanning imaging and to address the power delivery issue that has faced MCF-based lensless endoscopes. With it we achieve experimentally a factor 6.0 increase in two-photon signal yield while keeping the ability to point-scan by the memory effect and a factor 8.9 sacrificing the memory effect. To reach this optimal design, we first develop and validate a fast numerical model capable of predicting the essential properties of an arbitrarily tapered MCF from its structural parameters. We then use this model to identify the tapered MCF design parameters that result in a chosen set of target properties (point-spread function, delivered power, presence or absence of memory effect). We fabricate the identified target designs by stack-and-draw and postprocessing on a CO2 laser-based glass processing and splicing system. Finally, we demonstrate the performance gain of the fabricated tapered MCFs in two-photon imaging when used in a lensless endoscope system. Our results show that tailoring of the taper profile brings new degrees of freedom that can be efficiently exploited for lensless endoscopes.

International audience; We investigated in this work the radioluminescence properties of a Ce-doped multimode silica-based optical fiber (core diameter of 50 µm) manufactured by the sol–gel technique when exposed to the high-energy X-rays (~600 keV) of the ORIATRON facility of CEA. We demonstrated its potential to monitor in real-time the beam characteristics of this facility that can either operate in a pulsed regime (pulse duration of 4.8 µs, maximum repetition rate of 250 Hz) or in a quasi-continuous mode. The radiation-induced emission (radioluminescence and a minor Cerenkov contribution) linearly grew with the dose rate in the 15–130 mGy(SiO$_2$)/s range, and the afterglow measured after each pulse was sufficiently limited to allow a clear measurement of pulse trains. A sensor with ~11 cm of sensitive Ce-doped fiber spliced to rad-hard fluorine-doped optical fiber, for the emitted light transport to the photomultiplier tube, exhibited interesting beam monitoring performance, even if the Cerenkov emission in the transport fiber was also considered (~5% of the signal). The beam monitoring potential of this class of optical fiber was demonstrated for such facilities and the possibilities of extending the dose rate range are discussed based on possible architecture choices such as fiber type, length or size.

International audience

We report the development of a silica glass single-mode polarization-maintaining fiber with birefringence induced by artificial anisotropic glass in the circular core without any external stress zones or structured cladding. The fiber core is composed of silica and germanium-doped silica nanorods ordered in submicrometer interleaved layers. The fiber has a measured cut-off wavelength at 1113 nm, phase birefringence of 0.3×10−4, and an effective mode diameter of 10.5 µm at the wavelength of 1550 nm. The polarization extinction ratio in the fiber is 20 dB at 1550 nm. The fiber is compatible with the standard SMF-28 fiber and can be easily integrated using standard fusion splicing with losses of 0.1 dB.

We present a novel fiber-optic component, a “tapered multi-core fiber”, designed for integration into ultra-miniaturized endoscopes for minimally invasive imaging. We develop a numerical model and use it to identify optimal designs which we then fabricate and experimentally validate.

We demonstrate a novel fiber-optic component, a “tapered multi-core fiber”, designed for integration into ultra-miniaturized endoscopes for minimally invasive imaging. We develop a numerical model and use it to identify optimal designs which we then fabricate and experimentally validate.

We present Fiber Bragg Grating (FBG) inscribed in optical fiber, which maintains polarization by artificially anisotropic material in the core. The FBG has single Bragg peak stable for any state of polarization.

In this work, we demonstrate and evaluate a new design of micro-structured core erbium-doped few-mode fiber to be used as optical amplifier in the context of mode-division multiplexing. This concept is proposed so as to better control the distribution of the Er3+ ions in the core area, thus permitting to adjust the overall differential modal gains between the different signal modes. The design presented here consists of 19 erbium-doped inclusions embedded in a pedestal geometry guiding 10 modes in the C-band. It has been optimized numerically so as to reach the equalized amplification of all the signal modes. The fiber has been realized and combined with custom-made dual-wavelength mode multiplexers based on multi-plane light conversion to shape the signal and pump beams. Amplification properties have finally been evaluated experimentally.

International audience

The incorporation of Ce3+ ions in silicate glasses is a crucial issue for luminescence-based sensing applications. In this article, we report on silica glass preforms doped with cerium ions fabricated by modified chemical vapor deposition (MCVD) under different atmospheres in order to favor the Ce3+ oxidation state. Structural analysis and photophysical investigations are performed on the obtained glass rods. The preform fabricated under reducing atmosphere presents the highest photoluminescence (PL) quantum yield (QY). This preform drawn into a 125 µm-optical fiber, with a Ce-doped core diameter of about 40 µm, is characterized to confirm the presence of Ce3+ ions inside this optical fiber core. The fiber is then tested in an all-fibered X-ray dosimeter configuration. We demonstrate that this fiber allows the remote monitoring of the X-ray dose rate (flux) through a radioluminescence (RL) signal generated around 460 nm. The response dependence of RL versus dose rate exhibits a linear behavior over five decades, at least from 330 µGy(SiO2)/s up to 22.6 Gy(SiO2)/s. These results attest the potentialities of the MCVD-made Ce-doped material, obtained under reducing atmosphere, for real-time remote ionizing radiation dosimetry.

International audience; This work reports on the fabrication and the characterization of hybrid optical fibers with silicon core and silica cladding. Adopting a two-step manufacturing technique derived from the stack-and-draw method, silicon-core fibers with core dimensions ranging from about 0.8 mu m to 3.5 mu m have been successively drawn into hundreds of meter-long fibers. A 3.3 mu m diameter core fiber has been more extensively characterized and background losses for this as-drawn fiber are less than 0.2 dB/cm between 1250 nm and 1650 nm, with a minimum of 0.12 dB/cm around 1600 nm. The crystalline state of the core and the limited impact of oxygen contamination were confirmed by Raman scattering, x-ray diffraction, HR-STEM, and ToF-SIMS analysis. Transmission peaks associated with specific modal distributions are evidenced under certain injection conditions and their positions are shown to be in good accordance with mode cut-off wavelengths of a step-index silicon-core fiber.

International audience; Silicon-core fibers were drawn into hundreds of meter-long spans. The regular crystalline structure of the core and the absence of oxygen contamination are demonstrated together with loss below 0.2 dB/cm from 1250 to 1650 nm.

Cerium doped silica glasses are attractive materials for radiation dosimetry. In this article, Ce-doped air-clad optical fiber has been fabricated for real-time X-ray dose rate measurements through the radioluminescence (RL) signal. The structural properties of the obtained material were studied using Raman spectroscopy. The presence of Ce3+ ions inside the sol-gel-derived silica core was confirmed using photoluminescence (PL) measurements. This optical fiber, with a high numerical aperture, was tested as active and guiding material in an all-fibered remote X-ray dosimeter configuration. We demonstrated that the response dependence of RL versus dose rate is linear from 52 mGy(SiO2)/s up to at least 1.5 Gy(SiO2)/s, allowing to monitor the dose rate evolution during an irradiation run. The presented results confirm the potentialities of this microstructured optical fiber to monitor ionizing radiations in harsh environments. They also pave the way toward an alternative to the widely used approach that uses scintillator material at the end of a transport’s optical fiber.

International audience; Hybrid optical fibers, i.e. optical fibers that combine, in the same structure, glass with crystal, metal, polymer or a second type of glass, open access to a wide range of optical properties or optical functions not accessible to common single-glass-made optical fibers. Silicon-core fibers are one type of hybrid fibers that have been intensively studied since 2006 with the aim to take benefit of the mid-infrared transparency of silicon or to implement opto-electrical functions in the optical fiber itself. Some of the unique optical properties of these semiconductor-core fibers have been demonstrated but it is admitted that optical losses are still today a drag on the rise of performances and hence devote specific attention. Post-processing based on laser or thermal annealing can be applied on the as-drawn fibers to improve core crystallinity and then reduce optical losses. However, such processing techniques have been demonstrated on centimeter-long fibers only. In the present paper, we demonstrate as-drawn silicon-core fiber with loss level below 0.2 dB/cm on the 1250-1650nm wavelength range, this fiber being continuously manufactured over length exceeding one hundred of meters. Several fibers have been fabricated from a rod-in-stack approach and different core dimensions ranging from about 0.8 to 3.4 mu m have been successively realized and extensive characterizations (XRD, micro-Raman spectroscopy, TEM and ToF-SIMS analysis) have been conducted on the 3.4 mu m core fiber. The crystalline state of the core, the absence of oxygen contamination and the optical transmission from 1.1 to 4 mu m will be presented.

This Letter reports on a large mode area pixelated Bragg fiber in which some high refractive index rods were replaced by boron-doped rods that allows polarization maintaining behavior while keeping single-mode behavior. The realized all-solid fiber has a core diameter of 35 µm. The fundamental mode is circular with a 25 µm mode field diameter around 1 µm wavelength, and the polarization extinction ratio reaches 30 dB. Finally, this fiber is single-mode and bendable up to a 20 cm radius with fundamental mode losses lower than 0.3 dB/m.

International audience; We report the fabrication and characterization of the first double clad tubular anti-resonant hollow core fiber. It allows to deliver ultrashort pulses without temporal nor spectral distortions in the 700-1000 nm wavelength range and to efficiently collect scattered light in a high numerical aperture double clad. The output fiber mode is shaped with a silica microsphere generating a photonic nanojet, making it well suitable for nonlinear microendoscopy application. Additionally, we provide an open access software allowing to find optimal drawing parameters for the fabrication of tubular hollow core fibers.

Optically activated glasses are essential to the development of new radiation detection systems. In this study, a bulk glassy rod co-doped with Cu and Ce ions, was prepared via the sol-gel technique and was drawn at about 2000 &deg, C into a cylindrical capillary rod to evaluate its optical and radioluminescence properties. The sample showed optical absorption and photoluminescence (PL) bands attributed to Cu+ and Ce3+ ions. The presence of these two ions inside the host silica glass matrix was also confirmed using PL kinetics measurements. The X-ray dose rate was remotely monitored via the radioluminescence (RL) signal emitted by the Cu/Ce scintillating sensor. In order to transport the optical signal from the irradiation zone to the detection located in the instrumentation zone, an optical transport fiber was spliced to the sample under test. This RL signal exhibited a linear behavior regarding the dose rate in the range at least between 1.1 mGy(SiO2)/s and 34 Gy(SiO2)/s. In addition, a spectroscopic analysis of this RL signal at different dose rates revealed that the same energy levels attributed to Cu+ and Ce3+ ions are involved in both the RL mechanism and the PL phenomenon. Moreover, integrated intensities of the RL sub-bands related to both Cu+ and Ce3+ ions depend linearly on the dose rate at least in the investigated range from 102 mGy(SiO2)/s up to 4725 mGy(SiO2)/s. The presence of Ce3+ ions also reduces the formation of HC1 color centers after X-ray irradiation.

Ce-doped sol-gel silica glasses were prepared for real-time X-ray dose or dose rate monitoring using radioluminescence ( RL ) and optically stimulated luminescence (OSL). A small piece of this glass scintillator was connected to two optical fibers, allowing a remote measurement of the ionizing radiation dose through RL and OSL signals. By using this Ce-doped material, we particularly demonstrated that the RL signal shows a linear behavior at least up to dose rates of 1.2 Gy/s. Furthermore, the linear dose response of the OSL signal can be extended up to 500 Gy, independently of the used dose rate.

Optical fibers hold promise for accurate dosimetry in small field proton therapy due to their superior spatial resolution and the lack of significant Cerenkov contamination in proton beams. One known drawback for most scintillation detectors is signal quenching in areas of high linear energy transfer, as is the case in the Bragg peak region of a proton beam. In this study, we investigated the potential of innovative optical fiber bulk materials using the sol-gel technique for dosimetry in proton therapy. This type of glass is made of amorphous silica (SiO$${}_{2}$$ 2 ) and is doped with Gd$${}^{3+}$$ 3 + ions and possesses very interesting light emission properties with a luminescence band around 314 nm when exposed to protons. The fibers were manufactured at the University of Lille and tested at the TRIUMF Proton Therapy facility with 8.2–62.9 MeV protons and 2–6 nA of extracted beam current. Dose-rate dependence and quenching were measured and compared to other silica-based fibers also made by sol-gel techniques and doped with Ce$${}^{3+}$$ 3 + and Cu$${}^{+}$$ + . The three fibers present strong luminescence in the UV (Gd) or visible (Cu,Ce) under irradiation, with the emission intensities related directly to the proton flux. In addition, the 0.5 mm diameter Gd$${}^{3+}$$ 3 + -doped fiber shows superior resolution of the Bragg peak, indicating significantly reduced quenching in comparison to the Ce$${}^{3+}$$ 3 + and Cu$${}^{+}$$ + fibers with a Birks’ constant, k$${}_{B}$$ B , of (0.0162 $$\pm $$ ± 0.0003) cm/MeV in comparison to (0.0333 $$\pm $$ ± 0.0006) cm/MeV and (0.0352 $$\pm $$ ± 0.0003) cm/MeV, respectively. To our knowledge, this is the first report of such an interesting k$${}_{B}$$ B for a silica-based optical fiber material, showing clearly that this fiber presents lower quenching than common plastic scintillators. This result demonstrates the high potential of this inorganic fiber material for proton therapy dosimetry.

Gadolinium-doped silica glass was prepared, using the sol-gel route, for ionizing radiation dosimetry applications. Such a glassy rod was drawn to a cane at a temperature of 2000 °C. The structural and optical properties of the obtained material were studied using Raman, optical absorption, and photoluminescence spectroscopies. Thereafter, a small piece of this Gd-doped scintillating cane was spliced to a transport passive optical fiber, allowing the remote monitoring of the X-ray dose rate through a radioluminescence (RL) signal. The sample exhibited a linear RL intensity response versus the dose rate from 125 µGy(SiO2)/s up to 12.25 Gy/s. These results confirm the potentialities of this material for real-time remote ionizing radiation dosimetry. peerReviewed

The gas-phase reactions of five methoxyphenols (three disubstituted and two trisubstituted) with nitrate radicals were studied in an 8000 L atmospheric simulation chamber at atmospheric pressure and 294 ± 2 K. The NO3 rate constants were investigated with the relative kinetic method using PTR-ToF-MS and GC-FID to measure the concentrations of the organic compounds. The rate constants (in units of cm(3) molecule(-1) s(-1)) determined were: 2-methoxyphenol (guaiacol; 2-MP), k(2-MP) = (2.69 ± 0.57 × 10(-11); 3-methoxyphenol (3-MP), k(3-MP) = (1.15 ± 0.21) × 10(-11); 4-methoxyphenol (4-MP), k(4-MP) = (13.75 ± 7.97) × 10(-11); 2-methoxy-4-methylphenol, k(2-M-4-MeP) = (8.41 ± 5.58) × 10(-11) and 2,6-dimethoxyphenol (syringol; 2,6-DMP), k(2,6-DMP) = (15.84 ± 8.10) × 10(-11). The NO3 rate constants of the studied methoxyphenols are compared with those of other substituted aromatics, and the differences in the reactivity are construed regarding the substituents (type, number and position) on the aromatic ring. This study was also supplemented by a theoretical approach of the methoxyphenol reactions with nitrate radicals. The upper limits of the NO3 overall rate constants calculated were in the same order of magnitude than those experimentally determined. Theoretical calculations of the minimum energies of the adducts formed from the reaction of NO3 radicals with the methoxyphenols were also performed using a DFT approach (M06-2X/6-31G(d,p)). The results indicate that the NO3 addition reactions on the aromatic ring of the methoxyphenols are exothermic, with energy values ranging between -13 and -21 kcal mol(-1), depending on the environment of the carbon on which the oxygen atom of NO3 is attached. These energy values allowed identifying the most suitable carbon sites for the NO3 addition on the aromatic ring of the methoxyphenols: at the exception of the 3-MP, the NO3 ipso-addition to the hydroxyl group is one of the favored sites for all the studies compounds.

International audience; Bismuth-doped glasses are attractive materials for the development of new optical amplifiers and tunable laser sources. In this paper, Bi-dopedphosphosilicate glasses are prepared using the sol-doping technique in combination with shaping using cold isostatic pressing. After a first drawingat high temperature (2000 C), the obtained glass cane presents a wide near infrared (NIR) photoluminescence band under visible excitation. The authors show that this NIR optical activity, connected to phosphorus center, is preserved after a second drawing into a conventional optical fiber. These results confirm the potentialities of this synthesis approach for the fabrication of Bi-activated optical fibers.

Oral; International audience

A new few-mode fiber design taking advantage of a micro-structured core consisting of 19 secondary cores embedded in a pedestal geometry is presented. This design offers the possibility of precisely tailoring the rare earth ion distribution in the core in order to manage the differential modal gain. An optimized configuration of an erbium-doped few-mode fiber supporting 10 modes in the C-band with a theoretical low gain excursion is designed and realized. Preliminary optical characterizations of this fiber are presented.

A spectroscopic instrument based on an external cavity quantum cascade laser was developed for optical monitoring of dinitrogen pentoxide (N2O5) at the ppbv-level in a nocturnal tropospheric chemical reaction process in an atmospheric simulation chamber.

A spectroscopic instrument based on an external cavity quantum cascade laser was developed for optical monitoring of dinitrogen pentoxide (N2O5) at the ppbv-level in a nocturnal tropospheric chemical reaction process in an atmospheric simulation chamber.

International audience; This paper reports the design and the fabrication of an all-solid photonic bandgap fiber with core diameter larger than 100 µm, a record effective mode area of about 3700 µm 2 at 1035 nm and robust single-mode behavior on propagation length as short as 90 cm. These properties are obtained by using a pixelated Bragg fiber geometry together with an heterostructuration of the cladding and the appropriated generalized half wave stack condition applied to the first three higher order modes. We detail the numerical study that permitted to select the most efficient cladding geometry and present the experimental results that validate our approach.

A spectroscopic instrument based on a mid-infrared external cavity quantum cascade laser (EC-QCL) was developed for high-accuracy measurements of dinitrogen pentoxide (N

Accurate control of both the doping distribution inside the fiber core and the low refractive index contrast between the fiber core and cladding materials is essential for the development of high-power fiber lasers based on the use of single-mode large-mode-area (LMA) optical fibers. Herein, sol-gel monolithic F/Yb3+-codoped silica glasses were prepared from porous large silica xerogels doped with ytterbium salt solution, which had been subjected to fluorination with hexafluoroethane gas, before subsequent sintering. The fluorine content inside the doped glass has been varied by adjusting the fluorination duration. The space homogeneity of fluorine and ytterbium concentrations in the cylindrical preforms has been checked by chemical analysis and Raman spectroscopy. Moreover, the glass with the lowest fluorine content has been successfully integrated as a core material in a microstructured optical fiber made using the stack-and-draw method. This fiber was tested in an all-fiber cavity laser architecture to evaluate potential lasing performances of the F/Yb3+-codoped silica glass. It presents a maximum efficiency of 70.4%, achieved at 1031 nm from a 1.16 m length fiber. These results confirm the potentialities of the obtained F/Yb3+-codoped glasses for the fabrication of LMA optical fiber lasers.

The reaction of a series of oxygenated aromatics (two methoxybenzene and six methoxyphenol isomers) with chlorine atoms has been studied in two simulation chambers with volumes of 1080 and 480 L at the University of Wuppertal. Experiments were performed at 295 ± 2 K and a total pressure of synthetic air of 1 bar using the relative kinetic method with in situ Fourier transform infrared spectroscopy for chemical analysis. The following rate coefficients (in units of cubic centimeter per molecule per second) were determined: (1.07 ± 0.24) × 10(-10) for methoxybenzene, (1.20 ± 0.24) × 10(-10) for 1-methoxy-2-methylbenzene, (2.97 ± 0.66) × 10(-10) for 2-methoxyphenol (guaiacol), (2.99 ± 0.62) × 10(-10) for 3-methoxyphenol, (2.86 ± 0.58) × 10(-10) for 4-methoxyphenol, (3.35 ± 0.68) × 10(-10) for 2-methoxy-4-methylphenol, (4.73 ± 1.06) × 10(-10) for 2,3-dimethoxyphenol, and (2.71 ± 0.61) × 10(-10) for 2,6-dimethoxyphenol (syringol). To the best of our knowledge, this work represents the first determination of the rate coefficients for the gas-phase reaction of the chlorine atoms with the methoxy-aromatic compounds investigated. The reactivity of the methoxylated aromatics toward Cl is compared with that of other substituted aromatic compounds, and the differences in the rate coefficients are interpreted in terms of the type, number, and position of the different substituents on the aromatic ring. The atmospheric implications of the studied reactions are also discussed.

Ionic copper-doped silica glasses are attractive materials for radiation detection and dosimetry based on radioluminescence (RL) and optically stimulated luminescence (OSL). We characterized the optical responses, under X-rays, of a Cu+-doped silica glass rod prepared via the sol-gel technique and spliced to transport pure silica optical fibers. Both the low-dose and the low-dose rate regimes were specially investigated at room temperature. RL and photoluminescence (PL) measurements confirmed that the Cu+ ions are the luminescent centers of interest for the targeted applications. RL dose rate response dependence shows a linear behavior from 260 μGy(SiO2)/s up to 23 mGy(SiO2)/s, allowing the monitoring of the dose rate evolutions during an irradiation run. The OSL response also linearly depends on the dose from 42 mGy(SiO2) to 200 Gy(SiO2), enabling a precise dose measurement shortly after the irradiation. The presented results confirm the potentialities of this material to monitor ionizing radiations in harsh environments.

We report on the first polarization maintaining single-mode fiber that delivers a flat-top intensity profile at 1050 nm. A high quality fundamental flat mode was obtained. We showed that our fiber can be consider ed as single-mode in practice with low confinement losses. Its birefringence was measured to be 0.6x10 -4 , and the PER was measured at more than 20 dB even for a 20 m fiber long. Strategies to enhance this birefringence preserving the flat top profile and the single-mode behaviour as well are also discussed. Keywords: birefringence, microstructured fiber, single-mode , flat-top 1. INTRODUCTION Due to their advantages over bulk lasers, as compactness, lo ng term stability and reliability, good heat dissipation and no free-space alignment to name a few, fiber lasers are widespread amongst industrial and academic communities 1 . For most applications, a Gaussian-like beam is required or adequate. However for targ eted application as industrial processes (marking, drilling, cutting, heat treatment ), biological tissue in teractions or seeding large-scale laser facilities like the Laser MegaJoule (LMJ)

Compactness, long term stability and no free-space alignment are important advantages of fiber lasers over bulky systems. These fiber lasers have also demonstrated their capability to deliver high-power pulses and are thus suitable for numerous applications. Nevertheless the intensity profile delivered usually has a Gaussian-like shape, which most of the time is sufficient, but it could be interesting, for many applications (laser-biological tissues interactions, heat treatment, industrial laser processing or for seeding large-scale laser facilities like Laser MegaJoule) to obtain a homogeneous intensity profile at the fiber laser output. Moreover several of these applications required a linearly polarized output beam. In order to achieve all these requirements we have developed and realized a new fiber design. This fiber is the first polarization maintaining single-mode fiber delivering a flat top intensity. A high quality flat mode was obtained at 1.05μm through the use of a well-tailored index profile and single-mode behavior was verified by shifting the injection and using the S² imaging. Moreover, boron Stress Applying Parts (SAPs) including in the cladding led to a birefringence of 0.6x10-4 and a measured PER better than 20dB even for a long fiber length (~20 m). Alongside the fabrication, we developed a simulation code, using Comsol Multiphysics®, to take into account the stress dependency induced by the SAPs. Further modeling allows us to present an effectively single-mode fiber design, delivering a top-hat mode profile and exhibiting a polarizing behavior. © (2016) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

We report on the design and the fabrication of a new design of an all-solid Bragg fiber based on the pixelization and heterostructuration of a cladding made of only two high index rings. The thickness of the low index ring as well as the geometry of the heterostructuration (its symmetry and the number of removed pixels) have been chosen to maximize the confinement losses of the Higher Order Modes (HOM) (above 10 dB/m) while keeping the Fundamental Mode (FM) losses low (below 0.1 dB/m). The proposed geometry allows having access to different Mode Field Diameter (MFD) from 54 μm to 60 μm at 1 μm wavelength by drawing the same stack to different fiber (and hence, core) diameters. As a result, a record MFD of 60 μm is reported for a Solid Core Photonic Bandgap Fiber (SC-PBGF) and single-mode behavior is obtained experimentally even for a short fiber length (few tens centimeters) maintained straight.

International audience; We report the observation of a nonlinear propagation scenario in which a dispersive wave is transformed into a fundamental soliton in an axially-varying optical fiber. The dispersive wave is initially emitted in normal dispersion region and the fiber properties change longitudinally so that the dispersion becomes anomalous at the dispersive wave wavelength, which allows it to be transformed into a soliton. The solitonic nature of the field is demonstrated by solving the direct Zakharov-Shabat scattering problem. Experimental characterization performed in spectral and temporal domains show evidence of the solitonizatin process in an axially-varying photonic crystal fiber.

Syringol (2,6-dimethoxyphenol) is a potential marker compound for wood smoke emissions in the atmosphere. To investigate the atmospheric reactivity of this compound, the rate constant for its reaction with hydroxyl radicals (OH) has been determined in a simulation chamber (8 m 3 ) at 294 ± 2 K, atmospheric pressure and low relative humidity (2–4%) using the relative rate method. The syringol and reference compound concentrations were followed by GC/FID (Gas chromatography/Flame Ionization Detection). The determined rate constant (in units of cm 3 molecule −1 s −1 ) is k syringol = (9.66 ± 1.11) × 10 −11 . The calculated atmospheric lifetime for syringol is 1.8 h, indicating that it is too reactive to be used as a tracer for wood smoke emissions. Secondary Organic Aerosol (SOA) formation from the OH reaction with syringol was also investigated. The initial mixing ratios for syringol were in the range 495–3557 μg m −3 . The aerosol production was monitored using a SMPS (Scanning Mobility Particle Sizer). The SOA yields ( Y ) were determined as the ratio of the suspended aerosol mass corrected for wall losses ( M 0 ) to the total reacted syringol concentration assuming a particle density of 1.4 g cm −3 . The aerosol formation yield increases as the initial syringol concentration increases, and leads to aerosol yields ranging from 0.10 to 0.36. Y is a strong function of M 0 and the organic aerosol formation can be expressed by a one-product gas/particle partitioning absorption model. To our knowledge, this work represents the first investigation of the rate constant and SOA formation for the reaction of syringol with OH radicals. The atmospheric implications of this reaction are also discussed.