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Abstract Understanding light propagation and attenuation in cavities is limited by lack of applicable light sensing technologies. Here we demonstrate the use of light-sensitive metastable states in wide bandgap aluminosilicates (feldspar) as passive optical sensors for high-resolution mapping of light flux. We develop non-destructive, infrared photoluminescence (IRPL) imaging of trapped electrons in cracks as thin as 50 µm width to determine the spatio-temporal evolution of light sensitive metastable states in response to light exposure. Modelling of these data yields estimates of relative light flux at different depths along the crack surfaces. Contrary to expectation, the measured light flux does not scale with the crack width, and it is independent of crack orientation suggesting the dominance of diffused light propagation within the cracks. This work paves way for understanding of how light attenuates in the minutest of cavities for applications in areas as diverse as geomorphology, biology/ecology and civil engineering.

Water quality monitoring in coastal areas and estuaries poses significant challenges due to the intricate interplay of hydrodynamic, chemical, and biological processes, regardless of the chosen monitoring methods. In this study, we analyzed the applicability of different monitoring sources using in situ data, uncrewed-aerial-vehicle (UAV)-mounted hyperspectral sensing, and Sentinel-2-based multispectral imagery. In the first part of the study, we evaluated the applicability of existing empirical algorithms for water quality (WQ) parameter retrieval using hyperspectral, simulated multispectral, and satellite multispectral datasets and in situ measurements. In particular, we focused on three optically active WQ parameters: chlorophyll a (Chl,a), turbidity (TUR), and colored dissolved organic matter (CDOM) in oligotrophic coastal waters. We observed that most existing algorithms performed poorly when applied to different reflectance datasets, similar to previous findings in small and optically complex water bodies. Hence, we proposed a novel set of locally based empirical algorithms tailored for determining water quality parameters, which constituted the second part of our study. The newly developed regression-based algorithms utilized all possible combinations of spectral bands derived from UAV-generated hyperspectral data and exhibited coefficients of determination exceeding 0.9 for the three considered WQ parameters. The presented two-part approach was demonstrated in the semi-enclosed area of Kaštela Bay and the Jadro River estuary in the Central Eastern Adriatic Sea. This study introduces a promising and efficient screening method for UAV-based water quality monitoring in coastal areas worldwide. Such an approach may support decision-making processes related to coastal management and ultimately contribute to the conservation of coastal water ecosystems.

Abstract Interest in fast and easy detection of high-energy radiation (x-, γ-rays and neutrons) is closely related to numerous practical applications ranging from biomedicine and industry to homeland security issues. In this regard, crystals of hybrid halide perovskite have proven to be excellent detectors of x- and γ-rays, offering exceptionally high sensitivities in parallel to the ease of design and handling. Here, we demonstrate that by assembling a methylammonium lead tri-bromide perovskite single crystal (CH3NH3PbBr3 SC) with a Gadolinium (Gd) foil, one can very efficiently detect a flux of thermal neutrons. The neutrons absorbed by the Gd foil turn into γ-rays, which photo-generate charge carriers in the CH3NH3PbBr3 SC. The induced photo-carriers contribute to the electric current, which can easily be measured, providing information on the radiation intensity of thermal neutrons. The dependence on the beam size, bias voltage and the converting distance is investigated. To ensure stable and efficient charge extraction, the perovskite SCs were equipped with carbon electrodes. Furthermore, other types of conversion layers were also tested, including borated polyethylene sheets as well as Gd grains and Gd2O3 pellets directly engulfed into the SCs. Monte Carlo N-Particle (MCNP) radiation transport code calculations quantitatively confirmed the detection mechanism herein proposed.

In this study, we report the influence of vanadium oxide (VO), as a photosensitive component, on the photoactivity of TiO2 nanotubes (TNTs). A series of TNTs of varying tube diameter were synthesized by the anodization of titanium foils at different voltages, while vanadium oxide was deposited on TNTs by wet chemical deposition. An improvement in the optical properties of nanotubes was observed after the deposition of vanadium oxide. An improvement in the optical properties (redshift in UV-Vis spectra) of TNTs and TNT/VO was noted. The photocatalytic activity was improved with increasing tube diameter, while it was weakened after the deposition of VO. Furthermore, photoactivity was investigated in photodiodes based on TNTs or TNT/VO and single crystals of CH3NH3PbI3. The photoelectric measurement revealed that different TNT diameters did not influence the I-V characteristic of the photodiodes, while the deposition of VO improved the photocurrent for smaller TNTs.

Abstract Gamma‐rays (γ‐rays), wherever present, e.g., in medicine, nuclear environment, or homeland security, due to their strong impact on biological matter, should be closely monitored. There is a need for simple, sensitive γ‐ray detectors at affordable prices. Here, it is shown that γ‐ray detectors based on crystals of methylammonium lead tribromide (MAPbBr3) ideally meet these requirements. Specifically, the γ‐rays incident on a MAPbBr3 crystal generates photocarriers with a high mobility‐lifetime product, allowing radiation detection by photocurrent measurements at room temperatures. Moreover, the MAPbBr3 crystal‐based detectors, equipped with improved carbon electrodes, can operate at low bias (≈1.0 V), hence being suitable for applications in energy‐sparse environments, including space. The γ‐ray detectors reported herein are exposed to radiation from a 60Co source at dose rates up to 2.3 Gy h−1 under ambient conditions for over 100 h, without any sign of degradation. The excellent radiation tolerance stems from the intrinsic structural plasticity of the organic–inorganic halide perovskites, which can be attributed to a defect‐healing process by fast ion migration at the nanoscale level. The sensitivity of the γ‐ray detection upon volume is tested for MAPbBr3 crystals reaching up to 1000 cm3 (3.3 kg in weight) grown by a unique crystal growth technique.

An environmentally friendly analog of the prominent methylammonium lead halide perovskite, methylammonium bismuth bromide (MA3Bi2Br9), was prepared and investigated in the form of powder, single crystals and nanowires. Complete characterization via synchrotron X-ray diffraction data showed that the bulk crystal does not incorporate water into the structure. At the same time, water is absorbed on the surface of the crystal, and this modification leads to the changes in the resistivity of the material, thus making MA3Bi2Br9 an excellent candidate for use as a humidity sensor. The novel sensor was prepared from powder-pressed pellets with attached carbon electrodes and was characterized by being able to detect relative humidity over the full range (0.7–96% RH) at ambient temperature. Compared to commercial and literature values, the response and recovery times are very fast (down to 1.5 s/1.5 s).

The vertical distribution of chlorophyll in coastal waters is influenced by a combination of the hydrodynamic environment and different biotic and abiotic processes. The spatial and temporal occurrences of chlorophyll profiles provide a good representation of the changes in the marine environment. The majority of studies in the Adriatic Sea have so far been conducted in areas unaffected by anthropogenic pressure. Our study site is located near two marine outfalls, which are part of the public sewage system. This study aims to characterize the chlorophyll vertical distribution and describe its variability based on the stratification conditions and the presence of a wastewater effluent plume. Based on these conditions, we identified three characteristic scenarios/types of chlorophyll profiles. The first one occurs when the vertical mixing of the water column creates the upwelling of chlorophyll and nutrients to the upper part of the water column. The second and third scenarios occur during stratified conditions and differ by the extent of the effluent plume intrusion. Using modern fluorescence techniques, we identified and described three different vertical chlorophyll profiles, characterizing them according to their physical and biological parameters and processes. For cases with a visible effluent intrusion, we confirmed the importance of the pycnocline formation in keeping the effluent below and maintaining the higher water quality status at the top of the water column.

This paper proposes a framework for evaluation of the sources of uncertainty that can disrupt the flood emergency response process. During the flood response, flood emergency managers usually choose between several decision options under limited available lead-time, but they are often compelled with different sources of uncertainty. These sources can significantly affect the quality of decisions related to adequate response and rapid recovery of the affected system. The proposed framework considers efficient identification, integration, and quantification of system uncertainties related to the flood risk. Uncertainty analysis is performed from a decision-maker’s perspective and focused on the time period near and during the flood event. The major scope of proposed framework is to recognize and characterize sources of uncertainty which can potentially appear within the behavior of the observed system. Using a Bayesian network approach, a model is developed capable for quantification of different sources uncertainty in respect to their particular type. The proposed approach is validated on the Sava River case study, in the area of the city of Slavonski Brod, following the destructive 2014 flood event. The results indicate that, despite improvements of structural measures, the weir failure can still cause flooding of the approximately 1 km2 of otherwise safe area, resulting in the increased flood risk.

There are multiple factors affecting the behavior of water properties in an estuary, including the hydraulic properties of rivers and corresponding receiving water bodies, along with the potential solutes brought by rivers. Although there are various numerical models and analytical approaches to solving particular or holistic problems in estuaries, measurements are inevitably required. In this study, we developed an innovative low-cost probe based on the Arduino platform as an alternative to more expensive measuring systems. Our device is designed to measure position, temperature, and electrical conductivity in multiple realizations, and it consists of a floating container equipped with the following components: an Arduino Mega development board, a power management module, an SD card logging module, a Bluetooth module, a temperature measuring module, a global positioning satellite (GPS) position module, and a newly developed module for measuring electrical conductivity (EC). We emphasize that all used tools are open-source and greatly supported by the worldwide community. We tested our probe during a field campaign conducted at the estuary of River Jadro near Split (Croatia). Nine probes were released at the river mouth and their position, temperature, and EC were monitored and recorded during the experiment, which ended when the probes stopped, due to the river plume attenuation. The same experiment was repeated three times. All of the probes recorded consistent temperature data, while the EC data show more variable behavior, due to the higher sensitivity of the corresponding sensor. This was expected as a part of the natural process in the estuary. The measured data were additionally used to parameterize an analytical model for mean flow velocity and salinity as a proxy concentration. This showed a good match between the experimental results and the theoretical framework. This work, although focused on water surface applications in the near field zone of an estuary, should be considered as a promising step toward the development of innovative and affordable measurement devices.

The authors wish to make the following correction to their paper [...]

The application of advanced oxidation processes (AOPs) emerged as an interesting topic during the last decade. Many studies have been devoted to the complexity of phenomena imposed by AOPs, and a lot of effort was made to justify the application of AOPs. However, the reliability of AOPs has not been an issue of any extensive work. In this work, failure analysis and comparative reliability study were performed for the chosen AOP system, i.e. a laboratory scale photo- and sonoreactor, during the photocatalytic (UV/TiO2 process) and sonochemical (US/Fenton process) oxidation of model pollutants (dyes and carboxylic acids) in water. Furthermore, a three-criterion analysis approach for the risk assessment was proposed. The set criteria; (i) probability of failure, (ii) estimated cost for the 10 000 working hours and (iii) residual organic content in the system after the applied treatment, resulted in the calculated risk scores, Srisk that enlighten all the crucial aspects of the investigated systems. In conclusion, the analysis was related to the pilot scale reactors. [ABSTRACT FROM AUTHOR]

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Wastewater treatment plant (WWTP) effluents are pointed as hotspots for the introduction of both commensal and pathogenic bacteria as well as their antibiotic resistance genes (ARGs) in receiving water bodies. For the first time, the effect of partially treated submarine effluents was explored at the bottom and surface of the water column to provide a comprehensive overview of the structure of the microbiome and associated AR, and to assess environmental factors leading to their alteration. Seawater samples were collected over a 5-month period from submarine outfalls in central Adriatic Sea, Croatia. 16S rRNA amplicon sequencing was used to establish taxonomic and resistome profiles of the bacterial communities. The community differences observed between the two discharge areas, especially in the abundance of Proteobacteria and Firmicutes , could be due to the origin of wastewaters treated in WWTPs and the limiting environmental conditions such as temperature and nutrients. PICRUSt2 analysis inferred the total content of ARGs in the studied microbiomes and showed the highest abundance of resistance genes encoding multidrug efflux pumps, such as MexAB-OprM, AcrEF-TolC and MdtEF-TolC, followed by the modified peptidoglycan precursors, transporter genes encoding tetracycline, macrolide and phenicol resistance, and the bla operon conferring β-lactam resistance. A number of pathogenic genera introduced by effluents, including Acinetobacter, Arcobacter, Bacteroides, Escherichia-Shigella, Klebsiella, Pseudomonas, and Salmonella , were predicted to account for the majority of efflux pump-driven multidrug resistance, while Acinetobacter, Salmonella, Bacteroides and Pseudomonas were also shown to be the predominant carriers of non-efflux ARGs conferring resistance to most of nine antibiotic classes. Taken together, we evidenced the negative impact of submarine discharges of treated effluents via alteration of physico-chemical characteristics of the water column and enrichment of bacterial community with nonindigenous taxa carrying an arsenal of ARGs, which could contribute to the further propagation of the AR in the natural environment. [ABSTRACT FROM AUTHOR]

Gamma-rays ( γ -rays), wherever present, e.g., in medicine, nuclear environment, or homeland security, due to their strong impact on biological matter, should be closely monitored. There is a need for simple, sensitive γ -ray detectors at affordable prices. Here, it is shown that γ -ray detectors based on crystals of methylammonium lead tribromide (MAPbBr 3 ) ideally meet these requirements. Specifically, the γ -rays incident on a MAPbBr 3 crystal generates photocarriers with a high mobility-lifetime product, allowing radiation detection by photocurrent measurements at room temperatures. Moreover, the MAPbBr 3 crystal-based detectors, equipped with improved carbon electrodes, can operate at low bias (≈1.0 V), hence being suitable for applications in energy-sparse environments, including space. The γ -ray detectors reported herein are exposed to radiation from a  60 Co source at dose rates up to 2.3 Gy h -1  under ambient conditions for over 100 h, without any sign of degradation. The excellent radiation tolerance stems from the intrinsic structural plasticity of the organic-inorganic halide perovskites, which can be attributed to a defect-healing process by fast ion migration at the nanoscale level. The sensitivity of the γ -ray detection upon volume is tested for MAPbBr 3  crystals reaching up to 1000 cm 3 (3.3 kg in weight) grown by a unique crystal growth technique., Competing Interests: The authors declare no conflict of interest., (© 2020 The Authors. Advanced Science published by Wiley‐VCH GmbH.)

We have investigated the optical absorption of metallic and semiconducting carbon nanotubes/CH 3 NH 3 PbI 3 micro- and nanowire composites. Upon visible light illumination semiconducting carbon nanotube based samples show a photo-induced doping, originating from the charge carriers created in the perovskite while this kind of change is absent in the composites containing metallic nanotubes, due to their strikingly different electronic structure. The response in the nanotubes shows, beside a fast diffusion of photo-generated charges, a slow component similar to that observed in pristine CH 3 NH 3 PbI 3 attributed to structural rearrangement, and leading to slight, light induced changes of the optical gap of the perovskite. This charge transfer from the illuminated perovskite confirms that carbon nanotubes (especially semiconducting ones) can form efficient charge-transporting layers in the novel organometallic perovskite based optoelectronic devices.