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Abstract Clarifying the underlying mechanisms that govern ordering transitions in condensed matter systems is crucial for comprehending emergent properties and phenomena. While transitions are often classified as electronically driven or lattice-driven, we present a departure from this conventional picture in the case of the double perovskite Ba2MgReO6. Leveraging resonant and non-resonant elastic x-ray scattering techniques, we unveil the simultaneous ordering of structural distortions and charge quadrupoles at a critical temperature of T q ~ 33 K. Using a variety of complementary first-principles-based computational techniques, we demonstrate that, while electronic interactions drive the ordering at T q, it is ultimately the lattice distortions that dictate the specific ground state that emerges. Our findings highlight the crucial interplay between electronic and lattice degrees of freedom, providing a unified framework to understand and predict unconventional emergent phenomena in quantum materials.

We present ab initio calculations of hidden magnetoelectric multipolar order in Cr_{2}O_{3} and its iron-based analog, α-Fe_{2}O_{3}. First, we discuss the connection between the order of such hidden multipoles and the linear magnetoelectric effect. Next we show the presence of hidden antiferroically ordered magnetoelectric multipoles in both the prototypical magnetoelectric material Cr_{2}O_{3} and centrosymmetric α-Fe_{2}O_{3}, which has the same crystal structure as Cr_{2}O_{3} but a different magnetic dipolar ordering. In turn, we predict antimagnetoelectric effects, in which local magnetic dipole moments are induced in opposite directions under the application of an uniform external electric field to create an additional antiferromagnetic ordering. We confirm the predicted induced moments using first-principles calculations. Our results demonstrate the existence of hidden magnetoelectric multipoles leading to local linear magnetoelectric responses even in centrosymmetric magnetic materials, where a net bulk linear magnetoelectric effect is forbidden by symmetry, and broaden the definition of magnetoelectric materials by including those showing such local magnetoelectric responses.

We address magnetic neutron scattering in the presence of local noncentrosymmetric asymmetries of the magnetization density. Such inversion-symmetry breaking, combined with the absence of time-reversal symmetry, can be described in terms of magnetoelectric multipoles which form the second term after the magnetic dipole in the multipole expansion of the magnetization density. We provide a pedagogical review of the theoretical formalism of magnetic neutron diffraction in terms of the multipole expansion of the scattering cross-section. In particular, we show how to compute the contribution of magnetoelectric multipoles to the scattering amplitude starting from ab initio calculations. We also provide general guidelines on how to experimentally detect long-range order of magnetoelectric multipoles using either unpolarized or polarized neutron scattering. We apply the formalism to CuO, and we discuss first-principles predictions and experimental spherical neutron polarimetry measurements that are consistent with the presence of magnetoelectric multipoles in CuO.

A room temperature single-phase multiferroic with large and strongly coupled polarization and magnetization is a long-sought goal in multiferroics research. Here, the authors predict a promising candidate, layered-perovskite metal Bi5Mn5O17, which is a ferromagnet, ferroelectric, and ferrotoroid.

The Lensless Smart Sensor (LSS) developed by Rambus, Inc. is a low-power, low-cost visual sensing technology that captures information-rich optical data in a tiny form factor using a novel approach to optical sensing. The spiral gratings of LSS diffractive grating, coupled with sophisticated computational algorithms, allow point tracking down to millimeter-level accuracy. This work is focused on developing novel algorithms for the detection of multiple points and thereby enabling hand tracking and gesture recognition using the LSS. The algorithms are formulated based on geometrical and mathematical constraints around the placement of infrared light-emitting diodes (LEDs) on the hand. The developed techniques dynamically adapt the recognition and orientation of the hand and associated gestures. A detailed accuracy analysis for both hand tracking and gesture classification as a function of LED positions is conducted to validate the performance of the system. Our results indicate that the technology is a promising approach, as the current state-of-the-art focuses on human motion tracking that requires highly complex and expensive systems. A wearable, low-power, low-cost system could make a significant impact in this field, as it does not require complex hardware or additional sensors on the tracked segments.

ABSTRACT: In the United States, cleaning poultry transport containers prior to arrival at the broiler grow-out farm is not currently a widely adopted practice in the industry. However, previous studies have shown that transport containers have an important role in cross-contamination before the broilers arrive at the processing plant. The objective of this study was to evaluate the efficacy of pressurized steam followed by forced hot air to clean transport container flooring and compare it to conventional cleaning procedures. Fiberglass and plastic flooring were cut into even pieces and inoculated with chicken intestinal contents containing Salmonella Infantis or Campylobacter jejuni. The cleaning treatments were pressurized steam, forced hot air, pressurized steam followed by forced hot air, water pressure washing, water pressure washing before and after disinfectant, and no cleaning. Counts for Salmonella, Campylobacter, Escherichia coli, coliforms, and aerobic bacteria were assessed. All reductions were made in comparison to noncleaned samples. Forced hot air applied by itself was not efficient in reducing Campylobacter, coliforms, and E. coli; and limited reductions (less than 1 log10 CFU/cm2) were observed for Salmonella and aerobic bacteria. Then, for all bacteria types evaluated, pressurized steam by itself showed reductions of 2.4 to 3.5 log10 CFU/cm2. Samples that were cleaned with a single-pressure water wash showed reductions of 4.0 to 4.6 log10 CFU/cm2 for all bacteria types. For Salmonella, Campylobacter, and E. coli, the greatest reductions were observed when samples were cleaned with pressurized steam followed by forced hot air (4.3–6.1 log10 CFU/cm2) or water washed before and after disinfectant (4.5–6.2 log10 CFU/cm2), and these treatments did not differ from each other. Pressurized steam followed by forced hot air was shown to be an efficient cleaning procedure to reduce poultry-associated pathogens on transport cage flooring, with the benefit of using less water than conventional water cleaning. Processors may be able to adapt this process to reduce potential cross-contamination and lessen the level of pathogens entering the processing plant.

Salmonella and Campylobacter are two of the most common foodborne pathogens associated with poultry meat. Regulatory restrictions and consumer concerns have increased the interest for plant-derived antimicrobials and emerging novel technologies. The objective of this study was to determine the antimicrobial activity of photoactive compounds curcumin (CUR) and chlorophyllin (CH) followed by activating light exposure for the reduction of Salmonella and Campylobacter. Peroxyacetic acid (PAA) was also evaluated as a poultry industry standard antimicrobial processing aid. CUR and CH were evaluated in 96-well plates at concentrations of 100, 500, and 1,000 ppm, along with PAA at 100, 200, and 300 ppm, or distilled water (DW). Each well was inoculated with 105 CFU/mL of Salmonella Typhimurium or Campylobacter jejuni, and plates were exposed to activating light (430 nm) for 0 or 5 min. No detectable reductions were observed for Salmonella or Campylobacter when treated with CUR, CH, or 100 ppm PAA. However, when Salmonella was treated with 200 ppm PAA, counts were reduced from 4.57 to 2.52 log10 CFU/mL. When Salmonella was treated with 300 ppm PAA, counts were reduced to below detectable levels (5 CFU/mL). Campylobacter was reduced from 4.67 to 2.82 log10 CFU/mL when treated with 200 ppm PAA. However, no further reductions were observed when Campylobacter was treated with 300 ppm PAA (2.50 log10 CFU/mL). These results indicate that CUR and CH were not effective as antimicrobials under the evaluated conditions, particularly in comparison to the commonly used antimicrobial, PAA.

ABSTRACT: A successful hatch has a considerable economic impact on all poultry companies. The aim of the current study was to describe the possible effects of shell translucency (T score) and coloration lightness (L* value) on shell thickness, hatchability, and chick weight. A total of 4,320 eggs from 4 commercial Ross 708 breeder flocks (50–55-wk old) were used. Eggs were selected for T score and L* value. A 3-point subjective scoring system was used for T score (1 = low, 2 = medium, 3 = high), and an electronic colorimeter for L* value, sorting the eggs as light (avg. L* = 80.7) or dark (avg. L* = 76.0). Data were analyzed using the GLIMMIX procedure of SAS (V9.4) and Tukey's HSD test was performed to separate means, a significant difference was considered when P ≤ 0.05. Results suggest that the color of the eggshell was related to the egg weight on the day of collection (P = 0.0056) and at transfer (P = 0.0211), in both cases dark eggs were 0.6 g heavier than light eggs. Dark eggs had a 3.8% increased hatchability of egg set (P = 0.0481) and yielded 6 µm thicker shells (P = 0.0019) when compared to light eggs. Regarding translucency, egg weight at transfer was 0.8 g heavier for T score 1 eggs compared to T score 3 (P = 0.0358). The translucency score of 1 had a 6.9% higher hatchability of eggs set (P = 0.0127) and 0.7 g heavier chick weight (P = 0.0385) compared to T score 3. However, T score 1 eggs had shells 28 µm thinner than the T score 2 and 34 µm thinner than T score 3 (P < 0.0001). An interaction effect was observed for eggshell thickness, L* value, and T score, where eggs classified as light with T score 1 had thinner eggshells compared to those that were dark with T score 3 (P = 0.0292). These results suggest that eggshell translucency and coloration lightness can be good noninvasive indicators of eggshell thickness, hatchability, and chick weight in broiler breeder flocks.

ABSTRACT: Increased consumer concern for animal welfare has led some poultry producers to alter their stunning methods from electrical to controlled atmosphere stunning. The potential for different impacts on meat quality between commercially applied controlled atmosphere stunning (CAS) and electrical stunning (ES) using current US parameters needs further evaluation. Three trials were conducted in a commercial broiler processing facility that uses separate processing lines for ES and CAS. Blood glucose concentrations were measured from broilers stunned by either CAS or ES at: 1) lairage, 2) pre-stunning, and 3) post-stunning, using a glucose monitor. Occurrence of visible wing damage was evaluated post-defeathering and breast fillet meat quality was evaluated through measurement of pH, color, and drip loss at deboning and after 24 h. Data were analyzed using GLM or chi-square with a significance at P ≤ 0.05 and means were separated by Tukey's HSD. Blood glucose concentrations (mg/dL) from CAS and ES birds were not different at lairage (284, 272, P = 0.2646) or immediately prior to stunning (274, 283, P = 0.6425). Following stunning and neck cut, circulating blood glucose from birds stunned by CAS was higher than ES (418, 259, P < 0.0001). CAS carcasses had more visible wing damage than ES carcasses (3.6%, 2.2%, P < 0.0001). Breast fillet pH was lower, L* was higher, and a* was lower at debone for CAS fillets (5.81, 54.65, 1.96) compared to ES fillets (5.92, 53.15, 2.31, P < 0.0001, P = 0.0005, P = 0.0303). Drip loss did not differ between breast fillets from CAS or ES broilers (4.83, 4.84; P = 0.0859). The implications of increased blood glucose concentration post-CAS are unknown and require further evaluation. However, the increase in visible wing damage observed post-defeathering from CAS carcasses indicated a need for equipment parameter adjustments during the process from stunning through defeathering when using CAS for broiler stunning. Although differences were observed in breast fillet attributes at deboning, these differences would have minimal practical application and were no longer present at 24 h. Overall, use of CAS in a commercial facility resulted in differences in subsequent product quality when compared to ES.

Este estudio tiene como objetivo determinar el efecto del Mercosur, los acuerdos bilaterales de Chile y la conectividad vial en las exportaciones de bienes manufacturados de Argentina, Chile, Paraguay y Uruguay, durante el periodo 2002-2016. Para ello, se especifica un modelo gravitacional. Los principales resultados indican que no se observa efecto significativo del Mercosur en las exportaciones de manufacturas de Argentina, Paraguay y Uruguay, como tampoco de ningún acuerdo bilateral firmado por Chile. Además, las exportaciones de manufacturas de los países en estudio tienen un comportamiento dinámico, condicionado positivamente por el monto exportado de manufactura del año anterior. Mientras mayor sea el producto interno bruto per cápita del exportador e importador y los kilómetros de carretera pavimentada y líneas férreas del país exportador, mayor será el monto exportable en manufacturas. Por último, se confirma que los costos de transportes internacionales impiden incrementar las exportaciones de manufacturas.

ABSTRACT: Dust present in poultry houses can disseminate bacteria in air and deposit them on surfaces. This study evaluated bacteria in settled dust during growout of broilers from 2 flocks (Flocks A and B). Dust samples for bacteria analyses were obtained during 6 wk of growout (Flocks A and B) and 1 wk after flock termination (Flock B) by environmental swabbing and collecting dust in petri dishes from multiple locations inside the poultry house. For weekly swabbing, dust deposited during each wk of the sampling period (noncumulatively, n = 12/wk) and cumulatively (n = 12/wk) throughout the sampling period was collected. Swabbed dust samples were analyzed for counts (log10 CFU/28 cm2) of aerobic bacteria, E. coli, coliforms, and Salmonella recovery. For petri dish dust collection, dust was collected in weekly and bi-weekly time spans during the sampling period and then analyzed for Salmonella recovery. Data were analyzed by one-way ANOVA and Fisher's Exact Test and means were separated using LSD. Only aerobic plate counts changed over time in dust during growout (Flocks A and B; P < 0.0001). In noncumulatively settled dust, aerobic bacteria (Flocks A and B; P < 0.0001), E. coli (Flock A; P = 0.0432), and coliforms (Flock B; P = 0.0303) varied during growout with peak counts on wk 5 or wk 6, wk 4, and wk 4, respectively, after bird placement. Salmonella recovery did not vary in cumulatively (3/72, 10/84) and noncumulatively (0/12, 10/84) settled dust during growout in both flocks. In dust sampled by bi-weekly collection in petri dishes, Salmonella recovery was highest (5/6) between wk 2 to wk 4 for Flock B (P = 0.0118). Overall, this study displayed that settled dust bacteria levels can fluctuate during broiler growout, and dust can contain Salmonella.

ABSTRACT: The presence of Salmonella in air of poultry houses has been previously confirmed. Therefore, it is important to investigate the entry of Salmonella into broilers through air. The present study aimed to evaluate different levels of Salmonella Enteritidis aerosol inoculations in broiler chicks for colonization of ceca, trachea, and liver/spleen and persistence over time. In 3 independent trials, 112 one-day-old birds were randomly divided into 4 groups (n = 28/group). On d 1 of age, one group was exposed to an aerosol of sterile saline and the remaining three groups were exposed to an aerosol generated from one of 3 doses (103, 106, or 109 CFU/mL) of S. Enteritidis inoculum. Aerosol exposure time was 30 min/group and was performed using a nebulizer. On d 3, 7, 14, and 21 of age, ceca, trachea, and liver/spleen were aseptically removed. Ceca were cultured for Salmonella counts (log10 CFU/g) and all tissues were cultured for Salmonella prevalence. All tissues from the control group were Salmonella negative for all sampling days. On sampling d 3 and 7, ceca Salmonella counts were highest (5.14 and 5.11, respectively) when challenged with 109 Salmonella (P ≤ 0.0281). Ceca Salmonella counts increased from d 3 (2.43) to d 7 (4.43), then remained constant when challenged at 103 Salmonella, and counts decreased over time for all other groups. Tissue Salmonella prevalence increased with increasing challenge levels at all sampling timepoints (P ≤ 0.0213). Salmonella prevalence was low (0/18 to 4/18) and did not change over time following 103 Salmonella challenge (P ≥ 0.2394). Prevalence decreased over time in ceca and trachea following 106 and 109 Salmonella challenge (P ≤ 0.0483). Liver/spleen Salmonella prevalence increased from d 3 (13/18) to d 14 (18/18) and then decreased at d 21 (10/18) in birds exposed to an aerosol of 109 Salmonella but remained constant over time for rest of the Salmonella inoculated groups. Overall, this study demonstrated the Salmonella colonization and persistence in different tissues in broilers following exposure to aerosolized Salmonella.

Este estudio pretende determinar las variables que pueden estar influyendo en las exportaciones chilenas subdivididas en cuatro grupos de bienes: manufacturas; alimentos, bebidas y tabaco; minería y metales y; materias primas de origen agrícola para el período 2002-2016. El estudio permite concluir que los acuerdos de Chile con MERCOSUR, CA y China no son significativos en ningún grupo de bienes; el acuerdo con miembros del NAFTA presenta efecto negativo en las manufacturas y alimentos, bebidas y tabaco y; con países de la UE, efecto positivo sólo en materias primas de origen agrícola.

Consistent inter-individual differences in behaviour have been previously reported in adult shelter cats. In this study, we aimed to assess whether repeatable individual differences in behaviours exhibited by shelter cats in different situations were interrelated, forming behavioural syndromes. We tested 31 adult cats in five different behavioural tests, repeated three times each: a struggle test where an experimenter restrained the cat, a separation/confinement test where the cat spent 2 min in a pet carrier, a mouse test where the cat was presented with a live mouse in a jar, and two tests where the cat reacted to an unfamiliar human who remained either passive or actively approached the cat. Individual differences in behaviour were consistent (repeatable) across repeated trials for each of the tests. We also found associations between some of the behaviours shown in the different tests, several of which appeared to be due to differences in human-oriented behaviours. This study is the first to assess the presence of behavioural syndromes using repeated behavioural tests in different situations common in the daily life of a cat, and which may prove useful in improving the match between prospective owner and cat in shelter adoption programmes.