30 results on '"Amoret L. Bunn"'
Search Results
2. Role of uncertainties in protecting ecological resources during remediation and restoration
- Author
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Brian Looney, Michael Gochfeld, Christian Jeitner, Joanna Burger, and Amoret L. Bunn
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Washington ,Conservation of Natural Resources ,010504 meteorology & atmospheric sciences ,Environmental remediation ,Hanford Site ,South Carolina ,Health, Toxicology and Mutagenesis ,Savannah River Site ,010501 environmental sciences ,Toxicology ,complex mixtures ,01 natural sciences ,humanities ,Human health ,Environmental protection ,Ecological resources ,Environmental science ,Ecosystem ,Environmental Restoration and Remediation ,0105 earth and related environmental sciences - Abstract
Cleanup of contaminated waste sites is a National priority to protect human health and the environment, while restoring land to productive uses. While there are uncertainties with understanding risk to individuals from exposure, the aim of this study was to focus on uncertainties and complexities for ecological systems, complicated by hundreds of species occupying any remediation site which participate in multiple-interacting food webs. The ability to better predict the effectiveness of remediation in fostering future ecosystems might facilitate remedy selection and improve strategic environmental management. This investigation examined (1) uncertainties in ecosystem processes, (2) uncertainties in exposure from contamination before remediation, and (3) uncertainties during remediation. Two Department of Energy sites Hanford Site and Savannah River Site were used as case studies to illustrate how the uncertainties affect eco-receptors. Several types of ecological, physical, and human dimension uncertainties are defined. Ecological uncertainties include temporal, spatial, individual, developmental, and exogenous types. Physical uncertainties are weather-related, watershed variations, slope/aspect, soil/sediment structure and form, unforeseen events, and temporal patterns. Human dimension uncertainties include current land use, future land use, extractive and non-extractive recreation. The effects of remedial strategies varied between the two sites because Hanford is a primarily arid shrub-steppe ecotype, while Savannah River is a wet forest ecotype. Defining the associated ecological sensitivities and uncertainties and providing examples might help policy-makers, managers, planners, and contractors to be aware of issues to consider throughout planning, remediation, and restoration. Adding ecological uncertainty analysis to risk evaluations and remediation planning is analogous to using safety factors in human health risk assessment.
- Published
- 2021
- Full Text
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3. Internal Radiation Dose Evaluation for an Unruptured Post Release Tristructural Isotropic Fuel Particle for Advanced and Micro-reactor Applications
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Amoret L. Bunn, Philip J. Jensen, Caitlin A. Condon, and Pavlo Ivanusa
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Post release ,Materials science ,Nuclear fuel ,Epidemiology ,Health, Toxicology and Mutagenesis ,Rectosigmoid Colon ,Nuclear engineering ,Isotropy ,Internal radiation ,Effective dose (radiation) ,030218 nuclear medicine & medical imaging ,03 medical and health sciences ,0302 clinical medicine ,030220 oncology & carcinogenesis ,Radiology, Nuclear Medicine and imaging ,Particle size ,Microreactor - Abstract
There are unique benefits from advanced/micro-reactor designs and fuel types that offer safety features in the case of an accident that may reduce environmental consequences compared to conventional reactors and fuels. Tristructural isotropic (TRISO) fuel particles are a robust advanced nuclear fuel type that leads to the unique question of how unruptured, activated TRISO particles will interact with humans. TRISO particles are 900 μm in size, and that particle size restricts internal dose assessment to the ingestion pathway. Activity of the TRISO particle was established by High Temperature Engineering Test Reactor simulations. The TRISO particle encapsulation was assumed to be perfect; exploration of internal dose contribution from radionuclides released from encapsulation was not included. The TRISO particle was assumed to be mixed actively within each alimentary tract compartment such that homogenous distribution could be assumed according to the International Commission on Radiological Protection publication 133. The dose assessment results indicate that the rectosigmoid colon had the highest internal organ dose for both reference male (2.1 Sv) and female (2.3 Sv). The internal dose from ingestion of the scenario-specific TRISO particle was 0.25 Sv for the reference male and 0.29 Sv for the reference female, which exceeds the annual occupational effective dose limit of 0.05 Sv in the Code of Federal Regulations, 10 CFR Part 20 Subpart C. Similarly, the annual occupational limit of 0.5 Sv to any one organ would be exceeded for the left colon, right colon, and rectosigmoid colon for both the reference male and female.
- Published
- 2020
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4. Effects of Lead and Arsenic in Soils from Former Orchards on Growth of Three Plant Species
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Bradley G. Fritz, Delphine Appriou, Jonathan R. Counts, Bradley E. Sample, Amoret L. Bunn, Jared F. Dimson, and Molly T. West
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Soil ,Lead ,Health, Toxicology and Mutagenesis ,Environmental Chemistry ,Arsenates ,Soil Pollutants ,Arsenic - Abstract
Historical use of lead arsenate as a pesticide in former orchards of eastern Washington State (USA) has resulted in legacy lead (Pb) and arsenic (As) soil contamination. However, the impacts on plant growth in soils with residual Pb and As contamination have not yet been quantified. To this end, a comparative study of plant growth impacts was performed for native bluegrass (Poa secunda), invasive cheatgrass (Bromus tectorum), and buttercrunch lettuce (Lactuca sativa). Using standard plant growth protocols, germination frequency and biomass growth were measured over a wide range of Pb and arsenate concentrations, with maximum concentrations of 3400 and 790 mg kg
- Published
- 2021
5. Internal Radiation Dose Evaluation for an Unruptured Post Release Tristructural Istropic Fuel Particle for Advanced and Micro-reactor Applications
- Author
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Caitlin A, Condon, Pavlo, Ivanusa, Amoret L, Bunn, and Philip J, Jensen
- Subjects
Male ,Humans ,Female ,Radiation Dosage ,Radioactive Hazard Release - Abstract
There are unique benefits from advanced/micro-reactor designs and fuel types that offer safety features in the case of an accident that may reduce environmental consequences compared to conventional reactors and fuels. Tristructural isotropic (TRISO) fuel particles are a robust advanced nuclear fuel type that leads to the unique question of how unruptured, activated TRISO particles will interact with humans. TRISO particles are 900 μm in size, and that particle size restricts internal dose assessment to the ingestion pathway. Activity of the TRISO particle was established by High Temperature Engineering Test Reactor simulations. The TRISO particle encapsulation was assumed to be perfect; exploration of internal dose contribution from radionuclides released from encapsulation was not included. The TRISO particle was assumed to be mixed actively within each alimentary tract compartment such that homogenous distribution could be assumed according to the International Commission on Radiological Protection publication 133. The dose assessment results indicate that the rectosigmoid colon had the highest internal organ dose for both reference male (2.1 Sv) and female (2.3 Sv). The internal dose from ingestion of the scenario-specific TRISO particle was 0.25 Sv for the reference male and 0.29 Sv for the reference female, which exceeds the annual occupational effective dose limit of 0.05 Sv in the Code of Federal Regulations, 10 CFR Part 20 Subpart C. Similarly, the annual occupational limit of 0.5 Sv to any one organ would be exceeded for the left colon, right colon, and rectosigmoid colon for both the reference male and female.
- Published
- 2020
6. Fate and transport of unruptured tri-structural isotropic (TRISO) fuel particles in the event of environmental release for advanced and micro reactor applications
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Caitlin A. Condon, Patrick P. Mirick, Ciara B. Varnum-Lowry, Jonathan Whiting, Amoret L. Bunn, Pavlo Ivanusa, and Philip J. Jensen
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010504 meteorology & atmospheric sciences ,Health, Toxicology and Mutagenesis ,Nuclear engineering ,010501 environmental sciences ,01 natural sciences ,law.invention ,Nuclear Reactors ,Radiation Monitoring ,law ,Environmental Chemistry ,Waste Management and Disposal ,0105 earth and related environmental sciences ,Radioisotopes ,Radionuclide ,Atmosphere ,Isotropy ,General Medicine ,Nuclear reactor ,Pollution ,Environmental science ,Particle ,Microreactor ,Radioactive Hazard Release ,Surface water ,Event (particle physics) ,Groundwater - Abstract
Advanced nuclear reactor designs and advanced fuel types offer safety features that may reduce environmental consequences in an accident scenario when compared to conventional reactors and fuels. One advanced reactor fuel is tri-structural isotropic (TRISO) fuel particles which are approximately 0.9 mm in diameter. TRISO particle mobility, assuming the particle is unruptured and the encapsulated radionuclides are contained, was explored by a theoretical examination of transport through atmosphere, soil and groundwater, surface water, and non-human biota pathways. TRISO particles are too large and dense to travel in the atmosphere except under extreme conditions. TRISO particles are also too large to penetrate most soil profiles and so cannot be transported to or by groundwater. TRISO particles will settle out of the water column in surface waters and thus the transport will depend on the energy of the water body (e.g., waves or floods). TRISO particles could be transported by non-human biota. The size of TRISO particles could allow them to be intentionally ingested by non-human biota as a gastrolith or mimic something typical in an organism's diet. Generally, TRISO particles will have reduced environmental mobility compared to releases of radionuclides in the event of a conventional nuclear reactor accident. The extent of transport has implications in emergency planning zone designations and other considerations for licensing and deploying TRISO-fueled reactors. Further research and experimental work exploring TRISO particle mobility is required to understand the full environmental mobility of TRISO particles in the environment.
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- 2021
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7. A Methodology to Evaluate Ecological Resources and Risk Using Two Case Studies at the Department of Energy’s Hanford Site
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Jennifer A. Salisbury, Michael Gochfeld, Taryn Pittfield, Joanna Burger, Christian Jeitner, Amoret L. Bunn, Janelle L. Downs, and David S. Kosson
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Washington ,Conservation of Natural Resources ,010504 meteorology & atmospheric sciences ,Risk rating ,Hanford Site ,Forest management ,010501 environmental sciences ,Risk Assessment ,01 natural sciences ,Ecological resources ,Ecosystem ,Environmental Restoration and Remediation ,0105 earth and related environmental sciences ,Valuation (finance) ,Global and Planetary Change ,Ecology ,business.industry ,Endangered Species ,Environmental resource management ,Ecological assessment ,Pollution ,Rapid assessment ,Risk evaluation ,Environmental science ,Environmental Pollution ,business - Abstract
An assessment of the potential risks to ecological resources from remediation activities or other perturbations should involve a quantitative evaluation of resources on the remediation site and in the surrounding environment. We developed a risk methodology to rapidly evaluate potential impact on ecological resources for the U.S. Department of Energy's Hanford Site in southcentral Washington State. We describe the application of the risk evaluation for two case studies to illustrate its applicability. The ecological assessment involves examining previous sources of information for the site, defining different resource levels from 0 to 5. We also developed a risk rating scale from non-discernable to very high. Field assessment is the critical step to determine resource levels or to determine if current conditions are the same as previously evaluated. We provide a rapid assessment method for current ecological conditions that can be compared to previous site-specific data, or that can be used to assess resource value on other sites where ecological information is not generally available. The method is applicable to other Department of Energy's sites, where its development may involve a range of state regulators, resource trustees, Tribes and other stakeholders. Achieving consistency across Department of Energy's sites for valuation of ecological resources on remediation sites will assure Congress and the public that funds and personnel are being deployed appropriately.
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- 2016
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8. Simulation of the 2003 Foss Barge - Point Wells Oil Spill: A Comparison between BLOSOM and GNOME Oil Spill Models
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Amoret L. Bunn, Lucy Romeo, Kelly Rose, Jason Vielma, Rodrigo Duran, Jonathan Whiting, and Jennifer Bauer
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hindcast ,010504 meteorology & atmospheric sciences ,Meteorology ,Ocean Engineering ,Forcing (mathematics) ,010501 environmental sciences ,GNOME ,01 natural sciences ,windage ,lcsh:Oceanography ,lcsh:VM1-989 ,Hindcast ,Point (geometry) ,ocean trajectory ,oil spill model ,lcsh:GC1-1581 ,Trajectory (fluid mechanics) ,BLOSOM ,0105 earth and related environmental sciences ,Water Science and Technology ,Civil and Structural Engineering ,Ocean current ,BARGE ,lcsh:Naval architecture. Shipbuilding. Marine engineering ,Energy technology ,Point Wells ,Salish Sea ,model comparison ,Environmental science ,Foss Barge ,Gnome - Abstract
The Department of Energy&rsquo, s (DOE&rsquo, s) National Energy Technology Laboratory&rsquo, s (NETL&rsquo, s) Blowout and Spill Occurrence Model (BLOSOM), and the National Oceanic and Atmospheric Administration&rsquo, s (NOAA&rsquo, s) General NOAA Operational Modeling Environment (GNOME) are compared. Increasingly complex simulations are used to assess similarities and differences between the two models&rsquo, components. The simulations presented here are forced by ocean currents from a Finite Volume Community Ocean Model (FVCOM) implementation that has excellent skill in representing tidal motion, and with observed wind data that compensates for a coarse vertical ocean model resolution. The comprehensive comparison between GNOME and BLOSOM presented here, should aid modelers in interpreting their results. Beyond many similarities, aspects where both models are distinct are highlighted. Some suggestions for improvement are included, e.g., the inclusion of temporal interpolation of the forcing fields (BLOSOM) or the inclusion of a deflection angle option when parameterizing wind-driven processes (GNOME). Overall, GNOME and BLOSOM perform similarly, and are found to be complementary oil spill models. This paper also sheds light on what drove the historical Point Wells spill, and serves the additional purpose of being a learning resource for those interested in oil spill modeling. The increasingly complex approach used for the comparison is also used, in parallel, to illustrate the approach an oil spill modeler would typically follow when trying to hindcast or forecast an oil spill, including detailed technical information on basic aspects, like choosing a computational time step. We discuss our successful hindcast of the 2003 Point Wells oil spill that, to our knowledge, had remained unexplained. The oil spill models&rsquo, solutions are compared to the historical Point Wells&rsquo, oil trajectory, in time and space, as determined from overflight information. Our hindcast broadly replicates the correct locations at the correct times, using accurate tide and wind forcing. While the choice of wind coefficient we use is unconventional, a simplified analytic model supported by observations, suggests that it is justified under this study&rsquo, s circumstances. We highlight some of the key oceanographic findings as they may relate to other oil spills, and to the regional oceanography of the Salish Sea, including recommendations for future studies.
- Published
- 2018
9. The costs of delaying remediation on human, ecological, and eco-cultural resources: Considerations for the Department of Energy: A methodological framework
- Author
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Henry J. Mayer, James H. Clarke, Jennifer A. Salisbury, Kevin G. Brown, David S. Kosson, Lisa S. Bliss, Joanna Burger, Amoret L. Bunn, and Michael Gochfeld
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Washington ,Conservation of Natural Resources ,Environmental Engineering ,Resource (biology) ,Time Factors ,010504 meteorology & atmospheric sciences ,Ecology ,Hanford Site ,Environmental remediation ,Cost-Benefit Analysis ,Vulnerability ,010501 environmental sciences ,01 natural sciences ,Pollution ,United States ,Task (project management) ,Unit (housing) ,Water resources ,Interim ,Environmental Chemistry ,Business ,Waste Management and Disposal ,Environmental Restoration and Remediation ,0105 earth and related environmental sciences - Abstract
Remediation and restoration of the Nation's nuclear legacy of radiological and chemical contaminated areas is an ongoing and costly challenge for the U.S. Department of Energy (DOE). For large sites, such as the Hanford and Savannah River Sites, successful remediation involves complex decisions related to remedies, end-states, timing, and sequencing of cleanup of separate and related contaminated units within a site. Hanford Site cannot clean up every unit simultaneously due to limits in funding, personnel, and technology. This paper addresses one of the major considerations - the consequences of delaying remediation of a unit on different receptors (e.g. people, ecological, and eco-cultural resources), using the DOE Hanford Site as a case study. We develop a list of attributes that managers should consider for successful remediation, examine how delaying remediation could affect workers, the public and ecological resources (including water resources), and use some examples to illustrate potential effects of delays. The factors to consider when deciding whether and how long to delay remediation of a unit include personnel, information and data, funding, equipment, structural integrity, contaminant source, and resource vulnerability. Each of these factors affects receptors differently. Any remediation task may be dependent on other remediation projects, on the availability of transport, containers, interim storage and ultimate disposition decisions, or the availability of trained personnel. Delaying remediation may have consequences for people (e.g. workers, site neighbors), plants, animals, ecosystems, and eco-cultural resources (i.e. those cultural values that depend upon ecological resources). The risks, benefits, and uncertainties for evaluating the consequences of delaying remediation are described and discussed. Assessing the advantages and disadvantages of delaying remediation is important for health professionals, ecologists, resource trustees, regulators, Tribal members, recreationists, fishermen, hunters, conservationists, and a wide range of other stakeholders.
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- 2018
10. Investigating freshwater periphyton community response to uranium with phospholipid fatty acid and denaturing gradient gel electrophoresis analyses
- Author
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Jack A. Small, A. D. Peacock, Ann L. Miracle, Craig A. McKinstry, and Amoret L. Bunn
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Electrophoresis ,Geologic Sediments ,Time Factors ,River ecosystem ,Health, Toxicology and Mutagenesis ,Fresh Water ,Biology ,Rivers ,Water Movements ,Environmental Chemistry ,Ecosystem ,Biomass ,Periphyton ,Waste Management and Disposal ,Phospholipids ,Biomass (ecology) ,Models, Statistical ,Aquatic ecosystem ,Fatty Acids ,Water ,General Medicine ,Pollution ,Productivity (ecology) ,Microbial population biology ,Biofilms ,Environmental chemistry ,Uranium ,Temperature gradient gel electrophoresis - Abstract
Periphyton communities can be used as monitors of ecosystem health and as indicators of contamination in lotic systems. Measures of biomass, community structure, and genetic diversity were used to investigate impacts of uranium (U) exposure on periphyton. Laboratory exposures of periphyton in river water amended with 238U were performed for 5 days, followed by 2 days of U depuration in unamended river water. Productivity as measured by biomass was not affected by concentrations up to 100 microg238U L(-1). Phospholipid fatty acid (PLFA) profiles and denaturing gradient gel electrophoresis (DGGE) banding patterns revealed no changes in community or genetic structure related to U exposure. We suggest that the periphyton community as a whole was not significantly impacted by exposures of 238U up to a concentration of 100 microgL(-1). These findings have significance for the assessment and prediction of U impacts on aquatic ecosystems.
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- 2008
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11. Modeling Long-Term Risk to Environmental and Human Systems at the Hanford Nuclear Reservation: Scope and Findings from the Initial Model
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Leslie A. Nieves, Bruce A. Napier, Michael J. Scott, Amoret L. Bunn, Terri B. Miley, Ellen L. Prendergast, David W. Engel, Charlie A. Brandt, and Paul W. Eslinger
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Washington ,Global and Planetary Change ,Ecology ,Human systems engineering ,Ecological health ,Scope (project management) ,business.industry ,Hanford Site ,Environmental resource management ,Reservation ,Chemical waste ,Models, Theoretical ,Risk Assessment ,Pollution ,Hazardous waste ,Environmental protection ,Radioactive Waste ,Humans ,Environmental science ,Public Health ,business ,Monte Carlo Method ,Uncertainty analysis ,Radioactive Pollutants - Abstract
The Groundwater Protection Project at the US Department of Energy Hanford Site in Washington State is currently developing the means to assess the cumulative impact to human and ecological health and the regional economy and cultures from radioactive and chemical waste that will remain at the Hanford Site after the site closes. This integrated system is known as the System Assessment Capability (SAC). The SAC Risk/Impact Module discussed in the article uses media- and time-specific concentrations of contaminants estimated by the transport models of the integrated system to project potential impacts on the ecology of the Columbia River corridor, the health of persons who might live in or use the corridor or the upland Hanford environment, the local economy, and cultural resources. Preliminary Monte Carlo realizations from the SAC modeling system demonstrate the feasibility of large-scale uncertainty analysis of the complex relationships in the environmental transport of contaminants on the one hand and ecological, human, cultural, and economic risk on the other. Initial impact results show very small long-term risks for the 10 radionuclides and chemicals evaluated. The analysis also helps determine science priorities to reduce uncertainty and suggests what actions matter to reduce risks.
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- 2005
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12. 100-OL-1 Operable Unit Pilot Study: XRF Evaluation of Select Pre-Hanford Orchards
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Dominique M. Martinez, Alicia M. Gorton, Brad G. Fritz, Brent A. Pulsipher, Komal Rana, Amoret L. Bunn, Jill M. Brandenberger, Christian Pino, Lynn E. Bisping, and Dawn M. Wellman
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Engineering ,Work plan ,Waste management ,Cost estimate ,business.industry ,Hanford Site ,Data quality ,Sampling (statistics) ,Soil surface ,Orchard ,business ,Water resource management ,Unit (housing) - Abstract
Prior to the acquisition of land by the U.S. Department of War in February 1943 and the creation of the Hanford Site, the land along the Columbia River was home to over 1000 people. Farming and orchard operations by both homesteaders and commercial organizations were prevalent. Orchard activities and the associated application of lead arsenate pesticide ceased in 1943, when residents were moved from the Hanford Site at the beginning of the Manhattan Project. Today, the residues from historical application of lead arsenate pesticide persist in some locations on the Hanford Site. In 2012, the U.S. Department of Energy, U.S. Environmental Protection Agency, and Washington State Department of Ecology established the 100-OL-1 Operable Unit (OU) through the Hanford Federal Facility Agreement and Consent Order, known as the Tri-Party Agreement. The pre-Hanford orchard lands identified as the 100-OL-1 OU are located south of the Columbia River and east of the present-day Vernita Bridge, and extend southeast to the former Hanford townsite. The discontinuous orchard lands within 100-OL-1 OU are approximately 20 km2 (5000 ac). A pilot study was conducted to support the approval of the remedial investigation/feasibility study work plan to evaluate the 100-OL-1 OU. This pilot study evaluated the use more » of a field portable X-ray fluorescence (XRF) analyzer for evaluating lead and arsenic concentrations on the soil surface as an indicator of lead arsenate pesticide residues in the OU. The objectives of the pilot study included evaluating a field portable XRF analyzer as the analytical method for decision making, estimating the nature and extent of lead and arsenic in surface soils in four decision units, evaluating the results for the purpose of optimizing the sampling approach implemented in the remedial investigation, and collecting information to improve the cost estimate and planning the cultural resources review for sampling activities in the remedial investigation. Based on the results of the pilot study, the recommendations for the revision of the work plan are as follows: • characterize the surface soil using field portable XRF measurements with confirmatory inductively coupled plasma mass spectroscopy sampling for the remedial investigation • establish decision units of similar defined areas • establish a process for field investigation of soil concentrations exceeding the screening criteria at the border of the 100-OL-1 OU • define data quality objectives for the work plan using the results of the pilot study and refining the sampling approach for the remedial investigation. « less
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- 2014
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13. 100-OL-1 Operable Unit Field Portable X-Ray Fluorescence (XRF) Analyzer Pilot Study Plans
- Author
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Amoret L. Bunn, Brad G. Fritz, and Dawn M. Wellman
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Engineering ,Spectrum analyzer ,Work plan ,Waste management ,business.industry ,Environmental engineering ,Portable X-ray ,Soil surface ,business - Abstract
A pilot study is being conducted to support the approval of the Remedial Investigation/Feasibility Study (RI/FS) Work Plan to evaluate the 100-OL-1 Operable Unit (OU) pre-Hanford orchard lands. Based on comments received by the U.S. Environmental Protection Agency (EPA) and Washington State Department of Ecology, the pilot study will evaluate the use of field portable X-ray fluorescence (XRF) spectrometry measurements for evaluating lead and arsenic concentrations on the soil surface as an indicator of past use of lead arsenate pesticide residue in the OU. The work will be performed in the field during the summer of 2014, and assist in the planning for the characterization activities in the RI/FS.
- Published
- 2014
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14. Integrated Systems-Based Approach to Monitoring Environmental Remediation
- Author
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Michael J. Truex, Dawn M. Wellman, Amoret L. Bunn, Mart Oostrom, and Kenneth C. Carroll
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Risk analysis (engineering) ,Total cost ,Environmental remediation ,Integrated systems ,Key (cryptography) ,Environmental science ,Nuclear weapon ,Civil engineering - Abstract
The U.S. Department of Energy is responsible for risk reduction and cleanup of its nuclear weapons complex. Remediation strategies for some of the contamination may include techniques that mitigate risk, but leave contaminants in place. Monitoring to verify remedy performance and long-term mitigation of risk is key to implementing these strategies and can be a large portion of the total cost of remedy implementation. Especially in these situations, there is a need for innovative monitoring approaches that move away from the cost- and labor-intensive point-source monitoring. In this paper, alternative approaches for monitoring are presented for vadose zone, groundwater, groundwater/surface water interface, and surface water. To illustrate integrated, systems-based monitoring, this paper focuses on vadose zone contaminant remediation to mitigate impact to groundwater. In this context, vadose zone contamination is a source, or potential source, to groundwater plumes. The monitoring design uses a systems-based approach focused on developing a conceptual site model that highlights key features that control contaminant flux to groundwater. These features are derived considering the unsaturated flow and contaminant transport processes in the vadose zone and the nature of the waste discharge. Diagnostic properties and/or parameters related to both short- and long-term contaminant flux to groundwater can be identified and targeted for monitoring. The resolution of monitoring data needed to correspond to a functionally useful indicator of flux to groundwater can be estimated using quantitative analyses and the associated unsaturated flow properties relevant to the targeted site and vadose zone features. This monitoring design approach follows the process of developing a quantitative conceptual model suitable for supporting projections of future flux to groundwater. Support for such projections is important because it is likely that, in many cases, remediation decisions for the vadose zone will need to be made based all or in part on projected impacts to groundwater, and monitoring will then be applied to verify that remedy goals are being met.
- Published
- 2013
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15. Deep Vadose Zone?Applied Field Research Initiative Fiscal Year 2012 Annual Report
- Author
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Dawn M. Wellman, Amoret L. Bunn, Michael J. Truex, Elizabeth C. Golovich, and Timothy C. Johnson
- Subjects
Fiscal year ,Environmental remediation ,Vadose zone ,Field research ,Environmental science ,Annual report ,Water resource management ,Groundwater - Abstract
This annual report describes the background of the Deep Vadose Zone-Applied Field Research Initiative, and some of the programmatic approaches and transformational technologies in groundwater and deep vadose zone remediation developed during fiscal year 2012.
- Published
- 2013
- Full Text
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16. Scientific Opportunities for Monitoring at Environmental Remediation Sites (SOMERS): Integrated Systems-Based Approaches to Monitoring
- Author
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Paul Beam, Michelle H. Lee, Mark D. Freshley, Richard D. Miller, Michael J. Truex, Dawn Kaback, Justin Marble, Eric M. Pierce, Latrincy Whitehurst, Kurt D. Gerdes, Rula A. Deeb, G. M. Chamberlain, Richard P. Bush, Joe Rossabi, Carol Eddy-Dilek, John McCord, Dawn M. Wellman, Amoret L. Bunn, Tyler J. Gilmore, Ann L. Miracle, Yvette T. Collazo, Michael H. Young, Elizabeth L. Hawley, and Mark J. Peterson
- Subjects
Information management ,Risk analysis (engineering) ,Long term monitoring ,Integrated systems ,Key (cryptography) ,Environmental engineering ,Environmental science - Abstract
Through an inter-disciplinary effort, DOE is addressing a need to advance monitoring approaches from sole reliance on cost- and labor-intensive point-source monitoring to integrated systems-based approaches such as flux-based approaches and the use of early indicator parameters. Key objectives include identifying current scientific, technical and implementation opportunities and challenges, prioritizing science and technology strategies to meet current needs within the DOE complex for the most challenging environments, and developing an integrated and risk-informed monitoring framework.
- Published
- 2012
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17. Summary of TPH Monitoring Conducted at 100-NR-2- 2008 through 2010
- Author
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Amanda Stegen, David R. Yonge, Brad G. Fritz, Amoret L. Bunn, Richard J. Cameron, and Donaldo P. Mendoza
- Subjects
Hydrology ,Waste management ,Environmental science - Abstract
A summary of TPH monitoring conducted along the 100-N shoreline and the 100-NR-2 operable unit
- Published
- 2010
- Full Text
- View/download PDF
18. Phospholipid fatty acid biomarkers in a freshwater periphyton community exposed to uranium: discovery by non-linear statistical learning
- Author
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Bobbie-Jo M. Webb-Robertson, Amoret L. Bunn, and Vanessa L. Bailey
- Subjects
Health, Toxicology and Mutagenesis ,Linear classifier ,Fresh Water ,Biology ,Partial least squares regression ,Environmental Chemistry ,Food science ,Periphyton ,Waste Management and Disposal ,Phospholipids ,chemistry.chemical_classification ,Models, Statistical ,Bacteria ,Confounding ,Fatty Acids ,Fatty acid ,General Medicine ,Linear discriminant analysis ,Pollution ,Support vector machine ,Statistical classification ,chemistry ,Biochemistry ,Uranium ,Water Microbiology ,Biomarkers ,Water Pollutants, Chemical - Abstract
Phospholipid fatty acids (PLFA) have been widely used to characterize environmental microbial communities, generating community profiles that can distinguish phylogenetic or functional groups within the community. The poor specificity of organism groups with fatty acid biomarkers in the classic PLFA-microorganism associations is a confounding factor in many of the statistical classification/clustering approaches traditionally used to interpret PLFA profiles. In this paper we demonstrate that non-linear statistical learning methods, such as a support vector machine (SVM), can more accurately find patterns related to uranyl nitrate exposure in a freshwater periphyton community than linear methods, such as partial least squares discriminant analysis. In addition, probabilistic models of exposure can be derived from the identified lipid biomarkers to demonstrate the potential model-based approach that could be used in remediation. The SVM probability model separates dose groups at accuracies of ∼87.0%, ∼71.4%, ∼87.5%, and 100% for the four groups; Control (non-amended system), low dose (amended at 10 μg UL⁻¹), medium dose (amended at 100 μg UL⁻¹), and high dose (500 μg UL⁻¹). The SVM model achieved an overall cross-validated classification accuracy of ∼87% in contrast to ∼59% for the best linear classifier.
- Published
- 2010
19. Summary of TPH Monitoring Conducted at 100-NR-2 during CY 2008 and 2009
- Author
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Brad G. Fritz, Amoret L. Bunn, J. A. Stegen, Donaldo P. Mendoza, and david young
- Subjects
Waste management ,Environmental chemistry ,Environmental monitoring ,Environmental science ,Contamination - Abstract
This report covers a variety of environmental monitoring activities that were conducted over an 18 month period to provide characterization of a TPH-diesel contamination plume in the 100-NR-2 OU
- Published
- 2009
- Full Text
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20. Uranium in the Near-shore Aquatic Food Chain: Studies on Periphyton and Asian Clams
- Author
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Paul W. Eslinger, Bruce A. Napier, Charles A. Brandt, Amoret L. Bunn, and Terri B. Miley
- Subjects
inorganic chemicals ,Hanford Site ,Ecology ,fungi ,technology, industry, and agriculture ,chemistry.chemical_element ,Uranium ,complex mixtures ,Fishery ,Aufwuchs ,Food chain ,chemistry ,Benthic zone ,Environmental science ,Ecosystem ,Periphyton ,Groundwater - Abstract
The benthic aquatic organisms in the near-shore environment of the Columbia River are the first biological receptors that can be exposed to groundwater contaminants coming from the U.S. Department of Energy's Hanford Site. The primary contaminant of concern in the former nuclear fuels processing area at the Site, known as the 300 Area, is uranium. Currently, there are no national clean up criteria for uranium and ecological receptors. This report summarizes efforts to characterize biological uptake of uranium in the food chain of the benthic aquatic organisms and provide information to be used in future assessments of uranium and the ecosystem.
- Published
- 2007
- Full Text
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21. Current Conditions Risk Assessment for the 300-FF-5 Groundwater Operable Unit
- Author
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Amoret L. Bunn, Robert E. Peterson, Bruce A. Napier, James M. Becker, and Terri B. Miley
- Subjects
Record of Decision ,Remedial action ,Land use ,Interim ,Environmental science ,Risk assessment ,Baseline (configuration management) ,Environmental planning ,Groundwater ,Unit (housing) - Abstract
This report updates a baseline risk assessment for the 300 Area prepared in 1994. The update includes consideration of changes in contaminants of interest and in the environment that have occurred during the period of interim remedial action, i.e., 1996 to the present, as well as the sub-regions, for which no initial risk assessments have been conducted. In 1996, a record of decision (ROD) stipulated interim remedial action for groundwater affected by releases from 300 Area sources, as follows: (a) continued monitoring of groundwater that is contaminated above health-based levels to ensure that concentrations continue to decrease, and (b) institutional controls to ensure that groundwater use is restricted to prevent unacceptable exposure to groundwater contamination. In 2000, the groundwater beneath the two outlying sub-regions was added to the operable unit. In 2001, the first 5-year review of the ROD found that the interim remedy and remedial action objectives were still appropriate, although the review called for additional characterization activities. This report includes a current conditions baseline ecological and human health risk assessment using maximum concentrations in the environmental media of the 300-FF-5 Operable Unit and downstream conditions at the City of Richland, Washington. The scope for this assessment includes onlymore » current measured environmental concentrations and current use scenarios. Future environmental concentrations and future land uses are not considered in this assessment.« less
- Published
- 2007
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22. Investigation of the Hyporheic Zone at the 300 Area,Hanford Site
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Donaldo P. Mendoza, Tyler J. Gilmore, Amoret L. Bunn, Nancy P. Kohn, Rob D. Mackley, Brad G. Fritz, Doug McFarland, Evan V. Arntzen, and Gregory W. Patton
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Hydrology ,Shore ,Remedial action ,geography ,geography.geographical_feature_category ,Advection ,Environmental remediation ,Hanford Site ,Environmental science ,Hyporheic zone ,Aquifer ,Groundwater - Abstract
The Remediation Task of the Science and Technology (S&T) Project is intended to provide research to meet several objectives concerning the discharge of groundwater contamination into the river at the 300 Area of the Hanford Site. This report serves to meet the research objectives by developing baseline data for future evaluation of remedial technologies, evaluating the effects changing river stage on near-shore groundwater chemistry, improving estimates of contaminant flux to the river, providing estimates on the extent of contaminant discharge areas along the shoreline, and providing data to support computer models used to evaluate remedial alternatives. This report summarizes the activities conducted to date and provides an overview of data collected through July 2006. Recent geologic investigations (funded through other U. S. Department of Energy (DOE) programs) have provided a more complete geologic interpretation of the 300 Area and a characterization of the vertical extent of uranium contamination. Extrapolation of this geologic interpretation into the hyporheic zone is possible, but there is little data to provide corroboration. Penetration testing was conducted along the shoreline to develop evidence to support the extrapolation of the mapping of the geologic facies. In general, this penetration testing provided evidence supporting the extrapolation of themore » most recent geologic interpretation, but it also provided some higher resolution detail on the shape of the layer than constrains contaminant movement. Information on this confining layer will provide a more detailed estimate of the area of river bed that has the potential to be impacted by uranium discharge to the river from groundwater transport. Water sampling in the hyporheic zone has provided results that illustrate the degree of mixing that occurs in the hyporheic zone. Uranium concentrations measured at individual sampling locations can vary by several orders of magnitude depending on the river and near-shore aquifer elevations. It is shown in this report that the concentrations of all the measured constituents in water samples collected from the hyporheic zone vary according to the ratio of groundwater and river water in the sample. One important aspect of this is that specific conductance provides a sensitive indicator of the relative contribution of groundwater and river water in a particular sample. This is because of the large difference is specific conductance of groundwater (~400 μS/cm) and river water (~130 μS/cm). It appears that in the hyporheic zone, advection of contaminates occurs very quickly, and variations in concentrations are a function of dilution rather than any chemistry effects caused by the difference in water chemistry between groundwater and river water.« less
- Published
- 2007
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23. Hanford Site National Environmental Policy Act (NEPA) Characterization Report, Revision 17
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Duane A. Neitzel, Amoret L. Bunn, Sandra D. Cannon, Joanne P. Duncan, Richard A. Fowler, Brad G. Fritz, David W. Harvey, Paul L. Hendrickson, Dana J. Hoitink, Duane G. Horton, George V. Last, Ted M. Poston, Ellen L. Prendergast-Kennedy, Steve P. Reidel, Alan C. Rohay, Michael R. Sackschewsky, Michael J. Scott, and Paul D. Thorne
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- 2005
- Full Text
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24. Ecological Characterization Data for the 2004 Composite Analysis
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Amoret L. Bunn, Susan L. Thorsten, Brett L. Tiller, Mary Ann Simmons, Rhett K. Zufelt, Janelle L. Downs, and Jennifer A. Stegen
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geography ,Engineering ,geography.geographical_feature_category ,Ecology ,Hanford Site ,business.industry ,Radioactive waste ,Fiscal year ,Environmental impact statement ,Work (electrical) ,business ,Spatial analysis ,Groundwater ,Riparian zone - Abstract
A composite analysis is required by U.S. Department of Energy (DOE) Order 435.1 to ensure public safety through the management of active and planned low-level radioactive waste disposal facilities associated with the Hanford Site. The original Hanford Site Composite Analysis of 1998 must be revised and submitted to DOE Headquarters (DOE-HQ) in 2004 because of revisions to waste site information in the 100, 200, and 300 Areas, updated performance assessments and environmental impact statements (EIS), changes in inventory estimates for key sites and constituents, and a change in the definition of offsite receptors. Beginning in fiscal year (FY) 2003, the DOE Richland Operations Office (DOE-RL) initiated activities, including the development of data packages, to support the 2004 Composite Analysis. This report describes the data compiled in FY 2003 to support ecological site assessment modeling for the 2004 Composite Analysis. This work was conducted as part of the Characterization of Systems Task of the Groundwater Remediation Project (formerly the Groundwater Protection Program) managed by Fluor Hanford, Inc., Richland, Washington. The purpose of this report is to provide summaries of the characterization information and available spatial data on the biological resources and ecological receptors found in the upland, riparian, aquatic, and islandmore » habitats on the Hanford Site. These data constitute the reference information used to establish parameters for the ecological risk assessment module of the System Assessment Capability and other assessment activities requiring information on the presence and distribution of biota on the Hanford Site.« less
- Published
- 2004
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25. Hanford Site National Environmental Policy Act (NEPA) Characterization Report
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Duane A. Neitzel, Amoret L. Bunn, Sandra D. Cannon, Joanne P. Duncan, Richard A. Fowler, Brad G. Fritz, David W. Harvey, Paul L. Hendrickson, Dana J. Hoitink, Duane G. Horton, George V. Last, Ted M. Poston, Ellen L. Prendergast-Kennedy, Steve P. Reidel, Alan C. Rohay, Michael J. Scott, and Paul D. Thorne
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- 2004
- Full Text
- View/download PDF
26. Hanford Site National Environmental Policy Act (NEPA) Characterization, Revision 15
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Duane A. Neitzel, Amoret L. Bunn, Kenneth W. Burk, Sandra D. Cannon, Joanne P. Duncan, Richard A. Fowler, Brad G. Fritz, David W. Harvey, Paul L. Hendrickson, Duane G. Horton, George V. Last, Ted M. Poston, Ellen L. Prendergast-Kennedy, Steve P. Reidel, Michael J. Scott, Paul D. Thorne, and Dave M. Woody
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- 2003
- Full Text
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27. Groundwater Protection Program Science and Technology Summary Description
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Amoret L. Bunn, Steven B. Yabusaki, Tyler J. Gilmore, Mark D. Freshley, John M. Zachara, Charles T. Kincaid, Robert E. Peterson, Anderson L. Ward, and Glendon W. Gee
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Hanford Site ,Ecology (disciplines) ,Vadose zone ,Environmental engineering ,Environmental science ,Integrated approach ,Water resource management ,Groundwater - Abstract
The Hanford Site Groundwater Protection Program, formerly the Groundwater/Vadose Zone Integration Project, was established in 1997 to develop the integrated approach, technical capability, and scientific information needed to perform site-wide assessments of the potential effects of Hanford Site soil and groundwater contaminants on people and the ecology. To complete this mission, gaps in scientific understanding and technologies were identified, and research to close those gaps was initiated.
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- 2002
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28. Hanford Site National Environmental Policy Act (NEPA) Characterization
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Duane A. Neitzel, Amoret L. Bunn, Joanne P. Duncan, Tara O. Eschbach, Richard A. Fowler, Brad G. Fritz, Shannon M. Goodwin, David W. Harvey, Paul L. Hendrickson, Dana J. Hoitink, Duane G. Horton, George V. Last, Ted M. Poston, Ellen L. Prendergast-Kennedy, Alan C. Rohay, Michael J. Scott, and Paul D. Thorne
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- 2002
- Full Text
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29. 2001 Columbia River Recreation Survey -- Implications for Hanford Site Integrated Assessment
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John A. Jaksch, Ellen L. Prendergast, Dave M. Anderson, Michael J. Scott, Tara O. Eschbach, Amoret L. Bunn, Richard A. Fowler, and Terri B. Miley
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Fishery ,Current (stream) ,Shore ,Hydrology ,Geography ,geography.geographical_feature_category ,Land use ,Hanford Site ,Visitor pattern ,Fishing ,Economic impact analysis ,Recreation - Abstract
This report presents the results from the Columbia River Recreation Survey conducted in the summer of 2001. The survey combined on-site personal interviews with parties engaged in river recreation with on-site field observations to develop a picture of summer river recreation on the Columbia. The study area stretched from just below Priest Rapids Dam in the north to McNary Dam in the south, and was divided into four "Areas" that correspond to the river areas used by the Groundwater/Vadose Zone Integration Project. This study is part of the Groundwater/Vadose Zone Integration Project and was commissioned specifically to document the current recreation use levels in these areas of the river, and to elicit recreation-related expenditure information from visitors. This information informs economic and environmental models used to measure the economic risk posed by possible, but unlikely, releases of contaminants from the Hanford site into the Columbia River. During the study period, researchers collected 256 survey responses and 396 field observations from recreation sites up and down both shores of the river in the study area. Results presented include analysis of trip duration by river activity, trip frequency, and visitor place of origin. Economics-related results include trip expenditure profiles by activity andmore » place of origin. Data also were collected on fishing effort. Visitors also were asked to indicate what activity or destination substitution they would choose in the hypothetical example that the river could not be accessed. The report also highlights some limitations in the approach. Principally, by doing this research in the summer, the recreational use of the river in the other seasons was not documented. The report provides data that suggest the significance of the other seasons - particularly spring and fall - for salmon and steelhead fishing. This stretch of the Columbia is also well known for waterfowl hunting.« less
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- 2002
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30. A Stochastic Assessment of Nuclear Waste Management Practices at the Hanford Site, Washington
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Paul W. Eslinger, Amoret L. Bunn, David W. Engel, Charles T. Kincaid, William E. Nichols, and Robert W. Bryce
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Remedial action ,Municipal solid waste ,Materials science ,Waste management ,Hanford Site ,Vadose zone ,Radioactive waste ,Baseline (configuration management) ,Groundwater model ,Management practices - Abstract
Waste management and disposal decisions at the Hanford Site, Washington, depend in part on an understanding of the risks and impacts associated with alternate disposal and remedial actions. A proof-of-principle site-wide assessment of the risks and impacts associated with all wastes that will remain at the Hanford Site following cleanup has been performed for the first time. It simulates contaminant release, migration, and fate from the initiation of site operations in 1944 forward, and, thus, illustrates historical and near-term influences on long-term risk and impact.A stochastic simulation tool capable of addressing 1000 waste discharge and disposal sites and 10 contaminants for a period of 1000 years has been created and applied. Human health and ecological risks as well as impacts to the regional economy and local cultures are estimated. The methodology developed is known as the System Assessment Capability (SAC). It is currently in a Revision 0 state corresponding to a proof-of-principle demonstration.An initial assessment based on the planning baseline of the U.S. Department of Energy (Richland Operations office and office of River Protection) has been undertaken. Preliminary results of the assessment indicate variability in predictions is most influenced by uncertainty in:- geochemical adsorption (i.e., distribution coefficients, Kd) for contaminant release, vadose zone, and groundwater models; especially for uranium and iodine which are somewhat but not greatly adsorbed,- solid waste burial ground inventories of iodine-129, and- liquid discharge site inventories of technetium-99.It is apparent that variables governing change in performance are a function of space and time. Initially, these results point to the need for related models and data to be examined, and, if necessary, augmented through future laboratory and field studies to better quantify or reduce uncertainty.
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- 2002
- Full Text
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