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The objective of this study is to map, describe, and identify "water treatment using catalysts and/or nanomaterials" and their derivable aspects. A comprehensive search was conducted in academic databases such as WoS and Scopus, following the PRISMA methodology, to identify relevant studies published between 2010 and 2024. Inclusion and exclusion criteria were applied to select articles that address both experimental and theoretical aspects of photocatalysis in wastewater treatment. The methodology is developed through exploratory data analysis and the use of the Tree of Science algorithm. The first results indicate the roots, in which it is possible to gain knowledge of the environment for the implementation of a photoreactor it uses as a photocatalyst agent. A total of 94 relevant articles were identified. The results show that most studies focus on the degradation of organic pollutants using TiO2 as a photocatalyst. Additionally, there has been a significant increase in the number of publications and citations in recent years, indicating growing interest in this field. Then, in the trunk, some more solid ideas in terms of basic concepts, techniques and possible variations for the application of knowledge and development of future research related to the initial topic are indicated. Finally, through the leaves, new modifications and combinations of the photocatalytic materials are obtained, in search of improving their performance in terms of reduction in water contaminants. From the above, centrality in photocatalysis is identified as an alternative for water remediation using different photocatalysts. It is concluded that the total citation network contains, within the most important nodes, articles of high interest in the community, such as those authored by Zhang, Xiaofei; Nezamzadeh-Ejhieh, Alireza; or Li, Jingyi, from countries in the Middle East and the Asian continent, justified not only by the research capabilities of these countries, but also by the needs and problems that these regions face in terms of water scarcity. Future work indicates the need for and interest in improving various characteristics such as photocatalytic performance, the number of cycles that the material supports, and its reduction capacity in the presence of high concentrations of contaminants, with the intention of maximizing the benefits of its applicability in water treatment. [ABSTRACT FROM AUTHOR]

This study deals with the effect of Cu on hydroxyapatite (HAp) thin films on silicon substrates prepared by pulsed laser deposition (PLD) technique for Cu concentrations ranging from 0 to 0.8 wt.%. Fourier transform infrared spectroscopy and Raman spectroscopy provide additional evidence of HAp in the films, which exhibit characteristic HAp bands such as the 960 cm−1 phosphate ion band. The X‐ray diffraction patterns confirm the presence of HAp, without copper‐related peaks, suggesting that it is not incorporated into the HAp lattice, which is present as an amorphous phase. X‐ray photoelectron spectroscopy confirms the presence of Cu on the HAp thin films, possibly related to the adsorption of Cu2+ on HAp surfaces through electrostatic or interactions with (PO4)3− groups. Atomic force microscopy shows that the roughness of the films varies depending on the presence or absence of copper ions. Finally, density functional theory and kinetic Monte Carlo simulations explain the effects of atomic diffusion on roughness and HAp clustering. These changes correlate with the contact angle values, indicating the formation of hydrophobic films due to copper inclusions. [ABSTRACT FROM AUTHOR]

This research focuses on developing MIL-53-type compounds with Fe obtained with ligands derived from PET waste, followed by the controlled addition of hydrofluoric acid (HF). Incorporating HF into the MOF structure induced substantial changes in the material textural properties, resulting in a significant change in CO 2 adsorption. Furthermore, a distinctive structural alteration (breathing effect) was observed in the CO 2 isotherms at different temperatures; these structural changes have not been observed by X-ray diffraction (XRD) because this characterization has been performed at room temperature, whereas the adsorption experiments were conducted at 260, 273, and 303 K and different pressures. Subsequently, DFT studies were performed to investigate the CO 2 -filling mechanisms and elucidate the material respiration effect. This approach offers promising opportunities for sustainable materials with improved gas adsorption properties., Competing Interests: The authors declare no competing financial interest., (© 2024 The Authors. Published by American Chemical Society.)