1. Interleaved bond and magnetic frustration in triangular lattice $Ln$Cd$_3$P$_3$
- Author
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Alvarado, S. J. Gomez, Chamorro, J. R., Jackson, A. R., Pokharel, G., Gomez, R., Ortiz, B. R., Sarker, Suchismita, Kautzsch, L., Gallington, L. C., Seshadri, R., and Wilson, Stephen D.
- Subjects
Condensed Matter - Strongly Correlated Electrons - Abstract
We report the presence of frustrated bond order in the form of short-range charge correlations in the triangular lattice antiferromagnetic compounds $Ln$Cd$_3$P$_3$ ($Ln$ = La, Ce, Pr, and Nd). These compounds feature two-dimensional planes of trigonal-planar CdP$_3$ units that separate tetrahedral CdP$_4$ layers; collectively, these sandwich edge-sharing triangular lattice planes of $Ln$P$_6$ octahedra. Diffuse X-ray scattering data reveal an underlying bond instability within the unique CdP$_3$ units that breaks rotational symmetry along one Cd$-$P bond direction, with long-range ordering being frustrated via emergent kagome-ice bond correlations. Our results establish $Ln$Cd$_3$P$_3$ as a rare class of materials where frustrated magnetism across a tunable rare-earth triangular network is embedded within a dopable semiconductor with a frustrated bond order instability., Comment: 11 pages, 5 figures
- Published
- 2025