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The current study aims to develop new clay bricks doped with metallic waste for radiation shielding applications. The aforementioned new bricks were fabricated with various metallic waste concentrations under a pressure rate reaching ≈114 MPa and firing temperature of 1100 °C. The impacts of the metallic waste and the firing temperature on the developed brick samples' physical, radiation shielding, and structural properties were studied. In order to identify the fabricated bricks' mineral content, the X-ray diffraction pattern was used. Additionally, the fabricated bricks' porosity and density were experimentally determined, where the porosity was reduced by 28.03%, while their densities increased by ≈ 10.5% by raising the concentration of metallic waste. The linear attenuation coefficient (LAC) for the developed brick was investigated experimentally using a NaI (Tl) scintillation detector over the 0.033–1.408 MeV energy interval. The measured LAC values were enhanced by increasing the concentrations of metallic waste within the fabricated bricks over the examined energy interval. The fabricated brick's LAC enhancement improves the gamma-ray shielding characteristics. Therefore, the fabricated bricks are a cheap and suitable choice for radiation protection applications.

The current work aims to fabricate metal oxide-doped (PbO, Fe2O3, MgO, and Al2O3, each of which boasts a purity of 99%) zinc barium borate glasses through the melt quenching technique at the 1000 °C melting temperature. The results showed that adding 5 mol.% of metal oxides PbO, Fe2O3, Al2O3, and MgO increases the density of the zinc barium borate glasses. Additionally, the fabricated glasses' mechanical properties were determined based on the Makishima-Mackenzie model, which proved that the highest mechanical properties were achieved for glasses doped with Al2O3 compounds. The mechanical moduli for the glasses doped with Al2O3 reach 80.95 GPa (Young), 59.90 GPa (bulk), 31.75 GPa (shear), and 102.23 GPa (longitudinal). Additionally, the Al2O3-doped glasses' microhardness reaches 4.77 GPa. Moreover, estimation of the fabricated glasses' gamma-ray shielding capacity utilized Monte Carlo simulation. The highest linear attenuation coefficients are 29.132, 19.906, 19.243, and 18.923 cm−1 obtained at 0.033 MeV for glasses dopped by PbO, Fe2O3, MgO, and Al2O3, respectively. Therefore, glasses doped with 5 mol.% of PbO have high gamma-ray shielding capacities followed by glasses doped by Fe2O3.

The amorphous glasses containing PbO, ZnO, MgO, and B2O3 have been fabricated using the melt quenching technique. The structural properties have been analysed using the Fourier-transform infrared (FTIR) and Raman spectroscopy. Derivative of Absorption Spectra Fitting (DASF) method have been used to estimate the band gap energy from the UV–Vis absorption data which decreases from 3.02 eV to 2.66 eV with increasing the concentration of the PbO.The four glass samples 0.284 and 0.826 MeV showed unique variations in terms of gamma attenuation ability. LZMB4 glass sample proved to be the mist effective in terms of shielding of gamma radiation as it requires little distance compared to LZMB3, LZMB2 and LZMB1 to attenuate. RPE revealed a raise with increase in the thickness of the material and reduces as the energy raises. TF is superior in LZMB1 compared to LZMB2, LZMB3 and LZMB4, confirming that, LZMB4 will attenuate better. The ZEff of the materials was seen falling as the energy increases, confirming that the linear attenuation coefficient of the glass materials decreases when the energy is increased. The results confirmed that, glass material LZMB4 is the best option especially for gamma radiation shielding applications compared to LZMB3, followed by LZMB2, then LZMB1.

This investigation developed a novel polyester composite based on the addition of zinc oxide (ZnO) of different sizes. We prepared nine samples Containing different percentages and sizes of ZnO as well as the control sample (Pol-ZnO0). The attenuation factors of Pol-micro ZnO were estimated using Phy-x software, while the HPGe detector and various gamma sources were used to experimentally measure the all-prepared composites. In terms of the two methods for micro composites, good agreement was observed. The linear attenuation coefficient (LAC) of Pol-ZnO20, Pol-ZnO40, and Pol-ZnO60, two more samples one with ZnO nanoparticles instead of microparticles, and the other with half microparticles and half nanoparticles (referenced as 0.5 M + 0.5 N) were determined. For all the Polyester composites and energies, the mixture of microparticles and nanoparticles had greater LAC values than each of the particles on their own. For example, the LAC values for the Pol-ZnO20 polymer at 1.330 MeV are 0.0836, 0.0888, and 0.0903 cm−1 for the microparticles, nanoparticles, and mixture, respectively. The values of the prepared polymer samples' radiation protection efficiency (RPE) against energy with a thickness of 2 cm was determined experimentally. The Pol-ZnO60 0.5 M + 0.5 N sample has the highest RPE out of all the samples, followed by its nanoparticle counterpart, and then its microparticle counterpart. On the other hand, the Pol-ZnO0 sample, the polymer with no ZnO content, at all energies has the lowest RPE, followed by the three Pol-ZnO20 samples.

We focused on the analytical solution of strong nonlinearity and complicated time-fractional evolution equations, including the Sawada-Kotera equation, Ito equation, and Kaup-Kupershmidt equation, using an effective and accurate method known as the Aboodh residual power series method (ARPSM) in the framework of the Caputo operator. Therefore, the Caputo operator and the ARPSM are practical for figuring out a linear or nonlinear system with a fractional derivative. This technique was effectively proposed to obtain a set of analytical solutions for various types of fractional differential equations. The derived solutions enabled us to understand the mechanisms behind the propagation and generation of numerous nonlinear phenomena observed in diverse scientific domains, including plasma physics, fluid physics, and optical fibers. The fractional property also revealed some ambiguity that may be observed in many natural phenomena, and this is one of the most important distinguishing factors between fractional differential equations and non-fractional ones. We also helped clarify fractional calculus in nonlinear dynamics, motivating researchers to work in mathematical physics.

The current study investigated Saudi Arabian oil fly ash impacts on Egyptian clay bricks' structural and radiation shielding properties. To produce the required bricks, crushed clay minerals from the Hafafit area were mixed with 0, 10, 20, 30, and 40 % wt.% Saudi Arabian oil fly ash and pressed at a pressure rate of 68.55 MPa. Identification of the minerals in the chosen clay was achieved via X-ray diffraction. Additionally, the material's morphology and chemical composition were determined through scanning electron microscope and energy-dispersive X-ray. The fabricated bricks' density was reduced by 36.3 % through increasing the concentration of fly ash from 0 to 40 wt%. Then, the fly ash addition's influence on the fabricated clay bricks' γ-ray shielding properties was investigated by Monte Carlo simulation, which found a reduction in the fabricated bricks' linear attenuation coefficient (LAC) by 41.2, 36.0, 33.8, and 33.8 % at the 0.059, 0.103, 0.662, and 1.252 MeV γ-ray energies, respectively. The LAC reduction caused an increase in the fabricated bricks' half-value thickness, transmission factor, and the equivalent thickness of the lead. Moreover, the thicker fabricated sample thicknesses were found to have high γ-ray shielding capacity and can thus be used in radiation shielding applications.

Within the framework of time fractional calculus using the Caputo operator, the Aboodh residual power series method and the Aboodh transform iterative method were implemented to analyze three basic equations in mathematical physics: the heat equation, the diffusion equation, and Burger's equation. We investigated the analytical solutions of these equations using Aboodh techniques, which provide practical and precise methods for solving fractional differential equations. We clarified the behavior and properties of the obtained approximations using the suggested methods through exact mathematical derivations and computational analysis. The obtained approximations were analyzed numerically and graphically to verify their high accuracy and stability against different related parameters. Additionally, we examined the impact of varying the fractional parameter the profiles of all derived approximations. Our results confirm these methods, efficacy in capturing the complicated dynamics of fractional systems. Therefore, they enhance the comprehension and examination of time-fractional equations in many scientific and technical contexts and in modeling different physical problems related to fluid mediums and plasma physics.

Abstract Cobalt-doped titania nanocomposites were fabricated to be utilized for radiation shielding aims. The chemical composition of the composites was measured using the energy-dispersive X-ray spectrometer. Moreover, the structure of the composites was evaluated using the X-ray diffractometer, and the morphology of the fabricated composites was presented using the scanning electron microscope. Furthermore, the γ-ray shielding properties were estimated using the Monte Carlo simulation between 0.059 and 2.506 MeV. The linear attenuation coefficient of the fabricated composites decreased by factors of 93% for all samples by raising the incident γ-energy between 0.059 and 2.506 MeV. Moreover, the partial replacement of the Ti4+ by Co3+ slightly enhanced the linear attenuation coefficient from 0.607 to 0.630 cm−1 when the Co3+ increased from 0 to 3.7 wt%. The improvement in the linear attenuation coefficient causes an enhancement in other radiation shielding properties.

In the present study, six silicone rubber doped by tellurium borate oxides were fabricated using the casting method. The densities of the fabricated silicon rubber-doped by tellurium borate oxides samples were measured using the Archimedes Method. Moreover, the linear attenuation coefficient of silicone rubber doped tellurium borate oxides samples was evaluated experimentally using the hyper pure germanium, and the recorded linear attenuation coefficient values were affirmed using the theoretical Phy-X program. The experimental measurements were performed using the narrow beam transmission method with radioactive isotopes Am-241, Cs-137, and Co-60 with energies of 59, 661, 1173, and 1332 keV. The linear attenuation coefficient values showed an enhancement by 4.73 times, 1.20 time, 1.17, time, and 1.17 time, respectively at gamma photon energies of 59, 661, 1173, and 1332 keV, when the TeO2 concentration increased in the fabricated composites from 0 to 50 wt%. The enhancement of the linear attenuation coefficient values has a positive effect on the transmission rate values where the half-value thickness and transmission rate were decreased accompanied by an increase in the RPE.

In this study, halloysite nanoparticles-doped epoxy resin was synthesised using the casting method. The MH-300A density metre revealed that the density of the fabricated composites changed from 1.132 to 1.317 g/cm3 as the halloysite nanoparticle concentration increased. The Fourier transform infrared was recorded for the synthesised composites. Furthermore, the γ-ray shielding properties of the synthesised composites were evaluated using Monte Carlo simulation and a theoretical programme, XCOM. The linear attenuation coefficient of the epoxy resin increased by 43% (at γ-energy of 15 keV) and 14% (at γ-photon energy of 662 keV) when the concentration of the halloysite nanoparticles was increased from 0 wt% to 40 wt%, respectively.

Abstract We developed new composites for photons shielding applications. The composite were prepared with epoxy resin, red clay and bismuth oxide nanoparticles (Bi2O3 NPs). In order to establish which ratio of red clay to Bi2O3 NPs provides the best shielding capabilities, several different ratios of red clay to Bi2O3 NPs were tested. The transmission factor (TF) was calculated for two different thicknesses of each sample. From the TF data, we found that epoxy resin materials have a high attenuation capacity at low energy. For ERB-10 sample (40%Epoxy + 50% Red clay + 10% Bi2O3 NPs), the TF values are 52.3% and 14.3% for thicknesses of 0.5 and 1.5 cm (at 0.06 MeV). The composite which contains the maximum amount of Bi2O3 nanoparticles (40%Epoxy + 50% Red clay + 10% Bi2O3 NPs, coded as ERB-30) has lower TF than the other composites. The TF data demonstrated that ERB-30 is capable of producing more effective attenuation from gamma rays. We also determined the linear attenuation coefficient (LAC) for the prepared composites and we found that the LAC increases for a given energy in proportion to the Bi2O3 NPs ratio. For the ERB-0 (free Bi2O3 NPs), the LAC at 0.662 MeV is 0.143 cm−1, and it increases to 0.805 cm−1 when 10% of Bi2O3 NPs is added to the epoxy resin composite. The half value layer (HVL) results showed that the thickness necessary to shield that photons to its half intensity can be significantly lowered by increasing the weight fraction of the Bi2O3 NPs in the epoxy resin composite from 0 to 30%. The HVL for ERB-20 and ERB-30 were compared with other materials such as (Epoxy as a matrix material and Al2O3, Fe2O3, MgO and ZrO2 as filler oxides in the matrix at 0.662 MeV. The HVL values for ERB-20 and ERB-30 are 4.385 and 3.988 cm and this is lower than all the selected epoxy polymers.

The substitution of La2O3 by Tb2O3 was studied for glass samples with a chemical composition described by: 75P2O5 + (25 − x) La2O3 + xTb2O3, where x = 5, 10, 15, 20 mol%. The mechanical properties were predicted via the Makishima–Mackenzie model. The study demonstrated that when increasing the Tb2O3 content from 5 to 20 mol%, the elastic moduli of the glasses decreased, while the dissociation energy, packing density, and micro-hardness increased. In addition, the radiation shielding properties were studied using the MCNP5 code, which was utilized to simulate the linear attenuation coefficient (LAC) of the investigated samples. Furthermore, the mass attenuation coefficients (MAC) of the glasses were determined. The highest MAC was reported for the sample with 20 mol% of Tb2O3 and decreased from 0.358 to 0.0515 cm2/g between 0.184 and 1.408 MeV. Furthermore, the effective atomic number (Zeff), equivalent atomic number (Zeq), exposure buildup factor (EBF), and the energy absorption buildup factor (EABF) of the glasses were calculated utilizing BXCOM software. The substitution of La2O3 by Tb2O3 was revealed to enhance the shielding features of the TLP samples. Resumen: Se estudió la sustitución de La2O3 por Tb2O3 para cinco muestras de vidrio con una composición química descrita por la fórmula: 75P2O5 + (25-x) La2O3 + xTb2O3, donde x = 5, 10, 15 y 20% mol. Se evaluaron las propiedades mecánicas y de protección contra la radiación de las muestras de vidrio investigadas. Las propiedades mecánicas se predijeron utilizando el modelo de Makishima-Mackenzie. El estudio demostró que al aumentar el contenido de Tb2O3 de 5 al 20% en moles, los módulos elásticos (Young, Bulk, Shear y longitudinal) de los vidrios disminuyeron, mientras que aumentaron la energía de disociación, densidad de empaquetamiento y microdureza. Además, se estudiaron las propiedades de protección contra la radiación de las muestras de vidrio investigadas utilizando el código de transporte de partículas N de Monte Carlo (MCNP-5). Se utilizó MCNP-5 para simular el coeficiente de atenuación lineal (LAC) de las muestras investigadas. Con base en el LAC simulado, se determinaron los coeficientes de atenuación de masa (MAC) de las gafas. El MAC más alto se obtuvo para la muestra de vidrio con el 20% en moles de Tb2O3 y disminuyó de 0,358 a 0,0515 cm2/g cuando se incrementó la energía del fotón gamma de 0,184 a 1,408 MeV. Además, el número atómico efectivo (Zeff), el número atómico equivalente (Zeq), el factor de acumulación de exposición (EBF) y el factor de acumulación de absorción de energía (EABF) de los vidrios se calcularon utilizando el software BXCOM. Se reveló que la sustitución de La2O3 por Tb2O3 mejora las propiedades de protección contra la radiación de las muestras investigadas.

ZnO, MoS2, MoS2/ZnO/glass, and ZnO/MoS2/glass thin films have been deposited on glass substrates by chemical bath deposition techniques (CBD). XRD results confirmed the formation of MoS2, ZnO, MoS2/ZnO/glass, and ZnO/MoS2/glass films. All the films have a hexagonal structure. The grain size of heterostructured (MoS2/ZnO/glass and ZnO/MoS2/glass) films is larger than pure (ZnO and MoS2) films. The band gap energy of ZnO, MoS2, MoS2/ZnO/glass and ZnO/MoS2/glass is 3.14 eV, 1.52 eV, 1.62 eV and 2.67 eV, respectively. Photoluminescence (PL) emission peaks of ZnO are observed in the visible region. When ZnO film is deposited on MoS2 film, PL peaks are shifted to smaller wavelengths. A very high PL intensity peak of MoS2 is observed. When MoS2 film was deposited on ZnO film the peak intensity was reduced. The average sheet resistivity of glass/MoS2, glass/ZnO, MoS2/ZnO/glass and ZnO/MoS2/glass films is 6.44 × 104, 7.89 × 103, 5.65 × 104, and 2.45 × 103 (ohm-m), respectively. These materials have potential applications in perovskite solar cells.

In the present work, untreated Iraqi sand with grain sizes varied between 100 and 200 μm was used to produce a colored glass sample that has shielding features against the low gamma-ray energy. Therefore, a weight of 70–60 wt % sand was mixed with 9–14 wt% B2O3, 8–10 wt% Na2O, 4–6 wt% of CaO, 3–6 wt% Al2O3, in addition to 0.3% of Co2O3. After melting and annealing the glass sample, the X-ray diffraction spectrometry was applied to affirm the amorphous phase of the fabricated glass samples. Moreover, the X-ray dispersive energy spectrometry was used to measure the chemical composition, and the MH-300A densimeter was applied to measure the fabricated sample's density. The Makishima-Makinzie model was applied to predict the mechanical properties of the fabricated glass. Besides, the Monte Carlo simulation was used to estimate the fabricated glass sample's radiation shielding capacity in the low-energy region between 22.1 and 160.6 keV. Therefore, the simulated linear attenuation coefficient changed between 10.725 and 0.484 cm−1, raising the gamma-ray energy between 22.1 and 160.6 keV. Also, other shielding parameters such as a half-value layer, pure lead equivalent thickness, and buildup factors were calculated.

In the current study, the PbO compound was used in order to optimize the gamma-ray shielding properties of the polypropylene polymers. A series of polypropylene doped PbO were performed using various PbO concentrations varied between 0 and 50 wt%. The experimental measurement for the density of the fabricated sample showed that the samples’ density varied between 0.902 ± 0.004 and 1.645 ± 0.007 g/cm3, raising the PbO doping concentration between 0 wt% and 50 wt%. Furthermore, the scanning electron microscope was utilized to illustrate the distribution and morphology of the fabricated polypropylene doped PbO concentrations. The gamma-ray shielding capacity of the fabricated polypropylene doped PbO was examined and evaluated experimentally using a sodium iodide scintillation detector and different point sources in the gamma-ray energy interval between 0.059 and 1.408 MeV. The experimental results were affirmed via the Geant4 code, which depended on the Monte Carlo simulation. The difference recorded between the experimental and Geant4 calculations for the fabricated samples shielding properties was lies in between ±4%. The recorded linear attenuation coefficient at gamma-ray energy of 0.244 MeV varied between 0.1148 and 0.5837 cm−1, raising the PbO doping concentration between 0 wt% and 50 wt%. Moreover, the half-value thickness decreased with increasing the PbO doping ratio.

The optical properties and radioactive attenuation parameters of doped tungsten oxide soda-lime-silica (SLS) waste glass were investigated in the current work. A novel series of lead-free transparent glass samples were manufactured with the possibility of developing radiation-absorbing glass shielding materials. The glass composition is WO3–Bi2O3–ZnO–B2O3-SLS. A new approach was employed in the utilization of soda-lime-silica (SLS) glass as an alternative for pure silicon dioxide having 74.1% of SiO2 and other elements in it. The optical properties were investigated with the help of a UV–Visible Spectrophotometer. The results for the optical properties showed that when WO3 content is increased in the glass structure, the Urbach energy ΔE and refractive index n, increase from 0.337 to 0.431 and 2.84 to 2.94 respectively, the optical basicity Λ also increase with the increase in WO3 while the energy optical band gap Eopt registered a decrease. The metallization criterion (M) confirmed that the current glass samples are nonmetallic (insulator) because Rm/Vm

The preparation of suitable materials with satisfactory nuclear and mechanical properties to shield the ionizing radiation is a major concern in design the radiation protection. In this work, a group of heavy concrete samples were prepared containing varying concentrations of Tungsten oxide, and the mechanical and radiation shielding properties of the resulting samples was studied using theoretical and experimental techniques. Good agreement between the experimental test and the theoretical data was confirmed at all examined energies. Using WO3 in the present concretes increases the density of specimens as well as the photons shielding capability. The increase in the amount of WO3 caused a reduction in the half value layer and an increase in the radiation protection efficiency for the prepared concretes. The linear attenuation coefficient (LAC) for the control concrete reduces from 0.665 to 0.127 cm−1 over the selected energy range, while it is reduced from 1.803 to 0.134 cm−1 and from 2.014 to 0.138 cm−1 for Conc-1 and Conc-2 samples. The mean free path results demonstrated that all the specimens with additive materials (i.e. WO3 and barite) have lower MFP than the control concrete. Thus, incorporating WO3 and barite into the concrete significantly decreases the MFP of the specimens. The high-density concrete (i.e. Conc-5) absorbs gamma photons more efficaciously than the lower density samples. The radiation protection efficiency (RPE) for Concr-5 is 99% at 0.122 MeV, which suggests that this concrete can stop almost all the incoming photons with low energy.

The melt quenching process have been used to fabricate the PbO–B2O3–CuO–CaO glass samples. The density increases with the inclusion of PbO to the samples. The optical band gap decreases as PbO mol% concentration rises. With the rise in PbO concentration, the refractive index, dielectric constant, and optical dielectric constant increase from 2.141 to 2.248, 4.583 to 5.052, and 3.583 to 4.052, respectively. The selected glass samples were found to be non-metallic in nature. The radiation shielding features were reported using EpiXS software from 0.122 to 1.458 MeV. The mass attenuation coefficient (μm) decreases as the sample constituent PbO is replaced with B2O3. The 50PbO–20B2O3–15CuO–15CaO glass sample, which is denoted by A4, has the highest μm in all photon energy. The radiation protection efficiency (RPE) drops dramatically while the energy increases from 0.122 to 1.458 MeV. The RPE of all glass samples is virtually 1 at 0.122 MeV, implying that they can all block all incoming radiation of 0.122 MeV. The prepared glasses possess promising radiation shielding properties. The largest relative reduction in transmission (RRT) values have been recorded to be 82% at 0.122 MeV. At low energies, the effect of PbO on photon transmission through the glass is significant, but as the energy increases, the effect of PbO on photon transmission decreases.

This study aims to experimentally analyze the radiation shielding capabilities of micro and nano bismuth oxide waste glasses by evaluating the effect of particle size, bismuth oxide content, and energy on the attenuation abilities of the samples. Waste glasses were powdered and combined with varying amounts of bismuth oxide with different particle sizes to test a total of seven waste glasses using the collimate gamma-ray technique. Energy dispersive X-ray analysis and a scanning electron microscope were used to determine the homogeneity of the samples. The experimental mass attenuation coefficient for the micro Bi2O3 samples was compared with values obtained from the XCOM program to determine their accuracy. From these values, the linear attenuation factor and the radiation protection efficiency of the waste glass samples were obtained. The results demonstrated that the smaller particle size of the glasses with nanoparticles led to an enhancement in their radiation shielding properties compared to the samples with microparticles. This improvement occurs because of the greater homogeneity provided by the smaller particles, allowing for more interactions between the glasses and the incoming radiation, leading to greater attenuation. The pure glass sample has a radiation protection efficiency (RPE) of 45.29% at 0.06 MeV, while the samples with Bi2O3 have RPE values ranging from 83.85 to 99.73%. The RPE for the sample with 30 w.t% micro Bi2O3 is equal to 39.43% at 0.356 MeV while the sample with 30 w.t% nano Bi2O3 is equal to 44.44%. Thus, it was concluded that the nano bismuth oxide samples are more effective at shielding gamma-rays than the micro bismuth oxide waste glasses.

Abstract A series of six samples were prepared based on the chemical composition of 65B2O3 + 20ZnO + (15-x)LiF + xSnO2 (where x = 0, 0.25, 0.5, 0.75, 1, and 1.25 mol%) to study the role of SnO2 on enhancing the optical and radiation attenuation capacity of the prepared glasses. The preparation of the glass series was performed using the melt quenching method at 1100 °C for 60 min. The density of the fabricated samples was measured using an MH-300A densimeter. The optical parameters of the fabricated glasses were calculated based on the spectrum recorded by a Cary 5000 UV–Vis–NIR double beam spectrophotometer in a wavelength range of 200 to 3000 nm. Furthermore, Monte Carlo simulation code and the XCOM online database were used to estimate the gamma-ray shielding capacity of the fabricated samples from 0.244 to 2.506 MeV. The results show enhanced gamma-ray shielding capacity due to the replacement of LiF by SnO2. The linear attenuation coefficient at 0.244 MeV was enhanced from 0.352 to 0.389 cm−1. The half-value thickness of the investigated glasses decreased from 1.967 to 1.784 cm when the increasing addition of SnO2 from 0 to 1.25 mol%.

The nonlinear propagation of different types of DANW acoustic dust nonlinear waves has been investigated in a magnetized dusty plasma consisting of negatively charged dust particles, Maxwellian electrons, and ions. Application of the standard reductive perturbation theory is used to derive the corresponding three-dimensional nonlinear a complex Ginzburg–Landau (3D-CGLE) equation which governs the dynamics of the dust-acoustic wave packets. The stationary analytical solutions of the CGLE are numerically analysed where the effect of the physical parameters of the dusty plasma model on the wave’s propagation is taken into account. It has been found that there can be a relationship between the appearance of soliton waves and electromagnetic waves, as well as between shock-like waves and periodic travelling waves. Expression of the importance of these findings is the cornerstone of explaining the true relationship between the propagation of nonlinear waves in the physics of space, for example, the Earth’s magnetic field.

In this study, we investigated the impact of micro- and nano-sized barium oxide addition on the radiation-shielding properties of red clay tiles mixed with waste marble and different sizes of BaO (micro- or nanoparticles) for comparative analysis. The linear attenuation coefficients (LAC) of the prepared samples were measured using an HPGe detector between 0.060 and 1.333 MeV. Moreover, a comparison was made between the experimental micro-composites and values obtained by Phy-X software. The results revealed that the red clay/waste marble tile composites doped with nano-sized BaO demonstrated superior radiation-shielding properties compared to those doped with micro-sized BaO. At 1.33 MeV, WR-20mBaO (containing 20 wt % micro-sized BaO) and WR-20nBaO (containing 20 wt % nano-sized BaO) exhibited HVL values of 4.75 cm and 4.25 cm, respectively. The lower HVL value of WR-20nBaO indicates superior radiation-shielding performance, highlighting the potential benefits of using nano-sized BaO as a radiation-shielding additive. Our findings also demonstrated that increasing the amount of BaO deposited onto red clay mixed-waste marble resulted in improved radiation-shielding properties. Our study demonstrates that adjusting the concentration of BaO is a viable strategy for enhancing the radiation attenuation properties of red clay tiles. In addition, the addition of waste marble to the tiles enhances its mechanical properties, and it is also positively recycled in community service.

In this paper, we consider two different polyethylene filter plates coated with multi-walled carbon nanotubes (MWCNTs) and synthesized by surface molecularly imprinted technique, namely plate@MWCNTs@MIPs (PMIPs) and plate@MWCNTs@NIPs (PNIPs). They were used as effective adsorbents for selective adsorption and detection of prednisone (PS) in cosmetics. As a first assessment to investigate the performance of these adsorbents, the PS adsorption isotherms were analyzed using an advanced multilayer statistical physics model at three different temperatures ( 293, 303 and 313 K) and over a wide PS concentration range (0.09–1.5 mg/mL). The obtained analyzing results from the best fitting model showed that the PMIPs adsorbent displayed a high adsorption capacity (27.4 mg/g) due to the contribution of the number of PS molecules per site (nm) combined with the receptor sites density (Dm), which displayed a high recognition ability due to the adsorption energy. Modeling analysis process indicated that the PS molecules could be anchored on the PMIPs and PNIPs surfaces via a non-parallel orientation where the adsorption is a multi-molecular process. The calculated adsorption energies globally varied from 4.51 to 7.62 kJ/mol, confirming the physical nature of the adsorption process for the studied systems, which is beneficial in cosmetics. Finally, three thermodynamic potentials (entropy, internal energy and free enthalpy) were evaluated for a better understanding of the physico-chemical behavior of the adsorption process.

Geant4 simulation was applied to correct the coincidence summing (CS) effect in detecting a volumetric γ-ray sources, and this technique was applied to a152Eu standard sources. The radioactive sources were a liquid cylindrical, rectangular, and Marinelli beaker shapes of different volume for each one. Radionuclide track (RT) including coincidence summing and monoenergetic track without coincidence summing. The results obtained from two approaches compared with the experimental data and the modified KORSUM code for cylindrical γ-ray source. The comparison showed that the adopted method in this investigation is useful for coincidence summing corrections for a voluminous γ-ray sources.Moreover, this technique requires far less computation time than the techniques that depend on the calculation of total efficiency.

Owing to their low dielectric loss and high permittivity values, dielectric ceramics have garnered a lot of interest from the scientific and industrial sectors. These properties allow for their downsizing and use in a variety of electronic circuits. This present work focuses on the impact of the substitution of W6+ with Mo6+ on the structural and dielectric features of the crystalline phases in a similar TTB structure within the Ba0.54Na0.46Nb1.29W(0.37−x)MoxO5 system, with 0 ≤ x ≤ 0.33 mol%. These crystalline phases were elaborated using the conventional solid-state reaction method and analyzed with XRD, Raman, and dielectric techniques. The Rietveld refinement method showed that all these phases are characterized by tetragonal structure and the P4bm space group. The Raman spectra corresponded well to a TTB-like structure, and all the bands were assigned. The dielectric measurements of the prepared ceramic samples facilitated the determination of their phase transition temperature (Tc) and the dielectric responses. This investigation focused on determining dielectric permittivity (ε′) and its correlation with increases in MoO3 content in the ceramic structure.

Three different samples were synthesized based on polyepoxide resin, a solidifying agent, and a Bi2O3 doping compound. The polyepoxide resin and solidifying agent were added in a 2:1 ratio by weight and the Bi2O3 compound was added in ratios of 0, 5, and 10 wt. %. The density of the synthesized composites was measured using an MH-300A densimeter with an uncertainty in measurement of 0.001 g/cm3. The measurements showed that the density of the fabricated composite varied from 1.103 g/cm3 to 1.20 g/cm3 when the reinforcing Bi2O3 compound was raised from 0 wt. % to 10 wt. %. Furthermore, the γ-ray shielding parameters were evaluated based on the simulated mean track length of γ-photons inside the synthesized composites using MCNP-5 code. The simulated results show an enhancement in the shielding parameter when increasing the Bi2O3 concentration, where the linear attenuation coefficient values increased from 0.101 cm−1 to 0.118 cm−1 as the Bi2O3 concentration increased from 0 to 10 wt. %. The increase in the LAC has a positive effect on the other shielding properties.

This article contains detailed evaluation of thermal, mechanical, radiation shielding and thermoluminescence (TL) properties of heavy metal oxide (HMO) borosilicate glasses having composition xBi2O3- (60-x) B2O3- 20SiO2- 12ZnO- 8BaO (with x= 0, 2, 4, 6, 8, 10 and 12 mol%). Gamma shielding capacity of these glasses was examined in terms of mass attenuation coefficient (MAC) values, exposure and energy absorption build- up factor (EBF/EABF). The experimental MAC values were found to agree well with the theoretical results obtained from Photon Shielding and Dosimetry (PSD/Phy-X) software. Geometric Progression fitting method was used for the calculation of build- up factors in the photon energy region of 0.015-15 MeV with the help of five parameters (a, b, c, d and Xk). The pattern followed by build-up factors with the gamma energy and their variation for different penetration depths up to 40 mfp was observed and analysed. High values of equivalent atomic number and build up factors for high bismuth sample (12 mol%) gave evidence for its improved radiation shielding capacity. Furthermore, thermoluminescence study was done to assess the suitability of the synthesized glasses as a radiation dosimeter in the gamma dose range of 0.25 – 30 kGy. Here, 5 kGy irradiation exhibited major quenching in TL signal on adding bismuth to the glass network. TL performance of ZBiB-8 was noteworthy with charges trapped in high temperature trap centres with longer lifetime. TL dose response curve of ZBiB-8 showed good linearity in the dose range of 0.25 – 5 kGy. Fading analysis was done for this sample to find the loss in TL intensity in the course of one month. Heating the ZBiB-8 sample to 323 K (50 0C) for 15 min was found to be a proper annealing condition for re-using it as a thermoluminescence dosimeter (TLD).

The purpose of this effort is to create and characterize new borate-based glass samples in terms of their physical, structural, and gamma ray shielding capabilities. The density of the current samples, was examined experimentally and has a range of 2.2057–2.9055 g/cm3. The physical parameters such molar volume, ionic concentration, the volume of boron atoms per mole, optical basicity, and oxygen packing density (OPD) are computed by following the established approach. The XRD spectra is also recorded and there are two broad humps which shows that the structure of fabricated glasses is amorphous in nature. Moreover, the FTIR spectra were recorded in the spectral range 1600–400 cm−1. Using the Phy-X/PSD online tool, the gamma ray shielding capabilities of the manufactured glasses were examined. At the highest energy, LiKBTe0 has mass attenuation coefficient (MAC) equal to 0.039 cm2/g and LiKBTe20 has a MAC equal to 0.038 cm2/g. At 0.347 MeV, the LiKBTe20 sample has effective atomic number (Zeff) of 11.67 and the LiKBTe0 sample has a Zeff of 7.85, which is due to Te’s much greater atomic number compared to B. Half value layer (HVL) increases with increasing energy. When considering which glass best boosts shielding qualities, 10 Li2O- 20 K2O − 50 B2O3 – 20TeO2 glass comes out on top.

This study aims to evaluate the effect of particle size on the mass dependent attenuation ability of bulk and nanoparticles PbO. The mass attenuation coefficient, or MAC, of the samples was experimentally calculated using the HPGe detector at various selected energies (between 0.1218 MeV and 1.408 MeV). The experimental data were then compared to theoretical results obtained using the XCOM software to examine the validity of the experimental values. The two methods were found to strongly agree with each other. The half value layer (HVL) and tenth value layer (TVL) of the two samples were determined against increasing photon energies. The mass of the bulk PbO and PbO nanoparticles needed to attenuate half and 90% of the incoming radiation was evaluated. For both parameters, the results demonstrated that the mass needed to absorb the same amount of radiation was lower for the PbO nanoparticles, meaning that the PbO nanoparticles are more desirable in applications when mass is a concern, such as when fabricating a lead apron for instance.

The current investigation deals with the fabrication of two various composite-based bentonite clay minerals. The characterization and radiation shielding parameters for the two fabricated composites (calcinated and ball-milled calcinated bentonite) were studied. X-ray diffraction was utilized to illustrate the crystalline phase of the fabricated composites. Furthermore, Williamson and Hall’s method was used to determine the grain size of both the calcinated and ball-milled calcinated composites. The particle size, according to the calculation was 39.84 nm, and the strain was 0.216 for the calcinated bentonite, while the particle size of the ball-milled bentonite was 26.96 nm, and the strain was 0.219. In comparison, the transmission electron microscope (TEM) showed that the grain size of the calcinated bentonite was 566.59 nm, and it was 296.21 nm for the ball-milled calcinated bentonite. The density of the fabricated composites varied between 1.60 and 186 g/cm3 for the calcinated bentonite and between 1.83 and 2.075 g/cm3 for the ball-milled calcinated bentonite. Moreover, the radiation shielding capacity of the composites was analyzed. The results show that the gamma-ray attenuation capacity of ball-milled calcinated bentonite is high compared to ordinary calcinated bentonite. These results confirm the effect of particle grain size on optimizing the gamma-ray shielding capacity of the fabricated materials.

In the present investigation, La1−xGdxCr1−yFeyO3 nanoparticles were synthesized using facile micro-emulsion technique and monitored by XRD (X-ray diffraction), VSM (vibrating sample magnetometer), SEM (scanning electron microscopy), EDS (energy dispersive spectroscopy) and dielectric measurements. XRD analysis revealed the effective exchange of Fe and Gd ions into the regular structure of LaCrO3 and La1−xGdxCr1−yFeyO3 have orthorhombic crystal structure and crystallite size was in 30.20–34.1 nm range. The particles were of flakes morphology and EDX analysis revealed the purity and Fe and Gd ions incorporation into the structure of LaCrO3 and La1−xGdxCr1−yFeyO3. The magnetic hysteresis loop showed the paramagnetic behavior at room temperature and dielectric properties of La1−xGdxCr1−yFeyO3 were significantly affected with Fe and Gd contents. The PCA (photocatalytic activity) was performed against MB (methylene blue) dye under visible light exposure and up to 68% MB dye destruction was observed within 45 min of exposure. Results revealed the LaCrO3 properties are tunable with Fe and Gd doping to prepare catalyst active under solar light exposure.

For the near-infrared emission, Er3+ and Er3+/Yb3+ co-activated borate based glass hosts were synthesized by the method of melting andquenching. The emission intensity was maximum for 0.5 mol% Er3+ singly activated glass in the near-infrared (NIR) region covering the telecommunication window. The 2 mol% of Yb3+ co-doping enhanced the emission gain cross-section of the glass by two times contrast to 0.5 mol% Er3+ loaded glass. This enhancement shifted to lower spectral regions when P increased from 0 to 1. The effect of Yb3+ loading on the gain cross-section of the Er3+ co-activated glasses was analyzed using the McCumber theory. The results showed that the 0.5Er2Yb glass has a flat gain in the range of 1460–1640 nm, this suggest a lower pump threshold is enough to perform the laser functioning of a 1530 nm band and optical window of telecommunication applications.

The crystal structure and magnetic state of the (1 − x)BiFeO3-(x)BiMnO3 solid solution has been analyzed by X-ray diffraction using lab-based and synchrotron radiation facilities, magnetization measurements, differential thermal analysis, and differential scanning calorimetry. Dopant concentration increases lead to the room-temperature structural transitions from the polar-active rhombohedral phase to the antipolar orthorhombic phase, and then to the monoclinic phase accompanied by the formation of two-phase regions consisting of the adjacent structural phases in the concentration ranges 0.25 < x1 < 0.30 and 0.50 ≤ x2 < 0.65, respectively. The accompanied changes in the magnetic structure refer to the magnetic transitions from the modulated antiferromagnetic structure to the non-colinear antiferromagnetic structure, and then to the orbitally ordered ferromagnetic structure. The compounds with a two-phase structural state at room temperature are characterized by irreversible temperature-driven structural transitions, which favor the stabilization of high-temperature structural phases. The magnetic structure of the compounds also exhibits an irreversible temperature-induced transition, resulting in an increase of the contribution from the magnetic phase associated with the high-temperature structural phase. The relationship between the structural parameters and the magnetic state of the compounds with a metastable structure is studied and discussed depending on the chemical composition and heating prehistory.

The paper discusses the formation of Ta2O5 pillars with Ni tips during thin porous anodic alumina through-mask anodization on Si/SiO2 substrates. The tantalum nanopillars were formed through porous masks in electrolytes of phosphoric and oxalic acid. The Ni tips on the Ta2O5 pillars were formed via vacuum evaporation through the porous mask. The morphology, structure, and magnetic properties at 4.2 and 300 K of the Ta2O5 nanopillars with Ni tips have been studied using scanning electron microscopy, X-ray diffraction, and vibrating sample magnetometry. The main mechanism of the formation of the Ta2O5 pillars during through-mask anodization was revealed. The superparamagnetic behavior of the magnetic hysteresis loop of the Ta2O5 nanopillars with Ni tips was observed. Such nanostructures can be used to develop novel functional nanomaterials for magnetic, electronic, biomedical, and optical nano-scale devices.

Using the auto combustion flash method, Ni1−x+2Mgx+2Fe2+3O4 (x = 0, 0.2, 0.6, 0.8 and 1) nano-ferrites were synthesized. All samples were thermally treated at 973 K for 3 h. The structural analysis for the synthesized samples was performed using XRD, high-resolution transmission electron microscopy (HRTEM), and FTIR. Scanning electron microscopy (SEM) was undertaken to explore the surface morphology of all the samples. The thermal stability of these samples was investigated using thermogravimetric analysis (TGA). XRD data show the presence of a single spinel phase for all the prepared samples. The intensity of the principal peak of the spinel phase decreases as Mg content increases, showing that Mg delays crystallinity. The Mg content raised the average grain size (D) from 0.084 μm to 0.1365 μm. TGA shows two stages of weight loss variation. The vibrating sample magnetometer (VSM) measurement shows that magnetic parameters, such as initial permeability (μi) and saturation magnetization (Ms), decay with rising Mg content. The permeability and magnetic anisotropy at different frequencies and temperatures were studied to show the samples’ magnetic behavior and determine the Curie temperature (TC), which depends on the internal structure. The electrical resistivity behavior shows the semi-conductivity trend of the samples. Finally, the dielectric constant increases sharply at high temperatures, explained by the increased mobility of charge carriers, and decreases with increasing frequency.

In the present investigation, ZnO films co-doped with Mn and La were synthesized by the sol–gel technique. XRD analysis revealed that ZnO had a hexagonal structure. Mixed hexagonal and cubic phases appeared in ZnO containing Mn (1%) and La (1.5%). The grain size, d-spacing, unit cell, lattice parameters, atomic packing fraction, volume, strain, crystallinity, and bond length of co-doped ZnO films were determined as a function of doped ion contents. Through UV analysis, it was found that pristine ZnO had Eg = 3.5 eV, and it decreased when increasing the doping concentration, reaching the minimum value for the sample with 1% Mn and 1% La. The optical parameters of the films, such as absorption, transmittance, dielectric constants, and refractive index, were also analyzed. DSSCs were fabricated using the prepared ZnO films. For pure ZnO film, the values were: efficiency = 0.69%, current density = 2.5 mAcm−2, and open-circuit voltage = 0.56 V. When ZnO was co-doped with Mn and La, the efficiency increased significantly. DSSCs with a ZnO photoanode co-doped with 1% Mn and 1% La exhibited maximum values of Jsc = 4.28 mAcm−2, Voc = 0.6 V, and efficiency = 1.89%, which is 174% better than pristine ZnO-based DSSCs. This material is good for the electrode of perovskite solar cells.

A sensitization procedure is used to enhance the thermoluminescence (TL) sensitivity of phyllite to emit radiation. Phyllite is a type of foliated metamorphic rock made from slate. This study examines naturally grown phyllite rock, which had not been previously studied. Using a Thermo 3500 manual reader, the TL sensitivity of phyllite as a function of dosage was measured. The doses required to perform this study were administered using a 60Co source. The statistical regression test of the data had a significance level of p < 0.05. The study also included thermal and pre-dose effects. Using the sensitization procedure, the nonlinearity in TL dose–response was removed, and the sensitivity was increased 44 times that of its original value. The fading study showed a dependence on the test dose. According to the obtained results, the combination of linear dose–response and high sensitivity to gamma radiation makes phyllite an important rock for dating and retrospective dosimetry.

Thin films of beryllium and gold that are several tens of nanometers thick were obtained, for the first time, on silicon and quartz substrates by the ion-beam method with tenfold alternation of deposition and partial sputtering of the nanosized metal layer. Scanning electron and atomic force microscopy indicate the predominant lateral growth of nanosized metal layers along the substrate surface. Optical spectra indicate the suppression of the localized plasmon resonance. The growth of the film occurs under the influence of the high-energy component of the sputtered metal atoms’ flux. The main role in the formation of the nanosized metal film is played by the processes of the elastic collision of incident metal atoms with the atoms of a substrate and a growing metal film. Metal films that are obtained by the tenfold application of the deposition–sputtering of a nanoscale metal layer are characterized by stronger adhesion to the substrate and have better morphological, electrical, and optical characteristics than those that are obtained by means of direct single deposition.

The mechanical and radiation shielding properties for the PbO–MoO3–Li2O–B2O3 glass system were theoretically investigated in this paper. The PbO–MoO3–Li2O–B2O3 glass system (coded as investigated glasses) was fabricated using the melt quenching mechanism. The optical packing density (OPD) increases from 75.563 to 84.366, and oxygen molar volume (OMV) decreases from 13.234 to 11.853 cm3/mol when increasing the PbO concentration. The values of elastic moduli decreased from 47.06 to 39.67 GPa for Young, from 33.51 to 32.41 GPa for bulk, from 19.82 to 16.29 GPa for shear and from 59.94 to 54.14 GPa for longitudinal moduli as the PbO is increased. The radiation attenuation characteristics were reported at the photon energies used in diagnostic radiology. The mass attenuation coefficient (MAC) was evaluated using the three photoatomic data libraries EPICS2017, EPDL97, and XCOM, available in the EpiXS and Phy-X programs. The MAC for the five investigated glasses at 20 keV was much higher than the MAC at 40, 60 and 80 keV. The MAC for investigated glasses increased with the addition of PbO, with Pb-S1 demonstrating the lowest MAC, and Pb-S5 demonstrating the highest MAC. Additionally, the rate of the increment of MAC at 20 keV as the concentration of PbO increased was higher than that at 40, 60 and 80 keV. The effective atomic number (EAN) was determined using Phy-X program. The EAN follows the trend: Pb-S5 > Pb-S4 > Pb-S3 > Pb-S2 > Pb-S1. The EAN results proved that the glass with low amounts of B2O3 and higher amounts of PbO had good attenuation features. The EAN had the maximum values of 73.55–76.67 at 20 keV, whereas the lowest values occurred at 80 keV and varied between 53.63 and 63.39. The half-value layer (HVL) results showed that the Pb-S1 glass had the greatest HVL, while Pb-S5 had the least. There is a higher discrepancy between the tenth-value layer values at 80 keV than at 20 keV. At 20 keV, the difference between the highest and lowest TVL values (Pb-S1 and Pb-S5) was only 0.004 cm, while the difference at 80 keV was 0.152 cm. Pb-S5 is the most space-efficient radiation shield.

This research work aims to investigate the radiation shielding ability of a Yb3+-doped calcium borotellurite glass system. The system has the basic composition of CaF2–CaO–B2O3–TeO2–Yb2O3 but is denoted as TeBYbn for simplicity. The effect of increasing the TeO2 content in the glasses from 10 to 54 mol% was investigated, with five different chosen compositions and densities. The Phy-X/PSD program was used to investigate the mass attenuation coefficient (µ/ρ) of the samples. The mass attenuation coefficients were theoretically determined by using an online software for the calculation of shielding parameters. Other parameters were then calculated and analyzed, such as the linear attenuation coefficient (µ), transmission factor (TF), radiation protection efficiency (RPE), effective atomic number (Zeff), and mean free path (MFP). TeBYb5, the glass with the greatest TeO2 content, was shown to have the greatest µ/ρ; however, at greater energies, the differences between the values are practically negligible. µ was shown to increase with density, such as from 0.386 cm−1 to 0.687 cm−1 for TeBYb1 and TeBYb5 at 0.284 MeV, respectively. The least TF was found for samples with a thickness of 1.5 cm, proving an inverse correlation between the thickness of the sample and the TF. The HVL and TVL of the glasses decreased as the density of the samples increased, which means that TeBYb1 is the least effective out of the investigated glasses. The five samples proved to have a lower MFP than some other shielding glasses, demonstrating their capabilities as radiation shields. Based on the calculated parameters, TeBYb5 indicated the greatest photon attenuation ability.

Coronavirus (COVID-19), caused by the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2), has been identified as a deadly pandemic. The genomic analysis of SARS-CoV-2 is performed using a reverse transcription-polymerase chain reaction (RT-PCR) technique for identifying viral ribonucleic acid (RNA) in infected patients. However, the RT-PCR diagnostic technique is manually laborious and expensive; therefore, it is not readily accessible in every laboratory. Methodological simplification is crucial to combat the ongoing pandemic by introducing quick, efficient, and affordable diagnostic methods. Here, we report how microcantilever sensors offer promising opportunities for rapid COVID-19 detection. Our first attempt was to capture the single-stranded complementary DNA of SARS-CoV-2 through DNA hybridization. Therefore, the microcantilever surface was immobilized with an oligonucleotide probe and detected using complementary target DNA hybridization by a shift in microcantilever resonance frequency. Our results show that microcantilever sensors can discriminate between complementary and noncomplementary target DNA on a micro to nanoscale. Additionally, the microcantilever sensors’ aptitude toward partial complementary DNA determines their potential to identify new variants of coronavirus. Therefore, microcantilever sensing could be a vital tool in the effort to extinguish the spreading COVID-19 pandemic.