1. Photoelectric response in sandwich structures based on condensed layers of Ag2S quantum dots passivated with thioglycolic acid
- Author
-
Vladimir S. Gurchenko, Alim S. Mazinov, Mikhail S. Smirnov, Irina G. Grevtseva, Lolita P. Nesterenko, and Oleg V. Ovchinnikov
- Subjects
silver sulfide ,activation energy ,charge carrier mobility ,conduction mechanisms ,schottky barrier ,Chemistry ,QD1-999 - Abstract
The study is aimed at developing a technique for forming a structure with a Schottky barrier in the form of a mltilayer Al-Ag2S-ITO sandwich structure, which includes a condensate of colloidal Ag2S quantum dots passivated with thioglycolic acid molecules (Ag2S/TGA QDs). The spectral properties were studied using a USB2000+ spectrometer (Ocean Optics, USA) with a USB-DT light source (Ocean Optics, USA). Electrophysical and photoelectric properties of the structures were studied using a Keysight B1500A semiconductor device analyzer (Keysight tech, USA). The study of the temperature dependences of the properties in the temperature range from 300 to 360 K was carried out in a Shielded room (Faraday cage) placed in a muffle furnace. It was found that the conductivity of the Al-Ag2S-ITO structure is mostly governed by the Schottky barrier at the Al-condensed Ag2S QDs film junction. At the junction between the condensed Ag2S QDs film and Al, signs of the formation of a rectifying contact were found. Under the action of the optical radiation with a wavelength of 650 nm and less, which corresponds to the most probable exciton transition in the UV-Vis absorption of Ag2S/TGA QDs, an increase in the current was found for the negative branch of the J-V curve.
- Published
- 2023
- Full Text
- View/download PDF