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The main theme of the thesis is to design new porous-crystalline materials for application in carbon dioxide capture. This class of porous materials is highly crystalline and has pores like a sponge but which are much smaller. A library of new crystalline materials was designed through judicious selection of their chemical components to be specifically useful for this particular application. These materials have promising features towards achieving the ultimate goal of capturing carbon dioxide, by virtue of adding groups in their interior to specifically interact with the gas. An understanding of the structural chemistry of these new compounds is demonstrated.

Wind-flow dynamics has been extensively studied over horizontally uniform canopies, but agricultural plantations structured in rows such as vineyards have received less attention. Here, the wind flow over a vineyard is studied in neutral stratification from both large-eddy simulation (LES) and in situ measurements. The impact of row structure on the wind dynamics is investigated over a range of wind directions from cross-row to down-row, and a typical range of row aspect ratio (row separation/height ratio). It is shown that the mean flow over a vineyard is similar to that observed in uniform canopies, especially for wind directions from cross-row to diagonal. For down-row winds, the mean flow exhibits noticeable spatial variability across each elementary row-gap pattern, as the wind is channeled in the inter-row. This spatial variability increases with the aspect ratio. With down-row winds the turbulent structures are also more intermittent and generate larger turbulent kinetic energy and momentum flux. The displacement height and roughness length of the vineyard vary with the aspect ratio in a way similar to their variation with canopy density in uniform canopies. Both parameters take smaller values in down-row wind flow, for which the canopy appears more open. The analysis of velocity spectra and autocorrelation functions shows that vineyard canopies share similar features to uniform canopies in terms of turbulent coherent structures, with only minor changes with wind direction.