Search

Electrochemical molecularly imprinted polymers (e-MIPs) were grafted for the first time as a thin layer to the surface of a gold electrode to perform trace level electroanalysis of benzo(a)pyrene (BaP). This was achieved by controlled/living radical photopolymerization of a redox tracer monomer (ferrocenylmethyl methacrylate, FcMMA) with ethylene glycol dimethacrylate in the presence of benzo(a)pyrene as the template molecule. For that purpose, a novel photoiniferter-derived SAM was first deposited on the gold surface. The SAM formation was monitored by cyclic voltammetry and electrochemical impedance spectroscopy. Then, the “grafting from” of the e-MIP was achieved upon photoirradiation during a controlled time. Differential pulse voltammetry was used to quantify BaP in aqueous solution by following the modification of the signal of FcMMA. A limit of detection of 0.19 nM in water and a linear range of 0.66 nM to 4.30 nM, were determined, thus validating the enhancement of sensitivity induced by the close contact between the e-MIP and the electrode, and the improved transfer electron.

Abstract Due to the pseudo-scalar nature of the axion-like particle (ALP), the CP-conserving production of two Higgs bosons via the ALP necessarily involves an additional Z or γ boson. We examine the existing constraints from di-Higgs searches at Run 2 of the LHC and find that, despite the presence of extra objects in the final state, these searches are sensitive to a combination of ALP couplings to gluons and three-bosons in the TeV scale range. Additionally, we propose a specialized search strategy incorporating an energetic leptonic Z boson. This refined ALP-induced production process would allow for the identification of the h h → 4 b-jet final state and could potentially probe the TeV scale using data from Run 2 of the LHC. This production process can also occur through a coupling between the top quark and the ALP. We translate the current constraints on di-Higgs production into new limits on the ALP-top coupling.

Abstract In this article we study the phenomenological implications of multiple Higgs boson production from longitudinal vector boson scattering in the context of effective field theories. We find compact representations for effective tree-level amplitudes with up to four final state Higgs bosons. Total cross sections are then computed for scenarios relevant at the LHC in which we find the general Higgs Effective Theory (HEFT) prediction avoids the heavy suppression observed in Standard Model Effective Field Theory (SMEFT).

Abstract We introduce a new diagrammatic approach to perturbative quantum field theory, which we call flow-oriented perturbation theory (FOPT). Within it, Feynman graphs are replaced by strongly connected directed graphs (digraphs). FOPT is a coordinate space analogue of time-ordered perturbation theory and loop-tree duality, but it has the advantage of having combinatorial and canonical Feynman rules, combined with a simplified iε dependence of the resulting integrals. Moreover, we introduce a novel digraph-based representation for the S-matrix. The associated integrals involve the Fourier transform of the flow polytope. Due to this polytope’s properties, our S-matrix representation exhibits manifest infrared singularity factorization on a per-diagram level. Our findings reveal an interesting interplay between spurious singularities and Fourier transforms of polytopes.

I review the main results leading to Factorization of QCD amplitudes in momentum space and, in view of the analogue results in coordinate space, the one-loop jet function in coordinate space is computed and Landau's equations for the Abelian radiative corrections to it are studied. Furthermore, two of these radiative corrections are reduced in quadrature.

Although the neural systems that underlie spoken language are well-known, how they adapt to evolving social cues during natural conversations remains an unanswered question. In this work we investigate the neural correlates of face-to-face conversations between two individuals using functional near infrared spectroscopy (fNIRS) and acoustical analyses of concurrent audio recordings. Nineteen pairs of healthy adults engaged in live discussions on two controversial topics where their opinions were either in agreement or disagreement. Participants were matched according to their a priori opinions on these topics as assessed by questionnaire. Acoustic measures of the recorded speech including the fundamental frequency range, median fundamental frequency, syllable rate, and acoustic energy were elevated during disagreement relative to agreement. Consistent with both the a priori opinion ratings and the acoustic findings, neural activity associated with long-range functional networks, rather than the canonical language areas, was also differentiated by the two conditions. Specifically, the frontoparietal system including bilateral dorsolateral prefrontal cortex, left supramarginal gyrus, angular gyrus, and superior temporal gyrus showed increased activity while talking during disagreement. In contrast, talking during agreement was characterized by increased activity in a social and attention network including right supramarginal gyrus, bilateral frontal eye-fields, and left frontopolar regions. Further, these social and visual attention networks were more synchronous across brains during agreement than disagreement. Rather than localized modulation of the canonical language system, these findings are most consistent with a model of distributed and adaptive language-related processes including cross-brain neural coupling that serves dynamic verbal exchanges.

Effective Field Theories (EFTs) constructed as derivative expansions in powers of momentum, in the spirit of Chiral Perturbation Theory (ChPT), are a controllable approximation to strong dynamics as long as the energy of the interacting particles remains small, as they do not respect exact elastic unitarity. This limits their predictive power towards new physics at a higher scale if small separations from the Standard Model are found at the LHC or elsewhere. Unitarized chiral perturbation theory techniques have been devised to extend the reach of the EFT to regimes where partial waves are saturating unitarity, but their uncertainties have hitherto not been addressed thoroughly. Here we take one of the best known of them, the Inverse Amplitude Method (IAM), and carefully following its derivation, we quantify the uncertainty introduced at each step. We compare its hadron ChPT and its electroweak sector Higgs EFT applications. We find that the relative theoretical uncertainty of the IAM at the mass of the first resonance encountered in a partial-wave is of the same order in the counting as the starting uncertainty of the EFT at near-threshold energies, so that its unitarized extension should \textit{a priori} be expected to be reasonably successful. This is so provided a check for zeroes of the partial wave amplitude is carried out and, if they appear near the resonance region, we show how to modify adequately the IAM to take them into account.