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1. Iridium-Catalyzed Cycloaddition of Azides and 1-Bromoalkynes at Room Temperature

Author

Evelia Rasolofonjatovo, Frédéric Taran, Alexandra Bouriaud, Manon Chaumontet, Sergii Kolodych, and Sewan Theeramunkong

Subjects
Azides, Cycloaddition Reaction, Molecular Structure, Dimer, Organic Chemistry, Temperature, chemistry.chemical_element, Triazoles, Iridium, Biochemistry, Catalysis, Cycloaddition, Hydrocarbons, Brominated, chemistry.chemical_compound, Direct route, chemistry, Cyclization, Alkynes, Polymer chemistry, Physical and Theoretical Chemistry
Abstract

Iridium dimer complexes were found to catalyze the [3 + 2] cycloaddition reaction of azides with bromoalkynes, yielding 1,5-disubstituted 4-bromo-1,2,3-triazoles in reasonable to excellent yields under mild conditions. The reaction offers a direct route to new 1,4,5-trisubstituted triazoles.

Published
2013

2. ChemInform Abstract: Iridium-Catalyzed Cycloaddition of Azides and 1-Bromoalkynes at Room Temperature

Author

Frédéric Taran, Evelia Rasolofonjatovo, Sergii Kolodych, Alexandra Bouriaud, Manon Chaumontet, and Sewan Theeramunkong

Subjects
chemistry.chemical_compound, Direct route, chemistry, Dimer, Polymer chemistry, Triazole derivatives, chemistry.chemical_element, Organic chemistry, General Medicine, Iridium, Cycloaddition, Catalysis
Abstract

Iridium dimer complexes were found to catalyze the [3 + 2] cycloaddition reaction of azides with bromoalkynes, yielding 1,5-disubstituted 4-bromo-1,2,3-triazoles in reasonable to excellent yields under mild conditions. The reaction offers a direct route to new 1,4,5-trisubstituted triazoles.

Published
2014

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