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“Thick electrode using high voltage cathode” can be considered, since this research focuses on high voltage cathode materials.

Transitioning toward more sustainable materials and manufacturing methods will be critical to continue supporting the rapidly expanding market for lithium-ion batteries. Meanwhile, energy storage applications are demanding higher power and energy densities than ever before, with aggressive performance targets like fast charging and greatly extended operating ranges and durations. Due to its high operating voltage and cobalt-free chemistry, the spinel-type LiNi0.5Mn1.5O4 (LNMO) cathode material has attracted great interest as one of the few next-generation candidates capable of addressing this combination of challenges. However, severe capacity degradation and poor interphase stability have thus far impeded the practical application of LNMO. In this study, by leveraging a dry electrode coating process, we demonstrate LNMO electrodes with stable full cell operation (up to 68% after 1000 cycles) and ultra-high loading (up to 9.5 mAh/cm2 in half cells). This excellent cycling stability is ascribed to a stable cathode-electrolyte interphase, a highly distributed and interconnected electronic percolation network, and robust mechanical properties. High-quality images collected using plasma focused ion beam scanning electron microscopy (PFIB-SEM) provide additional insight into this behavior, with a complementary 2-D model illustrating how the electronic percolation network in the dry-coated electrodes more efficiently supports homogeneous electrochemical reaction pathways. These results strongly motivate that LNMO as a high voltage cobalt-free cathode chemistry combined with an energy-efficient dry electrode coating process opens the possibility for sustainable electrode manufacturing of cost-effective and high-energy-density cathode materials.

Essentially all research done to date on the mechanical properties of polymeric semiconductors (e.g., for organic photovoltaics and thin-film transistors) has had the underlying goal of increasing ...

The conductive polyelectrolyte complex poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is ubiquitous in research dealing with organic electronic devices (e.g., solar cells, wearable and implantable sensors, and electrochemical transistors). In many bioelectronic applications, the applicability of commercially available formulations of PEDOT:PSS (e.g., Clevios) is limited by its poor mechanical properties. Additives can be used to increase the compliance but pose a risk of leaching, which can result in device failure and increased toxicity (in biological settings). Thus, to increase the mechanical compliance of PEDOT:PSS without additives, we synthesized a library of intrinsically stretchable block copolymers. In particular, controlled radical polymerization using a reversible addition-fragmentation transfer process was used to generate block copolymers consisting of a block of PSS (of fixed length) appended to varying blocks of poly(poly(ethylene glycol) methyl ether acrylate) (PPEGMEA). These block copolymers (PSS

This paper demonstrates that a thin polymeric film (10–80 nm) can be continuously drawn from the meniscus of a nonpolar polymer solution at an air–water–fluoropolymer interface using a roll-to-roll...