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Significant gaps in our understanding of the oceanic cycling of neodymium (Nd) and the other rare earth elements (REEs) remain despite decades of research. One important observation which has not been adequately explained is that the concentration of dissolved Nd typically increases with depth, similar to nutrient profiles, while Nd isotopes appear to reflect conservative water mass mixing in the intermediate and deep ocean; this has been termed the “Nd paradox”. Here we present a detailed study of the dissolved Nd isotopic composition across a section at 40°S in the South Atlantic, collected by UK GEOTRACES cruise (section GA10). The South Atlantic represents a natural laboratory for our understanding of spatial controls on ocean geochemistry, because of the large variability of inputs, spatial differences in particulate cycling, and horizontal advection and mixing at depth between major northern- and southern-sourced water masses. This variability has also made the South Atlantic a critical region subject to intense investigations that aim at reconstructing past changes in ocean processes, such as changes in biological productivity and deep ocean circulation. Our Nd isotope results from the GA10 section provide observational data show the signal of water mass mixing and reversible scavenging. In the surface ocean (0–600 m), Nd isotopic compositions are distinct between different surface ocean currents and spatially can be tied to various continental sources. In the intermediate ocean (600–2500 m), the vertical Nd isotope distribution exhibits distinct signals of different water masses by horizontal advection, including upper North Atlantic Deep Water and Antarctic Intermediate Water formed in the Atlantic Ocean or the Indian Ocean. The Nd isotope distribution also reflects influence of reversible scavenging that smears the signals downwards in the water column (i.e., offset to more radiogenic values). In the deep ocean below 2500 m, Nd isotope distribution largely follows conservative water mass mixing model. Nd concentration in the deep ocean, however, deviates from conservative mixing and increases constantly with depth. We also observe that Nd isotopes appear to be shifted towards the composition of overlying water masses. These observations suggest that reversible scavenging of Nd onto organic and other types of particles is a major vertical process throughout the water column. We also suggest that this process can resolve the “Nd paradox” of decoupling of Nd concentration and isotopic composition due to mixing dynamics. Because abyssal water masses already have a high Nd concentration, a given amount of Nd added from the vertical process has less of an effect on Nd isotopic compositions in deep water masses than it does for intermediate water masses which have comparatively low Nd concentration.

Varying estimates of both present‐day strain accumulation and long‐term slip‐rate on the Doruneh left‐lateral strike‐slip fault, NE Iran, have led to suggestions that it exhibits large along‐strike and/or temporal changes in activity. In this paper, we make and compare estimates of slip‐rate measured using both geodesy and geomorphology, and spanning time periods ranging from decadal to 100 ka. To image the present‐day accumulation of strain we process seven years (2003‐2010) of data from six ENVISAT tracks covering the fault, with interferograms produced for 400 km‐long strips of data in order to image the long‐wavelength signals associated with interseismic strain accumulation across the locked fault. Our analysis shows that less than 4 mm/yr – and likely only 1‐3 mm/yr ‐ of slip accumulates across the fault. Using high‐resolution optical satellite imagery we make reconstructions of displacement across six alluvial fans whose surfaces cross the fault, in four separate river catchments. We determine the ages of these fans using infra‐red‐stimulated luminescence dating combined with U‐series dating of pedogenic carbonates. The six fans vary in age from ∼10‐100 kyr, and a regression line fitted to four of these yields a slip rate of 2.5 ± 0.3 mm/yr. We conclude that within the uncertainty of our measurements the slip‐rate has remained constant over the last ∼100 ka and is representative of the strain accumulation at the present‐day. The slip‐rate that we measure is consistent with the E‐W left‐lateral Doruneh fault accommodating N‐S right‐lateral faulting by 'bookshelf' faulting, with clockwise rotation about a vertical axis.

Significant gaps in our understanding of the oceanic cycling of neodymium (Nd) and the other rare earth elements (REEs) remain despite decades of research. One important observation which has not to date been adequately explained is that the concentration of dissolved Nd typically increases with depth, similar to nutrient profiles, while Nd isotopes appear to reflect conservative water mass mixing in the intermediate and deep ocean; this has been termed the “Nd paradox”. Here we present a detailed study of the dissolved Nd isotopic composition across a section at 40°S in the South Atlantic, collected by UK GEOTRACES cruise (section GA10). The South Atlantic represents a natural laboratory for our understanding of spatial controls on ocean geochemistry, because of the large variability of inputs, spatial differences in particulate cycling, and horizontal advection and mixing at depth between major northern- and southern- sourced water masses. This variability has also made the South Atlantic a critical region for reconstructing past changes in ocean processes such as changes in biological productivity and deep ocean circulation, using paleoceanographic proxies such as foraminiferal carbon and Nd isotopes.This GA10 section of Nd isotopes provides observational data showing chemical changes across water mass boundaries as a result of the horizontal advection of water mass chemistry by ocean circulation but also containing the imprint of reversible scavenging as the major vertical process. In the surface ocean (0 - 600 m), Nd isotopic compositions are distinct between different surface ocean currents and spatially can be tied to various continental sources. In the intermediate ocean (600 - 2500 m), the vertical Nd isotope distribution exhibits distinct signals of different water masses (i.e. a-AAIW, i-AAIW, and u-NADW) by horizontal advection, as well as influence of reversible scavenging that smears the signals downwards (i.e. offset to more radiogenic values). In the deep ocean below 2500 m, Nd isotope distribution follows conservative water mass mixing model. Nd concentration in the deep ocean, however, deviates from conservative mixing and increases constantly with depth. We also observe that Nd isotopes appear to be shifted towards the composition of overlying water masses. These observations suggests that reversible scavenging onto organic and other types of particles is a major vertical process throughout the water column. We also suggest that this process can resolve the “Nd paradox” of decoupling of Nd concentration and isotopic composition because abyssal water masses already have a high [Nd], so that a given amount of added Nd has less effect on ƐNd in deep water masses than it does for low [Nd] intermediate water masses.

The Great Barrier Reef (GBR) is an internationally recognized and widely studied ecosystem, yet little is known about its sea surface temperature evolution since the Last Glacial Maximum (LGM) (~20 kyr BP). Here, we present the first paleo‐application of Isopora coral‐derived SST calibrations to a suite of 25 previously published fossil Isopora from the central GBR spanning ~25‐11 kyr BP. The resultant multi‐coral Sr/Ca‐ and δ18O‐derived sea surface temperature anomaly (SSTA) histories are placed within the context of published relative sea level, reef sequence and coralgal reef assemblage evolution. Our new calculations indicate SSTs were cooler on average by ~5‐5.5°C at Noggin Pass (~17°S) and ~7‐8°C at Hydrographer's Passage (~20°S) (Sr/Ca‐derived) during the LGM, in line with previous estimates (Felis et al., 2014). We focus on contextualizing the Younger Dryas Chronozone (YDC, ~12.9‐11.7 kyr BP), whose southern hemisphere expression, in particular in Australia, is elusive and poorly constrained. Our record does not indicate cooling during the YDC with near modern temperatures reached during this interval on the GBR, supporting an asymmetric hemispheric presentation of this climate event. Building on a previous study (Felis et al., 2014), these fossil Isopora SSTA data from the GBR provide new insights into the deglacial reef response, with near‐modern warming during the YDC, since the LGM.

International audience; Previous drilling through submerged fossil coral reefs has greatly improved our understanding of the general pattern of sea-level change since the Last Glacial Maximum, however, how reefs responded to these changes remains uncertain. Here we document the evolution of the Great Barrier Reef (GBR), the world’s largest reef system, to major, abrupt environmental changes over the past 30 thousand years based on comprehensive sedimentological, biological and geochronological records from fossil reef cores. We show that reefs migrated seaward as sea level fell to its lowest level during the most recent glaciation (~20.5–20.7 thousand years ago (ka)), then landward as the shelf flooded and ocean temperatures increased during the subsequent deglacial period (~20–10 ka). Growth was interrupted by five reef-death events caused by subaerial exposure or sea-level rise outpacing reef growth. Around 10 ka, the reef drowned as the sea level continued to rise, flooding more of the shelf and causing a higher sediment flux. The GBR’s capacity for rapid lateral migration at rates of 0.2–1.5 m yr$^{−1}$ (and the ability to recruit locally) suggest that, as an ecosystem, the GBR has been more resilient to past sea-level and temperature fluctuations than previously thought, but it has been highly sensitive to increased sediment input over centennial–millennial timescales.

FB was funded by a NERC DTP (Grant award code NE/L002558/1), and RW and SWP by the NERC BETR Project (Grant award code NE/P013643/1). AS was funded by the School of GeoSciences, University of Edinburgh, and LA was funded by a Leeds Anniversary Research Scholarship. SWP acknowledges financial support from a Royal Society Wolfson Research Merit Award and a Leverhulme Research Fellowship. The late Ediacaran witnessed an increase in metazoan diversity and ecological complexity, marking the inception of the Cambrian Explosion. To constrain the drivers of this diversification, we combine redox and nutrient data for two shelf transects, with an inventory of biotic diversity and distribution from the Nama Group, Namibia (~550 to ~538 Million years ago; Ma). Unstable marine redox conditions characterised all water depths in inner to outer ramp settings from ~550 to 547 Ma, when the first skeletal metazoans appeared. However, a marked deepening of the redoxcline and a reduced frequency of anoxic incursions onto the inner to mid-ramp is recorded from ~547 Ma onwards, with full ventilation of the outer ramp by ~542 Ma. Phosphorus speciation data show that, whilst anoxic ferruginous conditions were initially conducive to the drawdown of bioavailable phosphorus, they also permitted a limited degree of phosphorus recycling back to the water column. A long-term decrease in nutrient delivery from continental weathering, coupled with a possible decrease in upwelling, led to the gradual ventilation of the Nama Group basins. This, in turn, further decreased anoxic recycling of bioavailable phosphorus to the water column, promoting the development of stable oxic conditions and the radiation of new mobile taxa. Publisher PDF

The history of sea level in regions impacted by glacio-isostasy provides constraints on past ice-sheet distribution and on the characteristics of deformation of the planet in response to loading. The Western North Atlantic–Caribbean region, and Bermuda in particular, is strongly affected by the glacial forebulge that forms as a result of the Laurentide ice-sheet present during glacial periods. The timing of growth of speleothems, at elevations close to sea level can provide records of minimum relative sea level (RSL). In this study we used U–Th dating to precisely date growth periods of speleothems from Bermuda which were found close to modern-day sea level. Results suggest that RSL at this location was above modern during MIS5e, MIS5c and MIS5a. These data support controversial previous indications that Bermudian RSL was significantly higher than RSL at other locations during MIS 5c and MIS 5a. We confirm that it is possible to explain a wide range of MIS5c-a relative sea levels observed across the Western North Atlantic–Caribbean in glacial isostatic adjustment models, but only with a limited range of mantle deformation constants. This study demonstrates the particular power of Bermuda as a gauge for response of the forebulge to glacial loading, and demonstrates the potential for highstands at this location to be significantly higher than in other regions, helping to explain the high sea levels observed for Bermuda from earlier highstands.

In the original version of this article (Kunkelova et al. 2018), published on 18 December 2018, there was 1 error in the author name of Dr. Yu.

Tem uma correção em http://hdl.handle.net/10400.1/12390 Indian-Asian monsoon has oscillated between warm/wet interglacial periods and cool/dry glacial periods with periodicities closely linked to variations in Earth’s orbital parameters. However, processes that control wet versus dry, i.e. aridity cyclical periods on the orbital time-scale in the low latitudes of the Indian-Asian continent remain poorly understood because records over millions of years are scarce. The sedimentary record from International Ocean Discovery Program (IODP) Expedition 359 provides a well-preserved, high-resolution, continuous archive of lithogenic input from the Maldives reflecting on low-latitude aridity cycles. Variability within the lithogenic component of sedimentary deposits of the Maldives results from changes in monsoon-controlled sedimentary sources. Here, we present X-ray fluorescence (XRF) core-scanning results from IODP Site U1467 for the past two million years, allowing full investigation of orbital periodicities. We specifically use the Fe/K as a terrestrial climate proxy reflecting on wet versus dry conditions in the source areas of the Indian-Asian landmass, or from further afield. The Fe/K record shows orbitally forced cycles reflecting on changes in the relative importance of aeolian (stronger winter monsoon) during glacial periods versus fluvial supply (stronger summer monsoon) during interglacial periods. For our chronology, we tuned the Fe/K cycles to precessional insolation changes, linking Fe/K maxima/minima to insolation minima/maxima with zero phase lag. Wavelet and spectral analyses of the Fe/K record show increased dominance of the 100 kyr cycles after the Mid Pleistocene Transition (MPT) at 1.25 Ma in tandem with the global ice volume benthic δ18O data (LR04 record). In contrast to the LR04 record, the Fe/K profile resolves 100-kyr-like cycles around the 130 kyr frequency band in the interval from 1.25 to 2 million years. These 100-kyr-like cycles likely form by bundling of two or three obliquity cycles, indicating that low-latitude Indian-Asian climate variability reflects on increased tilt sensitivity to regional eccentricity insolation changes (pacing tilt cycles) prior to the MPT. The implication of appearance of the 100 kyr cycles in the LR04 and the Fe/K records since the MPT suggests strengthening of a climate link between the low and high latitudes during this period of climate transition. SFRH/BPD/96960/2013; PTDC/MAR-PRO/3396/2014 info:eu-repo/semantics/publishedVersion

The GEOTRACES Intermediate Data Product 2017 (IDP2017) is the second publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2016. The IDP2017 includes data from the Atlantic, Pacific, Arctic, Southern and Indian oceans, with about twice the data volume of the previous IDP2014. For the first time, the IDP2017 contains data for a large suite of biogeochemical parameters as well as aerosol and rain data characterising atmospheric trace element and isotope (TEI) sources. The TEI data in the IDP2017 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at crossover stations. The IDP2017 consists of two parts: (1) a compilation of digital data for more than 450 TEIs as well as standard hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing an on-line atlas that includes more than 590 section plots and 130 animated 3D scenes. The digital data are provided in several formats, including ASCII, Excel spreadsheet, netCDF, and Ocean Data View collection. Users can download the full data packages or make their own custom selections with a new on-line data extraction service. In addition to the actual data values, the IDP2017 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering and for statistical analysis. Metadata about data originators, analytical methods and original publications related to the data are linked in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2017 as section plots and rotating 3D scenes. The basin-wide 3D scenes combine data from many cruises and provide quick overviews of large-scale tracer distributions. These 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of tracer plumes near ocean margins or along ridges. The IDP2017 is the result of a truly international effort involving 326 researchers from 25 countries. This publication provides the critical reference for unpublished data, as well as for studies that make use of a large cross-section of data from the IDP2017. This article is part of a special issue entitled: Conway GEOTRACES - edited by Tim M. Conway, Tristan Horner, Yves Plancherel, and Aridane G. González., National Science Foundation (U.S.) (Grant OCE-0608600), National Science Foundation (U.S.) (Grant OCE0938349), National Science Foundation (U.S.) (Grant OCE-1243377), National Science Foundation (U.S.) (Grant OCE-1546580)

The approximately 10,000-year-long Last Glacial Maximum, before the termination of the last ice age, was the coldest period in Earth’s recent climate history1. Relative to the Holocene epoch, atmospheric carbon dioxide was about 100 parts per million lower and tropical sea surface temperatures were about 3 to 5 degrees Celsius lower2,3. The Last Glacial Maximum began when global mean sea level (GMSL) abruptly dropped by about 40 metres around 31,000 years ago4 and was followed by about 10,000 years of rapid deglaciation into the Holocene1. The masses of the melting polar ice sheets and the change in ocean volume, and hence in GMSL, are primary constraints for climate models constructed to describe the transition between the Last Glacial Maximum and the Holocene, and future changes; but the rate, timing and magnitude of this transition remain uncertain. Here we show that sea level at the shelf edge of the Great Barrier Reef dropped by around 20 metres between 21,900 and 20,500 years ago, to −118 metres relative to the modern level. Our findings are based on recovered and radiometrically dated fossil corals and coralline algae assemblages, and represent relative sea level at the Great Barrier Reef, rather than GMSL. Subsequently, relative sea level rose at a rate of about 3.5 millimetres per year for around 4,000 years. The rise is consistent with the warming previously observed at 19,000 years ago1,5, but we now show that it occurred just after the 20-metre drop in relative sea level and the related increase in global ice volumes. The detailed structure of our record is robust because the Great Barrier Reef is remote from former ice sheets and tectonic activity. Relative sea level can be influenced by Earth’s response to regional changes in ice and water loadings and may differ greatly from GMSL. Consequently, we used glacio-isostatic models to derive GMSL, and find that the Last Glacial Maximum culminated 20,500 years ago in a GMSL low of about −125 to −130 metres. © 2018, Macmillan Publishers Ltd., part of Springer Nature. Japan Society for the Promotion of Science-JP16H06309,JP17H01168,JP26247085,JP15KK0151 Australian Research Council-DP1094001 National Eye Research Centre-NE/H014136/1 Institut National Polytechnique de Toulouse

Over 30 years of solar data have been acquired by the Birmingham Solar Oscillations Network (BiSON), an international network of telescopes used to study oscillations of the Sun. Five of the six BiSON telescopes are located at major observatories. The observational sites are, in order of increasing longitude: Mount Wilson (Hale) Observatory (MWO), California, USA; Las Campanas Observatory (LCO), Chile; Observatorio del Teide, Iza\~{n}a, Tenerife, Canary Islands; the South African Astronomical Observatory (SAAO), Sutherland, South Africa; Carnarvon, Western Australia; and the Paul Wild Observatory, Narrabri, New South Wales, Australia. The BiSON data may be used to measure atmospheric extinction coefficients in the $\mathrm{I_c}$ band (approximately 700-900 nm), and presented here are the derived atmospheric extinction coefficients from each site over the years 1984 to 2016., Comment: 15 pages, 10 figures, 4 tables. Accepted by Astronomical Journal: 2017 July 20

The approximately 10,000-year-long Last Glacial Maximum, before the termination of the last ice age, was the coldest period in Earth's recent climate history

We investigate the Gloria Knolls Slide (GKS) complex on the Great Barrier Reef margin of north-eastern Australia, the largest extant mixed carbonate-siliciclastic province in the world. Based on the most complete bathymetric and sub-bottom profile datasets available for the region, we describe the main surface and subsurface geomorphologic characteristics of this landslide complex. The GKS forms a 20 km along-slope and 8 km across-slope indentation in the margin, extending from 250 to 1350 m depth, and involves a volume of 32 km3 of sediment remobilized during three events. Three main seafloor terrains can be distinguished based on seafloor morphology: a source area, a proximal depositional area and a distal depositional area. The source area includes a main headwall scarp with a maximum height of 830 m and a secondary scarp at 670 m depth. The proximal depositional area is flat and smooth, and lacks debris exposed on the seafloor. The distal depositional area has a hummocky surface showing a distinctive cluster of eight knolls and over 70 small debris blocks. A dredge sample from the top of the largest knoll at a depth of 1170 m reveals the presence of a cold-water coral community. In the sub-bottom profiles, the mass-transport deposits in the GKS are identified below the background sediment drape as partially confined, wedge-shaped bodies of mostly weak amplitude, transparent reflectors in the proximal depositional area; and more discontinuous and chaotic in the distal depositional area. The failed sediment slabs of the GKS were evacuated, transported and disintegrated downslope in three events following a sequential failure process spreading successively from the lower slope to the upper slope. The first event initiated at the lower slope at the depth of the secondary scarp, moved downslope and disintegrated over the basin floor leaving coherent blocks. The subsequent second and third events were responsible for the formation upslope of the main scarp in the GKS. The timing of emplacement of the first GKS event, constrained by radiometric age of fossil biota from the surface of the largest slide block, was at least before 302 ± 19 ka. The presence of alternating mixed carbonate and siliciclastic lithologies that build the slope might have played an important role as a preconditioning factor in this region. Preliminary estimations suggest that unusually large seismic events were the most likely triggering mechanism for the GKS. This work contributes to the understanding of large mass-movement deposits in mixed carbonate-siliciclastic margins and provides a useful morphologic characterization and evolutionary model for assessing its tsunamigenic potential with further numerical simulations. In addition, the discovery of a cold-water coral community on top of the largest knoll has implications for identifying similar landslide-origin cold-water coral communities on the GBR margin.

Time-averaged fault slip-rates can be established by reliably dating the abandonment of an alluvial deposit that has been displaced by Quaternary movement along a cross-cutting fault. Unfortunately, many Quaternary dating techniques are hindered by uncertainties inherent to individual geochronometers. Such uncertainties can be minimised by combining multiple independent techniques. In this study, we combine 10Be exposure dating of boulder tops and U-series dating of layered pedogenic carbonate cements accumulated on the underside of clasts from two separate alluvial surfaces. These surfaces are both displaced by the active Ölgiy strike-slip fault in the Mongolian Altay Mountains. We date individual layers of pedogenic carbonate, and for the first time apply a Bayesian statistical analysis to the results to develop a history of carbonate accumulation. Our approach to the U-series dating provides an age of initiation of carbonate cement formation and avoids the problem of averaging contributions from younger layers within the carbonate. The U-series ages make it possible to distinguish 10Be samples that have anomalously young exposure ages and have hence been subject to the effects of post-depositional erosion or exhumation. The combination of 10Be and U-series dating methods provides better constrained age estimates than using either method in isolation and allows us to bracket the abandonment ages of the two surfaces as 18.0-28.1kyr and 38.4-76.4kyr. Our ages, combined with measurements of the displacement of the surfaces, yield a right-lateral slip-rate for the Ölgiy fault of 0.3-1.3mmyr-1, showing that it is a relatively important structure within the active tectonics of Mongolia and that it constitutes a substantial hazard to local populations.

Three new U-series ages from coral fragments found in the Belmont Formation of Bermuda fall in a range of ∼198 ka to ∼196 ka. These late MIS 7 ages are consistent with those of ∼201 ka and ∼199 ka measured in a previous study. The disputed interpretation of the Belmont Formation as a unit that is allostratigraphically distinct from subsequent MIS 5e deposits, of the Rocky Bay Formation, is vindicated by a minimum age of 196 ± 3 ka for the total of 6 coral fragments it has yielded. Emergent marine deposits of the Belmont Formation include sedimentary lithofacies that are considered to be reliable relative sea level indicators. Prominent among these is a facies representing the “beach step”: a feature that develops sub-tidally, directly at the base of the swash zone. From this facies, and others preserved along 6 km of Belmont Formation coastal exposure, it is concluded that MIS 7 relative mean sea level reached +4.5 m, and likely peaked at or above +6.0 m, relative to present sea level at Bermuda. Lower MIS 7 sea level positions that are evidenced and that have been quoted, in the past, are considered transitory positions, not maxima. The MIS 7 sea-level elevations on Bermuda, reconstructed in this study, are above the majority of those reported from elsewhere in the world. This challenges the long-standing notion of Bermuda as a vertically stable “tide-gauge”, but is consistent with glacio-hydroisostatic models which predict land-mass subsidence at intermediate field sites, such as Bermuda, at the end of long interglacials. However, because of evidence of instability at Bermuda in the form of seismic activity and faulting, which require further investigation, judgement is reserved on the global implications of this palaeo-sea-level anomaly.

SUMMARY Geomagnetic excursions are brief deviations of the geomagnetic field from behaviour expected during ‘normal secular’ variation. The Laschamp excursion at ∼41ka was one such deviation. Previously published records suggest rapid changes in field direction and a concurrent substantial decrease in field intensity associated with this excursion. Accurate dating of excursions, and determination of their durations from multiple locations, is vital to our understanding of global field behaviour during these deviations. We present here high-resolution palaeomagnetic records of the Laschamp excursion obtained from two Ocean Drilling Program (ODP) Sites, 1061 and 1062 on the Blake-Bahama Outer Ridge (ODP Leg 172). High sedimentation rates (∼30‐40cmkyr −1 ) at these locations allow determination of transitional field behaviour during the excursion. Palaeomagnetic measurements of discrete samples from four cores reveal a single excursional feature, across an interval of 30cm, associated with a broader palaeointensity low. We determine the age and duration of the Laschamp excursion using a stratigraphy linked to the δ 18 O record from the Greenland ice cores. This chronology dates the Laschamp excursion at the Blake Ridge to 41.3ka. The excursion is characterized by rapid transitions (less than 200yr) between stable normal polarity and a partially reversed polarity state. The palaeointensity record is in good agreement between the two sites, revealing two prominent minima. The first minimum is associated with the Laschamp excursion at 41ka and the second corresponds to the Mono Lake excursion at ∼35.5ka. We determine that the directional excursion during the Laschamp at this location was no longer than ∼400yr, occurring within a palaeointensity minimum that lasted 2000yr. The Laschamp excursion at this location is much shorter in duration than the Blake and Iceland Basin excursions.

Shallow-water tropical corals can be used to calibrate the radiocarbon timescale. In this paper, we present a new data set based on the comparison between 14C ages and U-Th ages measured in fossil corals collected offshore the island of Tahiti during the Integrated Oceanic Drilling Program (IODP) Expedition 310. After applying strict mineralogical and geochemical screening criteria, the Tahiti record provides new data for 2 distinct time windows: 7 data for the interval between 29 and 37 cal kyr BP and 58 for the last deglaciation period, notably a higher resolution for the 14–16 cal kyr BP time interval. There are 3 main outcomes of this study. First, it extends the previous Tahiti record beyond 13.9 cal kyr BP, the oldest U-Th age obtained on cores drilled onshore in the modern Tahiti barrier reef. Second, it strengthens the data set of the 14–15 cal kyr BP period, allowing for better documentation of the 14C age plateau in this time range. This age plateau corresponds to a drop of the atmospheric 14C synchronous with an abrupt period of sea-level rise (Melt Water Pulse 1 A, MWP-1 A). The Tahiti 14C record documents complex changes in the global carbon cycle due to variations in the exchange rates between its different reservoirs. Third, during the Heinrich event 1, the Tahiti record disagrees with the Cariaco record, but is in broad agreement with other marine and continental data.

International audience; We present uranium–thorium chronology for a 102 m core through a Pleistocene reef at Tahiti (French Polynesia) sampled during IODP Expedition 310 “Tahiti Sea Level”. We employ total and partial dissolution procedures on the older coral samples to investigate the diagenetic overprint of the uranium–thorium system. Although alteration of the U–Th system cannot be robustly corrected, diagenetic trends in the U–Th data, combined with sea level and subsidence constraints for the growth of the corals enables the age of critical samples to be constrained to marine isotope stage 9. We use the ages of the corals, together with δ18O based sea-level histories, to provide maximum constraints on possible paleo water-depths. These depth constraints are then compared to independent depth estimates based on algal and foraminiferal assemblages, microbioerosion patterns, and sedimentary facies, confirming the accuracy of these paleo water-depth estimates. We also use the fact that corals could not have grown above sea level to place a maximum constraint on the subsidence rate of Tahiti to be 0.39 m ka−1, with the most likely rate being close to the existing minimum estimate of 0.25 m ka−1.

Continental shelves and shelf seas play a central role in the global carbon cycle. However, their importance with respect to trace element and isotope (TEI) inputs to ocean basins is less well understood. Here, we present major findings on shelf TEI biogeochemistry from the GEOTRACES programme as well as a proof of concept for a new method to estimate shelf TEI fluxes. The case studies focus on advances in our understanding of TEI cycling in the Arctic, transformations within a major river estuary (Amazon), shelf sediment micronutrient fluxes and basin-scale estimates of submarine groundwater discharge. The proposed shelf flux tracer is 228-radium ( T 1/2 = 5.75 yr), which is continuously supplied to the shelf from coastal aquifers, sediment porewater exchange and rivers. Model-derived shelf 228 Ra fluxes are combined with TEI/ 228 Ra ratios to quantify ocean TEI fluxes from the western North Atlantic margin. The results from this new approach agree well with previous estimates for shelf Co, Fe, Mn and Zn inputs and exceed published estimates of atmospheric deposition by factors of approximately 3–23. Lastly, recommendations are made for additional GEOTRACES process studies and coastal margin-focused section cruises that will help refine the model and provide better insight on the mechanisms driving shelf-derived TEI fluxes to the ocean. This article is part of the themed issue ‘Biological and climatic impacts of ocean trace element chemistry’.

Measurements of 231 Pa, 230 Th and 232 Th concentrations have been made on five water-column profiles along the western margin of the Madagascar and Mascarene Basins in the southern Indian Ocean. These measurements help to fill a significant gap in the global coverage of water-column 232 Th, 230 Th and 231 Pa data. 232 Th concentrations vary, but generally increase with depth, suggesting higher particle loading in deeper waters, and the presence of a significant dissolved fraction of 232 Th. 230 Th concentrations increase with depth, and profiles are similar to the average of existing data from other regions. 231 Pa concentrations, on the other hand, show significant depth structure, apparently reflecting the various water masses sampled at this location. The modified remnants of North Atlantic Deep Water are found at a depth of 62000 m and exhibit elevated 231 Pa concentrations exported from the South Atlantic. Antarctic Intermediate and Bottom Waters have lower 231 Pa, probably due to scavenging onto opal particles during transit from the Southern Ocean. The differences between water masses raises a question: which water mass is important in controlling the 231 Pa/ 230 Th ratio in underlying sediments? A simple one-dimensional model is used to demonstrate that the 230 Th and 231 Pa exported to sea-floor sediments last equilibrates with waters close to the seafloor (within 61000 m), rather than averaging the whole water column. These findings suggest that 231 Paxs/ 230 Thxs in sediments provides information primarily about deep-water masses. In this region, sedimentary records will therefore provide information about the past flow of Antarctic Bottom Water into the Indian Ocean. Interpretation of data from other regions, such as the North Atlantic where this proxy has most successfully been applied, requires careful consideration of regional oceanography and knowledge of the composition of the water masses being investigated. D 2005 Elsevier B.V. All rights reserved.

Thirty-one new bulk-sediment U-Th dates are presented, together with an improved δ18O stratigraphy, for ODP Site 1008A on the slopes of the Bahamas Banks. These ages supplement and extend those from previous studies and provide constraints on the timing of sea-level highstands associated with marine isotope stages (MIS) 7 and 9. Ages are screened for reliability based on their initial U and Th isotope ratios, and on the aragonite fraction of the sediment. Twelve 'reliable' dates for MIS 7 suggest that its start is concordant with that predicted if climate is forced by northern-hemisphere summer insolation following the theory of Milankovitch. But U-Th and δ18O data indicate the presence of an additional highstand which post-dates the expected end of MIS 7 by up to 10 ka. This event is also seen in coral reconstructions of sea-level. It suggests that sea-level is not responding in any simple way to northern-hemisphere summer insolation, and that tuned chronologies which make such an assumption are in error by ≈10 ka at this time. U-Th dates for MIS 9 also suggest a potential mismatch between the actual timing of sea-level and that predicted by simple mid-latitude northern-hemisphere forcing. Four dates are earlier than that predicted for the start of MIS 9. Although the most extreme of these dates may not be reliable (based on the low-aragonite content of the sediment) the other three appear robust and suggest that full MIS 9 interglacial conditions were established at 343 ka. This is ≈8 ka prior to the date expected if this warm period were driven by northern-hemisphere summer insolation. © 2006 Elsevier Ltd. All rights reserved.

The significance of submerged fossil coral reefs as important archives of abrupt global sea level rise and climate change has been confirmed by investigations in the Caribbean [Fairbanks, 1989] and the Indo-Pacific (see Montaggioni [2005] for a summary) and by recent Integrated Ocean Drilling Program (IODP) activities in Tahiti [Camoin et al., 2007]. Similar submerged (40-130 meters) reef structures are preserved along the margin of the Great Barrier Reef (GBR), but they have not yet been systematically studied. The submerged reefs have the potential to provide critical new information about the nature of past global sea level and climate variability and about the response of the GBR to these past and perhaps future environmental changes [Beaman et al., 2008]. Equally important for GBR Marine Park managers is information about the role of the reefs as habitats and substrates for modern biological communities. Here we summarize the highlights and broader implications of a September- October 2007 expedition on the R/V Southern Surveyor (Australian Marine National Facility, voyage SS07/2007) to investigate the shelf edge, upper slope, and submarine canyons along the GBR margin.

Permafrost Thaw Predictions Permafrost contains twice as much carbon as the atmosphere which could have serious consequences if it were to be released by widespread thawing. Vaks et al. (p. 183 , published online 21 February) present a 450,000 year-long record of speleothem growth at selected locations in Siberia, which traces changes in the extent of permafrost over that time period. The authors conclude that conditions only slightly warmer than those of today would cause widespread thawing of continuous permafrost as far north as 60°N.

n AD 365 a great (Mw N 8) earthquake lifted up western Crete, exposing a shoreline encrusted by marine organisms, and up to 10 m of marine substrate beneath it. Radiocarbon ages determined for corals and bryozoans exposed between the paleo-shoreline and present sea level are consistent, within measurement error, with each other and with the date of the earthquake. But radiocarbon ages determined for the boring bivalve Lithophaga lithophaga found on the same substrate are at least 350 years, and up to 2000 years, older than the date of the earthquake that lifted them above sea level. These observations reveal two important effects that limit the use of radiocarbon lithophagid ages in tectonic and paleoseismological studies. The first is that the exceptional preservation potential of lithophagids allows them to remain intact and in situ long after natural death, while the substrate continues to be colonised until eventual uplift. The second, which we confirm with radiocarbon analysis of museum specimens of known age, is the incorporation of old (14C-free) carbon into lithophagid shells from the limestone host rock into which the lithophagids bored. The two effects are both significant in Crete and central Greece, and can cause the radiocarbon lithophagid ages to be up to 2000 years older than the uplift event which exposed them. Understanding these effects is important because lithophagids are far more abundantly preserved, and used to date uplift, than most other marine organisms. This study shows that they can rarely be used to distinguish uplift events, or date them to better than 1000 years, or even to distinguish whether observed uplift occurred in a single or in multiple events. After taking account of these uncertainties, the ages of the lithophagids are, however, consistent with the hypothesis that the highest prominent marine notches and exposed lithophagid holes within a few metres of sea level in Greece formed when sea level became relatively stable ~ 6000 years ago, following rapid rise after the last glacial maximum.

Tropical south-western Pacific temperatures are of vital importance to the Great Barrier Reef (GBR), but the role of sea surface temperatures (SSTs) in the growth of the GBR since the Last Glacial Maximum remains largely unknown. Here we present records of Sr/Ca and δ(18)O for Last Glacial Maximum and deglacial corals that show a considerably steeper meridional SST gradient than the present day in the central GBR. We find a 1-2 °C larger temperature decrease between 17° and 20°S about 20,000 to 13,000 years ago. The result is best explained by the northward expansion of cooler subtropical waters due to a weakening of the South Pacific gyre and East Australian Current. Our findings indicate that the GBR experienced substantial meridional temperature change during the last deglaciation, and serve to explain anomalous deglacial drying of northeastern Australia. Overall, the GBR developed through significant SST change and may be more resilient than previously thought.

The last deglaciation is characterized by a rapid sea-level rise and coeval abrupt environmental changes. The Barbados coral reef record suggests that this period has been punctuated by two brief intervals of accelerated melting (meltwater pulses, MWP), occurring at 14.08-13.61 ka and 11.4-11.1 ka (calendar years before present), that are superimposed on a smooth and continuous rise of sea level. Although their timing, magnitude, and even existence have been debated, those catastrophic sea-level rises are thought to have induced distinct reef drowning events. The reef response to sea-level and environmental changes during the last deglacial sea-level rise at Tahiti is reconstructed based on a chronological, sedimentological, and paleobiological study of cores drilled through the relict reef features on the modern forereef slopes during the Integrated Ocean Drilling Program Expedition 310, complemented by results on previous cores drilled through the Papeete reef. Reefs accreted continuously between 16 and 10 ka, mostly through aggradational processes, at growth rates averaging 10 mm yr-1. No cessation of reef growth, even temporary, has been evidenced during this period at Tahiti. Changes in the composition of coralgal assemblages coincide with abrupt variations in reef growth rates and characterize the response of the upward-growing reef pile to nonmonotonous sea-level rise and coeval environmental changes. The sea-level jump during MWP 1A, 16 ± 2 m of magnitude in ~350 yr, induced the retrogradation of shallow-water coral assemblages, gradual deepening, and incipient reef drowning. The Tahiti reef record does not support the occurrence of an abrupt reef drowning event coinciding with a sea-level pulse of ~15 m, and implies an apparent rise of 40 mm yr-1 during the time interval corresponding to MWP 1B at Barbados. © 2012 Geological Society of America.

Nineteen labs representing nine nations participated in the GEOTRACES intercalibration initiative that determined concentrations of 232Th, 230Th, 231Pa or 10Be in seawater, suspended particles or sediments. Results generally demonstrated good agreement among labs that analyzed marine sediments. Two sets of seawater samples, aliquots of particulate material filtered in situ, and/or aliquots of biogenic sediments were distributed to participating labs. Internal consistency among participating labs improved substantially between the first and second set of seawater samples. Contamination was a serious problem for 232Th. Standard Niskin™ bottles introduced no detectable contamination, whereas sample containers, reagents and labware were implicated as sources of contamination. No detectable differences in concentrations of dissolved 232Th, 230Th or 231Pa were observed among samples of seawater filtered through Nuclepore ™, Supor ™ or QMA™ (quartz) filters with pore diameters ranging between 0.4 and 1.0 μm. Isotope yield monitors equilibrate with dissolved Th in seawater on a time scale of much less than one day. Samples of filtered seawater acidified to a pH between 1.7 and 1.8 experienced no detectable loss of dissolved Th or Pa during storage for up to three years. The Bermuda Atlantic Time Series station will serve as a GEOTRACES baseline station for future intercalibration of 232Th and 230Th concentrations in seawater. Efforts to improve blanks and standard calibration are ongoing, as is the development of methods to determine concentrations of particulate nuclides, tests of different filtration methods, and an increasing awareness of the need to define protocols for reporting uncertainties.

Aeolian dust is a significant source of iron and other nutrients to the surface ocean, but constraining the size of this flux is difficult. Chemical tracers, such as Al, are useful, but are limited by lack of information about their rate of removal from surface seawater. In this study, we test the use of Th isotopes as an improved tracer of dust input by measuring 232 Th and 230 Th concentrations of upper-ocean seawater at six stations along a meridional Atlantic section that spans the Saharan dust plume. Open ocean 232 Th, like Al, is dominantly derived from dust dissolution, while 230 Th is produced in seawater by U decay and provides an assessment of Th removal rates. The highest 232 Th concentrations and 232 Th/ 230 Th ratios, particularly in the surface waters, are observed at stations expected to be influenced by input of Saharan dust. The pattern of 232 Th concentration is in agreement with dissolved Al distributions and SeaWiFS aerosol imagery, supporting the use of 232 Th as a proxy for short-term dust addition. Deeper in the water column, 232 Th concentration may also reflect longer-term dust inputs. In addition, lateral input of 232 Th from Mediterranean Outflow Water is detected at 1000 m in the north Atlantic. Surface-water residence times are calculated separately from 230 Th and 234 Th using a simple scavenging model and values from the two isotopes are generally consistent with one another. Th-230 residence times appear to reflect the longer-term value, however, rather than exhibiting the strong seasonal influence seen for 234 Th. These Th residence times allow dust flux to the surface ocean to be calculated using the known concentration of Th in dust, and assumed values for the solubility of dust Th in seawater. Resulting dust fluxes show good agreements with models of dust deposition if Th solubility is 1 to 5% in the north Atlantic (yielding fluxes of 0.4–19.2 g m − 2 yr − 1 ) and 5 to 10% in the south Atlantic (fluxes of 0.2–0.7 g m − 2 yr − 1 ). Despite the need for better constraints on the fractional solubility of dust Th, this study demonstrates the power of combining Th isotope measurements to constrain dust fluxes to the surface ocean.

The meridional overturning circulation (MOC) of the Atlantic Ocean is considered to be one of the most important components of the climate system. This is because its warm surface currents, such as the Gulf Stream, redistribute huge amounts of energy from tropical to high latitudes and influence regional weather and climate patterns, whereas its lower limb ventilates the deep ocean and affects the storage of carbon in the abyss, away from the atmosphere. Despite its significance for future climate, the operation of the MOC under contrasting climates of the past remains controversial. Nutrient-based proxies and recent model simulations indicate that during the Last Glacial Maximum the convective activity in the North Atlantic Ocean was much weaker than at present. In contrast, rate-sensitive radiogenic (231)Pa/(230)Th isotope ratios from the North Atlantic have been interpreted to indicate only minor changes in MOC strength. Here we show that the basin-scale abyssal circulation of the Atlantic Ocean was probably reversed during the Last Glacial Maximum and was dominated by northward water flow from the Southern Ocean. These conclusions are based on new high-resolution data from the South Atlantic Ocean that establish the basin-scale north to south gradient in (231)Pa/(230)Th, and thus the direction of the deep ocean circulation. Our findings are consistent with nutrient-based proxies and argue that further analysis of (231)Pa/(230)Th outside the North Atlantic basin will enhance our understanding of past ocean circulation, provided that spatial gradients are carefully considered. This broader perspective suggests that the modern pattern of the Atlantic MOC-with a prominent southerly flow of deep waters originating in the North Atlantic-arose only during the Holocene epoch.

The GEOTRACES Intermediate Data Product 2014 (IDP2014) is the first publicly available data product of the international GEOTRACES programme, and contains data measured and quality controlled before the end of 2013. It consists of two parts: (1) a compilation of digital data for more than 200 trace elements and isotopes (TEIs) as well as classical hydrographic parameters, and (2) the eGEOTRACES Electronic Atlas providing a strongly inter-linked on-line atlas including more than 300 section plots and 90 animated 3D scenes. The IDP2014 covers the Atlantic, Arctic, and Indian oceans, exhibiting highest data density in the Atlantic. The TEI data in the IDP2014 are quality controlled by careful assessment of intercalibration results and multi-laboratory data comparisons at cross-over stations. The digital data are provided in several formats, including ASCII spreadsheet, Excel spreadsheet, netCDF, and Ocean Data View collection. In addition to the actual data values the IDP2014 also contains data quality flags and 1-σ data error values where available. Quality flags and error values are useful for data filtering. Metadata about data originators, analytical methods and original publications related to the data are linked to the data in an easily accessible way. The eGEOTRACES Electronic Atlas is the visual representation of the IDP2014 data providing section plots and a new kind of animated 3D scenes. The basin-wide 3D scenes allow for viewing of data from many cruises at the same time, thereby providing quick overviews of large-scale tracer distributions. In addition, the 3D scenes provide geographical and bathymetric context that is crucial for the interpretation and assessment of observed tracer plumes, as well as for making inferences about controlling processes., National Science Foundation (U.S.) (OCE-0608600), National Science Foundation (U.S.) (OCE-0938349), National Science Foundation (U.S.) (OCE-1243377)

Results of studies involving numerous cores and ODP holes along the Great Barrier Reef (GBR) margin andadjacent Queensland Trough and Queensland Plateau have challenged the use of a reciprocal sedimentation model to describethe sedimentary response of slope and basin settings to glacioeustatic sea-level fluctuations. Upper-slope sedimentation resultsfrom the relationships between sea-level fluctuations, antecedent topography, and regional climate that play an important rolein the type and amount of sediment deposited on the upper slope during glacial, deglacial, and interglacial times. During theLast Glacial Maximum (LGM, . 20 ka ago) upper-slope sediments generally lacked siliciclastic material and arecharacterized by very low accumulation rates, whereas early deglacial-time (Termination I, TI) deposits are dominated bya siliciclastic and neritic carbonate pulse. Siliciclastic sedimentation was significantly reduced in the Holocene, while carbonatesedimentation remains elevated. A new borehole, IODP Expedition 325 Hole M0058A (Hole 58A), recovered 82% of a 40.4 mhole on the upper slope east of Noggin Passage on the central GBR margin near Cairns, Australia. Hole 58A providesa detailed sedimentary record during Termination II (TII), Marine Isotope Stage 6/5e (MIS-6/5e), deglacial transition, andthrough most of interglacial MIS-5. This hole, along with two others (ODP Leg 133 Holes 820A and 819A from the upperslope east of Grafton Passage), show carbonate–siliciclastic cyclicity as the result of glacioeustatic change with the GBR shelf.Sedimentation at Hole 58A is consistent with that of previous studies along the GBR margin (focusing on the LGM to present),and extends the upper-slope sedimentary record back to TII and interglacial MIS-5. A siliciclastic pulse similar to the oneduring TI occurred during the penultimate deglaciation, TII; however, the maximum neritic aragonite export to the upper slopeoccurred not during peak MIS-5e highstand when sea level was a few meters above modern position, but subsequently duringa time (MIS-5d to 5a) when lowered sea level fluctuated between 30 and 50 m below present sea level. Siliciclastic sedimentswere reworked and exported to the upper slope when the lowstand fluvial plain was re-flooded, whereas neritic carbonate exportto the slope reached a maximum when sea level fell and much of the mid to outer shelf re-entered the photic zone, subsequent toa drowning interval. Thus, this analysis refines the mixed-sedimentation models of upper-slope sedimentation along the centralGBR margin during the penultimate deglacial transgression and subsequent interglacial early and late highstand. This studyprovides further evidence that mixed carbonate–siliciclastic margins do not always behave in a predictable manner and thatmixed margins both modern and ancient would benefit from detailed study of sediment transport in the context of sea-level riseand fall.

International audience; This paper aims to reconstruct the palaeogeographic evolution of the Llanura Costera del Caribe (LCC) in eastern Hispaniola (Dominican Republic) during the Pleistocene, adding new insights to published information on Pliocene–Early Pleistocene deposits. The LCC is a generally flat region comprising the unfolded sedimentary cover of the Cordilleras Central and Oriental. Within this cover, the Pliocene–Early Pleistocene Yanigua Formation,mainly consisting of marl, changes seawards to the mainly limestone Los Haitises Formation. Both units formed in a shallow-water platform rimmed by a reef barrier at least in the latest depositional stages. The overlying Pleistocene La Isabela Formation consists of two major offlapping reef terraces, in which a reef core enclosed a lagoon, and prograded over forereef bioclastic debris. Two belts in LCC's morphostructure directly reflect its sedimentary evolution. The Inner Belt extends over the marly substrate of the Yanigua Formation and the Coastal Belt comprises three major surfaces corresponding to the depositional top of the Los Haitises Formation (Upper Surface), and to the Upper and Lower terraces of the La Isabela Formation (Intermediate and Lower Surfaces, respectively). The MIS 5e age of the 10–20 m high Lower Terrace implies a low uplift rate of 0.033–0.068 mm/yr for the Lower Surface. The Pliocene–Early Pleistocene platform was emergent in the Early–Middle Pleistocene. The Early Pleistocene reef barrier separated endorheic watersheds extending over the former shelf lagoon from the open ocean. Reefs built the Upper Terrace of the La Isabela Formation during one or several Middle Pleistocene highstands and the Lower Terrace during MIS 5e and previous highstands. Siliciclastic deposits in this terrace record the opening to the Caribbean Sea of watersheds in the eastern LCC. The Lower Terrace emersion and opening of the large drainage systems of the western and central LCC took place after MIS 5e. Relative sea level fall and emersion of a large area did not imply increased terrigenous sedimentation in the adjacent marine basin. Development of endorheic watersheds over most of the emergent surface delayed the diachronic arrival of siliciclastics into the marine basin for hundreds of thousands of years.

Tropical south-western Pacific temperatures are of vital importance to the Great Barrier Reef (GBR), but the role of sea surface temperatures (SSTs) in the growth of the GBR since the Last Glacial Maximum remains largely unknown. Here we present records of Sr/Ca and δ18O for Last Glacial Maximum and deglacial corals that show a considerably steeper meridional SST gradient than the present day in the central GBR. We find a 1–2 °C larger temperature decrease between 17° and 20°S about 20,000 to 13,000 years ago. The result is best explained by the northward expansion of cooler subtropical waters due to a weakening of the South Pacific gyre and East Australian Current. Our findings indicate that the GBR experienced substantial meridional temperature change during the last deglaciation, and serve to explain anomalous deglacial drying of northeastern Australia. Overall, the GBR developed through significant SST change and may be more resilient than previously thought., The Great Barrier Reef (GBR) is under threat from rising ocean temperatures, yet its response to past temperature change is poorly known. Felis et al. show that the GBR experienced a much steeper temperature gradient during the last deglaciation, suggesting it may be more resilient than previously thought.

Measurements of dissolved Th-230, Pa-231 and Th-232 were made for twelve full-depth profiles along a Southwest Atlantic section during GEOTRACES cruise GA02S. Sampling captures all the main Atlantic deep water masses along their meridional flow paths and allows insight into the control on Th and Pa in a setting where waters are flowing in opposing directions, with direct relevance to understanding the use of Pa-231/Th-230 as an ocean-circulation proxy. Water-column Th-230 increases linearly with depth, in line with expected reversible scavenging models. Pa-231 increases from the surface to similar to 1200-1500 m, but is invariant or decreases with greater depth, deviating from the behavior expected for reversible scavenging. Dissolved Pa-231/Th-230 ratios display a mid-water-column maximum at similar to 1000-2000 m which is broadly coincident with Upper Circumpolar Deep Water. Below 2000 m, nuclide distributions and ratios exhibit no dependence on water mass, nor any indication of progressive change within a water mass, challenging the use of Pa-231/Th-230 as a past circulation tracer in the South Atlantic. Calculation of horizontal transport of Th-230 and Pa-231 by ocean circulation indicates a net southward export out of the Atlantic of 19% of the Pa-231 and 3% of the Th-230 produced in that ocean. This removal is all from the North Atlantic while, in the South Atlantic, removal to sediment equals production. Simple one-dimensional modeling can simulate Th-230 profiles but not the mid-water-column maximum observed in Pa-231 profiles, suggesting an additional source of Pa-231 (perhaps lateral transport from the margin) or removal at depth due to bottom scavenging. Near seafloor minima in concentrations indicates bottom scavenging of Th-230 and (231)pa, which is enhanced in the presence of nepheloid layers, particularly for 231Pa. This additional scavenging fractionates Th-230 and Pa-231 and, in the presence of nepheloid layers, may lead to an increase in sedimentary Pa-231/Th-230 ratios. Th-232 concentrations were paired with Th-230-derived residence times in the upper 250 m of the water column to test the application of Th as a tracer of dust deposition. Maxima in Th-232 indicate high dust input from the African and possibly South American continents.

Submerged reefs are important recorders of palaeo-environments and sea-level change, and provide a substrate for modern mesophotic (deep-water, light-dependent) coral communities. Mesophotic reefs are rarely, if ever, described from the fossil record and nothing is known of their long-term record on Great Barrier Reef (GBR). Sedimentological and palaeo-ecological analyses coupled with 67 14C AMS and U-Th radiometric dates from dredged coral, algae and bryozoan specimens, recovered from depths of 45 to 130 m, reveal two distinct generations of fossil mesophotic coral community development on the submerged shelf edge reefs of the GBR. They occurred from 13–10 ka and 8 ka to present. We identified eleven sedimentary facies representing both autochthonous (in situ) and allochthonous (detrital) genesis, and their palaeo-environmental settings have been interpreted based on their sedimentological characteristics, biological assemblages, and the distribution of similar modern biota within the dredges. Facies on the shelf edge represent deep sedimentary environments, primarily forereef slope and open platform settings in palaeo-water depths of 45–95 m. Two coral-algal assemblages and one non-coral encruster assemblage were identified: 1) Massive and tabular corals including Porites, Montipora and faviids associated with Lithophylloids and minor Mastophoroids, 2) platy and encrusting corals including Porites, Montipora and Pachyseris associated with melobesioids and Sporolithon, and 3) Melobesiods and Sporolithon with acervulinids (foraminifera) and bryozoans. Based on their modern occurrence on the GBR and Coral Sea and modern specimens collected in dredges, these are interpreted as representing palaeo-water depths of < 60 m, < 80–100 m and > 100 m respectively. The first mesophotic generation developed at modern depths of 85–130 m from 13–10.2 ka and exhibit a deepening succession of < 60 to > 100 m palaeo-water depth through time. The second generation developed at depths of 45–70 m on the shelf edge from 7.8 ka to present and exhibit stable environmental conditions through time. The apparent hiatus that interrupted the mesophotic coral communities coincided with the timing of modern reef initiation on the GBR as well as a wide-spread flux of siliciclastic sediments from the shelf to the basin. For the first time we have observed the response of mesophotic reef communities to millennial scale environmental perturbations, within the context of global sea-level rise and environmental changes.

During Integrated Ocean Drilling Program Expedition 325, 34 holes were drilled along five transects in front of the Great Barrier Reef of Australia, penetrating some 700 m of late Pleistocene reef deposits (post-glacial; largely 20 to 10 kyr bp) in water depths of 42 to 127 m. In seven holes, drilled in water depths of 42 to 92 m on three transects, older Pleistocene (older than last glacial maximum, >20 kyr bp) reef deposits were recovered from lower core sections. In this study, facies, diagenetic features, mineralogy and stable isotope geochemistry of 100 samples from six of the latter holes were investigated and quantified. Lithologies are dominated by grain-supported textures, and were to a large part deposited in high-energy, reef or reef slope environments. Quantitative analyses allow 11 microfacies to be defined, including mixed skeletal packstone and grainstone, mudstone-wackestone, coral packstone, coral grainstone, coralline algal grainstone, coral-algal packstone, coralline algal packstone, Halimeda grainstone, microbialite and caliche. Microbialites, that are common in cavities of younger, post-glacial deposits, are rare in pre-last glacial maximum core sections, possibly due to a lack of open framework suitable for colonization by microbes. In pre-last glacial maximum deposits of holes M0032A and M0033A (>20 kyr bp), marine diagenetic features are dominant; samples consist largely of aragonite and high-magnesium calcite. Holes M0042A and M0057A, which contain the oldest rocks (>169 kyr bp), are characterized by meteoric diagenesis and samples mostly consist of low-magnesium calcite. Holes M0042A, M0055A and M0056A (>30 kyr bp), and a horizon in the upper part of hole M0057A, contain both marine and meteoric diagenetic features. However, only one change from marine to meteoric pore water is recorded in contrast with the changes in diagenetic environment that might be inferred from the sea-level history. Values of stable isotopes of oxygen and carbon are consistent with these findings. Samples from holes M0032A and M0033A reflect largely positive values (δO: -1 to +1‰ and δC: +1 to +4‰), whereas those from holes M0042A and M0057A are negative (δO: -4 to +2‰ and δC: -8 to +2‰). Holes M0055A and M0056A provide intermediate values, with slightly positive δC, and negative δO values. The type and intensity of meteroric diagenesis appears to have been controlled both by age and depth, i.e. the time available for diagenetic alteration, and reflects the relation between reef deposition and sea-level change.

Measurements of excess 230Th (230Thxs) have proved to be a useful tool in constraining changes in sedimentation rate, and improving our understanding of the fluxes of other components into marine sediments. To obtain the initial activity of 230Thxs (230Thxs0) in sediment: the total measured 230Th must be corrected for the presence of 230Th associated with detrital minerals, for ingrowth from uranium-bearing authigenic phases and then also corrected for the decay of 230Thxs since deposition. We describe a number of improvements in the way these corrections are applied to obtain more accurate determinations of 230Thxs0. We present a new method for the determination of a local estimate for the detrital 238U/232Th activity ratio; suggest more appropriate values for the isotopic composition of authigenic uranium; and question the assumption of secular equilibrium in detrital material. We also present a new, freely-available MATLAB® script called ‘XSage’ that can calculate 230Thxs0, from user-supplied datasets of uranium and thorium isotope activities from sedimentary samples following the theoretical approach described. ‘XSage’ can determine variations in sedimentation rate between stratigraphic horizons of known age and thus produce high-resolution age models. Using a Monte Carlo approach, the program calculates uncertainties for these age models and on the durations of intervals between tie-points. An example of the application of the XSage program using a previously published record is provided.

Geomagnetic excursions are recognized as intrinsic features of the Earth's magnetic field. High-resolution records of field behaviour, captured in marine sedimentary cores, present an opportunity to determine the temporal and geometric character of the field during geomagnetic excursions and provide constraints on the mechanisms producing field variability. We present here the highest resolution record yet published of the Blake geomagnetic excursion (similar to 125 ka) measured in three cores from Ocean Drilling Program (ODP) Site 1062 on the Blake-Bahama Outer Ridge. The Blake excursion has a controversial structure and timing but these cores have a sufficiently high sedimentation rate (similar to 10 cm ka(-1)) to allow detailed reconstruction of the field behaviour at this site during the excursion. Palaeomagnetic measurements of the cores reveal rapid transitions (

Past sea-level records provide invaluable information about the response of ice sheets to climate forcing. Some such records suggest that the last deglaciation was punctuated by a dramatic period of sea-level rise, of about 20 metres, in less than 500 years. Controversy about the amplitude and timing of this meltwater pulse (MWP-1A) has, however, led to uncertainty about the source of the melt water and its temporal and causal relationships with the abrupt climate changes of the deglaciation. Here we show that MWP-1A started no earlier than 14,650 years ago and ended before 14,310 years ago, making it coeval with the Bolling warming. Our results, based on corals drilled offshore from Tahiti during Integrated Ocean Drilling Project Expedition 310, reveal that the increase in sea level at Tahiti was between 12 and 22 metres, with a most probable value between 14 and 18 metres, establishing a significant meltwater contribution from the Southern Hemisphere. This implies that the rate of eustatic sea-level rise exceeded 40 millimetres per year during MWP-1A.

Fossil corals are unique archives of past seasonal climate variability, providing vital information about seasonal climate phenomena such as ENSO and monsoons. However, submarine diagenetic processes can potentially obscure the original climate signals and lead to false interpretations. Here we demonstrate the potential of laser ablation ICP-MS to rapidly detect secondary aragonite precipitates in fossil Porites colonies recovered by Integrated Ocean Drilling Program (IODP) Expedition 310 from submerged deglacial reefs off Tahiti. High resolution (100μm) measurements of coralline B/Ca, Mg/Ca, S/Ca, and U/Ca ratios are used to distinguish areas of pristine skeleton from those afflicted with secondary aragonite. Measurements of coralline Sr/Ca, U/Ca and oxygen isotope ratios, from areas identified as pristine, reveal that the seasonal range of sea surface temperature in the tropical south Pacific during the last deglaciation (14.7 and 11. ka) was similar to that of today. © 2010 Elsevier Ltd.

Early Riser How glacial-interglacial cycles and the long-term variability of sea level depend on the amount of energy received by Earth from the Sun is unclear. Thomas et al. (p. 1186 , published online 23 April; see the cover) report results from fossil corals found in Tahiti that indicate that sea level began to rise when insolation at 65° North latitude was near a minimum, not after it had begun to rise, as predicted by the Milankovitch theory. In contrast, the timing of the last deglaciation agrees well with the Milankovitch theory. Thus, glacial cycles do not behave as simply as the Milankovitch theory suggests.

This manuscript describes a new protocol for determination of Pa/Th/U in marine sediments. It is based on microwave-assisted digestion and represents an important reduction of working time over conventional hot-plate digestion methods, and the use of HClO(4) is avoided. Although Th and U are completely dissolved with a first microwave step, around 40% of (231)Pa remains undissolved, and a short hot-plate step with reverse aqua regia is required to achieve total digestion and spike equilibration. Next, the method involves a separation of these elements and a further purification of the Pa fraction using Dowex AG1-X8 resin. Separation with Bio-Rad and Sigma-Aldrich resins was compared; although both perform similarly for Th and U, Pa yields are higher with Bio-Rad. Finally, samples are measured using a Nu instruments multiple collector inductively coupled plasma mass spectrometer (MC-ICPMS). Overall chemical yields range around 50% for Pa, 60% for Th, and 70% for U.

A down-core 231Pa/230Th record has been measured from the southwestern Indian Ocean to reconstruct the history of deep water flow into this basin over the last glacial-interglacial cycle. The (231Paxs/230Thxs)0 ratio throughout the record is nearly constant at approximately 0.055, significantly lower than the production ratio of 0.093, indicating that the proxy is sensitive to changes in circulation and/or sediment flux at this site. The consistent value suggests that there has been no change in the inflow of Antarctic Bottom Water to the Indian Ocean during the last 140 ka, in contrast to the changes in deep circulation thought to occur in other ocean basins. The stability of the (231Paxs/230Thxs)0 value in the record contrasts with an existing sortable silt (SS) record from the same core. The observed SS variability is attributed to a local geostrophic effect amplifying small changes in circulation. A record of authigenic U from the same core suggests that there was reduced oxygen in bottom waters at the core locality during glacial periods. The consistency of the (231Paxs/230Thxs)0 record implies that this could not have arisen by local changes in productivity, thus suggesting a far-field control: either globally reduced bottom water oxygenation or increased productivity south of the Opal Belt during glacials.

The process of plate tectonics continually returns material from the Earth's surface to its interior. A major goal of geochemists has been to see if convective flow within the Earth ever allows such compositionally distinctive material to return to the surface. A study of lithium isotope variations in the upper mantle now provides firm evidence for such a 'recycled' signature in the chemical compositions of some submarine lavas that sample the convecting interior of the Earth. Yet the 'recycled' signature they record appears to arise not from former crustal plates themselves, as was expected, but from mantle material influenced by the subducting crust at convergence zones. The fate of the plates themselves thus remains elusive. ‘Recycled’ crustal materials, returned from the Earth's surface to the mantle by subduction, have long been invoked to explain compositional heterogeneity in the upper mantle1. Yet increasingly, problems have been noted with this model2,3. The debate can be definitively addressed using stable isotope ratios, which should only significantly vary in primitive, mantle-derived materials as a consequence of recycling. Here we present data showing a notable range in lithium isotope ratios in basalts from the East Pacific Rise, which correlate with traditional indices of mantle heterogeneity (for example, 143Nd/144Nd ratios). Such co-variations of stable and radiogenic isotopes in melts from a normal ridge segment provide critical evidence for the importance of recycled material in generating chemical heterogeneity in the upper mantle. Contrary to many models, however, the elevated lithium isotope ratios of the ‘enriched’ East Pacific Rise lavas imply that subducted ocean crust is not the agent of enrichment. Instead, we suggest that fluid-modified mantle, which is enriched during residency in a subduction zone, is mixed back into the upper mantle to cause compositional variability.

This thesis considers the use of two U-series nuclides – 231 Pa and 230 Th – as proxies for studying ocean circulation. A total of six water-column profiles of 231 Pa, 230 Th, and 232 Th have been measured from two regions of the southwestern Indian Ocean: the Madagascar and Mascarene Basins; and the southeastern continental margin of South Africa. Measurement by MC-ICP-MS of 10 litre water samples is possible for samples with as little as 4 and 2 fg of 231 Pa and 230 Th and yields typical uncertainties of 6% and 14% respectively. These profiles show that the scavenging and advection histories of water masses can affect their 231 Pa concentration, with distinct variations superimposed on a general increase in concentration with depth due to reversible scavenging. A 1D particle scavenging model is used to show that sedimentary (231 Paxs /230 Thxs )0 is most representative of the (231 Pa/230 Th) of the bottom most water mass at any one locality, although in turn this water mass (231 Pa/230 Th) will be dependent not only on its advection and scavenging history but also the 231 Pa and 230 Th concentrations of the overlying water masses during advection. Acknowledgment that sedimentary (231 Paxs /230 Thxs )0 is “set” by the bottommost water mass is important for interpretation of scenarios where changes in depth of circulation, as well as circulation strength, may have occurred. A record of sedimentary (231 Paxs /230 Thxs )0 has been recovered from a 6 m Kasten core from the Mascarene Basin covering the past 140 ka, in order to reconstruct flow of AABW into the basin. The (231 Paxs /230 Thxs )0 measured is below the production ration of 0.093 and shows no significant variation. This indicates that (231 Paxs /230 Thxs )0 is sensitive to changes in particle productivity and circulation at this location and that there has been little or no change in either environmental variable over the last full interglacial-glacial cycle. This finding is in contrast to other ocean basins, particularly the North Atlantic, where large changes in circulation are observed.

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca. 2 ng of Li. Les rapports isotopiques du Li de 4 materiaux de reference, de provenance Internationale, BHVO-2, JB-2, JG-2, JA-1 et d'eau de mer (Mediterranee, Pacifique et Atlantique Nord) ont ete determines par MC-ICP-MS (spectrometrie de masse avec source a plasma induit a multicollection). Ces materiaux de reference naturels ont ete choisis car ils balaient un large champ des rapports isotopiques du Lithium et couvrent differentes matrices afin de fournir un point de repere utile pour les etudes futures. Notre nouvelle technique analytique permet d'atteindre une precision et une reproductibilite (< ± 0.3%. 2s) nettement superieures a celles des methodes precedemment utilisees et presente I'avantage de pouvoir travailler avec des echantillons de petite masse, ∼ 2 ng de Li.