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This study used alfa grass fibres as a natural low-cost adsorbent to remove lead, copper, and zinc ions from aqueous solutions. The adsorbent was characterized by FTIR, SEM, BET surface area, ATG, and XRD techniques. The effects of pH, contact time, initial metal concentration, and adsorbent dosage on the adsorption efficiency were evaluated in batch experiments. The results showed that the adsorption of all metals was fast, and optimal removal efficiency was achieved within 25 min of contact time using 5000 mg/L of Alfa fibres at pH 6.3. The adsorption selectivity order was Pb2+ > Cu2+ > Zn2+ with Pb2+ removal efficiencies up to 97.6%. The adsorption kinetics were best explained by a pseudo-second-order kinetic model. The experimental adsorption data fitted very well with the Langmuir isotherm model, and less well with the Freundlich and Temkin isotherm models. The maximum adsorption capacities were respectively 14.492, 11.904, and 8.695 mg/g for Pb2+, Cu2+, and Zn2+. The results of this study indicated that Alfa fibres could be used as effective adsorbent for the removal of Pb2+, Cu2+, and Zn2+ from aqueous solutions. [ABSTRACT FROM AUTHOR]

Biosorption is an efficient and cost-effective method for heavy metals' remediation. However, saturated biosorbents may pose a serious problem for the environment. Flax fibres have shown very good adsorption capacities to remove zinc, copper and lead ions from contaminated aqueous solutions. In this study, adsorption–desorption cycles were conducted with loaded flax fibres in batch mode to recover heavy metals using four types of solutions: hydrochloric acid solution, nitric acid solution, sodium hydroxide solution and ultrapure water. Desorption kinetic studies, conducted with loaded flax fibres, showed very fast desorption of zinc, copper and lead when using nitric and hydrochloric acids with a selectivity sequence of Zn (totally desorbed) > Cu (94%) > Pb (80–73%). Desorption kinetic was slower with the use of sodium hydroxide and showed much lower desorption rates of Zn (62%) > Pb (12%) > Cu (7%). Desorption of zinc and copper from previously loaded fibres from binary metal ion system in lead solution was also investigated. Different concentrations ranging from 0.04 to 0.20 mmol/L were tested. The obtained results demonstrated a significant release in the order Zn (18–90%) > Cu (2–42%), while lead was still efficiently adsorbed. Retention efficiencies of zinc and copper and adsorption efficiency of lead resulted in the same adsorption efficiencies of the three metal ions onto flax fibres in the ternary metal ion system. [ABSTRACT FROM AUTHOR]

This study investigates the impact of interruption of injections on the transfer and retention of suspended particles (SP) in granular media. Columns packed with sand were operated in the laboratory, and a series of experiments of SP injections were conducted: the first by injecting SP without interrupting injection, the second and third experiments with 3 pauses of injection of 24 h and 48 h, respectively. Results showed that interrupted injections induced a significant release of particles showing peaks of concentration in the effluent immediately after the pause periods. These peaks increase with pause durations. Interruption of injections allowed the transport of coarser particles deeper into the columns. For all experiments carried out, the hydraulic conductivity, measured during injection, decreased with the number of pore volumes injected. This decrease is almost linear for continuous injection experiments. Whereas, the hydraulic conductivity decreased brutally when reinjecting SP, after pauses, highlighting the desaturation of the porous medium during pause periods. The results obtained show that all the phenomena (hydraulic conductivity drop, SP transport, and deeper transfer of coarser particles) occurred during the dynamic phase of the experiments for the first 75% of pore volumes injected. Beyond that, the porous medium is completely clogged. [ABSTRACT FROM AUTHOR]

Many geotechnical problems involve pavements in Algerian arid regions; the main among them being related to the scarcity of standard materials. Recently, numerous studies were carried out on the valorization of Saharan local materials for pavement design. In this context, dune sand, tuff and quarry waste are promising alternatives. In this study, the design of experiments was used to optimize formulations to meet the current unconfined compressive strength (UCS) recommendations according to grading distribution. For the studied local material, the use of UCS criterion extended the valid domain of formulations to poorly graded materials where the amount of dune sand could reach 54.5%. An optimal formulation was proposed and tested, composed of 46% dune sand, 36% tuff, 11% quarry waste and 7% water, fulfilling all current recommendations related to the pavement design in the Sahara region. Finally, the results show that the design of experiments can be a useful tool to optimize mixture formulations and valorize local materials such as dune sand. [ABSTRACT FROM AUTHOR]

A cotransport study of heavy metals and kaolinite particles in sand column with and without flax geotextiles was carried out. The objectives were to evaluate the potential role of kaolinite in heavy metals transfer and to analyse the influence of flax geotextiles on the transfer of these pollutants. The adsorption rates of heavy metals on the kaolinite particles were, respectively, 53%, 65% and 25% for copper, lead, and zinc. The injection of kaolinite with heavy metals resulted in a significant decrease in the retention efficiency of copper and lead in the filter. The presence of kaolinite in the injected solution has virtually no influence on the effectiveness of zinc fixation in the filter. The retention of heavy metals is in the order of Zn > Cu > Pb with a significant drop of retention efficiency of 34% for copper, 67% for lead, and less than 1% for zinc. The presence of kaolinite in the injected solution reversed the retention order of heavy metals when metals solution was injected alone. Flax geotextiles increase the ability of the filter to retain soluble and attached heavy metals. It improves the sand retention capacity and it retains soluble and attached metals in its structure. [ABSTRACT FROM AUTHOR]

Filtration tests were carried out in laboratory columns filled with crushed sand with and without flax geotextiles to study the transfer and retention of soluble heavy metals. Divalent cations of copper, zinc and lead were simultaneously and continuously injected in filtration columns. Results show that, when geotextiles discs are present the retention of metals in sand is favoured and retention profiles are modified. In addition, and unlike synthetic geotextiles, flax fibres geotextiles contribute to the retention of a significant fraction of the cationic metal pollutants in their own structure. The overall metals retention efficiency of the filter is improved. Competition between cationic metals for adsorption on retention sites occurs in the column in the order Pb > Cu > Zn. Most of the lead is retained in the inlet of the column while copper and even more zinc migrate deeper in the column. [ABSTRACT FROM AUTHOR]

A study was undertaken to characterise the evolution of the clogging of various porous media during filtration experiments. Long-term tracer tests were carried out at various flow velocities. To highlight the effects of intraporosity on transport and retention mechanisms, both single porosity and double porosity media (DPM) were used. The presence of matrix porosity in the two investigated DPM provided additional sites, promoting retention of suspended particles (SP). The particle size distribution (PSD) of the recovered particles increased with time. However, and due to the additional retention sites in intraporosity, the changes in PSD with time were slower for tests on DPM. Ultrasonic transmission was used to detect modifications to the properties of the porous media induced by particle retention. The results demonstrate the capacity of ultrasound for detecting the evolution of physical clogging as a consequence of particle deposition. [ABSTRACT FROM AUTHOR]