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Copyright of Iraqi Journal of Chemical & Petroleum Engineering is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The cost‐effective dual functions zeolite‐carbon composite (DFZCC) was prepared using an eco‐friendly substrate prepared from bio‐waste and an organic adhesive at intermediate conditions. The green synthesis method used in this study ensures that chemically harmless compounds are used to obtain a homogeneous distribution of zeolite over porous carbon. The greenly prepared dual‐function composite was extensively characterized using Fourier transform infrared, X‐ray diffraction, thermogravimetric analysis, N2 adsorption/desorption isotherms, field emission scanning electron microscope, dispersive analysis by X‐ray, and point of zero charges. DFZCC had a surface area of 248.84 m2/g and a pore volume of 0.141 cm3/g. DFZCC was used in the sorption process of Zn2+ ions from aqueous solutions, and it achieved higher removal (98%) at normal pH of 6.4 and temperature of 40°C. The Langmuir model was the best model for representing equilibrium data with a maximum sorption capacity of 6.711 mg/g. The kinetic studies showed that the pseudo‐second‐order model was the most appropriate model for representing experimental data. The intra‐particle diffusion kinetics demonstrated that the boundary film is the rate‐determining step in the sorption process. The sorption process of Zn2+ ions by DFZCC was spontaneous and endothermic. Moreover, solidification of the spent DFZCC by kaolin successfully reduced the leaching ions to the solution after 12 weeks from exposure to a salty solution. [ABSTRACT FROM AUTHOR]

Porous materials play an important role in creating a sustainable environment by improving wastewater treatment's efficacy. Porous materials, including adsorbents or ion exchangers, catalysts, metal–organic frameworks, composites, carbon materials, and membranes, have widespread applications in treating wastewater and air pollution. This review examines recent developments in porous materials, focusing on their effectiveness for different wastewater pollutants. Specifically, they can treat a wide range of water contaminants, and many remove over 95% of targeted contaminants. Recent advancements include a wider range of adsorption options, heterogeneous catalysis, a new UV/H2O2 procedure, ion exchange, Fenton oxidation, membrane activities, ozonation, membrane bioreactor, electrochemical treatment, wet air oxidation, and a carbon capture methodology utilizing various porous materials. A particular focus for innovative research is on developing technologies to synthesize porous materials and assess their performance in removing various pollutants from wastewater at varying experimental conditions. Porous materials can be essential in designing wastewater treatment systems to address the critical environmental issues of water stress and safe drinking water worldwide. [ABSTRACT FROM AUTHOR]

This work presents the development of polyvinyl chloride/functionalised multi-carbon nanotube (PVC/F-MWCNT) membranes and PVC/graphene oxide (PVC/GO) membranes for the improved removal of chemical oxygen demand (COD) from actual petroleum wastewater. Also, this work for the first time presents the proposed interaction mechanism between the contents of PVC/GO and PVC/F-MWCNT membranes as well as the interaction mechanism of each composite membrane with water molecules. The effect of both F-MWCNT and GO content on the characteristics and performance of the PVC/F-MWCNT membrane and PVC/GO membrane were studied. Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscope (SEM), atomic force microscopy (AFM), contact angle (CA), differential scanning calorimetry (DSC), porosity and tensile strength were used to examine the properties of F-MWCNT, GO, PVC/F-MWCNT and PVC/GO membranes. The composite membranes' performance was studied by measuring the rejection of chemical oxygen demand (COD) and mass flux. It was found that F-MWCNTs and GO played significant roles in the membranes' structural morphology. A significant improvement was obtained in the CA, porosity and tensile strength of the membranes by embedding the PVC casting solution with 0.12 wt% of each F-MWCNTand GO. The PVC/F-MWCNTs membrane showed higher performance in term of mass flux and COD rejection that reached 88.9%, which makes using a PVC/F-MWCNTs membrane preferable to remove COD from petroleum wastewater. [ABSTRACT FROM AUTHOR]

The present study investigated the thermodynamic properties of Mefenamic acid tablets at three temperatures (25, 35, 45oC) based on the experimental sorption data studied earlier in a previous study. The net isosteric heat of adsorption and the differential entropy were found to decrease as the water activity increases. A 4th order polynomial equation described both of them. A linear enthalpy-entropy relationship is disclosed with 95.6 % correlation factor. The isokinetic temperature was differed significantly from the harmonic mean temperature implying the linear enthalpy-entropy compensation and enthalpy drawn adsorption process. The enthalpies associated to GAB's model (GAB: Guggenhein - Anderson and de Boer) were also investigated and discussed. [ABSTRACT FROM AUTHOR]

Copyright of Iraqi Journal of Chemical & Petroleum Engineering is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

This paper presents studying the performance of three types of polyethersulfone (PES) membrane for the simultaneous removal of Co2+ ions, Cd2+ ions, and Pb2+ ions from binary and ternary aqueous solutions. Co2+ ions, Cd2+ ions, and Pb2+ ions with two different initial concentrations (e.g., 10 and 50 ppm) were selected as examples of heavy metals that contaminate the groundwater as a result of geological and human activities. This study investigated the effect of types of PES membrane and metal ions concentration on the separation process. For the binary aqueous solutions, the permeation flux of the PES2 membranes was higher for the separation process of solutions containing 50 ppm of Cd2+ ions and 10 ppm of Co2+ ions (24.7 L/m2·h) and Pb2+ ions (23.7 L/m2·h). All the metals in the binary solutions had high rejection when their initial concentration was lower than the initial concentration of the other metal present in the same solution. Using PES2, the maximum rejection of Cd2+ ions was 61.3% when the initial concentrations were 50 ppm Pb2+ ions: 10 ppm Cd2+ ions and 55.4% for Pb2+ ions when the initial concentrations were 10 ppm Pb2+ ions: 50 ppm Cd2+ ions. For the ternary aqueous solutions, the rejection and the permeation flux of the PES membranes increased with decreasing the heavy metal initial concentration. Using PES2, the maximum permeation flux was 21.6 L/m2·h when the initial concentration of the metals was 10 ppm; and the maximum rejection of the metals obtained at initial concentration of 10 ppm was 50.5% for Co2+ ions, 48.3% for Cd2+ ions, and 40% for Pb2+ ions. The results of the filtration process using PES2 of simulated contaminated-groundwater indicated the efficient treatment of groundwater containing Co2+, Cd2+, and Pb2+ ions. [ABSTRACT FROM AUTHOR]

The present work reports the performance of three types of polyethersulfone (PES) membrane in the removal of highly polluting and toxic lead Pb 2+ and cadmium Cd 2+ ions from a single salt. This study investigated the effect of operating variables, including pH, types of PES membrane, and feed concentration, on the separation process. The transport parameters and mass transfer coefficient (k) of the membranes were estimated using the combined film theory-solution-diffusion (CFSD), combined film theory-Spiegler-Kedem (CFSK), and combined film theory-finely-porous (CFFP) membrane transport models. Various parameters were used to estimate the enrichment factors, concentration polarization modulus, and Péclet number. The pH values significantly affected the permeation flux of the Pb 2+ solution but only had a slight effect on the Cd 2+ solution. However, Cd 2+ rejection was highly improved by increasing the pH value. The rejection of the PES membranes increased greatly as the heavy metal concentration rose, while the heavy metal concentration moderately affected the permeation flux. The maximum rejection of Pb 2+ in a single-salt solution was 99%, 97.5%, and 98% for a feed solution containing 10 mg Pb/L at pH 6, 6.2, and 5.7, for PES1, PES2, and PES3, respectively. The maximum rejection of Cd 2+ in single-salt solutions was 78%, 50.2%, and 44% for a feed solution containing 10 mg Cd/L at pH 6.5, 6.2, and 6.5, for PES1, PES2, and PES3, respectively. The analysis of the experimental data using the CFSD, CFSK, and CFFP models showed a good agreement between the theoretical and experimental results. The effective membrane thickness and active skin layer thickness were evaluated using the CFFP model, indicating that the Péclet number is important for determining the mechanism of separation by diffusion., Competing Interests: The authors declare no conflict of interest.