Search

Molecular deuteration is a powerful diagnostic tool for probing the physical conditions and chemical processes in astrophysical environments. In this work, we focus on formaldehyde deuteration in the protobinary system NGC\,1333 IRAS\,4A, located in the Perseus molecular cloud. Using high-resolution ($\sim$\,100\,au) ALMA observations, we investigate the [D$_2$CO]/[HDCO] ratio along the cavity walls of the outflows emanating from IRAS\,4A1. Our analysis reveals a consistent decrease in the deuteration ratio (from $\sim$\,60-20\% to $\sim$\,10\%) with increasing distance from the protostar (from $\sim$\,2000\,au to $\sim$\,4000\,au). Given the large measured [D$_2$CO]/[HDCO], both HDCO and D$_2$CO are likely injected by the shocks along the cavity walls into the gas-phase from the dust mantles, formed in the previous prestellar phase. We propose that the observed [D$_2$CO]/[HDCO] decrease is due to the density profile of the prestellar core from which NGC\,1333 IRAS\,4A was born. When considering the chemical processes at the base of formaldehyde deuteration, the IRAS\,4A's prestellar precursor had a predominantly flat density profile within 3000\,au and a decrease of density beyond this radius.

Characterizing the chemistry of complex organic molecules (COMs) at the epoch of planet formation provides insights into the chemical evolution of the interstellar medium (ISM) and the origin of organic materials in our Solar System. We report a detection of dimethyl ether (CH$_3$OCH$_3$) in the disk around the Herbig Ae star MWC 480 with the sensitive Atacama Large Millimeter/submillimeter Array observations. This is the first detection of CH$_3$OCH$_3$ in a non-transitional Class II disk. The spatially unresolved, compact (${\lesssim}$25 au in radius) nature, the broad line width ($\sim$30 km s$^{-1}$), and the high excitation temperature (${\sim}$200 K) indicate sublimation of COMs in the warm inner disk. Despite the detection of CH$_3$OCH$_3$, methanol (CH$_3$OH), the most abundant COM in the ISM, has not been detected, from which we constrain the column density ratio of CH$_3$OCH$_3$/CH$_3$OH ${\gtrsim}$7. This high ratio may indicate the reprocessing of COMs during the disk phase, as well as the effect of the physical structure in the inner disk. We also find that this ratio is higher than in COM-rich transition disks recently discovered. This may indicate that, in the full disk of MWC 480, COMs have experienced substantial chemical reprocessing in the innermost region, while the COM emission in the transition disks predominantly traces the inherited ice sublimating at the dust cavity edge located at larger radii (${\gtrsim}$20 au)., Comment: 16 pages, 6 figures, accepted for publication in ApJ

We present Atacama Large Millimeter/submillimeter Array (ALMA) observations of the binary Class 0 protostellar system BHR 71 IRS1 and IRS2 as part of the Early Planet Formation in Embedded Disks (eDisk) ALMA Large Program. We describe the $^{12}$CO ($J$=2--1), $^{13}$CO ($J$=2--1), C$^{18}$O ($J$=2--1), H$_2$CO ($J=3_{2,1}$--$2_{2,0}$), and SiO ($J$=5--4) molecular lines along with the 1.3 mm continuum at high spatial resolution ($\sim$0.08" or $\sim$5 au). Dust continuum emission is detected toward BHR 71 IRS1 and IRS2, with a central compact component and extended continuum emission. The compact components are smooth and show no sign of substructures such as spirals, rings or gaps. However, there is a brightness asymmetry along the minor axis of the presumed disk in IRS1, possibly indicative of an inclined geometrically and optically thick disk-like component. Using a position-velocity diagram analysis of the C$^{18}$O line, clear Keplerian motions were not detected toward either source. If Keplerian rotationally-supported disks are present, they are likely deeply embedded in their envelope. However, we can set upper limits of the central protostellar mass of 0.46 M$_\odot$ and 0.26 M$_\odot$ for BHR 71 IRS1 and BHR 71 IRS2, respectively. Outflows traced by $^{12}$CO and SiO are detected in both sources. The outflows can be divided into two components, a wide-angle outflow and a jet. In IRS1, the jet exhibits a double helical structure, reflecting the removal of angular momentum from the system. In IRS2, the jet is very collimated and shows a chain of knots, suggesting episodic accretion events., Comment: 38 pages, 29 figures, accepted in ApJ

Methane (CH4) is one of the major components of the icy mantle of cosmic dust prevalent in cold, dense regions of interstellar media, playing an important role in the synthesis of complex organic molecules and prebiotic molecules. Solid CH4 is considered to be formed via the successive hydrogenation of C atoms accreting onto dust: C + 4H -> CH4. However, most astrochemical models assume this reaction on the ice mantles of dust to be barrierless and efficient, without considering the states of adsorption. Recently, we found that C atoms exist in either the physisorbed or chemisorbed state on compact amorphous solid water, which is analogous to an interstellar ice mantle. These distinct adsorption states considerably affect the hydrogenation reactivity of the C atom. Herein, we elucidate the reactivities of physisorbed and chemisorbed C atoms with H atoms via sequential deposition and co-deposition processes. The results indicate that only physisorbed C atoms can produce CH4 on ice. Combining this finding with a previous estimate for the fraction of physisorbed C atoms on ice, we determined the upper limit for the conversion of C atoms into CH4 to be 30%., Comment: 24 pages, 4 figures, 1 table; accepted for publication in ApJ

We investigate the chemical evolution of complex organic molecules (COMs) in turbulent disks using gas-ice chemical reaction network simulations. We trace trajectories of dust particles considering advection, turbulent diffusion, gas drag, and vertical settling, for 10$^6$ yrs in a protoplanetary disk. Then, we solve a gas-ice chemical reaction network along the trajectories and obtain the temporal evolution of molecular abundances. We find that the COM abundances in particles can differ by more than two orders of magnitude even when the UV fluence (i.e., the time integral of UV flux) received by the particles are similar, suggesting that not only the UV fluence but also the time variation of the UV flux does matter for the evolution of COMs in disks. The impact of UV fluence on molecular abundances differs between oxygen-bearing and nitrogen-bearing COMs. While higher UV fluence results in oxygen being locked into CO$_2$, leading to reduced abundances of oxygen-bearing COMs such as CH$_3$OCH$_3$, mild UV exposure can promote their formation by supplying the precursor radicals. On the other hand, nitrogen is not locked up into specific molecules, allowing the formation of nitrogen-bearing COMs, particularly CH$_3$NH$_2$, even for the particle that receives the higher UV fluence. We also find that the final COM abundances are mostly determined by the inherited abundances from the protostellar core when the UV fluence received by dust particles is less than a critical value, while they are set by both the inherited abundances and the chemistry inside the disk at higher UV fluence., Comment: 19 pages, to be published in MNRAS

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates deemed important in diffusive chemistry on H$_{2}$O ices. We later include these ratios in our chemical reaction network model, where the binding and diffusion energies of icy species vary as a function of the surface composition. When the surface coverage of CO increases, the model shows an enhancement of O-bearing complex organic molecules, especially those formed from the intermediate products of CO hydrogenation (e.g. HCO) and CH$_{3}$/CH$_{2}$. Because the binding energy of CH$_{3}$/CH$_{2}$ is in the right range, its diffusion rate increases significantly with CO coverage. At $T>$14 K and with less influence, enhanced diffusion of HCO also contributes to the increase of the abundances of COM. We find, however, that chemistry is not always enhanced on CO ice and that the temperature and cosmic ray ionization rate of each astronomical object is crucial for this particular chemistry, revealing a highly non-trivial behavior that needs to be addressed on a per-case basis. Our results are highly relevant in the context of interstellar ice observations with JWST., Comment: Accepted for publication in Astronomy and Astrophysics

The exploration of outflows in protobinary systems presents a challenging yet crucial endeavour, offering valuable insights into the dynamic interplay between protostars and their evolution. In this study, we examine the morphology and dynamics of jets and outflows within the IRAS\,4A protobinary system. This analysis is based on ALMA observations of SiO(5--4), H$_2$CO(3$_{0,3}$--2$_{0,3}$), and HDCO(4$_{1,4}$--3$_{1,3}$) with a spatial resolution of $\sim$150\,au. Leveraging an astrochemical approach involving the use of diverse tracers beyond traditional ones has enabled the identification of novel features and a comprehensive understanding of the broader outflow dynamics. Our analysis reveals the presence of two jets in the redshifted emission, emanating from IRAS\,4A1 and IRAS\,4A2, respectively. Furthermore, we identify four distinct outflows in the region for the first time, with each protostar, 4A1 and 4A2, contributing to two of them. We characterise the morphology and orientation of each outflow, challenging previous suggestions of bends in their trajectories. The outflow cavities of IRAS\,4A1 exhibit extensions of 10$''$ and 13$''$ with position angles (PA) of 0$^{\circ}$ and -12$^{\circ}$, respectively, while those of IRAS\,4A2 are more extended, spanning 18$''$ and 25$''$ with PAs of 29$^{\circ}$ and 26$^{\circ}$. We propose that the misalignment of the cavities is due to a jet precession in each protostar, a notion supported by the observation that the more extended cavities of the same source exhibit lower velocities, indicating they may stem from older ejection events.

Young protostellar binary systems, with expected ages less than $\sim$10$^5$ years, are little modified since birth, providing key clues to binary formation and evolution. We present a first look at the young, Class 0 binary protostellar system R CrA IRAS 32 from the Early Planet Formation in Embedded Disks (eDisk) ALMA large program, which observed the system in the 1.3 mm continuum emission, $^{12}$CO (2-1), $^{13}$CO (2-1), C$^{18}$O (2-1), SO (6$_5$-5$_4$), and nine other molecular lines that trace disk, envelope, shocks, and outflows. With a continuum resolution of $\sim$0.03$^{\prime\prime}$ ($\sim$5 au, at a distance of 150 pc), we characterize the newly discovered binary system with a separation of 207 au, their circumstellar disks, and a circumbinary disk-like structure. The circumstellar disk radii are 26.9$\pm$0.3 and 22.8$\pm$0.3 au for sources A and B, respectively, and their circumstellar disk dust masses are estimated as 22.5$\pm$1.1 and 12.4$\pm$0.6 M$_{\Earth}$. The circumstellar disks and the circumbinary structure have well aligned position angles and inclinations, indicating formation in a smooth, ordered process such as disk fragmentation. In addition, the circumstellar disks have a near/far-side asymmetry in the continuum emission suggesting that the dust has yet to settle into a thin layer near the midplane. Spectral analysis of CO isotopologues reveals outflows that originate from both of the sources and possibly from the circumbinary disk-like structure. Furthermore, we detect Keplerian rotation in the $^{13}$CO isotopologues toward both circumstellar disks and likely Keplerian rotation in the circumbinary structure; the latter suggests that it is probably a circumbinary disk., Comment: 33 pages, 29 figures, 6 tables

An unbiased spectral survey of V883 Ori, an eruptive young star, was carried out with the Atacama Large Millimeter/submillimeter Array (ALMA) in Band 6. The detected line emission from various molecules reveals morphological/kinematical features in both the Keplerian disk and the infalling envelope. A direct infall signature, red-shifted absorption against continuum, has been detected in CO, HCO$^+$, HCN, HNC, and H$_2$CO. HCO$^+$ and SO show large arm-like structures that probably connect from an infalling envelope to the disk. HCN and H$_2$CO reveal a distinct boundary between the inner and outer disk and reveal tentative spiral structures connecting the outer disk to the inner disk. HNC shows a large central emission hole (r $\sim$0.3\arcsec) due to its chemical conversion to HCN at high temperatures. The HDO emission, a direct tracer of the water sublimation region, has been detected in the disk. Molecular emission from complex organic molecules (COMs) is confined within the HDO emission boundary, and HCO$^+$ has an emission hole in its distribution due to its destruction by water. Together, these features suggest that the current episode of eruption in V883 Ori may be triggered by the infall from the envelope to the outer disk, generating a spiral wave, which propagates inward and greatly enhances the accretion onto the central star., Comment: Accepted for publication in ApJ

We present MIRI MRS observations of the large, multi-gapped protoplanetary disk around the T-Tauri star AS 209. The observations reveal hundreds of water vapor lines from 4.9 to 25.5 $\mu$m towards the inner $\sim1$ au in the disk, including the first detection of ro-vibrational water emission in this disk. The spectrum is dominated by hot ($\sim800$ K) water vapor and OH gas, with only marginal detections of CO$_2$, HCN, and a possible colder water vapor component. Using slab models with a detailed treatment of opacities and line overlap, we retrieve the column density, emitting area, and excitation temperature of water vapor and OH, and provide upper limits for the observable mass of other molecules. Compared to MIRI spectra of other T-Tauri disks, the inner disk of AS 209 does not appear to be atypically depleted in CO$_2$ nor HCN. Based on \textit{Spitzer IRS} observations, we further find evidence for molecular emission variability over a 10-year baseline. Water, OH, and CO$_2$ line luminosities have decreased by factors 2-4 in the new MIRI epoch, yet there are minimal continuum emission variations. The origin of this variability is yet to be understood., Comment: Accepted for publication in ApJ

We present the outflows detected in HOPS 373SW, a protostar undergoing a modest $30\%$ brightness increase at 850 $\mu$m. Atacama Large Millimeter/submillimeter Array (ALMA) observations of shock tracers, including SiO 8--7, CH$_3$OH 7$_{\rm k}$--6$_{\rm k}$, and $^{12}$CO 3--2 emission, reveal several outflow features around HOPS 373SW. The knots in the extremely high-velocity SiO emission reveal the wiggle of the jet, for which a simple model derives a 37$^\circ$ inclination angle of the jet to the plane of the sky, a jet velocity of 90 km s$^{-1}$, and a period of 50 years. The slow SiO and CH$_3$OH emission traces U-shaped bow shocks surrounding the two CO outflows. One outflow is associated with the high-velocity jets, while the other is observed to be close to the plane of the sky. The misaligned outflows imply that previous episodic accretion events have either reoriented HOPS 373SW or that it is an unresolved protostellar binary system with misaligned outflows., Comment: Accepted for publication in ApJ

We performed synthetic observations of the Ulrich, Cassen, and Moosman (UCM) model to understand the relation between the physical structures of the infalling envelope around a protostar and their observational features in molecular lines, adopting L1527 as an example. We also compared the physical structure and synthetic position-velocity (P-V) diagrams of the UCM model and a simple ballistic (SB) model. There are multiple ways to compare synthetic data with observational data. We first calculated the correlation coefficient. The UCM model and the SB model show similarly good correlation with the observational data. While the correlation reflects the overall similarity between the cube datasets, we can alternatively compare specific local features, such as the centrifugal barrier in the SB model or the centrifugal radius in the UCM model. We evaluated systematic uncertainties in these methods. In the case of L1527, the stellar mass values estimated using these methods are all lower than the value derived from previous Keplerian analysis of the disk. This may indicate that the gas infall motion in the envelope is retarded by, e.g., magnetic fields. We also showed analytically that, in the UCM model, the spin-up feature of the P-V diagram is due to the infall velocity rather than the rotation. The line-of-sight velocity $V$ is thus $\propto x^{-0.5}$, where $x$ is the offset. If the infall is retarded, rotational velocity should dominate so that $V$ is proportional to $x^{-1}$, as is often observed in the protostellar envelope., Comment: 17 pages, 12 figures, published in ApJ, 2024 January 11

Complex organic molecules (COMs) in protoplanetary disks are key to understanding the origin of volatiles in comets in our solar system, yet the chemistry of COMs in protoplanetary disks remains poorly understood. Here we present Atacama Large Millimeter/submillimeter Array (ALMA) Band 3 observations of the disk around the young outbursting star V883 Ori, where the COMs sublimate from ices and are thus observable thanks to the warm condition of the disk. We have robustly identified ten oxygen-bearing COMs including $^{13}$C-isotopologues in the disk-integrated spectra. The radial distributions of the COM emission, revealed by the detailed analyses of the line profiles, show the inner emission cavity, similar to the previous observations in Band 6 and Band 7. We found that the COMs abundance ratios with respect to methanol are significantly higher than those in the warm protostellar envelopes of IRAS 16293-2422 and similar to the ratios in the solar system comet 67P/Churyumov-Gerasimenko, suggesting the efficient (re-)formation of COMs in protoplanetary disks. We also constrained the $^{12}$C/$^{13}$C and D/H ratios of COMs in protoplanetary disks for the first time. The $^{12}$C/$^{13}$C ratios of acetaldehyde, methyl formate, and dimethyl ether are consistently lower ($\sim$ 20-30) than the canonical ratio in the interstellar medium ($\sim$ 69), indicating the efficient $^{13}$C-fractionation of CO. The D/H ratios of methyl formate are slightly lower than the values in IRAS 16293-2422, possibly pointing to the destruction and reformation of COMs in disks. We also discuss the implications for nitrogen and sulfur chemistry in protoplanetary disks., Comment: 38 pages, 22 figures, Accepted for publication in AJ

While most debris disks consist of dust with little or no gas, a fraction has significant amounts of gas detected via emission lines of CO, ionized carbon, and/or atomic oxygen. Almost all such gaseous debris disks known are around A-type stars with ages up to 50 Myr. We show, using semi-analytic disk evolution modeling, that this can be understood if the gaseous debris disks are remnant protoplanetary disks that have become depleted of small grains compared to the interstellar medium. Photoelectric heating by the A-stars' FUV radiation is then inefficient, while the stars' EUV and X-ray emissions are weak owing to a lack of surface convective zones capable of driving magnetic activity. In this picture, stars outside the range of spectral types from A through early B are relatively hard to have such long-lived gas disks. Less-massive stars have stronger magnetic activity in the chromosphere, transition region, and corona with resulting EUV and X-ray emission, while more-massive stars have photospheres hot enough to produce strong EUV radiation. In both cases, primordial disk gas is likely to photoevaporate well before 50 Myr. These results come from 0D disk evolution models where we incorporate internal accretion stresses, MHD winds, and photoevaporation by EUV and X-ray photons with luminosities that are functions of the stellar mass and age. A key issue this work leaves open is how some disks become depleted in small dust so that FUV photoevaporation slows. Candidates include grains' growth, settling, radial drift, radiation force, and incorporation into planetary systems., Comment: Submitted to ApJL

We present ALMA observations of the Class I source Oph IRS63 in the context of the Early Planet Formation in Embedded Disks (eDisk) large program. Our ALMA observations of Oph IRS63 show a myriad of protostellar features, such as a shell-like bipolar outflow (in $^{12}$CO), an extended rotating envelope structure (in $^{13}$CO), a streamer connecting the envelope to the disk (in C$^{18}$O), and several small-scale spiral structures seen towards the edge of the dust continuum (in SO). By analyzing the velocity pattern of $^{13}$CO and C$^{18}$O, we measure a protostellar mass of $\rm M_\star = 0.5 \pm 0.2 $~$\rm M_\odot$ and confirm the presence of a disk rotating at almost Keplerian velocity that extends up to $\sim260$ au. These calculations also show that the gaseous disk is about four times larger than the dust disk, which could indicate dust evolution and radial drift. Furthermore, we model the C$^{18}$O streamer and SO spiral structures as features originating from an infalling rotating structure that continuously feeds the young protostellar disk. We compute an envelope-to-disk mass infall rate of $\sim 10^{-6}$~$\rm M_\odot \, yr^{-1}$ and compare it to the disk-to-star mass accretion rate of $\sim 10^{-8}$~$\rm M_\odot \, yr^{-1}$, from which we infer that the protostellar disk is in a mass build-up phase. At the current mass infall rate, we speculate that soon the disk will become too massive to be gravitationally stable., Comment: 26 pages and 17 figures

Protostellar disks are a ubiquitous part of the star formation process and the future sites of planet formation. As part of the Early Planet Formation in Embedded Disks (eDisk) large program, we present high-angular resolution dust continuum ($\sim40\,$mas) and molecular line ($\sim150\,$mas) observations of the Class 0 protostar, IRAS 15398-3359. The dust continuum is small, compact, and centrally peaked, while more extended dust structures are found in the outflow directions. We perform a 2D Gaussian fitting to find the deconvolved size and $2\sigma$ radius of the dust disk to be $4.5\times2.8\,\mathrm{au}$ and $3.8\,\mathrm{au}$, respectively. We estimate the gas+dust disk mass assuming optically thin continuum emission to be $0.6-1.8\,M_\mathrm{jup}$, indicating a very low-mass disk. The CO isotopologues trace components of the outflows and inner envelope, while SO traces a compact, rotating disk-like component. Using several rotation curve fittings on the PV diagram of the SO emission, the lower limits of the protostellar mass and gas disk radius are $0.022\,M_\odot$ and $31.2\,\mathrm{au}$ from our Modified 2 single power-law fitting. A conservative upper limit of the protostellar mass is inferred to be $0.1\,M_\odot$. The protostellar mass-accretion rate and the specific angular momentum at the protostellar disk edge are found to be between $1.3-6.1\times10^{-6}\,M_\odot\,\mathrm{yr^{-1}}$ and $1.2-3.8\times10^{-4}\,\mathrm{km\,s^{-1}\,pc}$, respectively, with an age estimated between $0.4-7.5\times10^{4}\,$yr. At this young age with no clear substructures in the disk, planet formation would likely not yet have started. This study highlights the importance of high-resolution observations and systematic fitting procedures when deriving dynamical properties of deeply embedded Class 0 protostars., Comment: 28 pages, 16 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

Precise estimates of protostellar masses are crucial to characterize the formation of stars of low masses down to brown-dwarfs (BDs; M* < 0.08 Msun). The most accurate estimation of protostellar mass uses the Keplerian rotation in the circumstellar disk around the protostar. To apply the Keplerian rotation method to a protostar at the low-mass end, we have observed the Class 0 protostar IRAS 16253-2429 using the Atacama Large Millimeter/submillimeter Array (ALMA) in the 1.3 mm continuum at an angular resolution of 0.07" (10 au), and in the 12CO, C18O, 13CO (J=2-1), and SO (J_N = 6_5-5_4) molecular lines, as part of the ALMA Large Program Early Planet Formation in Embedded Disks (eDisk). The continuum emission traces a non-axisymmetric, disk-like structure perpendicular to the associated 12CO outflow. The position-velocity (PV) diagrams in the C18O and 13CO lines can be interpreted as infalling and rotating motions. In contrast, the PV diagram along the major axis of the disk-like structure in the 12CO line allows us to identify Keplerian rotation. The central stellar mass and the disk radius are estimated to be ~0.12-0.17 Msun and ~13-19 au, respectively. The SO line suggests the existence of an accretion shock at a ring (r~28 au) surrounding the disk and a streamer from the eastern side of the envelope. IRAS 16253-2429 is not a proto-BD but has a central stellar mass close to the BD mass regime, and our results provide a typical picture of such very low-mass protostars., Comment: 41 pages, 14 figures

We present high-resolution, high-sensitivity observations of the Class 0 protostar RCrA IRS5N as part of the Atacama Large Milimeter/submilimeter Array (ALMA) large program Early Planet Formation in Embedded Disks (eDisk). The 1.3 mm continuum emission reveals a flattened continuum structure around IRS5N, consistent with a protostellar disk in the early phases of evolution. The continuum emission appears smooth and shows no substructures. However, a brightness asymmetry is observed along the minor axis of the disk, suggesting the disk is optically and geometrically thick. We estimate the disk mass to be between 0.007 and 0.02 M$_{\odot}$. Furthermore, molecular emission has been detected from various species, including C$^{18}$O (2$-$1), $^{12}$CO (2$-$1), $^{13}$CO (2$-$1), and H$_2$CO (3$_{0,3}-2_{0,2}$, 3$_{2,1}-2_{2,0}$, and 3$_{2,2}-2_{2,1}$). By conducting a position-velocity analysis of the C$^{18}$O (2$-$1) emission, we find that the disk of IRS5N exhibits characteristics consistent with Keplerian rotation around a central protostar with a mass of approximately 0.3 M$_{\odot}$. Additionally, we observe dust continuum emission from the nearby binary source, IRS5a/b. The emission in $^{12}$CO toward IRS5a/b seems to emanate from IRS5b and flow into IRS5a, suggesting material transport between their mutual orbits. The lack of a detected outflow and large-scale negatives in \tlvco~observed toward IRS5N suggests that much of the flux from IRS5N is being resolved out. Due to this substantial surrounding envelope, the central IRS5N protostar is expected to be significantly more massive in the future., Comment: 25 pages, 24 figures. Accepted for publication in ApJ

Theoretical models and observations suggest that the abundances of molecular ions in protoplanetary disks should be highly sensitive to the variable ionization conditions set by the young central star. We present a search for temporal flux variability of HCO+ J=1-0, which was observed as a part of the Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program. We split out and imaged the line and continuum data for each individual day the five sources were observed (HD 163296, AS 209, GM Aur, MWC 480, and IM Lup, with between 3 to 6 unique visits per source). Significant enhancement (>3\sigma) was not observed, but we find variations in the spectral profiles in all five disks. Variations in AS 209, GM Aur, and HD 163296 are tentatively attributed to variations in HCO+ flux, while variations in IM Lup and MWC 480 are most likely introduced by differences in the \textit{uv} coverage, which impact the amount of recovered flux during imaging. The tentative detections and low degree of variability are consistent with expectations of X-ray flare driven HCO+ variability, which requires relatively large flares to enhance the HCO+ rotational emission at significant (>20%) levels. These findings also demonstrate the need for dedicated monitoring campaigns with high signal to noise ratios to fully characterize X-ray flare driven chemistry., Comment: Accepted for publication in ApJ, 18 pages, 9 figures

We report the detection of the millimeter CH$_3$OH masers including a new detection of class I (11$_{0,11}$-10$_{1,10}$A) and class II (6$_{1,5}$-5$_{2,4}$E) maser transitions toward the high-mass protostar S255IR NIRS3 in post-burst phase. The CH$_3$OH emissions were detected as a mixture of maser and thermal characteristics. We examine the detected transitions using an excitation diagram and LTE model spectra and compare the observed properties with those of thermal lines. Class II CH$_3$OH maser transitions showed distinctive intensity and velocity distributions from those of thermal transitions. Bright distinct emission components in addition to the fragmented and arc-shaped emissions are only detected in class I CH$_3$OH maser transitions toward southern and western directions from the protostellar position, implying the presence of the slow outflow shocks., Comment: 9 pages, 4 Figures, 1 Table, Accepted for publication in ApJL

Many interstellar complex organic molecules (COMs) are believed to be produced on the surfaces of icy grains at low temperatures. Atomic carbon is considered responsible for the skeletal evolution processes, such as C-C bond formation, via insertion or addition reactions. Before reactions, C atoms must diffuse on the surface to encounter reaction partners; therefore, information on their diffusion process is critically important for evaluating the role of C atoms in the formation of COMs. In situ detection of C atoms on ice was achieved by a combination of photostimulated desorption and resonance enhanced multiphoton ionization methods. We found that C atoms weakly bound to the ice surface diffused approximately above 30 K and produced C2 molecules. The activation energy for C-atom surface diffusion was experimentally determined to be 88 meV (1,020 K), indicating that the diffusive reaction of C atoms is activated at approximately 22 K on interstellar ice. The facile diffusion of C at T > 22 K atoms on interstellar ice opens a previously overlooked chemical regime where the increase in complexity of COMs as driven by C atoms. Carbon addition chemistry can be an alternative source of chemical complexity in translucent clouds and protoplanetary disks with crucial implications in our current understanding on the origin and evolution of organic chemistry in our Universe., Comment: 33 pages (main + SI), 14 figures, 1 table

We have observed the Class 0/I protostellar system Ced110 IRS4 at an angular resolution of $0.05''$ ($\sim$10 au) as a part of the ALMA large program; Early Planet Formation in the Embedded Disks (eDisk). The 1.3 mm dust continuum emission reveals that Ced110 IRS4 is a binary system with a projected separation of $\sim$250 au. The continuum emissions associated with the main source and its companion, named Ced110 IRS4A and IRS4B respectively, exhibit disk-like shapes and likely arise from dust disks around the protostars. The continuum emission of Ced110 IRS4A has a radius of $\sim$91.7 au ($\sim0.485''$), and shows bumps along its major axis with an asymmetry. The bumps can be interpreted as an shallow, ring-like structure at a radius of $\sim$40 au ($\sim0.2''$) in the continuum emission, as demonstrated from two-dimensional intensity distribution models. A rotation curve analysis on the C$^{18}$O and $^{13}$CO $J=2$-1 lines reveals the presence of a Keplerian disk within a radius of 120 au around Ced110 IRS4A, which supports the interpretation that the dust continuum emission arises from a disk. The ring-like structure in the dust continuum emission might indicate a possible, annular substructure in the surface density of the embedded disk, although the possibility that it is an apparent structure due to the optically thick continuum emission cannot be ruled out., Comment: 32 pages, 23 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between CO and OH, which has a barrier. Highly accurate quantum chemical calculations were employed to analyze the stationary points of the potential energy surfaces of the title reaction in the gas phase on a H2O and CO clusters. Microcanonical transition state theory was used as a diagnostic tool for the efficiency of the reaction under ISM conditions. We simulate the kinetics of ice chemistry, considering different scenarios involving non-thermal processes and energy dissipation. The CO + OH reaction proceeds through the remarkably stable intermediate HOCO radical. On the H2O cluster, the formation of this intermediate is efficient, but the subsequent reaction leading to CO2 formation is not. Conversely, HOCO formation on the CO cluster is inefficient without external energy input. Thus, CO2 ice cannot be formed by the title reaction alone either on the H2O cluster or CO cluster. In the polar ice, CO2 ice formation is possible via CO + OH -> HOCO, followed by HOCO + H ->CO2 + H2, as demonstrated by abundant experimental literature. In apolar ice, CO2 formation is less efficient because HOCO formation requires external energy. Our finding is consistent with the JWST observations. Further experimental work is encouraged using low-temperature OH radicals., Comment: Accepted for publication in Astronomy and Astrophysics

We present the spectra of Complex Organic Molecules (COMs) detected in HOPS 373SW with the Atacama Large Millimeter/submillimeter Array (ALMA). HOPS 373SW, which is a component of a protostellar binary with a separation of 1500 au, has been discovered as a variable protostar by the JCMT Transient monitoring survey with a modest ~30% brightness increase at submillimeter wavelengths. Our ALMA Target of Opportunity (ToO) observation at ~345 GHz for HOPS 373SW revealed extremely young chemical characteristics with strong deuteration of methanol. The dust continuum opacity is very high toward the source center, obscuring line emission from within 0.03 arcsec. The other binary component, HOPS 373NE, was detected only in C17O in our observation, implying a cold and quiescent environment. We compare the COMs abundances relative to CH3OH in HOPS 373SW with those of V883 Ori, which is an eruptive disk object, as well as other hot corinos, to demonstrate the chemical evolution from envelope to disk. High abundances of singly, doubly, and triply deuterated methanol (CH2DOH, CHD2OH, and CD3OH) and a low CH3CN abundance in HOPS 373SW compared to other hot corinos suggest a very early evolutionary stage of HOPS 373SW in the hot corino phase. Since the COMs detected in HOPS 373SW would have been sublimated very recently from grain surfaces, HOPS 373SW is a promising place to study the surface chemistry of COMs in the cold prestellar phase, before sublimation., Comment: Accepted for publication in ApJ

We present observations of the Class 0 protostar IRAS 16544-1604 in CB 68 from the ''Early Planet Formation in Embedded Disks (eDisk)'' ALMA Large program. The ALMA observations target continuum and lines at 1.3-mm with an angular resolution of $\sim$5 au. The continuum image reveals a dusty protostellar disk with a radius of $\sim$30 au seen close to edge-on, and asymmetric structures both along the major and minor axes. While the asymmetry along the minor axis can be interpreted as the effect of the dust flaring, the asymmetry along the major axis comes from a real non-axisymmetric structure. The C$^{18}$O image cubes clearly show the gas in the disk that follows a Keplerian rotation pattern around a $\sim$0.14 $M_{\odot}$ central protostar. Furthermore, there are $\sim$1500 au-scale streamer-like features of gas connecting from North-East, North-North-West, and North-West to the disk, as well as the bending outflow as seen in the $^{12}$CO (2-1) emission. At the apparent landing point of NE streamer, there are SO (6$_5$-5$_4$) and SiO (5-4) emission detected. The spatial and velocity structure of NE streamer can be interpreted as a free-falling gas with a conserved specific angular momentum, and the detection of the SO and SiO emission at the tip of the streamer implies presence of accretion shocks. Our eDisk observations have unveiled that the Class 0 protostar in CB 68 has a Keplerian rotating disk with flaring and non-axisymmetric structure associated with accretion streamers and outflows., Comment: 30 pages, 24 figures, accepted for publication in The Astrophysical Journal as one of the first-look papers of the eDisk ALMA Large Program

While dust disks around optically visible, Class II protostars are found to be vertically thin, when and how dust settles to the midplane are unclear. As part of the Atacama Large Millimeter/submillimeter Array (ALMA) large program, Early Planet Formation in Embedded Disks, we analyze the edge-on, embedded, Class I protostar IRAS 04302+2247, also nicknamed the ``Butterfly Star." With a resolution of 0.05" (8~au), the 1.3 mm continuum shows an asymmetry along the minor axis which is evidence of an optically thick and geometrically thick disk viewed nearly edge-on. There is no evidence of rings and gaps, which could be due to the lack of radial substructure or the highly inclined and optically thick view. With 0.1" (16~au) resolution, we resolve the 2D snow surfaces, i.e., the boundary region between freeze-out and sublimation, for $^{12}$CO $J$=2--1, $^{13}$CO $J$=2--1, C$^{18}$O $J$=2--1, $H_{2}$CO $J$=$3_{0,3}$--$2_{0,2}$, and SO $J$=$6_{5}$--$5_{4}$, and constrain the CO midplane snow line to $\sim 130$ au. We find Keplerian rotation around a protostar of $1.6 \pm 0.4 M_{\odot}$ using C$^{18}$O. Through forward ray-tracing using RADMC-3D, we find that the dust scale height is $\sim 6$ au at a radius of 100~au from the central star and is comparable to the gas pressure scale height. The results suggest that the dust of this Class~I source has yet to vertically settle significantly., Comment: 33 pages, 21 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

Constraining the physical and chemical structure of young embedded disks is crucial to understanding the earliest stages of planet formation. As part of the Early Planet Formation in Embedded Disks Atacama Large Millimeter/submillimeter Array Large Program, we present high spatial resolution ($\sim$0$.\!\!^{\prime\prime}$1 or $\sim$15 au) observations of the 1.3 mm continuum and $^{13}$CO $J=$ 2-1, C$^{18}$O $J=$ 2-1, and SO $J_N=$ $6_5$-$5_4$ molecular lines toward the disk around the Class I protostar L1489 IRS. The continuum emission shows a ring-like structure at 56 au from the central protostar and a tenuous, optically thin emission extending beyond $\sim$300 au. The $^{13}$CO emission traces the warm disk surface, while the C$^{18}$O emission originates from near the disk midplane. The coincidence of the radial emission peak of C$^{18}$O with the dust ring may indicate a gap-ring structure in the gaseous disk as well. The SO emission shows a highly complex distribution, including a compact, prominent component at $\lesssim$30 au, which is likely to originate from thermally sublimated SO molecules. The compact SO emission also shows a velocity gradient along a slightly ($\sim15^\circ$) tilted direction with respect to the major axis of the dust disk, which we interpret as an inner warped disk in addition to the warp around $\sim$200 au suggested by previous work. These warped structures may be formed by a planet or companion with an inclined orbit, or by a gradual change in the angular momentum axis during gas infall., Comment: 24 pages, 12 figures. Accepted for publication in The Astrophysical Journal as one of the first-look papers of the eDisk ALMA Large Program

Studying the physical and chemical conditions of young embedded disks is crucial to constrain the initial conditions for planet formation. Here, we present Atacama Large Millimeter/submillimeter Array (ALMA) observations of dust continuum at $\sim$0.06" (8 au) resolution and molecular line emission at $\sim$0.17" (24 au) resolution toward the Class 0 protostar L1527 IRS from the Large Program eDisk (Early Planet Formation in Embedded Disks). The continuum emission is smooth without substructures, but asymmetric along both the major and minor axes of the disk as previously observed. The detected lines of $^{12}$CO, $^{13}$CO, C$^{18}$O, H$_2$CO, c-C$_3$H$_2$, SO, SiO, and DCN trace different components of the protostellar system, with a disk wind potentially visible in $^{12}$CO. The $^{13}$CO brightness temperature and the H$_2$CO line ratio confirm that the disk is too warm for CO freeze out, with the snowline located at $\sim$350 au in the envelope. Both molecules show potential evidence of a temperature increase around the disk-envelope interface. SO seems to originate predominantly in UV-irradiated regions such as the disk surface and the outflow cavity walls rather than at the disk-envelope interface as previously suggested. Finally, the continuum asymmetry along the minor axis is consistent with the inclination derived from the large-scale (100" or 14,000 au) outflow, but opposite to that based on the molecular jet and envelope emission, suggesting a misalignment in the system. Overall, these results highlight the importance of observing multiple molecular species in multiple transitions to characterize the physical and chemical environment of young disks., Comment: 27 pages, 16 figures, 2 tables, 10 pages appendix with 12 figures. Accepted for publication in ApJ as one of the first-look papers of the eDisk ALMA Large Program

We present an overview of the Large Program, ``Early Planet Formation in Embedded Disks (eDisk)'', conducted with the Atacama Large Millimeter/submillimeter Array (ALMA). The ubiquitous detections of substructures, particularly rings and gaps, in protoplanetary disks around T Tauri stars raise the possibility that at least some planet formation may have already started during the embedded stages of star formation. In order to address exactly how and when planet formation is initiated, the program focuses on searching for substructures in disks around 12 Class 0 and 7 Class I protostars in nearby ($< $200 pc) star-forming regions through 1.3 mm continuum observations at a resolution of $\sim7$ au (0.04"). The initial results show that the continuum emission, mostly arising from dust disks around the sample protostars, has relatively few distinctive substructures, such as rings and spirals, in marked contrast to Class II disks. The dramatic difference may suggest that substructures quickly develop in disks when the systems evolve from protostars to Class II sources or alternatively that high optical depth of the continuum emission could obscure internal structures. Kinematic information obtained through CO isotopologue lines and other lines reveals the presence of Keplerian disks around protostars, providing us with crucial physical parameters, in particular, the dynamical mass of the central protostars. We describe the background of the eDisk program, the sample selection and their ALMA observations, the data reduction, and also highlight representative first-look results., Comment: This is a publication of a series of eDisk ALMA large program first-look papers

The origin and evolution of gas in debris disks is still not well understood. Secondary gas production from cometary material or a primordial origin have been proposed. So far, observations have mostly concentrated on CO, with only few C observations available. We create an overview of the C and CO content of debris disk gas and use it test state-of-the-art models. We use new and archival ALMA observations of CO and CI emission, complemented by CII data from Herschel, for a sample of 14 debris disks. This expands the number of disks with ALMA measurements of both CO and CI by ten disks. We present new detections of CI emission towards three disks: HD 21997, HD 121191 and HD 121617. We use a simple disk model to derive gas masses and column densities. We find that current state-of-the-art models of secondary gas production overpredict the neutral carbon content of debris disk gas. This does not rule out a secondary origin, but might indicate that the models require an additional C removal process. Alternatively, the gas might be produced in transient events rather than a steady-state collisional cascade. We also test a primordial gas origin by comparing our results to a simplified thermo-chemical model. This yields promising results, but more detailed work is required before a conclusion can be reached. Our work demonstrates that the combination of C and CO data is a powerful tool to advance our understanding of debris disk gas., Comment: 90 pages, 60 figures. Accepted for publication in ApJ. version 2: additional acknowledgement. versions 3, 4: minor edits

We study the kinematics of the AS 209 disk using the J=2-1 transitions of $^{12}$CO, $^{13}$CO, and C$^{18}$O. We derive the radial, azimuthal, and vertical velocity of the gas, taking into account the lowered emission surface near the annular gap at ~1.7 (200 au) within which a candidate circumplanetary disk-hosting planet has been reported previously. In $^{12}$CO and $^{13}$CO, we find a coherent upward flow arising from the gap. The upward gas flow is as fast as $150~{\rm m~s}^{-1}$ in the regions traced by $^{12}$CO emission, which corresponds to about 50% of the local sound speed or $6\%$ of the local Keplerian speed. Such an upward gas flow is difficult to reconcile with an embedded planet alone. Instead, we propose that magnetically driven winds via ambipolar diffusion are triggered by the low gas density within the planet-carved gap, dominating the kinematics of the gap region. We estimate the ambipolar Elsasser number, Am, using the HCO$^+$ column density as a proxy for ion density and find that Am is ~0.1 at the radial location of the upward flow. This value is broadly consistent with the value at which numerical simulations find ambipolar diffusion drives strong winds. We hypothesize the activation of magnetically-driven winds in a planet-carved gap can control the growth of the embedded planet. We provide a scaling relationship which describes the wind-regulated terminal mass: adopting parameters relevant to 100 au from a solar-mass star, we find the wind-regulated terminal mass is about one Jupiter mass, which may help explain the dearth of directly imaged super-Jovian-mass planets., Comment: This paper has been accepted for publication in the Astrophysical Journal (ApJ)

Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$ 10$^{-10}$ relative to H2. This seemingly low abundance can be rationalized by destruction routes operating on interstellar dust grains. In this work, we tested the viability of this hypothesis under several prisms, finding that the origin of a lower abundance of \ce{NH2OH} can be explained by two chemical processes, one operating at low temperature (10 K) and the other at intermediate temperature (20 K). At low temperatures, enabling the hydrogen abstraction reaction HNO + H -> NO + H2, even in small amounts, partially inhibits the formation of NH2OH through successive hydrogenation of NO, and reduces its abundance on the grains. We found that enabling a 15--30 % of binding sites for this reaction results in reductions of \ce{NH2OH} abundance of $\sim$ 1-2 orders of magnitude. At warmer temperatures (20 K, in our study), the reaction NH2OH + H -> HNOH + H2, which was found to be fast (k$\sim$10$^{6}$ s$^{-1}$) in this work, followed by further abstractions by adsorbates that are immobile at 10 K (O, N) are the main route of \ce{NH2OH} destruction. Our results shed light on the abundance of hydroxylamine in space and pave the way to constraining the subsequent chemistry experienced by this molecule and its derivatives in the interstellar prebiotic chemistry canvas., Comment: Accepted for publication in MNRAS

The faint CO gases in debris disks are easily dissolved into C by UV irradiation, while CO can be reformed via reactions with hydrogen. The abundance ratio of C/CO could thus be a probe of the amount of hydrogen in the debris disks. We conduct radiative transfer calculations with chemical reactions for debris disks. For a typical dust-to-gas mass ratio of debris disks, CO formation proceeds without the involvement of H$_2$ because a small amount of dust grains makes H$_2$ formation inefficient. We find that the CO to C number density ratio depends on a combination of $n_\mathrm{H}Z^{0.4}\chi^{-1.1}$, where $n_\mathrm{H}$ is the hydrogen nucleus number density, $Z$ is the metallicity, and $\chi$ is the FUV flux normalized by the Habing flux. Using an analytic formula for the CO number density, we give constraints on the amount of hydrogen and metallicity for debris disks. CO formation is accelerated by excited H$_2$ either when the dust-to-gas mass ratio is increased or the energy barrier of chemisorption of hydrogen on the dust surface is decreased. This acceleration of CO formation occurs only when the shielding effects of CO are insignificant. In shielded regions, the CO fractions are almost independent of the parameters of dust grains., Comment: 29pages, 13figures, accepted for ApJ

We have observed the low-mass protostellar source, IRAS 15398$-$3359, at a resolution of 0.$''$2-0.$''$3, as part of the Atacama Large Millimeter/Submillimeter Array Large Program FAUST, to examine the presence of a hot corino in the vicinity of the protostar. We detect nine CH$_3$OH lines including the high excitation lines with upper state energies up to 500 K. The CH$_3$OH rotational temperature and the column density are derived to be 119$^{+20}_{-26}$ K and 3.2$^{+2.5}_{-1.0}\times$10$^{18}$ cm$^{-2}$, respectively. The beam filling factor is derived to be 0.018$^{+0.005}_{-0.003}$, indicating that the emitting region of CH$_3$OH is much smaller than the synthesized beam size and is not resolved. The emitting region of three high excitation lines, 18$_{3,15}-18_{2,16}$, A ($E_u=$447 K), 19$_{3,16}-19_{2,17}$, A ($E_u=$491 K), and 20$_{3,17}-20_{2,18}$, A ($E_u=$537 K), is located within the 50 au area around the protostar, and seems to have a slight extension toward the northwest. Toward the continuum peak, we also detect one emission line from CH$_2$DOH and two features of multiple CH$_3$OCHO lines. These results, in combination with previous reports, indicate that IRAS 15398$-$3359 is a source with hybrid properties showing both hot corino chemistry rich in complex organic molecules on small scales $\sim$10 au) and warm carbon-chain chemistry (WCCC) rich in carbon-chain species on large scales ($\sim$100-1000 au). A possible implication of the small emitting region is further discussed in relation to the origin of the hot corino activity., Comment: 20pages, 3figures

Energy redistribution after a chemical reaction is one of the few mechanisms to explain the diffusion and desorption of molecules which require more energy than the thermal energy available in quiescent molecular clouds (10 K). This energy distribution can be important in phosphorous hydrides, elusive yet fundamental molecules for interstellar prebiotic chemistry. We studied the reaction dynamics of the \ce{P + H -> PH} reaction on amorphous solid water, a reaction of astrophysical interest, using \emph{ab-initio} molecular dynamics with atomic forces evaluated by a neural network interatomic potential. We found that the exact nature of the initial phosphorous binding sites is less relevant for the energy dissipation process because the nascent PH molecule rapidly migrates to sites with higher binding energy after the reaction. Non-thermal diffusion and desorption-after-reaction were observed and occurred early in the dynamics, essentially decoupled from the dissipation of the chemical reaction energy. From an extensive sampling of reactions on sites, we constrained the average dissipated reaction energy within the simulation time (50 ps) to be between 50 and 70 %. Most importantly, the fraction of translational energy acquired by the formed molecule was found to be mostly between 1 and 5 %. Including these values, specifically for the test cases of 2% and 5% of translational energy conversion, in astrochemical models, reveals very low gas-phase abundances of PH$_{x}$ molecules and reflects that considering binding energy distributions is paramount for correctly merging microscopic and macroscopic modelling of non-thermal surface astrochemical processes. Finally, we found that PD molecules dissipate more of the reaction energy. This effect can be relevant for the deuterium fractionation and preferential distillation of molecules in the interstellar medium., Comment: Accepted for publication in Astronomy and Astrophysics

We review the recent observations of protoplanetary disks together with relevant theoretical studies with an emphasis on the evolution of volatiles. In the last several years Atacama Large Millimeter/submillimeter Array (ALMA) provided evidence of grain growth, gas-dust decoupling, and sub-structures such as rings and gaps in the dust continuum. Molecular line observations revealed radial and vertical distributions of molecular abundances and also provided significant constraints on the gas dynamics such as turbulence. While sub-millimeter and millimeter observations mainly probe the gas and dust outside the radius of several au, ice and inner warm gas are investigated at shorter wavelengths. Gas and dust dynamics are key to connecting these observational findings. One of the emerging trends is inhomogeneous distributions of elemental abundances, most probably due to dust-gas decoupling., Comment: COMETS III, in press. Table 1 and some contents are corrected and updated from the previous version (e.g. refer to JWST observations)

Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear whether this chemistry affects the composition of forming planetesimals due to limited observational constraints on the radial and vertical distribution of deuterated molecules. To shed light on this question, we introduce new ALMA observations of DCO$^+$ and DCN $J=2-1$ at an angular resolution of $0.5"$ (30 au) and combine them with archival data of higher energy transitions towards the protoplanetary disk around TW Hya. We carry out a radial excitation analysis assuming both LTE and non-LTE to localize the physical conditions traced by DCO$^+$ and DCN emission in the disk, thus assessing deuterium fractionation efficiencies and pathways at different disk locations. We find similar disk-averaged column densities of $1.9\times10^{12}$ and $9.8\times10^{11}$ cm$^{-2}$ for DCO$^{+}$ and DCN, with typical kinetic temperatures for both molecules of 20-30K, indicating a common origin near the comet- and planet-forming midplane. The observed DCO$^+$/DCN abundance ratio, combined with recent modeling results, provide tentative evidence of a gas phase C/O enhancement within $<40$ au. Observations of DCO$^+$ and DCN in other disks, as well as HCN and HCO$^+$, will be necessary to place the trends exhibited by TW Hya in context, and fully constrain the main deuteration mechanisms in disks., Comment: Fixed author information

The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In this paper, we present high spatial resolution observations of multiple emission lines of NH$_3$ toward the protobinary system NGC1333 IRAS4A with Karl G. Jansky Very Large Array (VLA). We spatially resolved the binary (hereafter 4A1 and 4A2) and detected compact emission of NH$_3$ transitions with high excitation energies ($\gtrsim$100 K) from the vicinity of the protostars, indicating the NH$_3$ ice has sublimated at the inner hot region. The NH$_3$ column density is estimated to be $\sim 10^{17}-10^{18}$ cm$^{-2}$. We also detected two NH$_2$D transitions, allowing us to constrain the deuterium fractionation of ammonia. The NH$_2$D/NH$_3$ ratios are as high as $\sim 0.3-1$ in both 4A1 and 4A2. From the comparisons with the astrochemical models in the literature, the high NH$_2$D/NH$_3$ ratios suggest that the formation of NH$_3$ ices mainly started in the prestellar phase after the formation of bulk water ice finished, and that the primary nitrogen reservoir in the star-forming cloud could be atomic nitrogen (or N atoms) rather than nitrogen-bearing species such as N$_2$ and NH$_3$. The implications on the physical properties of IRAS4A cores are discussed as well., Comment: 20 pages, 7 figures, accepted for publication in ApJ

We report the discovery of a circumplanetary disk (CPD) candidate embedded in the circumstellar disk of the T Tauri star AS 209 at a radial distance of about 200 au (on-sky separation of 1."4 from the star at a position angle of $161^\circ$), isolated via $^{13}$CO $J=2-1$ emission. This is the first instance of CPD detection via gaseous emission capable of tracing the overall CPD mass. The CPD is spatially unresolved with a $117\times82$ mas beam and manifests as a point source in $^{13}$CO, indicating that its diameter is $\lesssim14$ au. The CPD is embedded within an annular gap in the circumstellar disk previously identified using $^{12}$CO and near-infrared scattered light observations, and is associated with localized velocity perturbations in $^{12}$CO. The coincidence of these features suggests that they have a common origin: an embedded giant planet. We use the $^{13}$CO intensity to constrain the CPD gas temperature and mass. We find that the CPD temperature is $\gtrsim35$ K, higher than the circumstellar disk temperature at the radial location of the CPD, 22 K, suggesting that heating sources localized to the CPD must be present. The CPD gas mass is $\gtrsim 0.095 M_{\rm Jup} \simeq 30 M_{\rm Earth}$ adopting a standard $^{13}$CO abundance. From the non-detection of millimeter continuum emission at the location of the CPD ($3\sigma$ flux density $\lesssim26.4~\mu$Jy), we infer that the CPD dust mass is $\lesssim 0.027 M_{\rm Earth} \simeq 2.2$ lunar masses, indicating a low dust-to-gas mass ratio of $\lesssim9\times10^{-4}$. We discuss the formation mechanism of the CPD-hosting giant planet on a wide orbit in the framework of gravitational instability and pebble accretion., Comment: Accepted for publication in the ApJ Letters (July 7, 2022), 19 pages, 13 figures, interactive figures (Figure 7, 8, 9) are available at http://jaehanbae.com/as209/

We present near-infrared spectra of three low-luminosity protostars and one background star in the Perseus molecular cloud, acquired using the Infrared Camera (IRC) onboard the \textit{AKARI} space telescope. For the comparison with different star-forming environments, we also present spectra of the massive protostar AFGL 7009S, where the protostellar envelope is heated significantly, and the low-mass protostar RNO 91, which is suspected to be undergoing an episodic burst. We detected ice absorption features of \ch{H2O}, \ch{CO2}, and \ch{CO} at all spectra around the wavelengths of 3.05, 4.27, and 4.67 $\mu$m, respectively. At least two low-luminosity protostars, we also detected the \ch{XCN} ice feature at 4.62 $\mu$m. The presence of the crystalline \ch{H2O} ice and \ch{XCN} ice components indicates that the low-luminosity protostars experienced a hot phase via accretion bursts during the past mass accretion process. We compared the ice abundances of low-luminosity protostars with those of the embedded low-mass protostars and the dense molecular clouds and cores, suggesting that their ice abundances reflect the strength of prior bursts and the timescale after the last burst., Comment: 34 pages, 9 figures

We present high resolution Karl G. Jansky Very Large Array (VLA) observations of the protostar L1527 IRS at 7 mm, 1.3 cm, and 2 cm wavelengths. We detect the edge-on dust disk at all three wavelengths and find that it is asymmetric, with the southern side of the disk brighter than the northern side. We confirm this asymmetry through analytic modeling and also find that the disk is flared at 7 mm. We test the data against models including gap features in the intensity profile, and though we cannot rule such models out, they do not provide a statistically significant improvement in the quality of fit to the data. From these fits, we can however place constraints on allowed properties of any gaps that could be present in the true, underlying intensity profile. The physical nature of the asymmetry is difficult to associate with physical features due to the edge-on nature of the disk, but could be related to spiral arms or asymmetries seen in other imaging of more face-on disks., Comment: 20 pages, 5 figures, 3 tables; accepted for publication in the Astrophysical Journal

The activation energy for desorption (Edes) and that for surface diffusion (Esd) of adsorbed molecules on dust grains are two of the most important parameters for the chemistry in the interstellar medium. Although Edes is often measured by laboratory experiments, the measurement of Esd is sparse. Due to the lack of data, astrochemical models usually assume a simple scaling relation, Esd = fEdes, where f is a constant, irrespective of adsorbed species. Here, we experimentally measure Esd for CH4, H2S, OCS, CH3OH, and CH3CN on water-ice surfaces using an ultra-high-vacuum transmission electron microscope (UHV-TEM). Compiling the measured Esd values and Edes values from the literature, we find that the value of f ranges from ~0.2 to ~0.7, depending on the species. Unless f (or Esd) for the majority of species is available, a natural alternative approach for astrochemical models is running multiple simulations, varying f for each species randomly. In this approach, ranges of molecular abundances predicted by multiple simulations, rather than abundances predicted by each simulation, are important. We here run 10,000 simulations of astrochemical models of molecular clouds and protostellar envelopes, randomly assigning a value of f for each species. In the former case, we identify several key species whose Esd most strongly affects the uncertainties of the model predictions; Esd for those species should be investigated in future laboratory and quantum chemical studies. In the latter case, uncertainties in the Esd of many species contribute to the uncertainties in the model predictions., Comment: Accepted for publication in ApJL

The evolution of star-forming regions and their thermal balance are strongly influenced by their chemical composition, that, in turn, is determined by the physico-chemical processes that govern the transition between the gas phase and the solid state, specifically icy dust grains (e.g., particles adsorption and desorption). Gas-grain and grain-gas transitions as well as formation and sublimation of interstellar ices are thus essential elements of understanding astrophysical observations of cold environments (e.g., pre-stellar cores) where unexpected amounts of a large variety of chemical species have been observed in the gas phase. Adsorbed atoms and molecules also undergo chemical reactions which are not efficient in the gas phase. Therefore, the parameterization of the physical properties of atoms and molecules interacting with dust grain particles is clearly a key aspect to interpret astronomical observations and to build realistic and predictive astrochemical models. In this consensus evaluation, we focus on parameters controlling the thermal desorption of ices and how these determine pathways towards molecular complexity and define the location of snowlines, which ultimately influence the planet formation process. We review different crucial aspects of desorption parameters both from a theoretical and experimental point of view. We critically assess the desorption parameters commonly used in the astrochemical community for astrophysical relevant species and provide tables with recommended values. In addition, we show that a non-trivial determination of the pre-exponential factor nu using the Transition State Theory can affect the binding energy value. Finally, we conclude this work by discussing the limitations of theoretical and experimental approaches currently used to determine the desorption properties with suggestions for future improvements., Comment: 115 pages, 17 figures

We report a study of the low-mass Class-0 multiple system VLA 1623AB in the Ophiuchus star-forming region, using H$^{13}$CO$^+$ ($J=3-2$), CS ($J=5-4$), and CCH ($N=3-2$) lines as part of the ALMA Large Program FAUST. The analysis of the velocity fields revealed the rotation motion in the envelope and the velocity gradients in the outflows (about 2000 au down to 50 au). We further investigated the rotation of the circum-binary VLA 1623A disk as well as the VLA 1623B disk. We found that the minor axis of the circum-binary disk of VLA 1623A is misaligned by about 12 degrees with respect to the large-scale outflow and the rotation axis of the envelope. In contrast, the minor axis of the circum-binary disk is parallel to the large-scale magnetic field according to previous dust polarization observations, suggesting that the misalignment may be caused by the different directions of the envelope rotation and the magnetic field. If the velocity gradient of the outflow is caused by rotation, the outflow has a constant angular momentum and the launching radius is estimated to be $5-16$ au, although it cannot be ruled out that the velocity gradient is driven by entrainments of the two high-velocity outflows. Furthermore, we detected for the first time a velocity gradient associated with rotation toward the VLA 16293B disk. The velocity gradient is opposite to the one from the large-scale envelope, outflow, and circum-binary disk. The origin of its opposite gradient is also discussed., Comment: 27 pages, 21 figures, 2 Tables, Accepted for publication in ApJ

We have observed the 70 $\mu$m dark infrared dark cloud (IRDC) G14.492-00.139 in the N$_2$D$^+$ $J$=3--2, DCO$^+$ $J$=3--2, DCN $J$=3--2, and C$^{18}$O $J$=2--1 lines, using the Atacama Large Millimeter/submillimeter Array (ALMA) as part of the ALMA Survey of 70 $\mu$m Dark High-mass Clumps in Early Stages (ASHES). We find that the spatial distribution is different among the observed emission from the deuterated molecular lines. The N$_2$D$^+$ emission traces relatively quiescent regions, while both the DCO$^+$ and DCN emission emanates mainly from regions with signs of active star-formation. In addition, the DCO$^+$/N$_2$D$^+$ ratio is found to be lower in several dense cores than in starless cores embedded in low-mass star-forming regions. By comparing the observational results with chemical model calculations, we discuss the origin of the low DCO$^+$/N$_2$D$^+$ ratio in this IRDC clump. The low DCO$^+$/N$_2$D$^+$ ratio can be explained if the temperature of the dense cores is in the range between the sublimation temperature of N$_2$ ($\sim$20 K) and CO ($\sim$25 K). The results suggest that the dense cores in G14.492-00.139 are warmer and denser than the dense cores in low-mass star-forming regions., Comment: accepted for publication in ApJ

UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects, however to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N=1-0 transitions at 0.3'' resolution towards five disk systems. All disks show bright CN emission within $\sim$50-150 au, along with a diffuse emission shelf extending up to 600 au. In all sources we find that the CN/HCN column density ratio increases with disk radius from about unity to 100, likely tracing increased UV penetration that enhances selective HCN photodissociation in the outer disk. Additionally, multiple millimeter dust gaps and rings coincide with peaks and troughs, respectively, in the CN/HCN ratio, implying that some millimeter substructures are accompanied by changes to the UV penetration in more elevated disk layers. That the CN/HCN ratio is generally high (>1) points to a robust photochemistry shaping disk chemical compositions, and also means that CN is the dominant carrier of the prebiotically interesting nitrile group at most disk radii. We also find that the local column densities of CN and HCN are positively correlated despite emitting from vertically stratified disk regions, indicating that different disk layers are chemically linked. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

During the main phase of evolution of a protoplanetary disk, accretion regulates the inner-disk properties, such as the temperature and mass distribution, and in turn, the physical conditions associated with planet formation. The driving mechanism behind accretion remains uncertain; however, one promising mechanism is the removal of a fraction of angular momentum via a magnetohydrodynamic (MHD) disk wind launched from the inner tens of astronomical units of the disk. This paper utilizes CO isotopologue emission to study the unique molecular outflow originating from the HD 163296 protoplanetary disk obtained with the Atacama Large Millimeter/submillimeter Array. HD~163296 is one of the most well-studied Class II disks and is proposed to host multiple gas-giant planets. We robustly detect the large-scale rotating outflow in the 12CO J=2-1 and the 13CO J=2-1 and J=1-0 transitions. We constrain the kinematics, the excitation temperature of the molecular gas, and the mass-loss rate. The high ratio of the rates of ejection to accretion (5 - 50), together with the rotation signatures of the flow, provides solid evidence for an MHD disk wind. We find that the angular momentum removal by the wind is sufficient to drive accretion through the inner region of the disk; therefore, accretion driven by turbulent viscosity is not required to explain HD~163296's accretion. The low temperature of the molecular wind and its overall kinematics suggest that the MHD disk wind could be perturbed and shocked by the previously observed high-velocity atomic jet. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: Accepted ApJ July 30th 2021 This paper is part of the MAPS special issue of the Astrophysical Journal Supplement

Deuterium fractionation is dependent on various physical and chemical parameters. Thus, the formation location and thermal history of material in the solar system is often studied by measuring its D/H ratio. This requires knowledge about the deuteration processes operating during the planet formation era. We aim to study these processes by radially resolving the DCN/HCN (at 0.3" resolution) and N$_2$D$^+$/N$_2$H$^+$ (0.3 to 0.9") column density ratios toward the five protoplanetary disks observed by the Molecules with ALMA at Planet-forming scales (MAPS) Large Program. DCN is detected in all five sources, with one newly reported detection. N$_2$D$^+$ is detected in four sources, two of which are newly reported detections. We derive column density profiles that allow us to study the spatial variation of the DCN/HCN and N$_2$D$^+$/N$_2$H$^+$ ratios at high resolution. DCN/HCN varies considerably for different parts of the disks, ranging from $10^{-3}$ to $10^{-1}$. In particular, the inner disk regions generally show significantly lower HCN deuteration compared with the outer disk. In addition, our analysis confirms that two deuterium fractionation channels are active, which can alter the D/H ratio within the pool of organic molecules. N$_2$D$^+$ is found in the cold outer regions beyond $\sim$50 au, with N$_2$D$^+$/N$_2$H$^+$ ranging between $10^{-2}$ and 1 across the disk sample. This is consistent with the theoretical expectation that N$_2$H$^+$ deuteration proceeds via the low-temperature channel only. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement., Comment: Accepted for publication in the Astrophysical Journal Supplement. 55 pages, 30 figures. Replacement of earlier version with updated references

Constraining dust properties of planet-forming disks via high angular resolution observations is fundamental to understanding how solids are trapped in substructures and how dust growth may be favored or accelerated therein. We use ALMA dust continuum observations of the Molecules with ALMA at Planet-forming Scales (MAPS) disks and explore a large parameter space to constrain the radial distribution of solid mass and maximum grain size in each disk, including or excluding dust scattering. In the nonscattering model, the dust surface density and maximum grain size profiles decrease from the inner disks to the outer disks, with local maxima at the bright ring locations, as expected from dust trapping models. The inferred maximum grain sizes from the inner to outer disks decrease from ~1 cm to 1 mm. For IM Lup, HD 163296, and MWC 480 in the scattering model, two solutions are compatible with their observed inner disk emission: one solution corresponding to a maximum grain size of a few millimeters (similar to the nonscattering model), and the other corresponding to a few hundred micrometer sizes. Based on the estimated Toomre parameter, only IM Lup -- which shows a prominent spiral morphology in millimeter dust -- is found to be gravitationally unstable. The estimated maximum Stokes number in all the disks lies between 0.01 and 0.3, and the estimated turbulence parameters in the rings of AS 209 and HD 163296 are close to the threshold where dust growth is limited by turbulent fragmentation. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.