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The reform of state-own hospital under information age is approaching. All state-owned hospitals will be separated from their parent system through reorganization, restructuring, transferring and centralized management under information age, but there are numerous practical difficulties in this reform under information age. This paper followed up the whole reform process in a medical institution of A Group, summarized practical difficulties in the reform and provided preliminary suggestions for reasonable development of the reform. Practical difficulties in the reform of state-owned hospitals include unclear ownership, backlash among employees and compensation dispute under information age. Integrating internal resources, seizing market opportunities, seeking differentiate development, filling the gap in technology, keeping pace with medical reform and playing a positive role in transformation are reasonable approaches that can improve the reform of state-owned hospitals and provide referential significance for the reform of health system in China under information age.

A fully conjugated ligand 3,6-bis (8-hydroxyquinoline-5-propenyl)- N -butyl-carbazole (B8QPC) containing hole- and electron-transporting groups was firstly synthesized through the Wittig condensation polymerization. Corresponding polymeric complexes, B8QPC ( 1 ) with Cu(II) ( 2 ) and Zn(II) ( 3 ), were synthesized and characterized by FT-IR, elemental Analysis, conductivity measurement and gel permeation chromatography (GPC). GPC indicated that the number average molecular weights ( M n ) are about 3800 and the degree of polymerization ( n ) are about 5 for the polymeric complexes 2 and 3 . UV–vis and fluorescence spectra at room temperature revealed that both the polymeric complexes 2 and 3 emit blue luminescence at 473 and 513 nm ( λ em,max ) in DMSO solution and blue/green luminescence at 522 and 531 nm ( λ em,max ) in solid state, respectively. Thermal property measurements show that they have good thermal stability.

A novel ligand 3,6-bis(1,10-phenathroline-[5,6-d] imidazole-2-yl)carbazole (Bpic) containing hole- and electron-transporting groups was firstly designed. Its polymeric complexes of Bpic with Cu(∥), Zn(∥) were successfully synthesized. The UV-vis absorption, fluorescence spectra and thermal properties of these complexes were investigated. At room temperature, complexes 2, 3 emit blue luminescence from 445 to 485 nm in DMSO solution, and emit green/yellow and orange luminescence from 523 to 585 nm in solid state. In comparison with the free ligand, the polymeric complexes exhibit a bathochromic shift. It can be assigned to the extended π-conjugation of the complexes.

The polymeric metal complexes of 1,4-bis([1,10]phenanthroline-[5,6- d ]imidazol-2-yl)benzene (BPIB) with copper(II) and zinc(II) were synthesized and characterized by FT-IR, elemental analysis, conductivity measurements and gel permeation chromatography. The stoichiometry of the polymeric metal complexes was [(C 32 H 18 N 8 ) 7 (MCl 2 ) 8 ] (M = Cu(II), Zn(II)); BPIB forms a five-membered chelate ring. UV–vis and fluorescence spectra at room temperature revealed that the maximal emission of the complexes is red shifted as a result of coordination with the metal ions. Both complexes have good thermal stability and emit blue/green luminescence at 526 and 517 nm in the solid state and purple/blue luminescence at 423 and 434 nm in DMSO.

The polymeric complexes of 4,4′-bis[2-(2′-pyridyl)benzimidazolyl]biphenyl (Bmbp) with Co(II) (1), Ni(II) (2) and 1,3,5-tris[2-(2′-pyridyl)benzimidazolyl]benzene (Tmb) with Co(II) (3), Ni(II) (4) were successfully synthesized and characterized by using IR spectroscopy, elemental analysis, and gel permeation chromatography (GPC) analysis. Their cyclic voltametric behavior and thermal property were also studied. The results indicated these complexes display an irreversible redox process and have high thermal stability.

In this work, a combination process was developed in lab-scale for the purpose of removing pollutants in electroplating wastewater with high cyanide and metal loadings. Most of heavy metal ions were removed by Fe2+ reduction (for Cr6+) and subsequent precipitation (for Cr3+, Cu2+, and Ni2+ ions), and cyanide was efficiently removed by the formation of insoluble complex compounds with Fe2+ ions. During the following chemical oxidation process, the residual cyanide was mainly transformed to low-toxic cyanate, and Cu2+ and Ni2+ ions were released due to degradation of organic compounds and then removed by precipitation.