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The influence of gaseous hydrogen charging at 600 °C on the microstructure and mechanical behavior of wrought and Electron Beam Melted (EBM) Ti–6Al–4V alloys was investigated for hydrogen contents between 0.14 and 1.0 wt%. The small punch test (SPT) technique was used to characterize the mechanical behavior of all specimens. Both EBM and wrought alloys containing ∼6 wt% β and similar impurity levels showed similar phase content and mechanical property changes at all hydrogen contents, regardless of their original microstructural differences. This similarity can be explained by the high hydrogen diffusivity at the high temperature at which gaseous charging was carried out, and is in contrast to previous reports where EBM Ti–6Al–4V was found to be more sensitive to hydrogen embrittlement due to low-temperature electrochemical charging. After hydrogenation, α H and β H solid solutions were formed. The quantity of the α H phase reduced gradually with hydrogen content, while forming β H , α 2 , and hydrides. It was found that β H saturated at 0.27 wt% hydrogen content. Both alloys demonstrated relatively high strength and ductility up to hydrogen content of 0.2 wt%, i.e. below the β H saturation concentration. Above the β H saturation concentration, the mechanical properties of the maximum load (P max), deflection at maximum load (δ max), and absorbed energy (E) , degraded significantly due to hydride formation. [Display omitted] • The effects of gaseous hydrogenation on EBM and wrought Ti–6Al–4V were compared. • Both alloys had a similar phase and impurities content in the non-hydrogenated form. • Both alloys showed a similar mechanical behavior at any hydrogen content. • Above the β H saturation point, the mechanical properties degraded significantly. • Hydrogen-induced degradation is different after gaseous vs. electrochemical charging. [ABSTRACT FROM AUTHOR]