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We derive a very simple and effective stickiness criterion for solids having random roughness using a new asymptotic theory, which we validate with that of Persson and Scaraggi and independent numerical experiments. Previous claims that stickiness may depend on small scale quantities such as rms slopes and/or curvatures, obtained by making oversimplified assumptions on the contact area geometry, are largely incorrect, as the truncation of the PSD spectrum of roughness at short wavelengths is irrelevant. We find stickiness is destroyed typically at roughness amplitudes up to three orders of magnitude larger than the range of attractive forces. With typical nanometer values of the latter, the criterion gives justification to the qualitative well known empirical Dalhquist criterion for stickiness which demands adhesives to have elastic modulus lower than about 1MPa. The results clarifies a much debated question in both the scientific and technological world of adhesion, and may serve as benchmark for better comprehension of the role of roughness.

The double peeling of detachment of non-linear adhesive tapes from a flat Poly(methylmethacrylate) (PMMA) surface has been investigated from both experimental and theoretical point of view. Double peeling tests show that, as the detachment process advances, the peeling angle stabilizes on a limiting value {\theta}lim corresponding to a critical pull-off force Fc above which the tape is completely detached from the substrate. This observed behavior is in good agreement with results obtained following the new theory of multiple peeling and taking into account the hardening-softening non-linear behavior of the experimentally tested adhesive tapes and clarifies some aspects of the experimental data. In particular, the theoretical model shows that the value of the limiting peeling angle depends on the geometry of the adhesive tape as well as on the stiffness properties and on the interfacial energy {\Delta}{\gamma}. Finally, theoretical predictions confirm that solutions with a peeling angle lower than {\theta}lim are unstable., Comment: 14 pages, 8 figures

In this paper we present a generalized Cassi-Baxter equation to take into account the effect of drop pressure on the apparent contact angle theta_{app}. Also we determine the limiting pressure p_{W} which causes the impalement transition to the Wenzel state and the pull-off pressure p_{out} at which the drop detaches from the substrate. The calculations have been carried out for axial-symmetric pillars of three different shapes: conical, hemispherical topped and flat topped cylindrical pillars. Calculations show that, assuming the same pillar spacing, conical pillars may be more incline to undergo an impalement transition to the Wenzel state, but, on the other hand, they are characterized by a vanishing pull-off pressure which causes the drop not to adhere to the substrate and therefore to detach very easily. We infer that this property should strongly reduce the contact angle hysteresis as experimentally osberved in Ref. \cite{Martines-Conical-Shape}. It is possible to combine large resistance to impalement transition (i.e. large value of p_{W}) and small (or even vanishing) detaching pressure p_{out} by employing cylindrical pillars with conical tips. We also show that depending on the particular pillar geometry, the effect of drop pressure on the apparent contact angle theta_{app} may be more or less significant. In particular we show that in case of conical pillars increasing the drop pressure causes a significant decrease of theta_{app} in agreement with some experimental investigations \cite{LafunaTransitio}, whereas theta_{app} slightly increases for hemispherical or flat topped cylindrical pillars., Comment: 21 pages, 13 figures