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Submillimeter emission lines of carbon monoxide (CO) in Titan's atmosphere provide excellent probes of atmospheric temperature due to the molecule's long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) from 2012 to 2015 that contain strong CO rotational transitions. Utilizing ALMA's high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan's disk using datasets with beam sizes of ~0.3''. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere (~100-500 km) of spatially resolved regions. We measure the stratopause (320 km) to increase in temperature by 5 K in northern latitudes from 2012-2015, while temperatures rise throughout the stratosphere at lower latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMA's excellent sensitivity in the lower stratosphere (60-300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titan's atmospheric temperature lays the groundwork for future studies of other molecular species, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K., Comment: 11 pages, 9 figures, 3 tables

Saturn's polar stratosphere exhibits the seasonal growth and dissipation of broad, warm, vortices poleward of $\sim75^\circ$ latitude, which are strongest in the summer and absent in winter. The longevity of the exploration of the Saturn system by Cassini allows the use of infrared spectroscopy to trace the formation of the North Polar Stratospheric Vortex (NPSV), a region of enhanced temperatures and elevated hydrocarbon abundances at millibar pressures. We constrain the timescales of stratospheric vortex formation and dissipation in both hemispheres. Although the NPSV formed during late northern spring, by the end of Cassini's reconnaissance (shortly after northern summer solstice), it still did not display the contrasts in temperature and composition that were evident at the south pole during southern summer. The newly-formed NPSV was bounded by a strengthening stratospheric thermal gradient near $78^\circ$N. The emergent boundary was hexagonal, suggesting that the Rossby wave responsible for Saturn's long-lived polar hexagon - which was previously expected to be trapped in the troposphere - can influence the stratospheric temperatures some 300 km above Saturn's clouds., Comment: 51 pages, 12 figures, published in Nature Communications

Vinyl cyanide (C$_2$H$_3$CN) is theorized to form in Titan's atmosphere via high-altitude photochemistry and is of interest regarding the astrobiology of cold planetary surfaces due to its predicted ability to form cell membrane-like structures (azotosomes) in liquid methane. In this work, we follow up on the initial spectroscopic detection of C$_2$H$_3$CN on Titan by Palmer et al. (2017) with the detection of three new C$_2$H$_3$CN rotational emission lines at submillimeter frequencies. These new, high-resolution detections have allowed for the first spatial distribution mapping of C$_2$H$_3$CN on Titan. We present simultaneous observations of C$_2$H$_5$CN, HC$_3$N, and CH$_3$CN emission, and obtain the first (tentative) detection of C$_3$H$_8$ (propane) at radio wavelengths. We present disk-averaged vertical abundance profiles, two-dimensional spatial maps, and latitudinal flux profiles for the observed nitriles. Similarly to HC$_3$N and C$_2$H$_5$CN, which are theorized to be short-lived in Titan's atmosphere, C$_2$H$_3$CN is most abundant over the southern (winter) pole, whereas the longer-lived CH$_3$CN is more concentrated in the north. This abundance pattern is consistent with the combined effects of high-altitude photochemical production, poleward advection, and the subsequent reversal of Titan's atmospheric circulation system following the recent transition from northern to southern winter. We confirm that C$_2$H$_3$CN and C$_2$H$_5$CN are most abundant at altitudes above 200 km. Using a 300 km step model, the average abundance of C$_2$H$_3$CN is found to be $3.03\pm0.29$ ppb, with a C$_2$H$_5$CN/C$_2$H$_3$CN abundance ratio of $2.43\pm0.26$. Our HC$_3$N and CH$_3$CN spectra can be accurately modeled using abundance gradients above the tropopause, with fractional scale-heights of $2.05\pm0.16$ and $1.63\pm0.02$, respectively., Comment: Accepted for publication in the Astronomical Journal

The ice giants Uranus and Neptune are the least understood class of planets in our solar system but the most frequently observed type of exoplanets. Presumed to have a small rocky core, a deep interior comprising ~70% heavy elements surrounded by a more dilute outer envelope of H2 and He, Uranus and Neptune are fundamentally different from the better-explored gas giants Jupiter and Saturn. Because of the lack of dedicated exploration missions, our knowledge of the composition and atmospheric processes of these distant worlds is primarily derived from remote sensing from Earth-based observatories and space telescopes. As a result, Uranus's and Neptune's physical and atmospheric properties remain poorly constrained and their roles in the evolution of the Solar System not well understood. Exploration of an ice giant system is therefore a high-priority science objective as these systems (including the magnetosphere, satellites, rings, atmosphere, and interior) challenge our understanding of planetary formation and evolution. Here we describe the main scientific goals to be addressed by a future in situ exploration of an ice giant. An atmospheric entry probe targeting the 10-bar level, about 5 scale heights beneath the tropopause, would yield insight into two broad themes: i) the formation history of the ice giants and, in a broader extent, that of the Solar System, and ii) the processes at play in planetary atmospheres. The probe would descend under parachute to measure composition, structure, and dynamics, with data returned to Earth using a Carrier Relay Spacecraft as a relay station. In addition, possible mission concepts and partnerships are presented, and a strawman ice-giant probe payload is described. An ice-giant atmospheric probe could represent a significant ESA contribution to a future NASA ice-giant flagship mission., Comment: Submitted to Planetary and Space Science

The seasonal evolution of Saturn's polar atmospheric temperatures and hydrocarbon composition is derived from a decade of Cassini Composite Infrared Spectrometer (CIRS) 7-16 $\mu$m thermal infrared spectroscopy. We construct a near-continuous record of atmospheric variability poleward of 60$^\circ$ from northern winter/southern summer (2004, $L_s=293^\circ$) through the equinox (2009, $L_s=0^\circ$) to northern spring/southern autumn (2014, $L_s=56^\circ$). The hot tropospheric polar cyclones and the hexagonal shape of the north polar belt are both persistent features throughout the decade of observations. The hexagon vertices rotated westward by $\approx30^\circ$ longitude between March 2007 and April 2013, confirming that they are not stationary in the Voyager-defined System III longitude system as previously thought. The extended region of south polar stratospheric emission has cooled dramatically poleward of the sharp temperature gradient near 75$^\circ$S, coinciding with a depletion in the abundances of acetylene and ethane, and suggestive of stratospheric upwelling with vertical wind speeds of $w\approx+0.1$ mm/s. This is mirrored by a general warming of the northern polar stratosphere and an enhancement in acetylene and ethane abundances that appears to be most intense poleward of 75$^\circ$N, suggesting subsidence at $w\approx-0.15$ mm/s. However, the sharp gradient in stratospheric emission expected to form near 75$^\circ$N by northern summer solstice (2017, $L_s=90^\circ$) has not yet been observed, so we continue to await the development of a northern summer stratospheric vortex. North polar minima in tropospheric and stratospheric temperatures were detected in 2008-2010 (lagging one season, or 6-8 years, behind winter solstice); south polar maxima appear to have occurred before the start of the Cassini observations (1-2 years after summer solstice). [Abridged], Comment: Preprint of article accepted for publication in Icarus

In this paper we report new results concerning the seasonal atmospheric evolution near Titan's poles and equator using the Cassini Composite Infrared Spectrometer (CIRS). In previous papers (Coustenis et al. 2016 and 2018), after the 2010 equinox, we have monitored Titan's stratosphere since the beginning of the mission and reported recently on the observed strong temperature decrease and compositional enhancement above Titan's southern polar latitudes since 2012 of several trace species such as complex hydrocarbons and nitriles, which were previously observed only at high northern latitudes. This effect followed the transition of Titan's seasons from northern winter in 2002 to northern summer in 2017, while at that latter time, the southern hemisphere was entering winter. From 2013 until 2016, the northern polar region has shown a temperature increase of 10 K, while the south has shown a more significant decrease (up to 25 K) in a similar period of time. The stratosphere over the south pole of Titan shows a change in shape with a steeper positive slope and an increase in temperature in 2017 with respect to 2014, by 10-50 K in the 0.5 mbar-0.05 mbar pressure range, the larger 2017 temperatures observed in the higher atmospheric levels around 0.05 mbar, while in average the 70°S values return closer to the warmer ones found in 2012. While the south polar region is continuously enhanced since 2012, the chemical content in the north is showing a clear depletion for all molecules only since 2015 (Coustenis et al., 2018). We present here a complementary analysis of nadir spectra acquired by Cassini/CIRS at high resolution during the last year of the Cassini mission in 2017 and describe the temperature and composition variations near Titan's poles and at the equator over almost two Titan seasons. The 2017 data we have acquired and analyzed here are important because they are the only nadir ones afforded since 2014 close to the south pole at high resolution. They show no significant changes in the north with respect to 2016, but a large temperature increase in the southern polar stratosphere and a change in the temperature profiles shape while the South is also finally showing a related significant decrease in most of the abundances.

By the close of the Cassini mission in 2017 the Composite Infrared Spectrometer had recorded surface brightnesstemperatures on Titan for 13 yr (almost half a Titan year). We mapped temperatures in latitude from pole to pole inseven time segments from northern mid-winter to northern summer solstice. At the beginning of the mission thewarmest temperatures were centered at 13 S where they peaked at 93.9 K. Temperatures fell off by about 4 Ktoward the north pole and 2 K toward the south pole. As the seasons progressed the warmest temperatures shiftednorthward, tracking the subsolar point, and at northern summer solstice were centered at 24 N. While moving norththe peak temperature decreased by about 1 K, reaching 92.8 K at solstice. At solstice the fall-off toward the northand south poles were 1 K and 3 K, respectively. Thus the temperature range was the same 2 K at the two poles. Ourobserved surface temperatures agree with recent general circulation model results that take account of methanehydrology and imply that hemispherical differences in Titan's topography may play a role in the north?southasymmetry on Titan.

We have used data from the Cassini Composite Infrared Spectrometer to map the temperatures in Saturn's polar cyclones at the highest spatial resolution obtained during the Cassini mission. We find temperature contrasts of 7 K in the upper troposphere within 1.4° of both poles, roughly 50 percent larger than earlier measurements at lower spatial resolution. The polar hot spots weaken with depth, disappearing near 500 mbar. In the stratosphere, the polar hot spot becomes broader, extending 4° from the poles, and weakens with altitude disappearing near 1 mbar. A thermal relaxation model shows that the tropospheric hot spot is consistent with adiabatic heating from subsidence with a vertical velocity of about −0.05 mm/s above 500 mbar. The observed temperature gradients imply that the winds in the polar cyclone decay with increasing altitude over roughly three pressure scale heights above the 200‐mbar level.

The entry of the Cassini-Huygens spacecraft into orbit around Saturn in July 2004 marked the start of a golden era in the exploration of Titan, Saturn's giant moon. During the prime mission (2004-2008), ground-breaking discoveries were made by the Cassini orbiter including the equatorial dune fields (flyby T3, 2005), northern lakes and seas (T16, 2006), and the large positive and negative ions (T16 & T18, 2006), to name a few. In 2005 the Huygens probe descended through Titan's atmosphere, taking the first close-up pictures of the surface, including large networks of dendritic channels leading to a dried-up seabed, and also obtaining detailed profiles of temperature and gas composition during the atmospheric descent. The discoveries continued through the Equinox mission (2008-2010) and Solstice mission (2010-2017) totaling 127 targeted flybys of Titan in all. Now at the end of the mission, we are able to look back on the high-level scientific questions from the start of the mission, and assess the progress that has been made towards answering these. At the same time, new scientific questions regarding Titan have emerged from the new discoveries that have been made. In this paper we review a cross-section of important scientific questions that remain partially or completely unanswered, ranging from Titan's deep interior to the exosphere. Our intention is to help formulate the science goals for the next generation of planetary missions to Saturn and Titan, and to stimulate new experimental, observation and theoretical investigations in the interim, before such missions arrive again at Titan.

Submillimeter emission lines of carbon monoxide (CO) in Titan's atmosphere provide excellent probes of atmospheric temperature due to the molecule's long chemical lifetime and stable, well constrained volume mixing ratio. Here we present the analysis of 4 datasets obtained with the Atacama Large Millimeter/Submillimeter Array (ALMA) in 2012, 2013, 2014, and 2015 that contain strong CO rotational transitions. Utilizing ALMA's high spatial resolution in the 2012, 2014, and 2015 observations, we extract spectra from 3 separate regions on Titan's disk using datasets with beam sizes ranging from 0.35 ×0.28'' to 0.39 ×0.34''. Temperature profiles retrieved by the NEMESIS radiative transfer code are compared to Cassini Composite Infrared Spectrometer (CIRS) and radio occultation science results from similar latitude regions. Disk-averaged temperature profiles stay relatively constant from year to year, while small seasonal variations in atmospheric temperature are present from 2012 to 2015 in the stratosphere and mesosphere ( approx. 100-500 km) of spatially resolved regions. We measure the stratopause (320 km) to in- crease in temperature by 5 K in northern latitudes from 2012 to 2015, while temperatures rise throughout the stratosphere at lower latitudes. We observe generally cooler temperatures in the lower stratosphere ( approx. 100 km) than those obtained through Cassini radio occultation measurements, with the notable exception of warming in the northern latitudes and the absence of previous instabilities; both of these results are indicators that Titan's lower atmosphere responds to seasonal effects, particularly at higher latitudes. While retrieved temperature profiles cover a range of latitudes in these observations, deviations from CIRS nadir maps and radio occultation measurements convolved with the ALMA beam-footprint are not found to be statistically significant, and discrepancies are often found to be less than 5 K throughout the atmosphere. ALMA's excellent sensitivity in the lower stratosphere (60-300 km) provides a highly complementary dataset to contemporary CIRS and radio science observations, including altitude regions where both of those measurement sets contain large uncertainties. The demonstrated utility of CO emission lines in the submillimeter as a tracer of Titan's atmospheric temperature lays the groundwork for future studies of other molecular species -particularly those that exhibit strong polar abundance enhancements or are pressure-broadened in the lower atmosphere, as temperature profiles are found to consistently vary with latitude in all three years by up to 15 K.

We present new measurements of the deuterium abundance on Jupiter and Saturn, showing evidence that Saturn's atmosphere contains less deuterium than Jupiter's. We analyzed far-infrared spectra from the Cassini Composite Infrared Spectrometer to measure the abundance of HD on both giant planets. Our estimate of the Jovian D/H = (2.95 +/- 0.55) x 10(exp -5) is in agreement with previous measurements by ISO/SWS: (2.25 +/- 0.35) x 10(exp -5), and the Galileo probe: (2.6 +/- 0.7) x 10(exp -5). In contrast, our estimate of the Saturn value of (2.10 +/- 0.13) x 10(exp -5) is somewhat lower than on Jupiter (by a factor of 0.71(sub -0.15, sup +0..22)), contrary to model predictions of a higher ratio: Saturn/ Jupiter = 1.05-1.20. The Saturn D/H value is consistent with estimates for hydrogen in the protosolar nebula (2.1 +/- 0.5) x 10(exp -5), but its apparent divergence from the Jovian value suggests that our understanding of planetary formation and evolution is incomplete, which is in agreement with previous work.

The Cassini spacecraft orbiting Saturn carries the composite infrared spectrometer (CIRS) designed to study thermal emission from Saturn and its rings and moons. CIRS, a Fourier transform spectrometer, is an indispensable part of the payload providing unique measurements and important synergies with the other instruments. It takes full advantage of Cassini's 13-year-long mission and surpasses the capabilities of previous spectrometers on Voyager 1 and 2. The instrument, consisting of two interferometers sharing a telescope and a scan mechanism, covers over a factor of 100 in wavelength in the mid and far infrared. It is used to study temperature, composition, structure, and dynamics of the atmospheres of Jupiter, Saturn, and Titan, the rings of Saturn, and surfaces of the icy moons. CIRS has returned a large volume of scientific results, the culmination of over 30 years of instrument development, operation, data calibration, and analysis. As Cassini and CIRS reach the end of their mission in 2017, we expect that archived spectra will be used by scientists for many years to come.

Meridional brightness temperatures were measured on the surface of Titan during the 2004-2014 portion of the Cassini mission by the Composite Infrared Spectrometer. Temperatures mapped from pole to pole during five two year periods show a marked seasonal dependence. The surface temperature near the south pole over this time decreased by 2 K from 91.7 plus or minus 0.3 to 89.7 plus or minus 0.5 K while at the north pole the temperature increased by 1 K from 90.7 plus or minus 0.5 to 91.5 plus or minus 0.2 K. The latitude of maximum temperature moved from 19 S to 16 N, tracking the subsolar latitude. As the latitude changed, the maximum temperature remained constant at 93.65 plus or minus 0.15 K. In 2010 our temperatures repeated the north-south symmetry seen by Voyager one Titan year earlier in 1980. Early in the mission, temperatures at all latitudes had agreed with GCM predictions, but by 2014 temperatures in the north were lower than modeled by 1 K. The temperature rise in the north may be delayed by cooling of sea surfaces and moist ground brought on by seasonal methane precipitation and evaporation.

Far-IR 16-1000 micrometer spectra of Saturn's hydrogen-helium continuum measured by Cassini's Composite Infrared Spectrometer (CIRS) are inverted to construct a near-continuous record of upper tropospheric (70-700 mbar) temperatures and para-H2 fraction as a function of latitude, pressure and time for a third of a saturnian year (2004-2014, from northern winter to northern spring). The thermal field reveals evidence of reversing summertime asymmetries superimposed onto the belt/zone structure. The temperature structure is almost symmetric about the equator by 2014, with seasonal lag times that increase with depth and are qualitatively consistent with radiative climate models. Localised heating of the tropospheric hazes (100-250 mbar) create a distinct perturbation to the temperature profile that shifts in magnitude and location, declining in the autumn hemisphere and growing in the spring. Changes in the para-H2 (f(sub p)) distribution are subtle, with a 0.02-0.03 rise over the spring hemisphere (200-500 mbar) perturbed by (i) low-f(sub p) air advected by both the springtime storm of 2010 and equatorial upwelling; and (ii) subsidence of high-f(sub p) air at northern high latitudes, responsible for a developing north-south asymmetry in f(sub p). Conversely, the shifting asymmetry in the para-H2 disequilibrium primarily reflects the changing temperature structure (and hence the equilibrium distribution of f(sub p)), rather than actual changes in f(sub p) induced by chemical conversion or transport. CIRS results interpolated to the same point in the seasonal cycle as re-analysed Voyager-1 observations (early northern spring) show qualitative consistency from year to year (i.e., the same tropospheric asymmetries in temperature and f(sub p)), with the exception of the tropical tropopause near the equatorial zones and belts, where downward propagation of a cool temperature anomaly associated with Saturn's stratospheric oscillation could potentially perturb tropopause temperatures, para-H2 and winds. Quantitative differences between the Cassini and Voyager epochs suggest that the oscillation is not in phase with the seasonal cycle at these tropospheric depths (i.e., it should be described as quasi-periodic rather than 'semi annual'). Variability in the zonal wind field derived from latitudinal thermal gradients is small (less than 10 m/s per scale height near the tropopause) and mostly affects the broad retrograde jets, with the notable exception of large variability on the northern flank of the equatorial jet. The meridional potential vorticity (PV) gradient, and hence the 'staircase of PV' associated with spatial variations in the vigour of vertical mixing, has varied over the course of the mission but maintained its overall shape. PV gradients in latitude and altitude are used to estimate the atmospheric refractive index for the propagation of stationary planetary (Rossby) waves, predicting that such wave activity would be confined to regions of real refractivity (tropical regions plus bands at 35-45 in both hemispheres). The penetration depth of these regions into the upper troposphere is temporally variable (potentially associated with stratification changes), whereas the latitudinal structure is largely unchanged over time (associated with the zonal jet system).

A condensate cloud on Titan identified by its 220 cm−1 far-infrared signature continues to undergo seasonal changes at both the north and south poles. In the north, the cloud, which extends from 55 N to the pole, has been gradually decreasing in emission intensity since the beginning of the Cassini mission with a half-life of 3.8 years. The cloud in the south did not appear until 2012 but its intensity has increased rapidly, doubling every year. The shape of the cloud at the south pole is very different from that in the north. Mapping in 2013 December showed that the condensate emission was confined to a ring with a maximum at 80 S. The ring was centered 4deg from Titanʼs pole. The pattern of emission from stratospheric trace gases like nitriles and complex hydrocarbons (mapped in 2014 January) was also offset by 4deg, but had a central peak at the pole and a secondary maximum in a ring at about 70 S with a minimum at 80 S. The shape of the gas emission distribution can be explained by abundances that are high at the atmospheric pole and diminish toward the equator, combined with correspondingly increasing temperatures. We discuss possible causes for the condensate ring. The present rapid build up of the condensate cloud at the south pole is likely to transition to a gradual decline from 2015 to 2016. Key words: molecular processes - planets and satellites: atmospheres - planets and satellites: composition - planets and satellites: individual (Titan) - radiation mechanisms: thermal

We use far-infrared (20-200 micrometers) data from the Composite Infrared Spectrometer on the Cassini spacecraft to determine the zonal-mean temperature and hydrogen para-fraction in Saturn's upper troposphere from observations taken before and after the large northern hemisphere storm in 2010-2011. During the storm, zonal mean temperatures in the latitude band between approximately 25 deg N and 45 deg N (planetographic latitude) increased by about 3 K, while the zonal mean hydrogen para-fraction decreased by about 0.04 over the same latitudes, at pressures greater than about 300 mbar. These changes occurred over the same latitude range as the disturbed cloud band seen in visible images. The observations are consistent with low para-fraction gas being brought up from the level of the water cloud by the strong convective plume associated with the storm, while being heated by condensation of water vapor, and then advected zonally by the winds near the plume tops in the upper troposphere.

Since the Voyager 1 (V1) flyby in 1980, Titans exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titan year or 29.5 Earth years was completed in May 2010). In this study we search for temporal variations affecting Titans atmospheric thermal and chemical structure within that year. We process Cassini CIRS data taken during the Titan flybys from 2006-2013 and compare them to the 1980 V1IRIS spectra (re-analyzed here). We also consider data from Earth-based and -orbiting observatories (such as from the ISO, re-visited). When we compare the CIRS 2010 and the IRIS data we find limited inter-annual variations, below the 25 or35 levels for the lower and middle, or the high latitudes, respectively. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50degN to 50degS, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by GCM and photochemical models. However, some exceptions exist among the most complex hydrocarbons (C4H2 and C3H4), especially in the North. In the Southern latitudes, since 2012, we see a trend for an increase of several trace gases, possibly indicative of a seasonal atmospheric reversal. At the Northern latitudes we found enhanced abundances around the period of the northern spring equinox in mid-2009 (as in Bampasidis et al. 2012), which subsequently decreased (from 2010-2012) returning to values similar to those found in the V1 epoch a Titanian year before.

The massive eruption at 40 deg. N (planetographic latitude) on Saturn in 2010 December has produced significant and lasting effects in the northern hemisphere on temperature and species abundances. The northern storm region was observed on many occasions in 2011 by Cassini's Composite Infrared Spectrometer (CIRS). In 2011 May, temperatures in the stratosphere greater than 200 K were derived from CIRS spectra in the regions referred to as "beacons" (warm regions in the stratosphere). Ethylene has been detected in the beacon region in Saturn's northern storm region using CIRS. Ground-based observations using the high-resolution spectrometer Celeste on the McMath-Pierce Telescope on 2011 May 15 were used to confirm the detection and improve the altitude resolution in the retrieved profile. The derived ethylene profile from the CIRS data gives a C2H4 mole fraction of 5.9 +/- 4.5 x 10(exp -7) at 0.5 mbar, and from Celeste data it gives 2.7 +/- 0.45 x 10(exp -6) at 0.1 mbar. This is two orders of magnitude higher than the amount measured in the ultraviolet at other latitudes prior to the storm. It is also much higher than predicted by photochemical models, indicating that perhaps another production mechanism is required or a loss mechanism is being inhibited.

In August 2009 Titan passed through northern spring equinox, and the southern hemisphere passed into fall. Since then, the moon's atmosphere has been closely watched for evidence of the expected seasonal reversal of stratospheric circulation, with increased northern insolation leading to upwelling, and consequent downwelling at southern high latitudes. If the southern winter mirrors the northern winter, this circulation will be traced by increases in short-lived gas species advected downwards from the upper atmosphere to the stratosphere. The Cassini spacecraft in orbit around Saturn carries on board the Composite Infrared Spectrometer (CIRS), which has been actively monitoring the trace gas populations through measurement of the intensity of their infrared emission bands (7-1000 micron). In this presentation we will show fresh evidence from recent CIRS measurements in June 2012, that the shortest-lived and least abundant minor species (C3H4, C4H2, C6H6, HC3N) are indeed increasing dramatically southwards of 50S in the lower stratosphere. Intriguingly, the more stable gases (C2H2, HCN, CO2) have yet to show this trend, and continue to exhibit their 'summer' abundances, decreasing towards the south pole. Possible chemical and dynamical explanations of these results will be discussed , along with the potential of future CIRS measurements to monitor and elucidate these seasonal changes.

The massive storm at 40N on Saturn that began in December 2010 has produced significant and lasting effects in the northern hemisphere on temperature and species abundances (Fletcher et aL 2011). The northern storm region was observed on several occasions between March 2011 and April 2012 by Cassini's Composite Infrared Spectrometer (CIRS) at a spectral resolution (0.5/cm) which permits the study of trace species in Saturn's stratosphere. During this time period, stratospheric temperatures in regions referred to as "beacons" (warm regions at specific longitudes at the latitude of the storm) became significantly warmer than pre-storm values of 140K, peaking near 220K, and subsequently cooling. These warm temperatures led to greatly enhanced infrared emission due to C4H2, C3H4, C2H2, and C2H6 in the stratosphere as well as the first detection of C2H4 on Saturn in the thermal infrared (Hesman et al. 2012). Using CH4 as a thermometer of Saturn's stratosphere in the beacon regions, we can derive the mixing ratios of each of these molecules. The most common hydrocarbons (C2H2 and C2H6) serve as dynamical tracers on Saturn and their abundances may constrain vertical motion in the stratosphere. All of these hydrocarbons are products of methane photolysis. Since many of the photochemical reactions that produce heavier hydrocarbons such as C4H2 and C3H4 are temperature sensitive, the beacon region provides a natural laboratory for studying these reactions on Saturn. We will discuss the time evolution of the abundances of each of these hydrocarbons from their pre-storm values, through the period of maximum heating , and during the period of cooling that is taking place in Saturn's stratosphere.

The planet-encircling springtime storm in Saturn's troposphere (December 2010-July 2011, Fletcher, L.N. et al. [2011]. Science 332, 1413-1414; Sánchez-Lavega, A. et al. [2011]. Nature 475, 71-74; Fischer, G. et al. [2011]. Nature 475, 75-77) produced dramatic perturbations to stratospheric temperatures, winds and composition at mbar pressures that persisted long after the tropospheric disturbance had abated. Thermal infrared (IR) spectroscopy from the Cassini Composite Infrared Spectrometer (CIRS), supported by ground-based IR imaging from the VISIR instrument on the Very Large Telescope and the MIRSI instrument on NASA's IRTF, is used to track the evolution of a large, hot stratospheric anticyclone between January 2011 and March 2012. The evolutionary sequence can be divided into three phases: (I) the formation and intensification of two distinct warm airmasses near 0.5 mbar between 25 and 35degN (B1 and B2) between January-April 2011, moving westward with different zonal velocities, B1 residing directly above the convective tropospheric storm head; (II) the merging of the warm airmasses to form the large single 'stratospheric beacon' near 40degN (B0) between April and June 2011, disassociated from the storm head and at a higher pressure (2 mbar) than the original beacons, a downward shift of 1.4 scale heights (approximately 85 km) post-merger; and (III) the mature phase characterised by slow cooling (0.11 +/- 0.01 K/day) and longitudinal shrinkage of the anticyclone since July 2011. Peak temperatures of 221.6 +/- 1.4 K at 2 mbar were measured on May 5th 2011 immediately after the merger, some 80 K warmer than the quiescent surroundings. From July 2011 to the time of writing, B0 remained as a long-lived stable stratospheric phenomenon at 2 mbar, moving west with a near-constant velocity of 2.70 +/- 0.04 deg/day (24.5 +/- 0.4 m/s at 40degN relative to System III longitudes). No perturbations to visible clouds and hazes were detected during this period. With no direct tracers of motion in the stratosphere, we use thermal windshear calculations to estimate clockwise peripheral velocities of 200-400 m/s at 2 mbar around B0. The peripheral velocities of the two original airmasses were smaller (70-140 m/s). In August 2011, the size of the vortex as defined by the peripheral collar was 65deg longitude (50,000 km in diameter) and 25deg latitude. Stratospheric acetylene (C2H2) was uniformly enhanced by a factor of three within the vortex, whereas ethane (C2H6) remained unaffected. The passage of B0 generated a new band of warm stratospheric emission at 0.5 mbar at its northern edge, and there are hints of warm stratospheric structures associated with the beacons at higher altitudes (p < 0.1 mbar) than can be reliably observed by CIRS nadir spectroscopy. Analysis of the zonal windshear suggests that Rossby wave perturbations from the convective storm could have propagated vertically into the stratosphere at this point in Saturn's seasonal cycle, one possible source of energy for the formation of these stratospheric anticyclones.

Here we report the measurement of water vapor in Titan's stratosphere using the Cassini Composite Infrared Spectrometer (CIRS). CIRS senses water emissions in the far infrared spectral region near 50 micron, which we have modeled using two independent radiative transfer codes. From the analysis of nadir spectra we have derived a mixing ratio of 0.14 +/- 0.05 ppb at an altitude of 97 km, which corresponds to an integrated (from 0 to 600 km) surface normalized column abundance of 3.7 +/- 1.3 1014 molecules/cm2. In the latitude range 80S to 30N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of 0.13 +/- 0.04 ppb at an altitude of 115 km and 0.45 +/- 0.15 ppb at an altitude of 230 km, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models. We have also fitted our data using scaling factors of 0.1-0.6 to these photochemical model profiles, indicating that the models over-predict the water abundance in Titan's lower stratosphere.

A far-infrared emission band attributed to volatile or refractory haze in Titan's stratosphere has been decreasing in intensity since Cassini's arrival in 2004. The 220 cm(sup -1) feature, first seen by the Voyager Infrared Interferometer Spectrometer, has only been found in Titan's winter polar region. The emission peaks at about 140 km altitude near the winter stratospheric temperature minimum. Observations recorded over the period 2004-2012 by the Composite Infrared Spectrometer on Cassini show a decrease in the intensity of this feature by about a factor of four. Possible seasonal causes of this decline are an increase in photolytic destruction of source chemicals at high altitude, a lessening of condensation as solar heating increased, or a weakening of downwelling of vapors. As of early 2012, the 220 cm(sup -1) haze has not yet been detected in the south. The haze composition is unknown, but its decrease is similar to that of HC3N gas in Titan's polar stratosphere, pointing to a nitrile origin.

The existence of methane in Titan's atmosphere (approx. 6% level at the surface) presents a unique enigma, as photochemical models predict that the current inventory will be entirely depleted by photochemistry in a timescale of approx 20 Myr. In this paper, we examine the clues available from isotopic ratios (C-12/C-13 and D/H) in Titan's methane as to the past atmosphere history of this species. We first analyze recent infrared spectra of CH4 collected by the Cassini Composite Infrared Spectrometer, measuring simultaneously for the first time the abundances of all three detected minor isotopologues: (13)CH4, (12)CH3D, and (13)CH3D. From these we compute estimates of C-12/C-13 = 86.5 +/- 8.2 and D/H = (1.59 +/- 0.33) x 10(exp -4) , in agreement with recent results from the Huygens GCMS and Cassini INMS instruments. We also use the transition state theory to estimate the fractionation that occurs in carbon and hydrogen during a critical reaction that plays a key role in the chemical depletion of Titan's methane: CH4 + C2H yields CH3 + C2H2. Using these new measurements and predictions we proceed to model the time evolution of C-12/C-13 and D/H in Titan's methane under several prototypical replenishment scenarios. In our Model 1 (no resupply of CH4), we find that the present-day C-12/C-13 implies that the CH4 entered the atmosphere 60-1600 Myr ago if methane is depleted by chemistry and photolysis alone, but much more recently-most likely less than 10 Myr ago-if hydrodynamic escape is also occurring. On the other hand, if methane has been continuously supplied at the replenishment rate then the isotopic ratios provide no constraints, and likewise for the case where atmospheric methane is increasing, We conclude by discussing how these findings may be combined with other evidence to constrain the overall history of the atmospheric methane.

Water vapor in Titan's middle atmosphere has previously been detected only by disk-average observations from the Infrared Space Observatory (Coustenis et al., 1998). We report here the successful detection of stratospheric water vapor using the Cassini Composite Infrared Spectrometer (CIRS, Flasar et al., 2004) following an earlier null result (de Kok et al., 2007a). CIRS senses water emissions in the far-infrared spectral region near 50 microns, which we have modeled using two independent radiative transfer and inversion codes (NEMESIS, Irwin et al 2008 and ART, Coustenis et al., 2010). From the analysis of nadir spectra we have derived a mixing ratio of (0.14 plus or minus 0.05) ppb at 100 km, corresponding to a column abundance of approximately (3.7 plus or minus 1.3) x 10(exp 14) moles per square centimeter. Using limb observations, we obtained mixing ratios of (0.13 plus or minus 0.04) ppb at 125 km and (0.45 plus or minus 0.15) ppb at 225 km of altitude, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models. In the latitude range (80 deg. S - 30 deg. N) we see no evidence for latitudinal variations in these abundances within the error bars.

Since the first detection of water vapor in Titan's stratosphere by disk-average observations from the Infrared Space Observatory (Coustenis et al. 1998) we report here the successful detection of stratospheric water vapor using the Cassini Composite Infrared Spectrometer (CIRS, Flasar et al. 2004). CIRS senses water emissions in the far infrared spectral region near 50 microns, which we have modeled using two independent radiative transfer codes (NEMESIS, Irwin et al 2008 and ART, Coustenis et al. 2007, 2010). From the analysis of nadir spectra we have derived a mixing ratio of (0.14 0.05) ppb at an altitude of 97 kilometers, which corresponds to an integrated (from 0 to 600 kilometers) surface normalized column abundance of (3.7 plus or minus 1.3) x 10(exp 14) molecules per square centimeter. In the latitude range 80 S to 30 N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of (0.13 plus or minus 0.04) ppb at an altitude of 115 kilometers and (0.45 plus or minus 0.15) ppb at an altitude of 230 kilometers, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models (e.g. Lara et al. 1996, Wilson and Atreya 2004, Horst et al. 2008); retrieved scaling factors (from approximately 0.1 to approximately 0.6) to the water profile suggested by these models show that water vapor is present in Titan stratosphere with less abundance than predicted.

Analysis of Cassini Composite Infrared Spectrometer (CIRS) far-IR spectra enable the construction of Titan's temperature profile in the altitude region containing the tropopause. Whereas the methane V4 band at 1306/cm (7.7 microns) is the primary opacity source for deducing thermal structure between 100 km and 500 km, N2-N2 collision-induced absorption between 70 and 140/cm (143 microns and 71 microns) is utilized to determine temperatures at Titan's tropopause. Additional opacity due to aerosol and nitrile ices must also be taken into account in this part of the far-IR spectral region. The spectral characteristics of these particulate opacities have been deduced from CIRS limb data at 58degS, 15degS, 15degN, and 85degN. Empirically, the spectral shapes of these opacities appear to be independent of both latitude and altitude below 300 km (Anderson and Samuelson, 2011, Icarus 212, 762-778), justifying the extension of these spectral properties to all latitudes. We find that Titan's tropopause temperature is cooler than the HAS! value of 70.5K by approx. 6K. This leads to the possibility that subsidence at high northern latitudes can cause methane condensation in the winter polar stratosphere. A search for methane clouds in this region is in progress.

The massive storm at 40degN on Saturn that began in December 2010 has produced significant and lasting effects in the northern hemisphere on temperature and species abundances [I}. The northern storm region was observed at 0.5/cm spectral resolution in March 2011 by Cassini's Composite Infrared Spectrometer (CIRS). Temperatures in the stratosphere as high as 190 K were derived from CIRS spectra in warm regions referred to as "beacons". Other longitudes exhibit cold temperatures in the upper troposphere. These unusual conditions allow us to identify rare species such as C4H2, C3H4, and CO2 in the stratosphere, as well as to measure changes in the abundance of phosphine (PH3) in the troposphere. Phosphine is a disequilibrium species whose abundance is a tracer of upwelling from the deep atmosphere.

The thermal structure of Titan's atmosphere is reviewed, with particular emphasis on recent Cassini-Huygens results. Titan's has a similar troposphere-stratosphere-mesosphere pattern like Earth, but with a much more extended atmosphere, because of the weaker gravity, and also much lower temperatures, because of its greater distance from the sun. Titan's atmosphere exhibits an unusually large range in radiative relaxation times. In the troposphere, these are long compared to seasonal time scales, but in the stratosphere they are much shorter than a season. An exception is near the winter pole, where the stratospheric relaxation times at 100-170 km become comparable to the seasonal time scale; at the warm stratopause, they are comparable to a Titan day. Hence, seasonal behavior in the troposphere should be muted, but significant in the stratosphere. This is reflected in the small meridional contrast observed in temperatures in the troposphere and the large stratospheric contrasts noted above. A surprising feature of the vertical profiles of temperature is the abrupt transition between these regimes in at high northern latitudes in winter, where the temperatures in the lower stratosphere exhibit a sudden drop with increasing altitude. This could be a radiative effect, not associated with spatial variations in gaseous opacity, but rather from an optically thick condensate at thermal-infrared wavelengths. A curious aspect of Titan's middle atmosphere is that the axis of symmetry of the temperature field is tilted by several degrees relative to the rotational axis of the moon itself. Whether this is driven by solar heating or gravitational perturbations is not known. Titan's surface exhibits weak contrasts in temperature, approximately 3 K in the winter hemisphere. At low latitudes, there is evidence of a weak nocturnal boundary layer on the morning terminator, which is not radiatively controlled, but can be explained in terms of vertical mixing with a small eddy viscosity.

Thermal emission infrared observation of Saturn s atmosphere are being made by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft since its insertion in Saturn s orbit on July 2nd, 2004. The measurements made in both limb and nadir modes of observations consist of infrared spectra in the 10-1400/cm region with a variable spectral resolution of 0.53/cm and 2.8/cm, and exhibit rotational and vibrational spectral features that may be analyzed for retrieval of the thermal structure and constituent distribution of Saturn s atmosphere. In this paper, we present a comprehensive analysis of the CIRS infrared observed spectra for retrieval of Saturn s atmospheric composition focusing on the distributions of some selected hydrocarbons, phosphine, ammonia, and possible determination of the isotopic ratios of some species with sufficiently strong isolated spectral features. A comparison of the retrieved constituent distributions with the available data in the literature will be made.

The flybys of Jupiter by the Voyager spacecraft in 1979, and over two decades later by Cassini in 2000, have provided us with unique datasets from two different epochs, allowing the investigation of seasonal change in the atmosphere. In this paper we model zonal averages of thermal infrared spectra from the two instruments, Voyager 1 IRIS and Cassini CIRS, to retrieve the vertical and meridional profiles of temperature, and the abundances of the two minor hydrocarbons, acetylene (C2H2) and ethane (C2H6). The spatial variation of these gases is controlled by both chemistry and dynamics, and therefore their observed distribution gives us an insight into both processes, We find that the two gases paint quite different pictures of seasonal change. Whilst the 2-D cross-section of C2H6 abundance is slightly increased and more symmetric in 2000 (northern summer solstice) compared to 1979 (northern fall equinox), the major trend of equator to pole increase remains. For C2H2 on tile other hand, the Voyager epoch exhibits almost no latitudinal variation, whilst the Cassini era shows a marked decrease polewards in both hemispheres. At the present time, these experimental findings are in advance of interpretation, as there are no published models of 2-D Jovian seasonal chemical variation available for comparison.

The following six tables give the retrieved temperatures and volume mixing ratios of C2H2 and C2H6 and the formal errors on these results from the retrieval, as described in the manuscript. These are in the form of two-dimensional tables, specified on a latitudinal and vertical grid. The first column is the pressure in bar, and the second column gives the altitude in kilometers calculated from hydrostatic equilibrium, and applies to the equatorial profile only. The top row of the table specifies the planetographic latitude.

The following six tables give the retrieved temperatures and volume mixing ratios of C2H2 and C2H6 and the formal errors on these results from the retrieval, as described in the manuscript. These are in the form of two-dimensional tables, specified on a latitudinal and vertical grid. The first column is the pressure in bar, and the second column gives the altitude in kilometers calculated from hydrostatic equilibrium, and applies to the equatorial profile only. The top row of the table specifies the planetographic latitude.

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2001. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory [1] and subsequently confirmed by the Submillimeter Wave Astronomy Satellite [2], CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. long integrations at the full 0.5/cm spectral resolution were performed at targeted latitudes on Saturn. High emission angles were chosen to enhance stratospheric emission. Over the course of the prime and extended mission a set of observations has been built up spaced roughly every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v'4 band centered at 1501/cm. The origin of water vapor is believed to be from the ablation of micrometeorites containing eater ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney [3] proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al [4] interpreted a minimum in the abundance of acetylene from ultraviolet spectra gear 41S on Saturn as possibly due to an enhanced influx of water. We will be able to test the "ring rain" mechanism by searching, for localized water vapor enhancement at mid-latitudes. Our results may be used to constrain photochemical models of Saturn's stratosphere [5].

The radiative response of Titan's atmosphere varies by several orders of magnitude with altitude. This presents an interesting situation in which most of the stratosphere---at least that part above 100km is characterized by radiative relaxation times that are short compared to the length of a Titan season, and the troposphere and tropopause region by times that are larger than seasonal timescales. Consistent with this, Cassini CIRS spectra indicate stratospheric temperatures at 100-170 kin that are 20-30 K cooler at high northern latitudes in winter than those at equatorial and southern latitudes. Given the expectation that the situation will largely reverse in southern winter, the observed large meridional contrast is likely indicative of the expected seasonal variation at polar latitudes in both hemispheres. CIRS spectra do not as easily yield temperatures below 100 km in the lower stratosphere and tropopause region, because of the contribution of heterogeneously distributed aerosols and condensates to the infrared opacity. However, Cassini radio occultations probe both the stratosphere and troposphere, and below 80 km they show the thermal contrast with latitude to be muted, e.g, approx.5 K near the tropopause at 40-50 km and approx.3 K just above the surface. This is consistent with the large radiative relaxation times at these altitudes and with efficient meridional heat transport. What is curious is the manner in which temperatures in the north winter polar atmosphere make the transition between the troposphere and lower stratosphere, where seasonal variations are relatively small, and higher altitudes, where they are large. Temperatures at all latitudes sounded by the radio occultations exhibit similar behavior in the lower stratosphere, increasing with altitude. Between 80 and 100 kin, however, the temperatures at high northern latitudes exhibit a sudden drop with increasing altitude, producing the meridional contrast in the upper stratosphere described above. While the radiative relaxation time associated with infrared gaseous coolants decreases with altitude in the stratosphere, it is not likely to account for the abrupt transition observed. Possible mechanisms for this transition are discussed, including the presence of an optically thick. cloud at thermal-infrared wavelengths.

Titan's middle atmosphere is characterized by cyclostrophic winds and strong seasonal modulation. Cassini CIRS observations, obtained in northern winter, indicate that the stratosphere near l mbar is warmest at low latitudes, with the South Pole a few degrees colder and the North Pole approximately 20 K colder. Associated with the cold northern temperatures are strong circumpolar winds with speeds as high as 190 m/s. Within this vortex, the mixing ratios of several organic gases are enhanced relative to those at low latitudes. Comparison with Voyager thermal infrared measurements, obtained 25 years ago in northern spring, suggests that the enhancement currently observed will increase as the winter progresses. The stratopause height, increases from 0.1 mbar near the equator to 0.01 mbar near the North Pole, where it is the warmest part of the atmosphere, greater than 200 K. This implies subsidence at the pole, which is consistent with the enhanced organics observed. Condensate features, several still not identified, are also apparent in the infrared spectra at high northern latitudes. In many ways, the winter vortex observed on Titan, with cyclostrophic winds, resembles the polar winter vortices on the Earth, where the mean winds are geostrophic.

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained spectra of Titan during most of the 44 flybys of the Cassini prime mission. Water vapor on Titan was first detected using whole-disk observations from the Infrared Space Observatory (Coustenis et al 1998, Astron. Astrophys. 336, L85-L89). CIRS data permlt the retrieval of the latitudinal variation of water on Titan and some limited information on its vertical profile. Emission lines of H2O on Titan are very weak in the CIRS data. Thus, large spectral averages as well as improvements in calibration are necessary to detect water vapor. Water abundances were retrieved in nadir spectra at 55 South, the Equator, and at 19 North. Limb spectra of the Equator were also modeled to constrain the vertical distribution of water. Stratospheric temperatures in the 0.5 - 4.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304/cm. The temperature in the lower stratosphere (4 - 20 mbar) was derived from fitting pure rotation lines of CH4 between 80 and 160/cm. The origin of H2O and CO2 is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of water originates either within the Saturn system or from the interplanetary medium. Recently, Horst et al (J. Geophys. Res. 2008, in press) developed a photochemical model of Titan in which there are two external sources of oxygen. Oxygen ions (probably from Enceladus) precipitate into Titan's atmosphere to form CO at very high altitudes (1100 km). Water ice ablation at lower altitudes (700 km) forms H2O and subsequent chemistry produces CO2. CIRS measurements of CO, CO2, and now of H2O will provide valuable constraints to these photochemical models and - improve our understanding of oxygen chemistry on Titan.

The Composite Infrared Spectrometer (CIRS) on the Cassini spacecraft has obtained numerous spectra of Saturn at varying spectral and spatial resolutions since Saturn Orbit Insertion in 2004. Emission lines due to water vapor in Saturn's stratosphere were first detected using whole-disk observations from the Infrared Space Observatory (Feuchtgruber et al 1997) and subsequently confirmed by the Submillimeter Wave Astronomy Satellite (Rergin et al 2000). CIRS has detected water and the data permit the retrieval of the latitudinal variation of water on Saturn. Emission lines of H2O on Saturn are very weak in the CIRS data. Thus. large spectral averages as well as improvements in calibration are necessary to detect water vapor. Zonally averaged nadir spectra were produced every 10 degrees of latitude. Stratospheric temperatures in the 0.5 - 5.0 mbar range were obtained by inverting spectra of CH4 in the v4 band centered at 1304 cm(exp -1). The origin of water vapor is believed to be from the ablation of micrometeorites containing water ice, followed by photochemistry. This external source of oxygen originates either from the Saturn system (from the rings or perhaps from Enceladus) or from the interplanetary medium. Connerney (1986) proposed a mechanism to transport water from the inner edge of the B-ring along magnetic field lines to specific latitudes (50N and 44S) on Saturn. Prange et al (2006) interpreted a minimum in the abundance of acetylene from ultraviolet spectra near 41S on Saturn as possibly due to an enhanced influx of water. Existing CIRS far-IR spectra are at relatively low spatial resolution, but observations at closer range planned for the extended mission will be able to test the "ring rain" mechanism by searching for localized water vapor enhancement at midlatitudes.

The atmosphere of Titan has a spectral window of low opacity around 530/cm in the thermal infrared where radiation from the surface can be detected from space. The Composite Infrared spectrometer1 (CIRS) uses this window to measure the surface brightness temperature of Titan. By combining all observations from the Cassini tour it is possible to go beyond previous Voyager IRIS studies in latitude mapping of surface temperature. CIRS finds an average equatorial surface brightness temperature of 93.7+/-0.6 K, which is close to the 93.65+/-0.25 K value measured at the surface by Huygens HASi. The temperature decreases toward the poles, reaching 91.6+/-0.7 K at 90 S and 90.0+/-1.0 K at 87 N. The temperature distribution is centered in latitude at approximately 12 S, consistent with Titan's season of late northern winter. Near the equator the temperature varies with longitude and is higher in the trailing hemisphere, where the lower albedo may lead to relatively greater surface heating5. Modeling of radiances at 590/cm constrains the atmospheric H2 mole fraction to 0.12+/-0.06 %, in agreement with results from Voyager iris.