50 results on '"Acciona"'
Search Results
2. Conveni per a la implementació de millores de la mobilitat generada per la implantació de l'activitat logística d'Amazon al barri del Bon Pastor de Barcelona [versió en castellà]
- Author
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Gerència d'Urbanisme, Ajuntament de Sant Adrià de Besòs, Acciona Inmobiliaria, S.L.U., Amazon Road Transports Spain, S.L., Gerència d'Urbanisme, Ajuntament de Sant Adrià de Besòs, Acciona Inmobiliaria, S.L.U., and Amazon Road Transports Spain, S.L.
- Published
- 2022
3. Implantació d'un parc fotovoltaic d'autoconsum a l'EDAR d'Amposta
- Author
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Universitat Politècnica de Catalunya. Departament d'Enginyeria Electrònica, Acciona Agua, Bordonau Farrerons, José, Miró Argany, Xavier, Universitat Politècnica de Catalunya. Departament d'Enginyeria Electrònica, Acciona Agua, Bordonau Farrerons, José, and Miró Argany, Xavier
- Abstract
En aquest projecte s’ha realitzat un estudi del funcionament, equipament elèctric i perfils de consum de la EDAR d’Amposta amb l’objectiu de dissenyar una instal·lació fotovoltaica d’autoconsum que compleixi els requeriments per l’entorn on estaria situada. S’han tingut en compte les particularitats com és l’entorn de la planta, l’emplaçament, el clima, la normativa energètica actual d’autoconsum, etc. S’incorporen els càlculs necessaris pel correcte disseny de la planta fotovoltaica, com poden ser el càlcul de l’energia generada, el càlcul de secció dels cables, l’afectació de la força del vent a l’estructura i el càlcul d’ombres. En el disseny de la planta fotovoltaica s’han adjuntat els elements necessaris per la realització del projecte, incloent plànols de l’entorn, distribució de les sèries, esquema unifilar de la instal·lació, caracterització del material més destacat com pot ser el mòdul fotovoltaic i l’inversor i descripció tècnica dels elements més importants. S’ha realitzat una anàlisi de viabilitat on es pot trobar una comparació entre la generació fotovoltaica i el consum elèctric de la planta, caracteritzant les ràtios d’autoconsum i de cobertura. Finalment es pot trobar un estudi econòmic on es detalla el pressupost i la rendibilitat general de la instal·lació incorporant el nou tipus de tarifa elèctrica 3.0 TD. El disseny específic de la planta i la modelització de l’entorn s’han dut a terme mitjançant el programa d’edició Autocad™, Objectius de Desenvolupament Sostenible::7 - Energia Assequible i No Contaminant::7.2 - Per a 2030, augmentar substancialment el percentatge d’energia renovable en el conjunt de fonts d’energia, Objectius de Desenvolupament Sostenible::9 - Indústria, Innovació i Infraestructura::9.1 - Desenvolupar infraestructures fiables, sostenibles, resilients i de qualitat, incloent infraestructures regionals i transfrontereres, per tal de donar suport al desenvolupament econòmic i al benestar humà, amb especial atenció a l’accés assequible i equitatiu per a totes les persones
- Published
- 2022
4. Demo-followers' District Round Table
- Author
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ACCIONA
- Subjects
Demo followers, Replication, Technologies - Abstract
In WEDISTRICT project, industry innovators from 9 European countries will integrate multiple sources of renewable energy and excess heat to showcase solutions for 100% fossil free district heating and cooling systems being aligned with the foremost goal of the European Green Deal which is reaching climate-neutrality in 2050. The WEDISTRICT solutions will be implemented in four real-scale projects in Spain, Romania, Poland and Sweden. These demosites will showcase technological montages that can be replicated across different climate zones and building types. The demosites will be used to establish best practices that will transform the heating and cooling sector. As part of the project, other virtual demosites have been set-up. These virtual demosites are based on new or existing DHC system wishing to test improvements based on WEDISTRICT concepts (e.g: RES, waste heat recovery option). The virtual demosites are counted as WEDISTRICT demo-followers. Each virtual demosite has one referent WEDISTRICT partner in charge of its evaluation. Discussions have started to gather information regarding virtual demosites expectations, needs and action plan. Key DHC system characteristics as central station size, equipment features, thermal and cooling profiles, current operation strategies, economic information and other useful inputs have been collected in order to agree on the main challenges in terms of energy efficiency and costs reduction. The main objective of the activity is to support the current system, in retrofit cases, or propose the new generation plan, in greenfield cases, of the demo-followers, demonstrating the WEDISTRICT replicability potential by multiplying examples of DHC based on renewable energies. Each virtual demosite will integrate the most suitable technologies and operation strategies for improving the energy efficiency and lowering the emissions, considering the best cost-effective solutions. To summarize, the WEDISTRICT demo-followers’ community focuses on the large-scale replication potential of the technologies. Key outcomes of the project will be established guidelines based on the real and virtual demos aiming at advising for DHC systems improvement and optimisation, adapting the solution to the country and climate in which the DH/C is installed. The use of local resources, renewable energies, and waste heat recovery technologies will be encouraged.
- Published
- 2021
- Full Text
- View/download PDF
5. Adaptación e integración de sistemas multifuncionales en el medio físico. Herramientas para la Accesibilidad al Patrimonio (E2.25)
- Author
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ACCIONA and Institut Universitari d'Estudis Europeus. ACCEPLAN
- Subjects
Patrimoni arquitectònic Conservació i restauració - Abstract
En aquesta subtasca es pretén crear eines d'accessibilitat estudiant els productes existents, la seva adaptabilitat i possibilitat de transformació per a crear un nou producte d'accessibilitat universal. Es tracta d'una investigació sobre l'adaptació integració en el mitjà físic i desenvolupament de determinats dispositius destinats a salvar les barreres en els punts d'enllaç entre les diferents escales del Patrimoni que permeti resoldre la cadena de l'accessibilitat al Patrimoni Cultural.
- Published
- 2021
6. Microeukaryote community in a partial nitritation reactor prior to anammox and an insight into the potential of ciliates as performance bioindicators
- Author
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Generalitat de Catalunya, Acciona, Canals, Oriol, Massana, Ramon, Riera, Joan L., Balagué, Vanessa, Salvadó, H., Generalitat de Catalunya, Acciona, Canals, Oriol, Massana, Ramon, Riera, Joan L., Balagué, Vanessa, and Salvadó, H.
- Abstract
An in-depth, long-term, multidisciplinary study was conducted in order to study the microeukaryote community in a partial nitritation (PN) reactor prior to anammox. The PN reactor operated with moving bed biofilm reactor (MBBR) technology, using plastic supports (carriers) for biofilm development. The microeukaryote community from the biofilm (BF) and the surrounding media (mixed liquor or ML) were analysed separately. Despite the physicochemical conditions under which the PN-MBBR operated (an average of 305.9 ± 117 mg TAN l and 328.4 ± 131.9 mg N-NO l), up to 24 microeukaryotic taxa were observed by microscope. Microeukaryote species showed an uneven distribution in the PN-MBBR, thus suggesting the existence of two habitats: the BF, preferred by species with specific structures for adhering to a substrate, such as the stalked Peritrichia, and the ML, preferred by free-swimming or non-substrate dependent species. The results indicated that most ciliate population dynamics mainly responded to the nitrous acid and free ammonia concentrations and, to a lesser extent, to sCOD values. In the BF, variations in the population of Epistylis camprubii and Opercularia coarctata suggest the existence of competition between these species due to niche overlap. A V4 18S rDNA molecular survey (Illumina) was carried out for some samples with the aim of obtaining maximum coverage of the main eukaryote species that were microscopically detected throughout the study. The diversity and abundance data provided by both detection methods were compared. The study helped identify broader tolerance ranges of the microeukaryote taxa to the physicochemical parameters analysed
- Published
- 2018
7. C4R D 4.3.2 Demonstration of new monitoring techniques
- Author
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Acciona, S.A. and Acciona, S.A.
- Abstract
This Deliverable D4.3.2 presents the results of the research carried out in task 4.3.4 of SP4 Advanced Monitoring - WP4.3 Implementation in new structures. The aim of this deliverable is to describe the specific design, installation process, testing protocol and test results from the monitoring system devised in previous tasks (and described in D4.3.1). Said system has been installed in the demonstrators for the new infrastructure concepts developed in SP1, which shall also be thoroughly described in the document., Capacity4Rail
- Published
- 2017
8. Ni-Co electrodes prepared by electroless-plating deposition. A study of their electrocatalytic activity for the hydrogen and oxygen evolution reactions
- Author
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Acciona, Consejo Superior de Investigaciones Científicas (España), Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, García Fierro, José Luis, Acciona, Consejo Superior de Investigaciones Científicas (España), Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, and García Fierro, José Luis
- Abstract
Nickel–cobalt based electrodes with different Ni–Co ratios have been prepared by electroless-plating deposition from NiSO4 and CoSO4 solutions. The performance of the electrodes for the HER and OER reactions has been examined by linear sweep voltammetry. The electrode containing only nickel (Ni-ELP) displays the lowest overpotential for the HER. On the other hand, the Ni–Co electrode with Co concentrations of 30 at% (Ni70Co30-ELP) exhibits the lowest overpotential for OER. Durability tests have been carried out with these two electrodes. The potential of electrolytic cell at 0.3 A cm−2, using Ni-ELP for the HER and Ni70Co30-ELP for the OER, was of 2.2 V. Characterization of the used electrodes by SEM/EDS reveals that the structure of the electrodes remains stable after H2O alkaline electrolysis for 70 h. The results presented in this work show that the electroless-plating method is a successful way to prepare stable nickel electrodes for alkaline water electrolysis.
- Published
- 2015
9. Adaptación e integración de sistemas multifuncionales en el medio físico. Herramientas para la Accesibilidad al Patrimonio (E2.25)
- Author
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ACCIONA and Institut Universitari d'Estudis Europeus. ACCEPLAN
- Subjects
72 - Arquitectura ,Patrimoni arquitectònic -- Conservació i restauració - Abstract
En aquesta subtasca es pretén crear eines d'accessibilitat estudiant els productes existents, la seva adaptabilitat i possibilitat de transformació per a crear un nou producte d'accessibilitat universal. Es tracta d'una investigació sobre l'adaptació integració en el mitjà físic i desenvolupament de determinats dispositius destinats a salvar les barreres en els punts d'enllaç entre les diferents escales del Patrimoni que permeti resoldre la cadena de l'accessibilitat al Patrimoni Cultural.
- Published
- 2010
10. Performance characterization of a PCM storage tank
- Author
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Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, Ministerio de Ciencia e Innovación, ACCIONA, S.A., López Navarro, Alejandro, Biosca Taronger, Javier, Corberán Salvador, José Miguel, Peñalosa, C., Lázaro, A., Dolado, P., Payá Herrero, Jorge, Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, Ministerio de Ciencia e Innovación, ACCIONA, S.A., López Navarro, Alejandro, Biosca Taronger, Javier, Corberán Salvador, José Miguel, Peñalosa, C., Lázaro, A., Dolado, P., and Payá Herrero, Jorge
- Abstract
This paper presents the experimental results of a versatile latent heat storage tank capable of working with organic phase-change materials within a temperature range from -10 °C to 100 °C. The tank contains a paraffin with a phase-change temperature between 3 °C and 8 °C. Firstly, this study focuses on explaining the design criteria which were followed to build the tank. Secondly, a full experimental characterization of the performance has been carried out. The enthalpy temperature curve, the specific heat and density have been measured for the tested paraffin. The performance of the tank has been analyzed in terms of the vertical stratification within the PCM, the effectiveness, the reacted fraction and the total heat transfer of the tank. The results indicate that up to 78% of the maximum capacity is reached within 4 h. The performance is mainly controlled by the supply temperature and the effect of the mass flow rate is almost negligible given that all the tests are in laminar flow.
- Published
- 2014
11. Electrolisis alcalina con electrodos Ni-Co preparados por electroless-plating
- Author
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Ministerio de Ciencia e Innovación (España), Consejo Superior de Investigaciones Científicas (España), Ingeteam, Acciona, Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, García Fierro, José Luis, Ministerio de Ciencia e Innovación (España), Consejo Superior de Investigaciones Científicas (España), Ingeteam, Acciona, Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, and García Fierro, José Luis
- Abstract
Se han preparado electrodos basados en níquel-cobalto, con diferentes relaciones Ni-Co, mediante el método de electroless-plating, a partir de disoluciones de NiSO4 and CoSO4. La morfología y la composición de los electrodos Ni-Co fue analizada mediante XPS y SEM. Mediante voltamperometría de barrido lineal se estudió la actividad electrocatalítica de los electrodos Ni-Co tanto para la reacción de producción de hidrógeno (HER) como para la de producción de oxígeno (OER) en medio alcalino. El electrodo basado únicamente en níquel (Ni-ELP) muestra el sobrepotencial más bajo para la HER. Sin embargo, las curvas de polarización muestran que el electrodo Ni-Co con un concentración de 30 at.% (Ni70Co30-ELP) es el que produce el menor sobrepotencial para la OER. Se realizaron también ensayos de durabilidad con estos dos electrodos en un electrolizador construido en el laboratorio. El voltaje de la celda electrolítica a 0.3 A·cm-2, usando Ni-ELP para la HER y Ni70Co30-ELP para la OER, fue 2.2 V, mostrando una alta estabilidad durante 70 horas de operación. La caracterización de los electrodos usados en este ensayo de durabilidad demuestra la alta estabilidad de los mismos. Finalmente, los resultados presentados en este trabajo indican que la técnica de electroless-plating es un método muy adecuado para preparar electrodos de níquel para electrolizadores alcalinos.
- Published
- 2014
12. Ni/Fe electrodes prepared by electrodeposition method over different substrates for oxygen evolution reaction in alkaline medium
- Author
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Ministerio de Educación y Ciencia (España), Acciona, Ministerio de Ciencia e Innovación (España), Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, García Fierro, José Luis, Ministerio de Educación y Ciencia (España), Acciona, Ministerio de Ciencia e Innovación (España), Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, and García Fierro, José Luis
- Abstract
A series of Ni/Fe electrodes have been prepared by electrodeposition of metal salt precursors on different substrates. The surface morphology, chemical composition and electrochemical characteristics of these electrodes were studied by various physico-chemical techniques such as X-ray Photoelectron Spectroscopy (XPS) and Scanning Electron Microscopy (SEM). The electrochemical properties of the electrodes were examined by steady-state polarization curves. First, the influence of features such as Ni/Fe composition and type of substrate for the oxygen evolution reaction (OER) were determined by electrochemical techniques in a conventional 3-electrodes cell. The overpotential for the OER is lower for the electrodes with the higher concentrations of Ni. The electrodes with a Ni/Fe composition of 75/25 wt.% electrodeposited on steel mesh and/or 75/25 and 50/50 wt.% on nickel foam result in the most active configurations for the OER. These electrodes were further tested as anodes for alkaline water electrolysis during at least 70 h. In order to understand their activity and stability, the used electrodes were also characterized by SEM and compared to the fresh electrodes. Among the compositions and substrates examined, the Ni50Fe50-Nf electrode exhibited the lowest overpotential (2.1 V) for the OER and the higher stability as anode in an alkaline water electrolysis cell.
- Published
- 2014
13. Sizing and analysis of big scale and isolated electric systems based on renewable sources with energy storage
- Author
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Oscar Alonso Sadaba, Santiago Galbete Goyena, and S. A. Acciona
- Subjects
Microeconomics ,Sustainable development ,Engineering ,Renewable energy credit ,Electricity generation ,business.industry ,Scale (chemistry) ,Production (economics) ,Environmental economics ,business ,Sizing ,Energy storage ,Renewable energy - Abstract
A considerable number of institutions, companies and societies demand and trust the possibility of a sustainable world where the energetic production is based on renewable sources. Most likely future problem of the no-controllable renewable electric production (mainly wind and solar) may be the temporally variability. To follow the power demand is necessary controllable generation. The paper analyses based on hypothetical situations how to manage through storage systems the no-controllable productions to get the complete substitution of the no-renewable power plants. Data from real renewable plants has been used to explore in big electric systems (Spain) the optimal sizing of said storage systems. It is shown that with a potential renewable overproduction around 150% versus a yearly demand only a 1.5% energy storage capacity versus demand should be necessary.
- Published
- 2009
- Full Text
- View/download PDF
14. Experimental investigations on the influence of ice floating in an internal melt ice-on-coil tank
- Author
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Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, ACCIONA, S.A., López Navarro, Alejandro, Biosca Taronger, Javier, Torregrosa Jaime, Bárbara, Corberán Salvador, José Miguel, Bote García, J.L., Payá Herrero, Jorge, Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, ACCIONA, S.A., López Navarro, Alejandro, Biosca Taronger, Javier, Torregrosa Jaime, Bárbara, Corberán Salvador, José Miguel, Bote García, J.L., and Payá Herrero, Jorge
- Abstract
In this paper, the discharge of an experimental ice-storage tank is analyzed. The storage tank is an internal melt-ice-on-coil system. The discharge process has been studied for different mass flow rates and supply temperatures in the range from 10 ºC to 15 ºC. The results indicate that once the ice breaks and floats toward the top of the tank, convection in the ice/water mixture is enhanced and the heat transfer fluid in the top coils becomes colder than in the bottom coils. Thus, an increase of the cooling power is generally observed around the ice-breaking point. Two correlations have been developed to reproduce the effect of the mass flow rate and supply temperature on the discharge duration and the mean cooling power.
- Published
- 2013
15. Experimental analysis of a paraffin-based cold storage tank
- Author
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Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, ACCIONA, S.A., Torregrosa-Jaime, Barbara, López-Navarro, Alejandro, Corberán, José M., Esteban-Matías, J. C., Klinkner, L., Payá-Herrero, Jorge, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, ACCIONA, S.A., Torregrosa-Jaime, Barbara, López-Navarro, Alejandro, Corberán, José M., Esteban-Matías, J. C., Klinkner, L., and Payá-Herrero, Jorge
- Abstract
[EN] The aim of this study is to characterize a paraffin-based cold storage tank. Novel experimental results are presented for this system which combines a significant amount of paraffin (1450 kg) immersed around 18 spiral-shaped coils disposed in counter-current flow. The paraffin has a phase-change temperature in the range 4 8 °C as measured by a 3-layer calorimeter. Different tests have been carried out with a constant mass flow rate and supply temperature. Around 31% of the paraffin has hardly any contact with the coils and hereby acts as a dead mass. The results show the importance of natural convection within the phase-change-material, particularly during the melting process. The highest efficiency has been achieved for the lowest supply temperatures and mass flow rates of the heat transfer fluid.
- Published
- 2013
16. Experimental investigation of the temperatures and performance of a commercial ice-storage tank
- Author
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Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, ACCIONA, S.A., López-Navarro, Alejandro, Biosca Taronger, Javier, Torregrosa-Jaime, Barbara, Martínez Galván, Israel Octavio, Corberán, José M., Esteban-Matías, J. C., Payá-Herrero, Jorge, Universitat Politècnica de València. Departamento de Termodinámica Aplicada - Departament de Termodinàmica Aplicada, Universitat Politècnica de València. Instituto de Ingeniería Energética - Institut d'Enginyeria Energètica, ACCIONA, S.A., López-Navarro, Alejandro, Biosca Taronger, Javier, Torregrosa-Jaime, Barbara, Martínez Galván, Israel Octavio, Corberán, José M., Esteban-Matías, J. C., and Payá-Herrero, Jorge
- Abstract
[EN] This paper presents the results of an experimental installation with an internal melt-ice-on-coil tank which has a total capacity of 172 kWh. The aim of this work is to analyse the freezing process in a tank with counter-current spiral-shaped coils immersed in around 1855l water. An experimental campaign has been performed with different inlet temperatures and mass flow rates of the heat transfer fluid. This study analyses (i) the chiller performance, (ii) the ice-formation process and (iii) the energy consumption of the installation. Supply temperatures between 2.5 C and 5.2 C have been sufficient to charge the tank without using any nucleating agents. The lowest energy consumption has been achieved for the fastest charging tests.
- Published
- 2012
17. Sizing and analysis of big scale and isolated electric systems based on renewable sources with energy storage
- Author
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Goyena, Santiago Galbete, primary, Sadaba, Oscar Alonso, additional, and Acciona, S. A., additional
- Published
- 2009
- Full Text
- View/download PDF
18. Implantació d'un parc fotovoltaic d'autoconsum a l'EDAR d'Amposta
- Author
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Miró Argany, Xavier, Bordonau Farrerons, José, Universitat Politècnica de Catalunya. Departament d'Enginyeria Electrònica, and Acciona Agua
- Subjects
Instal·lacions fotovoltaiques -- Amposta (Catalunya) -- Disseny i construcció ,Sewage disposal plants -- Amposta (Spain) -- Energy conservation ,Photovoltaic power systems -- Amposta (Spain) -- Design and construction ,Aigües residuals -- Plantes de tractament -- Amposta (Catalunya) -- Estalvi d'energia ,Energies::Energia solar fotovoltaica::Instal·lacions solars de baixa potència connectades a la xarxa [Àrees temàtiques de la UPC] - Abstract
En aquest projecte s’ha realitzat un estudi del funcionament, equipament elèctric i perfils de consum de la EDAR d’Amposta amb l’objectiu de dissenyar una instal·lació fotovoltaica d’autoconsum que compleixi els requeriments per l’entorn on estaria situada. S’han tingut en compte les particularitats com és l’entorn de la planta, l’emplaçament, el clima, la normativa energètica actual d’autoconsum, etc. S’incorporen els càlculs necessaris pel correcte disseny de la planta fotovoltaica, com poden ser el càlcul de l’energia generada, el càlcul de secció dels cables, l’afectació de la força del vent a l’estructura i el càlcul d’ombres. En el disseny de la planta fotovoltaica s’han adjuntat els elements necessaris per la realització del projecte, incloent plànols de l’entorn, distribució de les sèries, esquema unifilar de la instal·lació, caracterització del material més destacat com pot ser el mòdul fotovoltaic i l’inversor i descripció tècnica dels elements més importants. S’ha realitzat una anàlisi de viabilitat on es pot trobar una comparació entre la generació fotovoltaica i el consum elèctric de la planta, caracteritzant les ràtios d’autoconsum i de cobertura. Finalment es pot trobar un estudi econòmic on es detalla el pressupost i la rendibilitat general de la instal·lació incorporant el nou tipus de tarifa elèctrica 3.0 TD. El disseny específic de la planta i la modelització de l’entorn s’han dut a terme mitjançant el programa d’edició Autocad™ Objectius de Desenvolupament Sostenible::7 - Energia Assequible i No Contaminant::7.2 - Per a 2030, augmentar substancialment el percentatge d’energia renovable en el conjunt de fonts d’energia Objectius de Desenvolupament Sostenible::9 - Indústria, Innovació i Infraestructura::9.1 - Desenvolupar infraestructures fiables, sostenibles, resilients i de qualitat, incloent infraestructures regionals i transfrontereres, per tal de donar suport al desenvolupament econòmic i al benestar humà, amb especial atenció a l’accés assequible i equitatiu per a totes les persones
- Published
- 2022
19. Design Basis of Movable Scaffolding Systems Following American and European Code Provisions and Recommendations
- Author
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Hugo Corres Peiretti, Leonardo Todisco, Marck Anthony Mora Quispe, Universidad Politécnica de Madrid, and ACCIONA
- Subjects
Bridging (networking) ,Computer science ,structural design codes ,Bridge engineering ,Control (management) ,0211 other engineering and technologies ,020101 civil engineering ,02 engineering and technology ,Construction engineering ,Bridge (nautical) ,0201 civil engineering ,021105 building & construction ,Code (cryptography) ,TE1-450 ,temporary structures ,design challenges ,Highway engineering. Roads and pavements ,Civil and Structural Engineering ,movable scaffolding systems (mms) ,Basis (linear algebra) ,design standards ,constructive method ,Building and Construction ,bridge construction equipment ,bridge construction ,design guidance ,movable scaffolding systems (MMS) ,TG1-470 - Abstract
Construction of bridges span-by-span with Movable Scaffolding Systems (MSSs) is a very efficient and competitive technology. Normally used for spans between 25 and 70m, the technology has allowed reaching longer spans due to technological advances, specifically in bridge construction equipment. Thereby, the use of MSS has become widespread and well-accepted in a large number of locations across the USA and Europe. Nevertheless, despite its extended application, there is no single specific code provision that can explain, control, and give recommendations about all aspects of MSS during its design and usage. On the contrary, the information is spread over several documents. This paper aims at bridging this gap by providing an extensive review of code provisions and recommendations that can be valid for the MSS design. Applicability of these documents is discussed by analysing loads, safety factors, load combinations, limit states, as well as structural analysis and design. After this, a proposal of a design basis for MSS is presented for each aspect mentioned following provisions and recommendations of the considered codes.
- Published
- 2021
20. Basal oxidation of conserved cysteines modulates cardiac titin stiffness and dynamics
- Author
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Elías Herrero-Galán, Inés Martínez-Martín, Cristina Sánchez-González, Natalia Vicente, Elena Bonzón-Kulichenko, Enrique Calvo, Carmen Suay-Corredera, Maria Rosaria Pricolo, Ángel Fernández-Trasancos, Diana Velázquez-Carreras, Claudio Badía Careaga, Mahmoud Abdellatif, Simon Sedej, Peter P. Rainer, David Giganti, Raúl Pérez-Jiménez, Jesús Vázquez, Jorge Alegre-Cebollada, Ministerio de Ciencia e Innovación (España), Comunidad de Madrid (España), European Research Council, European Science Foundation, Unión Europea. Fondo Europeo de Desarrollo Regional (FEDER/ERDF), Instituto de Salud Carlos III, Fundación La Caixa, European Research Area Network on Cardiovascular Diseases, FWF Austrian Science Fund, Fundación ProCNIC, Agencia Estatal de Investigación (España), Ministerio de Ciencia e Innovación. Centro de Excelencia Severo Ochoa (España), Acciona, Comunidad de Madrid, Austrian Science Fund, and Subprograma de Apoyo a Centros de Excelencia Severo Ochoa (MINECO), España
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Sarcomeres ,Heart Diseases ,Myocardium ,Organic Chemistry ,Clinical Biochemistry ,Biochemistry ,Elasticity ,Mice ,Animals ,Humans ,Connectin ,Cysteine ,Oxidation-Reduction ,Protein Kinases - Abstract
Titin, as the main protein responsible for the passive stiffness of the sarcomere, plays a key role in diastolic function and is a determinant factor in the etiology of heart disease. Titin stiffness depends on unfolding and folding transitions of immunoglobulin-like (Ig) domains of the I-band, and recent studies have shown that oxidative modifications of cryptic cysteines belonging to these Ig domains modulate their mechanical properties in vitro. However, the relevance of this mode of titin mechanical modulation in vivo remains largely unknown. Here, we describe the high evolutionary conservation of titin mechanical cysteines and show that they are remarkably oxidized in murine cardiac tissue. Mass spectrometry analyses indicate a similar landscape of basal oxidation in murine and human myocardium. Monte Carlo simulations illustrate how disulfides and S-thiolations on these cysteines increase the dynamics of the protein at physiological forces, while enabling load- and isoform-dependent regulation of titin stiffness. Our results demonstrate the role of conserved cysteines in the modulation of titin mechanical properties in vivo and point to potential redox-based pathomechanisms in heart disease. This work was supported by the Ministerio de Ciencia e Innovación (MCIN/AEI/10.13039/501100011033) grants BIO2014-54768-P, BIO2017-83640-P (AEI/FEDER, UE), PID2020-120426GB-I00, RYC2014-16604 to JAC and PGC2018-097019-B-I00 to JV, the Regional Government of Madrid grants S2018/NMT-4443 (Tec4Bio, 50% cofinanced by the European Social Fund and the European Regional Development Fund for the programming period 2014-2020) and PEJ16/MED/TL-1593 to JAC and the Instituto de Salud Carlos III (Fondo de Investigacion ´ Sanitaria grant PRB3, PT17/0019/0003- ISCIII-SGEFI /ERDF, ProteoRed), and “la Caixa” Banking Foundation (project code HR17-00247) to JV. We acknowledge funding from the European Research Area Network on Cardiovascular Diseases through grant MINOTAUR to SS (The Austrian Science Fund – FWF, I3301) and JAC (ISCIII-AC16/00045). The CNIC is supported by the Instituto de Salud Carlos III (ISCIII), the Ministerio de Ciencia e Innovacion ´ (MCIN) and the Pro CNIC Foundation, and is a Severo Ochoa Center of Excellence (grant CEX2020-001041-S funded by MCIN/AEI/10.13039/501100011033). IMM was the recipient of a CNIC-ACCIONA Masters Fellowship and holds a fellowship from “La Caixa” Foundation (ID 100010434, fellowship code LCF/BQ/DR20/11790009). CSC is the recipient of an FPI-SO predoctoral fellowship BES-2016-076638. We thank Wolfgang A. Linke and Pablo García-Pavía for critical feedback. We are also thankful for the insights of four anonymous reviewers. Sí
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- 2022
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21. AUMENTO DE LA RESILIENCIA DE LAS CARRETERAS MEDIANTE EL USO COMBINADO DE TECNOLOGÍA MULTISENSOR Y MODELOS CLIMÁTICOS
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SEVILLA DE LA LLAVE, Irene, Chrobocinski, Philippe, BAMPAS, Fotios, SCHMIDT, Franziska, KERLE, Norman, KOSTARIDIS, Antonis, Doulamis, Anastasios, RUSSOTTO, Remy, ACCIONA INFRAESTRUCTURAS, parent, Airbus Defence and Space, Airbus Group, Expérimentation et modélisation pour le génie civil et urbain (MAST-EMGCU), Université Gustave Eiffel, CTO C4Controls, National Technical University of Athens [Athens] (NTUA), and H2020 PANOPTIS
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INFRASTRUCTURE DE TRANSPORT ,[SPI.GCIV]Engineering Sciences [physics]/Civil Engineering ,MAINTENANCE ,VISION PAR ORDINATEUR ,CHANGEMENT CLIMATIQUE ,AIDE A LA DECISION (DSS) ,SURVEILLANCE ,APPRENTISSAGE MACHINE (ML) ,CAPTEUR ,SYSTEME D&apos ,RESILIENCE ,DRONE - Abstract
VI Congreso Cuidades Inteligentes, Madrid, ESPAGNE, 15-/09/2020 - 15/09/2020; Le projet PANOPTIS, financé par la Commission européenne dans le cadre du programme H2020, vise à accroître la résilience (capacité d'adaptation) des routes aux conditions météorologiques défavorables, telles que les phénomènes météorologiques extrêmes ou les inondations, et à d'autres événements à risque comme les tremblements de terre ou les glissements de terrain. L'objectif principal du projet est de combiner des scénarios de changement climatique régionalisés (appliqués aux infrastructures), avec des outils de simulation structurels et géotechniques et des données réelles tirées directement des infrastructures routières (ponts, pentes, routes) par un réseau multi-capteurs comprenant des capteurs au sol, des drones et des satellites, afin de fournir aux gestionnaires d'infrastructures de transport un outil de contrôle intégré, capable d'améliorer la gestion des infrastructures dans les phases de planification, de maintenance et d'exploitation. Le projet PANOPTIS a débuté en juin 2018, et pendant la première phase du projet, qui couvre approximativement les deux premières années, toutes les technologies innovantes qui composent l'outil PANOPTIS sont en cours de mise au point. Au cours de la deuxième phase du projet, qui débutera à l'été 2020, ACCIONA Engineering mettra en oeuvre toutes les technologies et méthodologies développées dans la section 2 de l'autoroute A-2, qui est longue de 77,5 km et qui traverse la province de Guadalajara. Il s'agit d'une section de concession d'autoroute de première génération gérée par ACCIONA Concessions et entretenue par ACCIONA Maintenance.
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- 2020
22. Improving Resilience of Transport Instrastructure to Climate Change and other natural and Manmande events based on the combined use of Terrestrial and Airbone Sensors and Advanced Modelling Tools
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SEVILLA, Irène, Chrobocinski, Philippe, BARMPAS, Fotios, SCHMIDT, Franziska, KERLE, Norman, KOSTARIDIS, Antonis, Doulamis, Anastasios, RUSSOTTO, Rémy, ACCIONA Ingeniería, parent, Airbus Defence and Space, Airbus Group, Aristotle University of Thessaloniki, Expérimentation et modélisation pour le génie civil et urbain (IFSTTAR/MAST/EMGCU), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-Communauté Université Paris-Est, University of Twente [Netherlands], C4Controls Ltd, National Technical University of Athens [Athens] (NTUA), Confederation of Organisations in Road Transport Enforcement (CORTE), and PANOPTIS
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CONFERENCE ,[SPI]Engineering Sciences [physics] ,INFRASTRUCTURE ROUTIERE ,CLIMAT ,CHANGEMENT CLIMATIQUE ,[SDE.MCG]Environmental Sciences/Global Changes ,INFRASTRUCTURE ,CAPTEUR ,RESILIENCE ,SURVEILLANCE DE SANTE STRUCTURALE ,GRECE ,INFRASTRUCTURE (TRANSPORT) - Abstract
CONAMA2018, MADRID, Espagne, 26-/11/2018 - 29/11/2018; The project PANOPTIS, funded by the European Commission under the H2020 Programme, aims at increasing the resilience of the transport infrastructures (focusing on roads) and ensuring reliable network availability under unfavourable conditions, such as extreme weather, landslides, and earthquakes. The main target is to combine downscaled climate change scenarios (applied to road infrastructures) with structural and geotechnical simulation tools and with actual data from a multi-sensor network (terrestrial and airborne-based), so as to provide the operators with an integrated tool able to support more effective management of their infrastructures at planning, maintenance and operation level. During the first stage of the project, the consortium will develop advanced technologies to monitor and control transport infrastructures, such as a Geotechnical and Structural Simulation Tool (SGSA) to predict structural and geotechnical risks in road infrastructures; drone-technologies applied to road upkeep and incident management; improved computer vision and machine learning techniques for damage diagnosis of infrastructure, and early warning systems to help operators identify and communicate emerging systemic risks. At the same time, experts in climate modelling, will analyse the possible short and long term effects of climate change on transport infrastructure (e.g. flooding, heavier snows). All the information from the different sensors, models and applications will be integrated and processed through a unique Resilience Assessment Platform that will support operators in the introduction of adaptation and mitigation strategies based on multi-risk scenarios.During the second stage of the project, ACCIONA Engineering will implement the developed technologies and methodologies in a section of the Spanish A-2 motorway, in the province of Guadalajara. PANOPTIS integrated Platform will help optimize the management and maintenance of the Ministry of Public Works' concession for a 77.5-km section, all in collaboration with ACCIONA Infrastructure Maintenance (AMISA) and ACCIONA Concessions. In parallel, PANOPTIS platform will also be implemented in a section of 62 Km of a Greek motorway, renowned for its seismic activity. The trials in Greece hosted by the operator Egnatia Odos will integrate the motorway that serves the Airport of Thessaloniki. So the scenario will integrate a modal transfer segment.; Le projet PANOPTIS, financé par la Commission européenne dans le cadre du programme H2020, vise à accroître la résilience de l'infrastructure de transport et à permettre une disponibilité fiable du réseau dans des conditions défavorables, telles que les conditions météorologiques extrêmes, les glissements de terrain et les tremblements de terre. L'objectif principal doit être associé à un réseau multi-capteurs (terrestre et aéroporté) pour permettre une gestion plus efficace de leurs infrastructures au niveau de la planification, de la maintenance et de l'exploitation. Au cours de la première phase du projet, le consortium développera des technologies avancées pour surveiller et contrôler les infrastructures de transport, telles que l'outil de simulation géotechnique et structurelle (SGSA) permettant de prévoir les risques structurels et géotechniques dans les infrastructures routières; technologies de drones appliquées à l'entretien des routes et à la gestion des incidents; la vision par ordinateur et les techniques d'apprentissage automatique pour le diagnostic des infrastructures et les systèmes d'alerte précoce. Dans le même temps, des experts en modélisation du climat analyseront le potentiel du changement climatique sur les infrastructures de transport (par exemple, les inondations, les neiges plus lourdes). Toutes les informations provenant des différents capteurs, modèles et applications seront intégrées dans un scénario unique comportant plusieurs risques. Au cours de la deuxième phase du projet, ACCIONA Engineering mettra en oeuvre les technologies et les méthodologies dans une section de l'autoroute espagnole A-2, dans la province de Guadalajara. La plate-forme intégrée PANOPTIS contribuera à optimiser la gestion et la maintenance de la concession du ministère des Travaux publics pour une section de 77,5 km, le tout en collaboration avec ACCIONA Infrastructure Maintenance (AMISA) et ACCIONA Concessions. Parallèlement, la plate-forme PANOPTIS sera également mise en oeuvre dans une section de 62 Km d'une autoroute grecque réputée pour son activité sismique. Les essais en Grèce organisés par l'opérateur Egnatia Odos vont rejoindre l'aéroport de Thessalonique. Le scénario intégrera donc un segment de transfert modal.
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- 2018
23. Single-imprint moth-eye anti-reflective and self-cleaning film with enhanced resistance
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Navarro-Baena I., Jacobo-Martín A., Hernández J.J., Castro Smirnov J.R., Viela F., Monclús M.A., Osorio M.R., Molina-Aldareguia J.M., Rodríguez I. and The present work was performed within the framework of the NANOLEAP project. This project has received funding from the European Union’s Horizon 2020 Research and Innovation Program under the grant agreement no 646397. The research has been partially supported by the Ministry of Education and Research of the Madrid Community (ref. PEJ15/IND/AI-0626) and the European Social Fund (ESF). The authors are grateful to the personnel of the Institute of Optica 'Daza de Valdés', IO-CSIC, Madrid, for the equipment support on the optical characterization and to Irene Sevilla de la Llave y Javier Sacristán Bermejo from ACCIONA Construction Technological Center for performing the accelerated weathering tests and for the technical assistance designing the experiments. IMDEA Nanociencia acknowledges support from the Severo Ochoa Programme for Centres of Excellence in R&D (MINECO, Grant SEV-2016-0686).
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- 2018
24. Microeukaryote community in a partial nitritation reactor prior to anammox and an insight into the potential of ciliates as performance bioindicators
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Humbert Salvadó, Joan Lluís Riera, Vanessa Balagué, Ramon Massana, Oriol Canals, Generalitat de Catalunya, and Acciona
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Ammoniacal nitrogen ,media_common.quotation_subject ,0208 environmental biotechnology ,Population ,Bioengineering ,02 engineering and technology ,010501 environmental sciences ,Biology ,Opercularia ,01 natural sciences ,Competition (biology) ,Bioreactors ,Illumina ,Abundance (ecology) ,Ammonium Compounds ,Ciliophora ,Protozoa ,education ,Molecular Biology ,0105 earth and related environmental sciences ,media_common ,Ciliate ,education.field_of_study ,Ciliates ,Toxicity ,Moving bed biofilm reactor ,Ecology ,General Medicine ,biology.organism_classification ,Nitrification ,Substrate (marine biology) ,020801 environmental engineering ,Anammox ,Environmental chemistry ,Biofilms ,Oxidation-Reduction ,Biotechnology - Abstract
Special issue International Society of Environmental Biotechnology 2016.-- 10 pages, 3 figures, 5 tables, supplementary data https://doi.org/10.1016/j.nbt.2017.05.003, An in-depth, long-term, multidisciplinary study was conducted in order to study the microeukaryote community in a partial nitritation (PN) reactor prior to anammox. The PN reactor operated with moving bed biofilm reactor (MBBR) technology, using plastic supports (carriers) for biofilm development. The microeukaryote community from the biofilm (BF) and the surrounding media (mixed liquor or ML) were analysed separately. Despite the physicochemical conditions under which the PN-MBBR operated (an average of 305.9 ± 117 mg TAN l and 328.4 ± 131.9 mg N-NO l), up to 24 microeukaryotic taxa were observed by microscope. Microeukaryote species showed an uneven distribution in the PN-MBBR, thus suggesting the existence of two habitats: the BF, preferred by species with specific structures for adhering to a substrate, such as the stalked Peritrichia, and the ML, preferred by free-swimming or non-substrate dependent species. The results indicated that most ciliate population dynamics mainly responded to the nitrous acid and free ammonia concentrations and, to a lesser extent, to sCOD values. In the BF, variations in the population of Epistylis camprubii and Opercularia coarctata suggest the existence of competition between these species due to niche overlap. A V4 18S rDNA molecular survey (Illumina) was carried out for some samples with the aim of obtaining maximum coverage of the main eukaryote species that were microscopically detected throughout the study. The diversity and abundance data provided by both detection methods were compared. The study helped identify broader tolerance ranges of the microeukaryote taxa to the physicochemical parameters analysed, This work was financially supported by ACCIONA Agua ( 306393 FBG – UB) and partially funded by a grant of the Catalan Government as the Consolidated Research Group VirBaP (2014SRG914)
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- 2018
25. Pavement life cycle assessment: A comparison of American and European tools
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Rocío Fernández Flores, Gerardo W. Flintsch, Senthilmurugan Thyagarajan, Elisabeth Keijzer, João Santos, Environnement, Aménagement, Sécurité et Eco-conception (IFSTTAR/AME/EASE), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-PRES Université Nantes Angers Le Mans (UNAM), Turner Fairbank Highway Research Center, parent, TNO Climate, Air and Sustainability [Utrecht], Acciona SA, Center for Sustainable Transportation Infrastructure1, EC/FP7/605748/EU/Development of a novel ECO-LABELing EU-harmonized methodology for cost-effective, safer and greener road products and infrastructures/ECOLABEL, and Cadic, Ifsttar
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050210 logistics & transportation ,Engineering ,LIFE CYCLE ASSESSMENT ,CHAUSSEE ,[SPI] Engineering Sciences [physics] ,business.industry ,05 social sciences ,0211 other engineering and technologies ,ENVIRONMENTAL IMPACT INDICATORS ,02 engineering and technology ,010501 environmental sciences ,01 natural sciences ,Construction engineering ,[SPI]Engineering Sciences [physics] ,INDICATEUR ,021105 building & construction ,0502 economics and business ,11. Sustainability ,Forensic engineering ,TOOL ,IMPACT ENVIRONNEMENTAL ,business ,Life-cycle assessment ,0105 earth and related environmental sciences - Abstract
Pavement Life-Cycle Assessment Symposium 2017, CHAMPAIGN, ETATS-UNIS, 12-/04/2017 - 13/04/2017; Road pavements have considerable environmental burdens associated with their initial construction, maintenance and usage. This fact has led the pavement stakeholder commu-nity make congregate efforts to better understand and mitigate these negative effects. Life cycle assessment (LCA) is a versatile methodology adopted to quantify the effect of deci-sions regarding the selection of resources and processes. However, there is a considerable variety of tools for conducting pavement LCAs. The objective of this paper is to provide the pavement stakeholder community with insights on the potential differences in the life cycle impact assessment results of a pavement by applying American and European LCA tools, namely PaLATE V2.2, VTTI/UC asphalt pavement LCA model, GaBi, DuboCalc and ECORCE-M, to a Spanish pavement reconstruction project. Construction and mainte-nance life cycle stages were considered in the comparison. Based on the impact assess-ment methods adopted by the different tools, the following indicators and impact catego-ries were analyzed: energy consumption, climate change, acidification, eutrophication and photochemical ozone creation. The results of the case study showed that it is of pivotal importance to develop (1) a more standardized framework for performing a LCA of road pavement that can be adapted to various tools and (2) local databases of materials and processes, which follow national and international standards.
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- 2017
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26. COMPARISON OF LIFE CYCLE ASSESSMENT TOOLS FOR ROAD PAVEMENT INFRASTRUCTURE
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Gerardo W. Flintsch, João Santos, Senthilmurugan Thyagarajan, Rocío Fernández Flores, Elisabeth Keijzer, Environnement, Aménagement, Sécurité et Eco-conception (IFSTTAR/AME/EASE), Institut Français des Sciences et Technologies des Transports, de l'Aménagement et des Réseaux (IFSTTAR)-PRES Université Nantes Angers Le Mans (UNAM), Turner Fairbank Highway Research Center, parent, TNO Climate, Air and Sustainability [Utrecht], The Netherlands Organisation for Applied Scientific Research (TNO), Acciona SA, Center for Sustainable Transportation Infrastructure, VTTI, 3500 Transportation Research Plaza, Blacksburg, VA 24061, EC/FP7/605748/EU/Development of a novel ECO-LABELing EU-harmonized methodology for cost-effective, safer and greener road products and infrastructures/ECOLABEL, and Construction Management and Engineering
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INDICATORS ,CHAUSSEE (CORPS DE) ,Engineering ,CHAUSSEE ,020209 energy ,0211 other engineering and technologies ,02 engineering and technology ,METHODE ,CYCLE DE VIE ,Transport engineering ,ROAD ,[SPI]Engineering Sciences [physics] ,Asphalt pavement ,11. Sustainability ,021105 building & construction ,0202 electrical engineering, electronic engineering, information engineering ,Life-cycle assessment ,Civil and Structural Engineering ,Virginia tech ,LIFE CYCLE ASSESSMENT ,business.industry ,Impact assessment ,Mechanical Engineering ,Stakeholder ,Variety (cybernetics) ,13. Climate action ,business ,METHODOLOGIE - Abstract
Road pavements have considerable environmental burdens associated with their initial construction, maintenance, and usage, which have led the pavement stakeholder community to join efforts to understand and mitigate these negative effects better. Life-cycle assessment (LCA) is a versatile methodology for quantifying the effect of decisions regarding the selection of resources and processes. However, there is a considerable variety of tools for conducting pavement LCA. This paper provides the pavement stakeholder community with insights into the potential differences in the life-cycle impact assessment results of a pavement by applying American and European LCA tools, namely, PaLATE Version 2.2, the Virginia Tech Transportation Institute–University of California asphalt pavement LCA model, GaBi, DuboCalc, and ECORCE-M, to a Spanish pavement reconstruction project. Construction and maintenance life-cycle stages were considered in the comparison. On the basis of the impact assessment methods adopted by the various tools, the following indicators and impact categories were analyzed: energy consumption, climate change, acidification, eutrophication, and photochemical ozone creation. The results of the case study showed the need to develop ( a) a standardized framework for performing a road pavement LCA that can be adapted to various tools and ( b) local databases of materials and processes that follow national and international standards.
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- 2017
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27. Ni/Fe electrodes prepared by electrodeposition method over different substrates for oxygen evolution reaction in alkaline medium
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Francisco J. Pérez-Alonso, Sergio Rojas, Miguel A. Peña, José Luis García Fierro, C. Adán, Ministerio de Educación y Ciencia (España), Acciona, and Ministerio de Ciencia e Innovación (España)
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Materials science ,Renewable Energy, Sustainability and the Environment ,Type of substrate ,Alkaline water electrolysis ,Inorganic chemistry ,Oxygen evolution ,Energy Engineering and Power Technology ,chemistry.chemical_element ,Durability test ,Overpotential ,Electrodeposition method ,Condensed Matter Physics ,Electrochemistry ,Anode ,Nickel ,Fuel Technology ,chemistry ,Electrode ,Polarization (electrochemistry) ,Electrolyzer prototype ,Ni/Fe electrodes - Abstract
A series of Ni/Fe electrodes have been prepared by electrodeposition of metal salt precursors on different substrates. The surface morphology, chemical composition and electrochemical characteristics of these electrodes were studied by various physico-chemical techniques such as X-ray Photoelectron Spectroscopy (XPS) and Scanning Electron Microscopy (SEM). The electrochemical properties of the electrodes were examined by steady-state polarization curves. First, the influence of features such as Ni/Fe composition and type of substrate for the oxygen evolution reaction (OER) were determined by electrochemical techniques in a conventional 3-electrodes cell. The overpotential for the OER is lower for the electrodes with the higher concentrations of Ni. The electrodes with a Ni/Fe composition of 75/25 wt.% electrodeposited on steel mesh and/or 75/25 and 50/50 wt.% on nickel foam result in the most active configurations for the OER. These electrodes were further tested as anodes for alkaline water electrolysis during at least 70 h. In order to understand their activity and stability, the used electrodes were also characterized by SEM and compared to the fresh electrodes. Among the compositions and substrates examined, the Ni50Fe50-Nf electrode exhibited the lowest overpotential (2.1 V) for the OER and the higher stability as anode in an alkaline water electrolysis cell., Project ENE2010-15381 from the Spanish Education and Science Ministry is also acknowledged. C. Adán thanks the MICINN for the Juan de la Cierva postdoctoral contract (JCI-2010-06430).
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- 2014
28. Electrolisis alcalina con electrodos Ni-Co preparados por electroless-plating
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Pérez-Alonso, Francisco, Adán, Cristina, Rojas Muñoz, Sergio, Peña Jiménez, Miguel Antonio, García Fierro, José Luis, Ministerio de Ciencia e Innovación (España), Consejo Superior de Investigaciones Científicas (España), Ingeteam, and Acciona
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Electrodos Ni-Co ,HER-OER ,Electroless-plating ,Electrolisis alcalina ,Producción de hidrógeno - Abstract
Trabajo presentado en el Congreso Iberoamericano de Hidrógeno y Pilas de Combustible, celebrado en Barcelona (España) del 15 al 17 de octubre de 2014., Se han preparado electrodos basados en níquel-cobalto, con diferentes relaciones Ni-Co, mediante el método de electroless-plating, a partir de disoluciones de NiSO4 and CoSO4. La morfología y la composición de los electrodos Ni-Co fue analizada mediante XPS y SEM. Mediante voltamperometría de barrido lineal se estudió la actividad electrocatalítica de los electrodos Ni-Co tanto para la reacción de producción de hidrógeno (HER) como para la de producción de oxígeno (OER) en medio alcalino. El electrodo basado únicamente en níquel (Ni-ELP) muestra el sobrepotencial más bajo para la HER. Sin embargo, las curvas de polarización muestran que el electrodo Ni-Co con un concentración de 30 at.% (Ni70Co30-ELP) es el que produce el menor sobrepotencial para la OER. Se realizaron también ensayos de durabilidad con estos dos electrodos en un electrolizador construido en el laboratorio. El voltaje de la celda electrolítica a 0.3 A·cm-2, usando Ni-ELP para la HER y Ni70Co30-ELP para la OER, fue 2.2 V, mostrando una alta estabilidad durante 70 horas de operación. La caracterización de los electrodos usados en este ensayo de durabilidad demuestra la alta estabilidad de los mismos. Finalmente, los resultados presentados en este trabajo indican que la técnica de electroless-plating es un método muy adecuado para preparar electrodos de níquel para electrolizadores alcalinos., ACCIONA Energía e Ingeteam, por permitir la publicación de estos resultados obtenidos en el proyecto CENIT-SPHERA. Subvención del proyecto CSIC 201080E116. C. Adán agradece al MICINN por el contrato Juan de la Cierva (JCI-2010-06430).
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- 2014
29. Resonant Eddy Current Sensor Design for Corrosion Detection of Reinforcing Steel.
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Thibbotuwa UC, Cortés A, Casado AM, and Irizar A
- Abstract
This paper introduces an LC resonator-based single-frequency eddy current (EC) sensor designed for corrosion detection in reinforcing bars (rebars) embedded within concrete structures. The work addresses the challenges of the limited detection ranges and reduced sensitivity over longer distances, prevalent in current EC sensor applications. The sensor development process involved a systematic experimental approach to carefully selecting each parameter in the LC resonator. The sensor design aimed to assess the condition of the rebar from a distance of up to 5-6 cm outside the concrete and provide insights into different corrosion levels. By examining the characteristics of the inductors, the parallel resistance Rp of the eddy current coil was identified as a key parameter reflecting the corrosion conditions in the rebar. The relationship between the Rp fluctuations and temperature variations was investigated, with the data indicating that an approximately 155 Ω variation can be expected per 1 °C change within the temperature range of 20-25 °C, allowing for temperature compensation if necessary. Subsequently, the sensor's performance was evaluated by placing a rebar within a concrete block, where controlled mechanical degradation cycles were applied to simulate uniform corrosion in the rebar. The experimental results show that our EC sensor can detect material loss around the rebar with accuracy of approximately 0.17 mm.
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- 2024
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30. Bioaugmentation and vermicompost facilitated the hydrocarbon bioremediation: scaling up from lab to field for petroleum-contaminated soils.
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Curiel-Alegre S, Khan AHA, Rad C, Velasco-Arroyo B, Rumbo C, Rivilla R, Durán D, Redondo-Nieto M, Borràs E, Molognoni D, Martín-Castellote S, Juez B, and Barros R
- Abstract
The biodegradation of total petroleum hydrocarbon (TPH) in soil is very challenging due to the complex recalcitrant nature of hydrocarbon, hydrophobicity, indigenous microbial adaptation and competition, and harsh environmental conditions. This work further confirmed that limited natural attenuation of petroleum hydrocarbons (TPHs) (15% removal) necessitates efficient bioremediation strategies. Hence, a scaling-up experiment for testing and optimizing the use of biopiles for bioremediation of TPH polluted soils was conducted with three 500-kg pilots of polluted soil, and respective treatments were implemented: including control soil (CT), bioaugmentation and vermicompost treatment (BAVC), and a combined application of BAVC along with bioelectrochemical snorkels (BESBAVC), all maintained at 40% field capacity. This study identified that at pilot scale level, a successful application of BAVC treatment can achieve 90.3% TPH removal after 90 days. BAVC's effectiveness stemmed from synergistic mechanisms. Introduced microbial consortia were capable of TPH degradation, while vermicompost provided essential nutrients, enhanced aeration, and, potentially, acted as a biosorbent. Hence, it can be concluded that the combined application of BAVC significantly enhances TPH removal compared to natural attenuation. While the combined application of a bioelectrochemical snorkel (BES) with BAVC also showed a significant TPH removal, it did not differ statistically from the individual application of BAVC, under applied conditions. Further research is needed to optimize BES integration with BAVC for broader applicability. This study demonstrates BAVC as a scalable and mechanistically sound approach for TPH bioremediation in soil., (© 2024. The Author(s).)
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- 2024
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31. Fluence requirements in existing UV disinfection facilities to comply with EU validation performance targets for reclaimed water: a case study.
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Verónica Carabias A, Gil MI, Pérez JM, Abellán M, Rancaño A, José Simón P, Truchado P, and Allende A
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- Water, Disinfection, Escherichia coli
- Abstract
Since 2020, there is a new European Regulation (EU, 2020/741) on minimum requirements for water reuse, where routine and validation monitoring requirements (log reductions of indicator microorganisms and reference pathogens) have been established. Many reclamation facilities that are already in operation might have difficulties to comply with these performance targets. Existing disinfection systems must be expanded and upgraded. In the case of UV disinfection systems, fluence requirements must be determined to properly design with a focus on the safety and economic-environmental viability of reclaimed water. This study can be used as a reference to develop fluence-response curves for Clostridium perfringens spores, Escherichia coli, and total and F-specific coliphages, indicator microorganisms referred to in the new European Regulation. Eight UV-LED collimated beam tests were performed. Samples were obtained from filtered effluent of secondary treatment from two wastewater treatment plants (WWTPs) which ranged between 30 and 54%. Results showed UV sensitivity of 33.46 mJ/cm
2 log I for C. perfringens spores and 2.86 mJ/cm2 log I for E. coli, both from environmental origin. Coliphages were inactivated below the limit of quantitation. The non-dominance of MS2 phages in environmental F-specific coliphages was observed.- Published
- 2023
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32. Interactive robots for health in Europe: Technology readiness and adoption potential.
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Östlund B, Malvezzi M, Frennert S, Funk M, Gonzalez-Vargas J, Baur K, Alimisis D, Thorsteinsson F, Alonso-Cepeda A, Fau G, Haufe F, Di Pardo M, and Moreno JC
- Subjects
- Technology, Europe, Robotics methods
- Abstract
Introduction: Social robots are accompanied by high expectations of what they can bring to society and in the healthcare sector. So far, promising assumptions have been presented about how and where social robots are most relevant. We know that the industry has used robots for a long time, but what about social uptake outside industry, specifically, in the healthcare sector? This study discusses what trends are discernible, to better understand the gap between technology readiness and adoption of interactive robots in the welfare and health sectors in Europe., Methods: An assessment of interactive robot applications at the upper levels of the Technology Readiness Level scale is combined with an assessment of adoption potential based on Rogers' theory of diffusion of innovation. Most robot solutions are dedicated to individual rehabilitation or frailty and stress. Fewer solutions are developed for managing welfare services or public healthcare., Results: The results show that while robots are ready from the technological point of view, most of the applications had a low score for demand according to the stakeholders., Discussion: To enhance social uptake, a more initiated discussion, and more studies on the connections between technology readiness and adoption and use are suggested. Applications being available to users does not mean they have an advantage over previous solutions. Acceptance of robots is also heavily dependent on the impact of regulations as part of the welfare and healthcare sectors in Europe., Competing Interests: JG-V was employed by Ottobock SE & Co. FT was employed by ÖSSUR. GF was employed by Space Applications Services. KB was employed by CYBATHLON. The remaining authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest., (Copyright © 2023 Östlund, Malvezzi, Frennert, Funk, Gonzalez-Vargas, Baur, Alimisis, Thorsteinsson, Alonso-Cepeda, Fau, Haufe, Di Pardo and Moreno.)
- Published
- 2023
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33. Surveillance on ESBL- Escherichia coli and Indicator ARG in Wastewater and Reclaimed Water of Four Regions of Spain: Impact of Different Disinfection Treatments.
- Author
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Oliveira M, Truchado P, Cordero-García R, Gil MI, Soler MA, Rancaño A, García F, Álvarez-Ordóñez A, and Allende A
- Abstract
In the present study, the occurrence of indicator antibiotic-resistant bacteria (ARB) and antibiotic resistance genes (ARGs) both in the influent and the effluent of four Spanish wastewater treatment plants (WWTPs) was monitored for 12 months, and the susceptibility profiles of 89 recovered extended spectrum β-lactamase (ESBL)-producing Escherichia coli isolates were obtained against a wide range of antimicrobials. The aim of the study was to better understand whether the current wastewater treatment practices allow us to obtain safe reclaimed water mitigating the spread of ARB and ARGs to the environment. Results showed high concentrations of ESBL-producing E. coli as well as a high prevalence of a range of ARGs in the influent samples. The reclamation treatments implemented in the WWTPs were effective in reducing both the occurrence of ESBL E. coli and ARGs, although significant differences were observed among WWTPs. Despite these reductions in occurrence observed upon wastewater treatment, our findings suggest that WWTP effluents may represent an important source of ARGs, which could be transferred among environmental bacteria and disseminate antimicrobial resistance through the food chain. Remarkably, no major differences were observed in the susceptibility profiles of the ESBL E. coli isolated from influent and effluent waters, indicating that water treatments do not give rise to the emergence of new resistance phenotypes.
- Published
- 2023
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34. Strategies for mitigating chlorinated disinfection byproducts in wastewater treatment plants.
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Albolafio S, Marín A, Allende A, García F, Simón-Andreu PJ, Soler MA, and Gil MI
- Subjects
- Disinfection, Humans, SARS-CoV-2, COVID-19, Water Purification
- Abstract
A case study of 15 wastewater treatment plants (WWTPs) at a full-scale was assessed for the risks of disinfection byproduct (DBP) formation, mainly the regulated trihalomethanes (THMs) and haloacetic acids (HAAs) and chlorate as an inorganic byproduct regulated recently in the EU. Raw wastewater from large, medium/small urban areas were treated with single or combined disinfection processes (i.e., chlorine, peracetic acid (PAA) and ultraviolet (UV) radiation). Sampling was executed once a month over seven months for the medium/small WWTPs and twice a month for the large ones. Due to the potential risk of SARS-CoV-2 contaminated wastewater, several inactivation methods were examined before the DBP analysis. Due to the inactivation step, the stability of THM4 and HAA9 suffered reductions, monitoring their presence only in the effluents after the disinfection treatments. In contrast, chlorate levels remained unchanged after the inactivation treatment; thus both raw wastewater and effluents were examined for their occurrence before disinfection treatments. Results showed that chlorate residues in the raw wastewater varied greatly from undetected levels to as high as 42.2 mg L
-1 . As the continuous monitoring of DBPs was performed, a positive correlation with chlorine or chlorine/UV was found. Changes in the physicochemical parameters indicated that the quality of the raw wastewater varied considerably depending on the WWTPs, and it influenced byproduct formation. In all WWTPs, chlorine alone or combined with UV significantly increased the presence of THMs, HAAs, and chlorate levels in the treated effluents. When the same WWTPs changed to PAA or PAA/UV, DBPs were diminished completely. This study highlights the risk of chlorate residues in raw wastewater during the pandemic. It also showed how the chemical risks of DBP formation could be reduced by changing the chlorinated disinfection technologies to PAA or PAA/UV, particularly if reclaimed water is intended for agricultural irrigation to minimize DBP residues., (Copyright © 2021 The Authors. Published by Elsevier Ltd.. All rights reserved.)- Published
- 2022
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35. Experimental Carbonation Study for a Durability Assessment of Novel Cementitious Materials.
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Hanžič L, Robič S, Machner A, Bjørndal MH, De Weerdt K, Gu Y, Bary B, Lample Carreras RM, and Šajna A
- Abstract
Durability predictions of concrete structures are derived from experience-based requirements and descriptive exposure classes. To support durability predictions, a numerical model related to the carbonation resistance of concrete was developed. The model couples the rate of carbonation with the drying rate. This paper presents the accelerated carbonation and moisture transport experiments performed to calibrate and verify the numerical model. They were conducted on mortars with a water-cement ratio of either 0.6 or 0.5, incorporating either a novel cement CEM II/C (S-LL) (EnM group) or commercially available CEM II/A-S cement (RefM group). The carbonation rate was determined by visual assessment and thermogravimetric analysis (TGA). Moisture transport experiments, consisting of drying and resaturation, utilized the gravimetric method. Higher carbonation rates expressed in mm/day
-0.5 were found in the EnM group than in the RefM group. However, the TGA showed that the initial portlandite (CH) content was lower in the EnM than in the RefM, which could explain the difference in carbonation rates. The resaturation experiments indicate an increase in the suction porosity in the carbonated specimens compared to the non-carbonated specimens. The study concludes that low clinker content causes lower resistance to carbonation, since less CH is available in the surface layers; thus, the carbonation front progresses more rapidly towards the core.- Published
- 2021
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36. Long-Term Performance of Nanomodified Coated Concrete Structures under Hostile Marine Climate Conditions.
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Esteban-Arranz A, de la Osa AR, García-Lorefice WE, Sacristan J, and Sánchez-Silva L
- Abstract
Epoxy resin coatings are commonly used to protect concrete structures due to their excellent chemical corrosion resistance and strong adhesion capacity. However, these coatings are susceptible to damage by surface abrasion and long-term contact with marine climate conditions, deteriorating their appearance and performance. This study aims to optimize the performance of cement-based epoxy resin coatings, bisphenol-A and polyol, in aggressive environments by functionalizing the selected systems with different nanoparticles such as activated carbon, surface modified nanoclay, silica and zinc oxide. Nanomodified coatings were applied to concrete specimens and subjected to three weeks in a spray salt chamber and three weeks in a QUV chamber. They were found to present improved thermal resistance and curing degree after the weathering test. Their water permeability, adhesion, and abrasion resistance properties were evaluated before and after this test. The results showed that the nature of the nanocomposites determined their water permeability; the bare resin presented the worst result. Additionally, nanomodified composites with activated carbon and silica showed the best adherence and abrasion resistance properties, due to the effect of this aging test on their thermal stability and curing degree.
- Published
- 2021
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37. Effect of COD on mainstream anammox: Evaluation of process performance, granule morphology and nitrous oxide production.
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Pijuan M, Ribera-Guardia A, Balcázar JL, Micó MM, and de la Torre T
- Subjects
- Ammonium Compounds, Anaerobiosis, Bioreactors, Denitrification, Nitrogen, Oxidation-Reduction, Nitrous Oxide chemistry
- Abstract
The effect of COD addition into an anammox reactor was assessed during short and long term exposure. The short term exposure was assessed via batch tests and lasted 48 h. Results indicated the presence of a very active denitrifying community able to consume COD using nitrate and nitrite as electron acceptors. However, the presence of COD did not result in an increase of the ammonium concentration at the end of the tests indicating that anammox activity was not suppressed by the addition of COD. Different COD concentrations (125, 225 and 175 mg COD/L) were also added in the reactor during 3 periods within its operation (period II, III and V respectively). Long term COD addition (up to 102 d of continuous addition during period II and III) caused a decrease of the anammox activity and a shift on the microbial community, with a decrease on the anammox fraction. However, the anammox process was never lost and it fully recovered as soon as COD addition stopped. Finally, dissolved N
2 O was monitored under periods with and without COD addition, showing higher concentrations during transient periods from COD addition to no addition. The results of this paper provide evidence of how a long term COD exposure into an anammox reactor affect the overall nitrogen removal process, the granular structure of the anammox biomass, its microbial composition and for the first time, its N2 O emissions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)- Published
- 2020
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38. Produced water treatment by advanced oxidation processes.
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Jiménez S, Andreozzi M, Micó MM, Álvarez MG, and Contreras S
- Abstract
Different Advanced Oxidation Processes (AOPs) such as photocatalysis, Fenton-based processes and ozonation were studied to include one of these technologies within an integrated solution for produced water (PW) polishing. Synthetic PW was prepared adding toluene, xylene, naphthalene, phenol, acetic and malonic acids to a seawater matrix. Despite that in all AOPs studied in this work BTEX and naphthalene were removed, the efficiency (in terms of TOC removal) of each treatment varied largely. Among these techniques, photocatalysis was found to be the less effective for the treatment of PW, as TOC removals lower than 20% were obtained for the best scenario after 4 h treatment. In the contrary, best results were obtained by ozonation combined with H
2 O2 , where all the organic components were removed, including a high percentage of acetic acid, which was not abated by the rest of the AOPs studied. The optimum conditions for ozonation were 4 g h-1 O3 and 1500 mg L-1 H2 O2 at pH 10, where after 2 h a 74% of TOC removal was achieved and the acetic acid elimination was 78%. This condition enabled that ozonation process accounted for the lowest electric energy consumption per order of target compound destruction regarding total organic carbon (TOC)., (Copyright © 2019 The Authors. Published by Elsevier B.V. All rights reserved.)- Published
- 2019
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39. State of the art of produced water treatment.
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Jiménez S, Micó MM, Arnaldos M, Medina F, and Contreras S
- Subjects
- Oxidation-Reduction, Wastewater chemistry, Water chemistry, Oil and Gas Fields chemistry, Oil and Gas Industry methods, Petroleum Pollution prevention & control, Waste Disposal, Fluid methods, Water Pollutants, Chemical chemistry, Water Purification methods
- Abstract
Produced water (PW) is the wastewater generated when water from underground reservoirs is brought to the surface during oil or gas extraction. PW is generated in large amounts and has a complex composition, containing various toxic organic and inorganic compounds. PW is currently treated in conventional trains that include phase separators, decanters, cyclones and coarse filters in order to comply with existing regulation for discharge. These treatment trains do not achieve more restrictive limitations related to the reuse of the effluent (reinjection into extraction wells) or other beneficial uses (e.g., irrigation). Therefore, and to prevent environmental pollution, further polishing processes need to be carried out. Characterization of the PW to determine major constituents is the first step to select the optimum treatment for PW, coupled with environmental factors, economic considerations, and local regulatory framework. This review tries to provide an overview of different treatments that are being applied to polish this type of effluents. These technologies include membranes, physical, biological, thermal or chemical treatments, where special emphasis has been made on advanced oxidation processes due to the advantages offered by these processes. Commercial treatments, based on the combination, modification and improvement of simpler treatments, were also discussed., (Copyright © 2017 Elsevier Ltd. All rights reserved.)
- Published
- 2018
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40. How well-mixed is well mixed? Hydrodynamic-biokinetic model integration in an aerated tank of a full-scale water resource recovery facility.
- Author
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Rehman U, Audenaert W, Amerlinck Y, Maere T, Arnaldos M, and Nopens I
- Subjects
- Hydrodynamics, Bioreactors, Models, Theoretical, Oxygen, Waste Disposal, Fluid methods
- Abstract
Current water resource recovery facility (WRRF) models only consider local concentration variations caused by inadequate mixing to a very limited extent, which often leads to a need for (rigorous) calibration. The main objective of this study is to visualize local impacts of mixing by developing an integrated hydrodynamic-biokinetic model for an aeration compartment of a full-scale WRRF. Such a model is able to predict local variations in concentrations and thus allows judging their importance at a process level. In order to achieve this, full-scale hydrodynamics have been simulated using computational fluid dynamics (CFD) through a detailed description of the gas and liquid phases and validated experimentally. In a second step, full ASM1 biokinetic model was integrated with the CFD model to account for the impact of mixing at the process level. The integrated model was subsequently used to evaluate effects of changing influent and aeration flows on process performance. Regions of poor mixing resulting in non-uniform substrate distributions were observed even in areas commonly assumed to be well-mixed. The concept of concentration distribution plots was introduced to quantify and clearly present spatial variations in local process concentrations. Moreover, the results of the CFD-biokinetic model were concisely compared with a conventional tanks-in-series (TIS) approach. It was found that TIS model needs calibration and a single parameter set does not suffice to describe the system under both dry and wet weather conditions. Finally, it was concluded that local mixing conditions have significant consequences in terms of optimal sensor location, control system design and process evaluation.
- Published
- 2017
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41. Integrated processes for produced water polishing: Enhanced flotation/sedimentation combined with advanced oxidation processes.
- Author
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Jiménez S, Micó MM, Arnaldos M, Ferrero E, Malfeito JJ, Medina F, and Contreras S
- Subjects
- Chlorides chemistry, Ferric Compounds chemistry, Flocculation, Glass, Hydrogen Peroxide chemistry, Microspheres, Oils chemistry, Oxidation-Reduction, Phenols isolation & purification, Recycling, Waste Disposal, Fluid methods, Water Pollutants, Chemical analysis, Wastewater chemistry, Water chemistry, Water Purification methods
- Abstract
In this study, bench scale dissolved air flotation (DAF) and settling processes have been studied and compared to a novel flotation technology based on the use of glass microspheres of limited buoyancy and its combination with conventional DAF, (Enhanced DAF or E-DAF). They were evaluated as pretreatments for advanced oxidation processes (AOPs) to polish produced water (PW) for reuse purposes. Settling and E-DAF without air injection showed adequate turbidity and oil and grease (O&G) removals, with eliminations higher than 87% and 90% respectively, employing 70 mg L
-1 of FeCl3 and 83 min of settling time, and 57.9 mg L-1 of FeCl3 , 300 mg L-1 of microspheres and a flocculation rate of 40 rpm in the E-DAF process. A linear correlation was observed between final O&G concentration and turbidity after E-DAF. In order to polish the O&G content of the effluent even further, to remove soluble compounds as phenol and to take advantage of residual iron after these treatments, Fenton and photo-Fenton reactions were essayed. After 6 h of the Fenton reaction at pH 3, the addition of 1660 mg L-1 of H2 O2 and 133 mg L-1 of iron showed a maximum O&G elimination of 57.6% and a phenol removal up to 80%. Photo-Fenton process showed better results after 3 h, adding 600 mg L-1 of H2 O2 and 300 mg L-1 of iron, at pH 3, with a higher fraction of elimination of the O&G content (73.7%) and phenol (95%) compared to the conventional Fenton process., (Copyright © 2016 Elsevier Ltd. All rights reserved.)- Published
- 2017
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42. Airborne engineered nanomaterials in the workplace-a review of release and worker exposure during nanomaterial production and handling processes.
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Ding Y, Kuhlbusch TAJ, Van Tongeren M, Jiménez AS, Tuinman I, Chen R, Alvarez IL, Mikolajczyk U, Nickel C, Meyer J, Kaminski H, Wohlleben W, Stahlmecke B, Clavaguera S, and Riediker M
- Subjects
- Humans, Industry, Risk Assessment, Workplace, Air Pollutants, Occupational analysis, Nanostructures chemistry, Occupational Exposure analysis
- Abstract
For exposure and risk assessment in occupational settings involving engineered nanomaterials (ENMs), it is important to understand the mechanisms of release and how they are influenced by the ENM, the matrix material, and process characteristics. This review summarizes studies providing ENM release information in occupational settings, during different industrial activities and using various nanomaterials. It also assesses the contextual information - such as the amounts of materials handled, protective measures, and measurement strategies - to understand which release scenarios can result in exposure. High-energy processes such as synthesis, spraying, and machining were associated with the release of large numbers of predominantly small-sized particles. Low-energy processes, including laboratory handling, cleaning, and industrial bagging activities, usually resulted in slight or moderate releases of relatively large agglomerates. The present analysis suggests that process-based release potential can be ranked, thus helping to prioritize release assessments, which is useful for tiered exposure assessment approaches and for guiding the implementation of workplace safety strategies. The contextual information provided in the literature was often insufficient to directly link release to exposure. The studies that did allow an analysis suggested that significant worker exposure might mainly occur when engineering safeguards and personal protection strategies were not carried out as recommended., (Copyright © 2016 Elsevier B.V. All rights reserved.)
- Published
- 2017
- Full Text
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43. Tracking and quantification of nitrifying bacteria in biofilm and mixed liquor of a partial nitrification MBBR pilot plant using fluorescence in situ hybridization.
- Author
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Abzazou T, Araujo RM, Auset M, and Salvadó H
- Subjects
- Bacteria genetics, Bacteria growth & development, Bacteria metabolism, Bioreactors microbiology, Nitrification physiology, Waste Disposal, Fluid methods
- Abstract
A moving bead biofilm reactor (MBBR) pilot plant was implemented as a partial nitrification process for pre-treatment of ammonium-rich liquors (676 ± 195 mg L(-1)), and studied for 479 days under variations in hydraulic retention time. The main purpose of this work, was the study of dynamics abundance of total bacteria and single-cells nitrifying bacteria belonging to ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) in biofilms and mixed liquor of the plant. The microbial monitoring was successfully achieved using fluorescence in situ hybridization combined with flocs disaggregation protocol as a useful microbial monitoring tool. A partial nitrification process with a N-NH4(+) removal rate of about 38.6 ± 14.8% was successfully achieved at 211 days after start-up, with a clear dominance of AOB, which accounted for 11.3 ± 17.0% of total bacterial cells compared with only 2.1 ± 4.0% of NOB. The effluent obtained was subsequently supplied to an Anammox reactor for complete ammonium treatment., (Copyright © 2015 Elsevier B.V. All rights reserved.)
- Published
- 2016
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44. From the affinity constant to the half-saturation index: understanding conventional modeling concepts in novel wastewater treatment processes.
- Author
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Arnaldos M, Amerlinck Y, Rehman U, Maere T, Van Hoey S, Naessens W, and Nopens I
- Subjects
- Kinetics, Models, Theoretical, Sewage analysis, Waste Disposal, Fluid, Wastewater analysis, Water Pollutants, Chemical analysis
- Abstract
The "affinity constant" (KS) concept is applied in wastewater treatment models to incorporate the effect of substrate limitation on process performance. As an increasing number of wastewater treatment processes rely on low substrate concentrations, a proper understanding of these so-called constants is critical in order to soundly model and evaluate emerging treatment systems. In this paper, an in-depth analysis of the KS concept has been carried out, focusing on the different physical and biological phenomena that affect its observed value. By structuring the factors influencing half-saturation indices (newly proposed nomenclature) into advectional, diffusional and biological, light has been shed onto some of the apparent inconsistencies present in the literature. Particularly, the importance of non-ideal mixing as a source of variability between observed KS values in different systems has been illustrated. Additionally, discussion on the differences existent between substrates that affect half-saturation indices has been carried out; it has been shown that the observed KS for some substrates will reflect transport or biological limitations more than others. Finally, potential modeling strategies that could alleviate the shortcomings of the KS concept have been provided. These could be of special importance when considering the evaluation and design of emerging wastewater treatment processes., (Copyright © 2014 Elsevier Ltd. All rights reserved.)
- Published
- 2015
- Full Text
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45. High salinity effect on bioremediation of pretreated pesticide lixiviates from greenhouses.
- Author
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Micó MM, González Ó, Bacardit J, Malfeito J, and Sans C
- Subjects
- Aluminum Silicates metabolism, Bacteria classification, Biodegradation, Environmental, Clay, DNA, Bacterial genetics, Filtration, Hydrogen Peroxide chemistry, Microbiota, Oxidation-Reduction, Photolysis, RNA, Ribosomal, 16S genetics, Bioreactors, Pesticides metabolism, Salinity, Waste Disposal, Fluid methods, Water Pollutants, Chemical metabolism
- Abstract
Hydroponics culture greenhouses usually work in closed and semi-closed irrigation systems for nutrients and water-saving purposes. Photo-Fenton reaction has been revealed as an efficient way to depollute that kind of recycled effluents containing pesticides, even for high salinity concentrations. However, the inefficacy of organic matter chemical depletion imposes the use of a subsequent treatment. This work proposes the suitability of an integration of advanced oxidation process with a subsequent bioreactor to treat greenhouse lixiviates effluents at high or extremely high conductivity (salts concentration: up to 42 g L⁻¹). As a first step in this study, the performance of a series of sequencing batch reactors was monitored in order to check the biocompatibility of photo-Fenton pretreated effluents depending on their salinity content. In the second step, those same pretreated effluents were loaded to a biofiltration column filled with expanded clay. Finally, bacterial 16S rRNA gene sequencing was carried out to analyse microbial diversity of the biomass developed in the column. Results stated that the chemical-biological coupled system is effective for the treatment of water effluents containing pesticides. The integrated system is able to deplete more than 80% of the organic load, even under extremely high salinity.
- Published
- 2015
- Full Text
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46. Trace organics removal using three membrane bioreactor configurations: MBR, IFAS-MBR and MBMBR.
- Author
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de la Torre T, Alonso E, Santos JL, Rodríguez C, Gómez MA, and Malfeito JJ
- Subjects
- Alkanesulfonic Acids metabolism, Biofilms, Biomass, Equipment Design, Membranes, Artificial, Organic Chemicals isolation & purification, Organic Chemicals metabolism, Osmosis, Polyphenols metabolism, Sewage, Waste Disposal, Fluid methods, Wastewater, Bioreactors, Waste Disposal, Fluid instrumentation
- Abstract
Seventeen pharmaceutically active compounds and 22 other trace organic pollutants were analysed regularly in the influent and permeate from a semi-real plant treating municipal wastewater. The plant was operated during 29 months with different configurations which basically differed in the type of biomass present in the system. These processes were the integrated fixed-film activated sludge membrane bioreactor (IFAS-MBR), which combined suspended and attached biomass, the moving bed membrane bioreactor (MBMBR) (only attached biomass) and the MBR (only suspended biomass). Moreover, removal rates were compared to those of the wastewater treatment plant (WWTP) operating nearby with conventional activated sludge treatment. Reverse osmosis (RO) was used after the pilot plant to improve removal rates. The highest elimination was found for the IFAS-MBR, especially for hormones (100% removal); this was attributed to the presence of biofilm, which may lead to different conditions (aerobic-anoxic-anaerobic) along its profile, which increases the degradation possibilities, and also to a higher sludge age of the biofilm, which allows complete acclimation to the contaminants. Operating conditions played an important role, high mixed liquor suspended solids (MLSS) and sludge retention time (SRT) being necessary to achieve these high removal rates. Although pharmaceuticals and linear alkylbenzene sulfonates showed high removal rates (65-100%), nonylphenols and phthalate could only be removed to 10-30%. RO significantly increased removal rates to 88% mean removal rate.
- Published
- 2015
- Full Text
- View/download PDF
47. Occurrence and enrichment of 'bacterial sherpas': climb to sustainability in wastewater treatment.
- Author
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Arnaldos M and Pagilla KR
- Subjects
- Microbial Consortia, Nitrification, Nitrogen metabolism, Oxidation-Reduction, Oxygen metabolism, Sewage microbiology, Wastewater, Water Purification, Acclimatization, Ammonia metabolism, Bacteria metabolism, Bioreactors microbiology, Hemoglobins metabolism
- Abstract
The paper presents research on hemoglobin (Hb)-expressing bacteria in biological wastewater treatment systems. The outcome(s) will greatly reduce the aeration needs of wastewater treatment plants (WWTPs) and provide insight into emerging biological nitrogen removal processes using low dissolved oxygen (DO) conditions. In anthropogenic terms, the bacteria that express Hb could be considered as 'bacterial sherpas' that can function under low DO conditions. Hitherto, this functionality of bacteria has not been realized due to the initial response of the aerobic treatment stage: namely, morphology change by bacteria to filamentous forms to overcome oxygen mass transfer limitations causing bulking/foaming and nitrification inhibition. There is evidence, however, of the potential expression of Hb proteins by activated sludge (AS) bacteria. First, bacteria known to possess genes coding Hb proteins have been isolated from AS systems. Secondly, there is evidence that WWTPs are able to operate their biological processes at low DO without sludge bulking or incomplete nitrification. Our research has focused on nitrifying systems and has shown that this is due to prolonged operation at low DO conditions (0.1 mg O2/L), which allows sufficient time for bacterial acclimation. Additionally, it has been shown that enhanced Hb expression is linked to acclimation to low DO conditions.
- Published
- 2015
- Full Text
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48. Applicability of the "Frame of Reference" approach for environmental monitoring of offshore renewable energy projects.
- Author
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Garel E, Rey CC, Ferreira O, and van Koningsveld M
- Subjects
- Animals, Humans, Oceans and Seas, Environmental Monitoring methods, Renewable Energy
- Abstract
This paper assesses the applicability of the Frame of Reference (FoR) approach for the environmental monitoring of large-scale offshore Marine Renewable Energy (MRE) projects. The focus is on projects harvesting energy from winds, waves and currents. Environmental concerns induced by MRE projects are reported based on a classification scheme identifying stressors, receptors, effects and impacts. Although the potential effects of stressors on most receptors are identified, there are large knowledge gaps regarding the corresponding (positive and negative) impacts. In that context, the development of offshore MRE requires the implementation of fit-for-purpose monitoring activities aimed at environmental protection and knowledge development. Taking European legislation as an example, it is suggested to adopt standardized monitoring protocols for the enhanced usage and utility of environmental indicators. Towards this objective, the use of the FoR approach is advocated since it provides guidance for the definition and use of coherent set of environmental state indicators. After a description of this framework, various examples of applications are provided considering a virtual MRE project located in European waters. Finally, some conclusions and recommendations are provided for the successful implementation of the FoR approach and for future studies., (Copyright © 2014 Elsevier Ltd. All rights reserved.)
- Published
- 2014
- Full Text
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49. Fosetyl-Al photo-Fenton degradation and its endogenous catalyst inhibition.
- Author
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Micó MM, Zapata A, Maldonado MI, Bacardit J, Malfeito J, and Sans C
- Subjects
- Biological Oxygen Demand Analysis, Catalysis, Fungicides, Industrial metabolism, Hydroxyl Radical chemistry, Organophosphorus Compounds metabolism, Oxidation-Reduction, Sunlight, Ultraviolet Rays, Water Pollutants, Chemical metabolism, Water Purification, Ferrous Compounds chemistry, Fungicides, Industrial chemistry, Hydrogen Peroxide chemistry, Organophosphorus Compounds chemistry, Water Pollutants, Chemical chemistry
- Abstract
Interferences from many sources can affect photo-Fenton reaction performance. Among them, catalyst inhibition can be caused by the complexation and/or precipitation of iron species by the organic matter and salts present in the reaction media. This is the case of the oxidation of effluents containing organophosphorous fosetyl-Al. The degradation of this fungicide generates phosphate anions that scavenge iron and hinder Fe(II) availability. Experimental design was applied to artificially enlighten photo-Fenton reaction, in order to evaluate fosetyl-Al degradation. The performed experiments suggested how iron inhibition takes place. The monitoring of photo-Fenton reaction over a mixture of fosetyl-Al with other two pesticides also showed the interferences caused by the presence of the fungicide on other species degradation. Solar empowered photo-Fenton was also essayed for comparison purposes. Artificial and solar light photo-Fenton reactions were revealed as effective treatments for the elimination of tested fungicide. However, the phosphate ions generated during fosetyl oxidation decreased iron availability, what hampered organic matter degradation., (Copyright © 2014 Elsevier B.V. All rights reserved.)
- Published
- 2014
- Full Text
- View/download PDF
50. Using visual design experts in critique-based evaluation of 2D vector visualization methods.
- Author
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Acevedo D, Jackson CD, Drury F, and Laidlaw DH
- Subjects
- Art, Computer Graphics, Professional Competence, Task Performance and Analysis, User-Computer Interface, Visual Perception
- Abstract
We describe an experiment in which art and illustration experts evaluated six 2D vector visualization methods. We found that these expert critiques mirrored previously recorded experimental results; these findings support that using artists, visual designers and illustrators to critique scientific visualizations can be faster and more productive than quantitative user studies. Our participants successfully evaluated how well the given methods would let users complete a given set of tasks. Our results show a statistically significant correlation with a previous objective study: designers' subjective predictions of user performance by these methods match users measured performance. The experts improved the evaluation by providing insights into the reasons for the effectiveness of each visualization method and suggesting specific improvements.
- Published
- 2008
- Full Text
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