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The bentonite material is currently used in a variety of applications ranging from hydraulic barriers and waste-buffer protection to other special uses in industry and underground disposal of high-level nuclear waste. In the deep geological repository for high-level radioactive waste, the clay acting as a buffer material between the host rock and the canister is subjected to thermal load, which could impact its geotechnical properties. Thus this study is aimed at investigating the swell and compressibility of bentonite subjected to heating at 200 °C, 400 °C, and 600 °C. The impact of heating on the index properties, the swell and compression and hydraulic conductivity is explored. The change in temperature due to weather fluctuations was found to have a minor effect on physical behavior, but this effect is found to be significant when the temperature is raised to high levels in the order of 200 °C–600 °C (Celsius). The rate at which swell and hydraulic conductivity is developed is presented in this study. The result indicated an elimination of the swellable clay minerals effect in the bentonite clay upon exposure to a temperature of 600 °C. This study introduces useful information and data for modeling the behavior of bentonite when subjected to elevated temperatures for use in application for deep geological repository for high-level radioactive waste storage and other applications.