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Macdonald, Robie W. Gratton, Yves Macdonald, Robie/A-7896-2012 Macdonald, Robie/0000-0002-1141-8520 CCGS Amundsen; CASES (Canadian Arctic Shelf Exchange Study) NSERC network (Natural Sciences and Engineering Research Council of Canada); Canadian Fund for Innovation; Canadian Coast Guard; Department of Fisheries and Oceans Canada; NSERC Discovery We thank the officers and crew of the CCGS Amundsen for their support and dedication to the CASES expedition. We are indebted to Constance Guignard, Nes Sutherland, Pascale Collin, Simon Belanger, Jens Ehn, Mike Arychuk and Owen Owens for their care and perseverance in collecting and analyzing the TA, TIC and pH samples at sea. Thanks must go to the CTD data acquisition group for these basic but critical measurements and the calibration of the various probes. Most of the plots and maps in this study were created with the ODV Software [Schlitzer, 2009]. We also thank A. Proshutinsky and two anonymous reviewers who provided constructive comments that helped to improve our manuscript. This study was funded through the CASES (Canadian Arctic Shelf Exchange Study) NSERC network (Natural Sciences and Engineering Research Council of Canada) and a Canadian Fund for Innovation grant to support the upgrade and operation of the CCGS Amundsen. Additional financial contributions were provided by the Canadian Coast Guard, the Strategic Science Fund of the Department of Fisheries and Oceans Canada, and NSERC Discovery grants to A. Mucci and Y. Gratton. 10 AMER GEOPHYSICAL UNION WASHINGTON J GEOPHYS RES-OCEANS; We examined the seasonal variability of water mass distributions in the southeastern Beaufort Sea from data collected between September 2003 and August 2004. Salinity, total alkalinity (TA) and isotopic composition (delta O-18) of seawater were used together as tracers of freshwater input, i.e., meteoric water and sea ice meltwater. We used an optimum multiparameter analysis to identify the different water masses, including the Mackenzie River, sea ice melt (SIM), winter polar mixed layer (PML), upper halocline water (UHW) with core salinity of 33.1 psu (Pacific origin) and Atlantic Water. Computed values of CO2 fugacity in seawater (fCO(2)-sw) show that the surface mixed layer (SML) remains mostly undersaturated (328 +/- 55 mu atm, n = 552) with respect to the average atmospheric CO2 concentration (380 +/- 5 mu atm) over the study period. The influence of the Mackenzie River (fCO(2-SW) > 500 mu atm) was relatively small in the southeastern Beaufort Sea, and significant fractions were only observed on the inner Mackenzie Shelf. The contribution of sea ice melt (fCO(2-SW) < 300 mu atm) to the SML could reach 30% beyond the shelf break and close to the ice pack in autumn. The density of the PML increased through the winter due to cooling and brine rejection. The winter PML reached a maximum depth of 70 m in late April. The UHW (fCO(2-SW) > 600 mu atm) was usually located between 120 and 180 m depth, but could contribute to the SML during wind-driven upwelling events, in summer and autumn, and during brine-driven eddies, in winter.