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In the present work, a lot of efforts have been made to reduce the sulfur particles, as main pollutants, from gasoline with using cerium (Ce) and Al(NO3)3 nano composites measured with Reference method: ASTM D7039‐15. The sulfur crystallite number was around 7235 ppm for DS (Ni (NO3)2 and urea). These unwanted sulfur particles reached to 3028 ppm for y (Al (NO3)3)/x (Ce)=0.25 in weight ratio, without using centrifuge process. This result is a very good due to some points: The present experimental works have been done at the room temperature and atmosphere environment, whilst many other works, as addressed here, have needed higher temperature and pressures. To our knowledge, Ce, Aluminum nitrate and urea as nano composite materials have need been used for desulfurization processes. Moreover, some relevant techniques such as X‐ray powder diffraction (XRD), Energy dispersive X‐ray analysis (EDX), Fourier Transform Infrared (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), UV‐Vis spectroscopy, transmission electron microscopy (TEM), and Dynamic light scattering (DLS) have also been used. [ABSTRACT FROM AUTHOR]

The addition of Ca and Sb in Cr‐bearing steel presents improved corrosion resistance during the field exposure test in a marine atmosphere environment. Through local hydrolysis reactions, Ca and Sb can form CaO, Sb2O3, and Sb2O5 to prevent the intrusion Cl− into the corrosion product film, which improves the protectiveness of the corrosion product film and reduces the corrosion rate. The formation of CaCl2 decreases the relative content of β‐FeOOH and makes the corrosion product film more stable. Due to the inhibition of Sb on the local acidification of corrosion product film, Ca and Cr are able to bond with more hydroxide for generating the corresponding oxides and improving the corrosion resistance of Cr‐bearing steel. [ABSTRACT FROM AUTHOR]

Exposure to nature has been linked to improved mental health. This raises an interesting question of whether incorporating natural features, such as bodies of water, into the built environment can also improve mental health. This study determined whether the presence or absence of bodies of water in leisure areas in the natural and built environment impacts people's direct attention, preference for certain types of landscapes, feelings of restorativeness when in those landscapes, and physiological indicators, such as heart rate and electromyographic readings. The study included 136 participants. The results showed that in their resting state, participants were substantially less physiologically stressed when they were in the presence of bodies of water in natural settings than in their absence in the built environment. However, when the built environment included bodies of water, people's heart rates were lower when viewing, feeling, and reporting on the atmosphere of these environments. The results showed that people can reduce tension and stress by spending time around bodies of water in the natural areas of leisure settings. Furthermore, natural environments, with or without bodies of water, can help alleviate direct attention fatigue and are preferred to the built environment. However, leisure areas in the built environment that incorporate bodies of water can generate positive emotions. Our study demonstrated that leisure areas with waterscapes in both built and natural environments may enhance physiological and psychological well-being. [ABSTRACT FROM AUTHOR]

Copyright of Retos: Nuevas Perspectivas de Educación Física, Deporte y Recreación is the property of Federacion Espanola de Asociaciones de Docentes de Educacion Fisica and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Education is the right of every person to improve the quality of themself through a comfortable atmosphere and environment. For students with special needs, this greatly influences progress both in terms of skills and how learning is interpreted. London School Beyond Academy (LSBA) is a skills education institution that has succeeded in forming special needs students to be able to enjoy the teaching and learning process through a conducive environment and understand them well. The purpose of this research is to find out the meaning of learning for special needs students who attend LSBA. Through Alfred Schutz's thinking, this study found that the intersubjective or everyday world is an element that plays a role in the thinking of special needs students in understanding meaning. This study uses a qualitative method with a phenomenological study by selecting four special needs students, three lecturers and one parent. There are five themes that come up in this research for the meaning of learning for special needs students. The themes are increasing knowledge and becoming smarter, making more friends, having fun, achievement and learning because of parents. The supporting factors for learning for students with special needs are parents as the main ones, then siblings, the school environment, extended family, people closest to them other than family and friends. The self-concept of students with special needs examined in this research shows a positive selfconcept. This research provides benefits for schools, parents and all other related parties in understanding students with special needs in learning. [ABSTRACT FROM AUTHOR]

The perception of urban and rural environments is multi-dimensional, shaped by the individual preferences of observers, residents, and visitors. Landmarks play a crucial role in the image of a city or rural area, aiding orientation and creating memorable experiences. It enhances navigability, fosters a sense of attachment, and contributes to place identity. Monuments and heritage structures significantly influence the visual ambiance of these environments. The visibility of heritage structures depends on factors such as height, surrounding buildings, skyline, and location. Using Sketch-up software, this paper assesses the visibility of the Rajagopuram in Thiruvasi village, Tamil Nadu. The study evaluates Rajagopuram's visibility from various distances, concluding that it is a prominent landmark that enhances visual recognition and fosters a strong sense of attachment and place identity. The study underscores the importance of preserving heritage buildings to maintain historical and cultural significance amidst modern changes. [ABSTRACT FROM AUTHOR]

In the design and optimisation of marine wireless communication and navigation systems, a thorough investigation of radio wave propagation characteristics under atmospheric ducting conditions is essential. The authors aim to enhance the efficiency of radio wave propagation loss prediction in marine atmospheric ducting environments, proposing a prediction model based on Fast Reordered‐Alternate Direction Decomposition (FR‐ADD). By approximating the diffraction term into three independent components, exploiting the commutative properties of the Fourier transform to reduce the spatial dimensions, and incorporating a rapid algorithm for the parabolic equation, the model optimises the stepping process and significantly improves computational efficiency. Simulation experiments demonstrate that, in the long‐distance and complex marine ducting environments, the model not only maintains prediction accuracy but also substantially reduces computational load and prediction time, effectively realising over‐the‐horizon propagation prediction. In the experiment of radio wave propagation characteristics in the Yellow and Bohai Seas, the simulation data from the FR‐ADD model showed significant correlation with actual measurements and simulations from the AREPS software, confirming the method's efficiency and practicality. [ABSTRACT FROM AUTHOR]

The increase in the number of motor vehicles has intensified the impact of traffic sources on air quality. Our aim was to illustrate the characteristics of PM2.5 emissions from vehicles fueled with E10 (a blend of 10% ethanol and 90% gasoline). A 21-day PM2.5 sampling in a fully enclosed urban tunnel and the component analysis were completed, and the characteristics, sources, and health risks of tunnel PM2.5 were studied. Moreover, the PM2.5 pH and its sensitivity were investigated by the thermodynamic model (ISORROPIA-II). In addition, exposure models were used to assess the health risks of different heavy metals in PM2.5 to humans through respiratory pathways. The two-point Cu/Sb ratio (entrance: 4.0 ± 1.4; exit: 4.4 ± 1.7) was close to the diagnostic criteria indicating a significant impact from brake wear. NO3−, NH4+, and SO42− constituted the main components of water-soluble ions in PM2.5 of the tunnel, accounting for 83.0–84.6% of the total concentration of inorganic ions. The organic carbon/elemental carbon ratio of the tunnel was greater than 2, indicating that the contribution of gasoline vehicle exhaust was significant. The average emission factors of PM2.5 in the fleet was 31.4 ± 16.6 mg/(veh·km). The pH value of PM2.5 in a tunnel environment (4.6 ± 0.3) was more acidic than that in an urban environment (4.9 ± 0.6). The main sensitive factors of PM2.5 pH in the urban atmosphere and tunnel environment were total ammonia (sum of gas and aerosol, NH3) and temperature, respectively. The results of the health risk assessment showed that Pb posed a potential carcinogenic risk, while As and Cd presented unacceptable risks for tunnel workers. The non-carcinogenic risk index of heavy metals of PM2.5 in the tunnel environment exceeded the safety threshold. [ABSTRACT FROM AUTHOR]

In this work, the well-known Ince–Gaussian beams (IGBs) are reproduced by expanding them in the Laguerre Gaussian basis. The established formula will derive the analytical expression of the average intensity of the IGBs propagating through the turbulent atmosphere by using the extended Huygens–Fresnel diffraction integral in the framework of Rytov theory. This work is concerned with finding a closed-form expression for the average intensity of IGBs propagating through weak and strong Kolmogorov turbulence and completes other scientific research works that deal with numerical approach. The numerical simulations of the analytical average intensity at the receiver plane and the effective beam spot size of the IGBs propagating through turbulent atmosphere environment are presented in this paper. The influences of the beam profile parameters and the turbulence strength on the evolution of the diffracted beam are investigated and discussed. The present results can be a useful tool to predict the behavior of IGBs for the applications in turbulent atmosphere. [ABSTRACT FROM AUTHOR]

The ocular surface system interacts with, reacts with, and adapts to the daily continuous insults, trauma, and stimuli caused by direct exposure to the atmosphere and environment. Several tissue and para-inflammatory mechanisms interact to guarantee such an ultimate function, hence maintaining its healthy homeostatic equilibrium. Evaporation seriously affects the homeostasis of the system, thereby becoming a critical trigger in the pathogenesis of the vicious cycle of dry eye disease (DED). Tear film lipid composition, distribution, spreading, and efficiency are crucial factors in controlling water evaporation, and are involved in the onset of the hyperosmolar and inflammatory cascades of DED. The structure of tear film lipids, and subsequently the tear film, have a considerable impact on tears' properties and main functions, leading to a peculiar clinical picture and specific management. [ABSTRACT FROM AUTHOR]

The deep ultraviolet photochemistry of aqueous pyruvate is believed to have been essential to the origin of life, and near ultraviolet excitation of pyruvate in aqueous aerosols is assumed to contribute significantly to the photochemistry of the Earth's atmosphere. However, the primary photochemistry of aqueous pyruvate is unknown. Here we study the susceptibility of aqueous pyruvate to photodissociation by deep ultraviolet and near ultraviolet irradiation with femtosecond spectroscopy supported by density functional theory calculations. The primary photo-dynamics of the aqueous pyruvate show that upon deep-UV excitation at 200 nm, about one in five excited pyruvate anions have dissociated by decarboxylation 100 ps after the excitation, while the rest of the pyruvate anions return to the ground state. Upon near-UV photoexcitation at a wavelength of 340 nm, the dissociation yield of aqueous pyruvate 200 ps after the excitation is insignificant and no products are observed. The experimental results are explained by our calculations, which show that aqueous pyruvate anions excited at 200 nm have sufficient excess energy for decarboxylation, whereas excitation at 340 nm provides the aqueous pyruvate anions with insufficient energy to overcome the decarboxylation barrier. The photochemistry of the pyruvate anion plays an important role in the Earth's atmosphere and aqueous environments. Here, the authors show that excitation of aqueous pyruvate by 200 nm light leads to decarboxylation with a quantum efficiency of 20%, while excitation by 340 nm light does not cause a reaction. [ABSTRACT FROM AUTHOR]

Polarization dynamics and domain structure evolution in ferroelectric Al0.93B0.07N are studied using piezoresponse force microscopy and spectroscopies in ambient and controlled atmosphere environments. The application of negative unipolar and bipolar first‐order reverse curve (FORC) waveforms leads to a protrusion‐like feature on the Al0.93B0.07N surface and a reduction of electromechanical response due to electrochemical reactivity. A surface change is also observed on the application of fast alternating current bias. At the same time, the application of positive biases does not lead to surface changes. Comparatively in a controlled glove box atmosphere, stable polarization patterns can be observed, with minuscule changes in surface morphology. This surface morphology change is not isolated to applying biases to free surface, a similar topographical change is also observed at the electrode edges when cycling a capacitor in an ambient environment. The study suggests that surface electrochemical reactivity may have a significant impact on the functionality of this material in the ambient environment. However, even in the controlled atmosphere, the participation of the surface ions in polarization switching phenomena and ionic compensation is possible. [ABSTRACT FROM AUTHOR]

Chromospheric oscillations can give us insight into the physical environment in the solar atmosphere, both in quiet Sun and flaring conditions. Many authors have reported increases in the prevalence of 3-minute oscillations which are thought to be excited by events which impact the chromosphere such as flares. In this study, we utilized the Ca  ii 8542 Å line to study the oscillatory behaviour of the chromosphere in an active region which underwent two B-class flares. We analysed oscillations in both intensity and velocity, and found different behaviours in both. Intensity oscillations were most prevalent over the umbrae of sunspots and magnetic pores in the active region, and the extent of the area which contained significant oscillations was found to decrease when comparing times after the flares to before. By measuring the evolution of the magnetic field, we found that this could be because the areas surrounding the umbrae were becoming more 'penumbral' with an increase to the magnetic field inclination. Velocity oscillations were found across the active region both before and after the flares but were observed clearly in areas which were brightened by the second flare. By comparing to EUV imaging, it was seen that strong chromospheric velocity oscillations with 3–4-minute periods occurred at the same time and location as a flare loop cooling 30 min after the second flare peak. This could be evidence of disturbances in the loop exciting a response from the chromosphere at its acoustic cut-off frequency. [ABSTRACT FROM AUTHOR]

Sodium-bearing species such as NaCl in the gas phase have been observed in an assortment of carbon-rich and oxygen-rich stellar atmospheres and interstellar environments such as the high-mass protostellar disc surrounding Orion Src1 and the proto-binary system, IRAS 16547−4247. Their detection in relatively low-temperature regions is yet to be made. In this paper, we consider the synthesis of sodium-bearing species with an emphasis on NaCl, via both gas-phase and grain-surface chemistry under assorted interstellar conditions. We also consider the chemistry leading to the gas-phase species NaH and NaOH. Two classes of numerical simulations were run: models under isothermal conditions at temperatures from 10 to 800 K with varied intervals, and three-phase warm-up models that consist of an initial isothermal collapse at 10 K, followed by a warm-up phase in which temperature rises linearly to 200 K, and finally a hot core phase. We have included reactive desorption for both models to produce gaseous NaCl, NaH, and NaOH. We found that for isothermal models over a broad parameter space, the fractional abundances of gaseous NaCl and NaOH can reach above 2 × 10−10 and approx. 1 × 10−10, respectively, are in the detection range of observational facilities such as Atacama Large Millimeter/Submillimeter Array and JWST. For warm-up models, we found that if we consider molecules to be co-desorbed with water, gaseous NaCl can have a sufficiently large abundance for detection. We then conclude that both gaseous NaCl and NaOH can be detected; however, more experiments and quantum mechanical calculations are needed to constrain the relevant reaction rates better. [ABSTRACT FROM AUTHOR]

The kinetical behavior and mechanism of micro-galvanic corrosion of Q690 bainitic weathering steel welded joint in marine atmosphere were investigated. The results showed that a micro-galvanic corrosion cell formed among different regions of the Q690 welded joint. The kinetical behavior of micro-galvanic corrosion could be divided into four stages: the initiation and development of micro-galvanic corrosion, the decreasing of galvanic corrosion rate, the polarity reversal of galvanic couple, and the disappearance of galvanic effect. The difference of corrosion rate between Q690 steel and its welded joint is closely related to the micro-galvanic corrosion kinetic behavior. [ABSTRACT FROM AUTHOR]

Paintings can exert a strong effect on their viewers by creating atmospheres. But how is it possible for a painting to create an atmosphere? My goal in this paper is to provide a partial answer to this question by focusing on the depiction of light. I argue that paintings can elicit experiences of atmospheres in part because they can depict pictorial space as filled with ambient light that has a distinctive phenomenal character. It is in virtue of this distinctive phenomenal character that the depicted ambient light can make a significant contribution to the overall phenomenal character of the experienced atmosphere. [ABSTRACT FROM AUTHOR]

Though the welding technology has undergone a phenomenal change over the last five decades, the atmosphere or our environment is still under severe risk through the welding activities, including global warming. The main hazard due to welding activities are fumes and gases. In most of the welding operations, welding smoke is generated in large volume, which is a complex mixture of very fine particles (fumes) and airborne gases. To overcome the situation, green welding is the only way forward. Use of friction stir welding (FSW) is one of the ways towards green welding as well as to protect the environment somehow. Other less pollutant welding processes are also to be adopted as far as possible. Another way to protect our environment and to adopt green welding is to train the welders through virtual reality driven welding simulator. [ABSTRACT FROM AUTHOR]

Most 2D materials are unstable under ambient conditions. Assembly of van der Waals heterostructures in the inert atmosphere of the glove box with ex situ lithography partially solves the problem of device fabrication out of unstable materials. In our paper, we demonstrate an approach to the next-generation inert-atmosphere (nitrogen, <20 ppm oxygen content) fabrication setup, including optical contact mask lithography with a 2 μ m resolution, metal evaporation, lift-off and placement of the sample to the cryostat for electric measurements in the same inert atmosphere environment. We consider basic construction principles, budget considerations, and showcase the fabrication and subsequent degradation of black-phosphorous-based structures within weeks. The proposed solutions are surprisingly compact and inexpensive, making them feasible for implementation in numerous 2D materials laboratories. [ABSTRACT FROM AUTHOR]

To be able to meet global grand challenges (climate change; biodiversity loss; environmental pollution; scarcity of water, food and energy supplies; acidification; deforestation; chemicalization; pandemics), which all are closely interlinked with each other, we need comprehensive open data with proper metadata, along with open science. The large data sets from ground-based in situ observations, ground and satellite remote sensing, and multiscale modeling need to be utilized seamlessly. In this opinion paper, we demonstrate the power of the SMEAR (Station for Measuring Earth surface–Atmosphere Relations) concept via several examples, such as detection of new particle formation and the particles' subsequent growth, quantifying atmosphere–ecosystem feedback loops, and combining comprehensive observations with emergency science and services, as well as studying the effect of COVID-19 restrictions on different air quality and climate variables. The future needs and the potential of comprehensive observations of the environment are summarized. [ABSTRACT FROM AUTHOR]

Students' academic and social adaptation is linked to factors such as their initial study motivations, the atmosphere of the academic environment and their perception of academic wellbeing. This paper analyses the initial adaptation of first-degree students in their first semester through a quantitative ex post facto study with a descriptive-exploratory approach, using a questionnaire as the information-gathering instrument. Findings shed light on the concept of initial adaptation itself (through the creation of an index) and validate the study of the construct through three factors: initial motivation, the academic environment and perception of academic wellbeing. Also, the influence on initial adaptation of the academic and social context of the degree course taken is demonstrated:, as the constitutive features of the degree contribute information predicting how students will integrate into the institution. Therefore, it is suggested that institutional means and actions should be designed and put in place in accordance with measurements that indicate how students function best in a specific context (the bachelor's degree), in order to boost motivation and the perception of academic wellbeing. [ABSTRACT FROM AUTHOR]

The influence of humidity and oxygen on the formation of the structure and strength properties of manufactured products based on magnesium oxide and the organic binder SFPR-054 was studied. It was ascertained that conduction of the polymerization process at 25°C without access to air effects approximately five-fold higher sample strength compared to the samples polymerized in dry form at 300°C. The data obtained suggest that an increase in the structural and mechanical properties of manufactured products on the basis of magnesium oxide contributes to moistening of the batch, retention of the pressed product and the polymerization process in an oxygen-free environment or in an atmosphere of water vapors. [ABSTRACT FROM AUTHOR]

In this research, the degradation behavior and failure mechanism of silicone rubber seal rings under the synergistic effects of multiple factors in the marine atmosphere are fully investigated. Firstly, four aging factors of air, temperature, compressive stress, and chemical medium were determined by analyzing the service environment profile of silicone rubber seal under a marine atmosphere environment. Secondly, to better simulate the actual service environment of silicone rubber and shorten the test period, an artificially accelerated aging test was designed and carried out in the laboratory. In this paper, temperature is utilized as the accelerating stress. According to the results of the pre-test, the accelerating stress level is finally determined to be 110–150 ∘ C. In addition, the compression set applied is consistent with the constant compression permanent deformation value of 28% of the silicone rubber in the actual service process. Finally, through the macroscopic physical properties and microstructure analysis of the samples before and after aging, the corresponding test results are given, and the failure mechanism is analyzed and discussed in detail. Through the above test results and discussion, it can be concluded that the aging process of multi-factor coupling on the lower silicone rubber seal ring is uneven, and its aging process is not a simple superposition of multiple environmental factors. More importantly, the above test data and results are of great significance for evaluating the service life of silicone rubber seals, which can be utilized in the future to improve the reliability and durability of related equipment in the marine environment. [ABSTRACT FROM AUTHOR]

Yachts emit harmful gases to human health and the environment into the atmosphere and marinas and surrounding vicinity are the most affected regions by these pollutants. This study applied a bottom‐up approach involving emission factors to make an anthropogenic emissions inventory of yachts and to offer solutions for reducing emissions by investigating the NMVOC, NOx, NH3, CO, and PM emissions from 2002 yacht movements between June 1 and August 31, 2019 at Turgutreis D‐Marin in Bodrum Turkey. These emissions are categorized based on yacht operation modes and types. Quarterly yachting emissions are estimated as 3099 tons for NMVOC, 0.003 tons for NH3, 14,526 tons for NOx, 1896 tons for PM, and 15,576 tons for CO. [ABSTRACT FROM AUTHOR]

Net primary productivity is an essential measure of plant biology and the net flow of carbon between the atmosphere and the terrestrial environment. This aids in comprehending how much carbon is fixed by terrestrial plants and the factors that affect it, thus requiring a thorough grasp of net primary productivity dynamics and how they interact with the climate in arid and humid regions. This study applied remote sensing techniques to evaluate the spatial distribution and climatic variables of the net primary productivity in the Niger River Basin, using the Carnegie Ames Stanford Approach model and correlation analysis. The study revealed that the net primary productivity fell from 338.18 gC/m2 in 2000 to 334.44 gC/m2 in 2020. The correlation result shows that while precipitation (R2=0.87) and actual evapotranspiration (R2=0.83) revealed a positive correlation, temperature (R2=0.328), solar radiation (R2=0.585), and potential evapotranspiration (R2=0.78) shows a negative correlation with the net primary productivity. The study shows that precipitation has a major influence on changes in the net primary production of the NRB. The results of the study may help to better understand how climate studies affect environmental ecology while recommending policymakers to safeguard the Niger River Basin from activities that can deteriorate the environment. [ABSTRACT FROM AUTHOR]

Mercury is a highly toxic heavy metal whose emission sources can be both natural and the result of anthropic activity. Its polluting action on soils, and its ability to spread through the atmosphere and aquatic environments, constitutes a threat to human and environmental health; both for its bioaccumulation capacity and for biomagnification through the trophic chain. For this reason, there is a growing scientific and social interest in the reduction of this heavy metal in ecosystems. Bioremediation based on the use of microorganisms and/or plants is postulated as a sustainable alternative to traditional physicochemical methods. The main strategies used for this purpose (individually or in combination) are the volatilization of the contaminant, biosorption, phytoextraction and phytoremediation. All these tools are based on taking advantage of the natural and evolutionary capacity that different organisms have developed to adapt to the presence of various pollutants in the environment. Based on the consulted bibliography, these bioremediation methodologies focus on the use of microorganisms (freely or associated with plants) have been successfully applied in different ecosystems, postulating themselves as a respectful alternative for the future for the recovery of degraded environments. For these reasons there is a growing interest in the scientific community to design and use new techniques in a "One Health" context, which allow interpreting the positive impact of bioremediation. In this sense, the universalization of Omics techniques has allowed to abound in the knowledge of new bacterial taxa, and their biotechnological application. This study pretends to cover the present knowledge about mercury bioremediation techniques. In the same way, some new techniques and perspectives are presented in order to expand the frontiers of future research. [ABSTRACT FROM AUTHOR]

An approach based on an artificial neural network (ANN) for the prediction of NOx emissions from underground load–haul–dumping (LHD) vehicles powered by diesel engines is proposed. A Feed-Forward Neural Network, the Multi-Layer Perceptron (MLP), is used to establish a nonlinear relationship between input and output layers. The predicted values of NOx emissions have less than 15% error compared to the real values measured by the LHD onboard monitoring system by the standard sensor. This is considered quite good efficiency for dynamic behaviour prediction of extremely complex systems. The achieved accuracy of NOx prediction allows the application of the ANN-based "soft sensor" in environmental impact estimation and ventilation system demand planning, which depends on the number of working LHDs in the underground mine. The proposed solution to model NOx concentrations from mining machines will help to provide a better understanding of the atmosphere of the working environment and will also contribute to improving the safety of underground crews. [ABSTRACT FROM AUTHOR]

Liquid–vapor interfaces, particularly those between aqueous solutions and air, drive numerous important chemical and physical processes in the atmosphere and in the environment. X-ray photoelectron spectroscopy is an excellent method for the investigation of these interfaces due to its surface sensitivity, elemental and chemical specificity, and the possibility to obtain information on the depth distribution of solute and solvent species in the interfacial region. In this Perspective, we review the progress that was made in this field over the past decades and discuss the challenges that need to be overcome for investigations of heterogeneous reactions at liquid–vapor interfaces under close-to-realistic environmental conditions. We close with an outlook on where some of the most exciting and promising developments might lie in this field. [ABSTRACT FROM AUTHOR]

Radicals are prevalent in gas-phase environments such as the atmosphere, combustion systems, and the interstellar medium. To understand the properties of the processes occurring in these environments, it is helpful to study radical reaction systems in isolation—thereby avoiding competing reactions from impurities. There are very few methods for generating a pure beam of gas-phase radicals, and those that do exist involve complex setups. Here, we provide a straightforward and versatile solution. A magnetic radical filter (MRF), composed of four Halbach arrays and two skimming blades, can generate a beam of velocity-selected low-field-seeking hydrogen atoms. As there is no line-of-sight through the device, all species that are unaffected by the magnetic fields are physically blocked; only the target radicals are successfully guided around the skimming blades. The positions of the arrays and blades can be adjusted, enabling the velocity distribution of the beam (and even the target radical species) to be modified. The MRF is employed as a stand-alone device—filtering radicals directly from the source. Our findings open up the prospect of studying a range of radical reaction systems with a high degree of control over the properties of the radical reactants. [ABSTRACT FROM AUTHOR]

To prevail in the fierce competition of in-store experiences, some firms have focused on providing pleasant ambient scents. However, equivocal results on scent effects make generalizations and managerial guidance uncertain. While efforts to consolidate research findings have been conducted, a comprehensive quantitative integration is notably lacking. In this meta-analysis, the authors integrate 671 available effects from ambient scent experiments and show that exposure to pleasant ambient scents on average produces a substantial increase in the level of customer responses (3%–15%). The effects of ambient scent depend on situational contingencies and are, for example, positively related to congruency, unidimensional aroma structure, ascribed familiarity of a scent, service exchange, proportion of female participants in the sample, and imagined (vs. fictitious) offering. Thus, the authors estimate expenditures would increase by 3% and 23% for an average and a most favorable condition, respectively. The authors also examine effect patterns, identifying, for example, ambient scent as more cognitive than affective and nonlinear effects of perceived concentration. Using the insights, they develop a research agenda and provide clear strategic guidance to leverage ambient scent effects. [ABSTRACT FROM AUTHOR]

In this paper, the corrosion performance of galvanized steel was investigated in a simulated marine environment, under UV irradiation coupling with an alternating wet and dry cycle in a NaCl solution. The surface morphology, composition, and corrosion performance of galvanized steel before and after different alternating wet and dry corrosion under UV irradiation were investigated. The results show that the corrosion current density gradually increases and the corrosion resistance decreases as a function of the alternating wet and dry corrosion cycles. Meanwhile, UV irradiation accelerates the increase in the corrosion current density and the decrease in the corrosion resistance. In addition, the corrosion product ZnO shows a semiconductor property, and the photo-induced electrons and holes produced under UV can participate in the corrosion reaction and promote the formation of loose corrosion products Zn(OH)2, Zn5(OH)8Cl2, and Al2Cl3(OH)5·4H2O, thus accelerating the corrosion of galvanized steel in the atmosphere environment. [ABSTRACT FROM AUTHOR]

As part of China's Tianwen-1 Mars mission, the Mars Surface Composition Detector (MarSCoDe) instrument on the Zhurong rover adopts laser-induced breakdown spectroscopy (LIBS) to perform chemical component detection of the materials on the Martian surface. However, it has always been a challenging issue to achieve high accuracy in LIBS quantification. This study investigated the effect of chemometrics and spectral data preprocessing approaches on LIBS quantification accuracy based on different chemometrics algorithms and diverse preprocessing methods. A total of 2340 LIBS spectra were collected from 39 kinds of geochemical samples by a laboratory duplicate model of the MarSCoDe instrument. The samples and the MarSCoDe laboratory model were placed in a simulated Martian atmosphere environment based on equipment called the Mars-Simulated Detection Environment Experiment Platform (MarSDEEP). To quantify the concentration of MgO in the samples, we employed two common LIBS chemometrics; i.e., partial least squares (PLS) and a back-propagation neural network (BPNN). Meanwhile, in addition to necessary routine preprocessing such as dark subtraction, we used five specific preprocessing approaches, namely intensity normalization, baseline removal, Mg-peak wavelength correction, Mg-peak feature engineering, and concentration range reduction. The results indicated that the performance of the BPNN was better than that of the PLS and that the preprocessing of Mg-peak wavelength correction had the most prominent effect to improve the quantification accuracy. The results of this study are expected to provide inspiration for the processing and analysis of the in situ LIBS data acquired by MarSCoDe on Mars. [ABSTRACT FROM AUTHOR]

As a greenhouse gas, nitrous oxide (N2O) is increasingly damaging the atmosphere and environment, and the capture of N2O using ionic liquids (ILs) has recently attracted wide attention. Machine learning can be utilized to rapidly screen ILs suitable for N2O removal. In this study, intelligent predictions of nitrous oxide capture in designable ionic liquids are proposed based on a series of machine learning methods, including linear regression, voting, and a two-layer feed-forward neural network (TLFFNN). The voting model can utilize various algorithms and is highly generalizable to various systems. The TLFFNN model produced the most accurate prediction, with an MSE of 0.00002 and R2 of 0.9981 on test sets. The acceptable performance of the TLFFNN model demonstrates its utility as an accurate and promising candidate model for the prediction of N2O solubility in ILs over other intelligent models. Based on the analysis of the thermodynamic and molecular properties of ionic liquids, in the low-pressure zone, components of [(OH)2IM] and [AC] perform best in capturing N2O, while in the high-pressure zone, components of [(ETO)2IM] and [SCN] are best. This finding will provide new chemical insights for the industrial synthesis of ionic liquids in capturing N2O. [ABSTRACT FROM AUTHOR]

In view of the drastic changes in the ocean - atmosphere environment, the accurate and efficient identification of coral reef substrate information is essential for the dynamic monitoring of coral reefs. Based on the Landsat8 satellite data of the Yongle Atoll in the Xisha Islands of four periods during 2013-2021, this study proposed a decision tree classification model using spectral and texture indices according to the spectral and texture differences between different substrates. Then, the coral information was extracted using object-oriented and pixel-based classification methods. In addition, the changes in the substrate of the Yongle Atoll were quantitatively analyzed. The results are as follows: (1) The results of the object - oriented classification are superior to those of pixel - based classification overall. Moreover, the decision tree classification results yielded Kappa coefficients of 0.63 ?? 0.68, with classification accuracy about 7 ~ 10 percentage points higher than that of conventional supervised classification; (2) Coral thickets are mostly distributed in the central, weakly - hydrodynamic parts of islands and reefs. The corals in the Yinyu Reef and the Jinyin Island exhibit a planar distribution pattern, while those in other islands and reefs mostly show a zonal distribution pattern; (3) The areas of coral thickets and sandbanks in the Yongle Atoll changed significantly overall. Although the total area of coral thickets increased by 1.689 km², the coral thickets in the Shiyu, Jinqing, Quanfu, and Shanhu islands and the Lingyang reef were severely degraded, with areas decreasing by 0.107 ~ 0.892 km². This study verified that the substrate index established using medium spatial resolution images is reliable and can be applied to remote sensing information extraction of corals. Therefore, this study will provide technical support for the investigation and scientific management of coral reef resources. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Beijing University of Civil Engineering & Architecture is the property of Journal of Beijing University of Civil Engineering & Architecture Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)