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Tuning magnetic properties of magnetic topological materials is of interest to realize elusive physical phenomena such as quantum anomalous hall effect (QAHE) at higher temperatures and design topological spintronic devices. However, current topological materials exhibit Curie temperature (TC) values far below room temperature. In recent years, significant progress has been made to control and optimize TC, particularly through defect engineering of these structures. Most recently we showed evidence of TC values up to 80K for (MnSb2Te4)x(Sb2Te3)1-x, where x is greater than or equal to 0.7 and less than or equal to 0.85, by controlling the compositions and Mn content in these structures. Here we show further enhancement of the TC, as high as 100K, by maintaining high Mn content and reducing the growth rate from 0.9 nm/min to 0.5 nm/min. Derivative curves reveal the presence of two TC components contributing to the overall value and propose TC1 and TC2 have distinct origins: excess Mn in SLs and Mn in Sb2-yMnyTe3QLs alloys, respectively. In pursuit of elucidating the mechanisms promoting higher Curie temperature values in this system, we show evidence of structural disorder where Mn is occupying not only Sb sites but also Te sites, providing evidence of significant excess Mn and a new crystal structure:(Mn1+ySb2-yTe4)x(Sb2-yMnyTe3)1-x. Our work shows progress in understanding how to control magnetic defects to enhance desired magnetic properties and the mechanism promoting these high TC in magnetic topological materials such as (Mn1+ySb2-yTe4)x(Sb2-yMnyTe3)1-x.

Redox monolayers are the base for a wide variety of devices including high-frequency molecular diodes or biomolecular sensors. We introduce a formalism to describe the electrochemical shot-noise of such monolayer, confirmed experimentally at room temperature in liquid. The proposed method, carried out at equilibrium, avoids parasitic capacitance, increases the sensitivity and allows to obtain quantitative information such as the electronic coupling (or standard electron transfer rates), its dispersion and the number of molecules. Unlike in solid-state physics, the homogeneity in energy levels and transfer rates in the monolayer yields a Lorentzian spectrum. This first step for shot-noise studies in molecular electrochemical systems opens perspectives for quantum transport studies in liquid environment at room temperature as well as highly sensitive measurements for bioelectrochemical sensors., Comment: 6 pages, 4 Figures (main) + 15 pages, 11 Figures (SM)

While perovskite solar cells (PSCs) are now reaching high power conversion efficiencies (PCEs), further performance improvement requires a fine management and an optimization of the light pathway and harvesting in the cells. These go through an accurate understanding, characterization and modelling of the optical processes occurring in these complex, often textured, multi-layered systems. In the present work, we have considered a typical methylammonium lead iodide (MAPI) solar cell built on a fluorine-doped tin oxide (FTO) electrode of high roughness (43 nm RMS). By variable-angle spectroscopic ellipsometry (VASE) of the full PSC device, we have been able to determine the optical constants of all the device layers. We have designed a one-dimensional (1D) optical model of the stacked layers where the rough texture is described as layers of effective-medium index. We have supported the model using data extracted from scanning electron microscopy, diffuse spectroscopy and photovoltaic efficiency measurements. We show that the 1D model, while insufficient to describe scattering by the FTO plate alone, gives an accurate description of the full device optical properties. By comparison with the experimental external quantum efficiency (EQE), we estimate the internal quantum efficiency (IQE) and the effect of the losses related to electron transfer. Based on this work, we finally discuss the optical losses mechanisms and the possible strategies that can be implemented to improve light management within PSC devices and further increase their performances., Comment: 14 pages, 5 figures

There is presently a tremendous activity around the field of topological superconductivity and Majorana fermions. Among the many questions raised, it has become increasingly important to establish the topological or non-topological origin of features associated with Majorana fermions such as zero-bias peaks. Here, we compare in-gap features associated either with isolated magnetic impurities or with magnetic clusters strongly coupled to the atomically thin superconductor Pb/Si(111). We study this system by means of scanning tunneling microscopy and spectroscopy (STM/STS). We take advantage of the fact that the Pb/Si(111) monolayer can exist either in a crystal-ordered phase or in an incommensurate disordered phase to compare the observed spectroscopic features in both phases. This allows us to demonstrate that the strongly resolved in-gap states we found around the magnetic clusters in the disordered phase of Pb have a clear topological origin., Comment: 11 pages, 5 figures. To be published in European Physical Journal Special Topics.dedicated to the conference FQMT'17

Performance, genericity and flexibility are three valuable qualities for scientific environments that tend to be antagonistic. C++ provides excellent support for both performances and genericity thanks to its support for (class and function) templates. However, a C++ templated library can hardly be qualified as flexible: data of unexpected types cannot enter the system, which hinders user interactions. This paper describes the approach that was taken in the Vcsn platform to add flexibility on top of C++ templates, including runtime template instantiation.

We introduce (weighted) rational expressions to denote series over Cartesian products of monoids. To this end, we propose the operator $|$ to build multitape expressions such as $(a^+|x + b^+|y)^*$. We define expansions, which generalize the concept of derivative of a rational expression, but relieved from the need of a free monoid. We propose an algorithm based on expansions to build multitape automata from multitape expressions., Comment: arXiv admin note: text overlap with arXiv:1605.01530

Just like insulators can host topological Dirac states at their edges, superconductors can also exhibit topological phases characterized by Majorana edge states. Remarkable zero-energy states have been recently observed at the two ends of proximity induced superconducting wires, and were interpreted as localized Majorana end states in one-dimensional (1D) topological superconductor. By contrast, propagating Majorana states should exist at the 1D edges of two-dimensional (2D) topological superconductors. Here we report the direct observation of dispersive in-gap states surrounding topological superconducting domains made of a single atomic layer of Pb covering magnetic islands of Co/Si(111). We interpret the observed continuous dispersion across the superconducting gap in terms of a spatial topological transition accompanied by a chiral edge mode and residual gaped helical edge states. Our experimental approach enables the engineering and control of a large variety of novel quantum phases. This opens new horizons in the field of quantum materials and quantum electronics where the magnetization of the domains could be used as a control parameter for the manipulation of topological states., Comment: 12 pages, 3 figures

We present an algorithm to build an automaton from a rational expression. This approach introduces support for extended weighted expressions. Inspired by derived-term based algorithms, its core relies on a different construct, rational expansions. We introduce an inductive algorithm to compute the expansion of an expression from which the automaton follows. This algorithm is independent of the size of the alphabet, and actually even supports infinite alphabets. It can easily be accommodated to generate deterministic (weighted) automata. These constructs are implemented in Vcsn, a free-software platform dedicated to weighted automata and rational expressions., Comment: 21 pages

The microscopic nature of an insulating state in the vicinity of a superconducting state, in the presence of disorder, is a hotly debated question. While the simplest scenario proposes that Coulomb interactions destroy the Cooper pairs at the transition, leading to localization of single electrons, an alternate possibility supported by experimental observations suggests that Cooper pairs instead directly localize. The question of the homogeneity, granularity, or possibly glassiness of the material on the verge of this transition is intimately related to this fundamental issue. Here, by combining macroscopic and nano-scale studies of superconducting ultrathin NbN films, we reveal nanoscopic electronic inhomogeneities that emerge when the film thickness is reduced. In addition, while thicker films display a purely two-dimensional behaviour in the superconducting fluctuations, we demonstrate a zero-dimensional regime for the thinner samples precisely on the scale of the inhomogeneities. Such behavior is somehow intermediate between the Fermi and Bose insulator paradigms and calls for further investigation to understand the way Cooper pairs continuously evolve from a bound state of fermionic objects into localized bosonic entities., Comment: 29 pages 9 figures

Urbi SDK is a software platform for the development of portable robotic applications. It features the Urbi UObject C++ middleware, to manage hardware drivers and/or possibly remote software components, and urbiscript, a domain specific programming language to orchestrate them. Reactivity is a key feature of Urbi SDK, embodied in events in urbiscript. This paper presents the support for events in urbiscript., Comment: DSLRob'10

This article was withdrawn by the authors due to misinterpretation of experimental data., Comment: This paper has been withdrawn

We have put into evidence the existence of an antiferromagnetic coupling between iron epilayers separated by a ZnSe crystalline semiconductor. The effect has been observed for ZnSe spacers thinner than 4 nm at room-temperature. The coupling constant increases linearly with temperature with a constant slope of ~5.5x 10-9 J/m2K. The mechanisms that may explain such exchange interaction are discussed in the manuscript. It results that thermally-induced effective exchange coupling mediated by spin-dependent on and off resonant tunnelling of electrons via localized mid-gap defect states in the ZnSe spacer layer appears to be the most plausible mechanism to induce the antiferromagnetic coupling., Comment: 29 pages, 8 figures